EU-SICHERHEITSDATENBLATT CLO (Claryfied Oil) ABSCHNITT 1 ...

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Heavy Fuel Oil Components9.8. Use of Heavy Fuel Oil as a Fuel – Professional9.8.1. Exposure ScenarioSection 1 Exposure Scenario Title Heavy Fuel OilTitleUse as a FuelUse DescriptorSector(s) of Use 22Process Categories 1, 2, 3, 8a, 8b, 16Further information on the mapping and allocation ofPROC codes is contained in Table 9.1Environmental Release Categories9a, 9bSpecific Environmental Release Category ESVOC SpERC 9.12b.v1Processes, tasks, activities coveredCovers the use as a fuel (or fuel additives and additive components) within closed or containedsystems, including incidental exposures during activities associated with its transfer, use, equipmentmaintenance and handling of waste.Assessment MethodSee Section 3.Section 2 Operational conditions and risk management measuresSection 2.1 Control of worker exposureProduct characteristicsPhysical form of product LiquidVapour pressure (kPa) Liquid, vapour pressure
Heavy Fuel Oil ComponentsCS15 General exposures(closed systems).CS502 Bulk closedunloadingCS8 Drum/batch transfersCS507 RefuellingGEST_12I Use as a fuel.CS 107 (closed system)CS39 Equipment cleaningand maintenanceHandle substance within a closed system E47. Sample via a closed loopor other system to avoid exposure E8. Avoid carrying out activitiesinvolving exposure for more than 1 hour OC27. Provide a good standardof controlled ventilation (10 to 15 air changes per hour) E40. Wearchemically resistant gloves (tested to EN374) in combination with ‘basic’employee training PPE16.Provide a good standard of controlled ventilation (10 to 15 air changesper hour) E40. Wear chemically resistant gloves (tested to EN374) incombination with ‘basic’ employee training PPE16. Avoid carrying outactivities involving exposure for more than 1 hour OC27. , or G9: Ensurematerial transfers are under containment or extract ventilation E66.Provide a good standard of controlled ventilation (10 to 15 air changesper hour) E40. Wear chemically resistant gloves (tested to EN374) incombination with ‘basic’ employee training PPE16.Avoid carrying out activities involving exposure for more than 1 hourOC27. , or G9: Ensure material transfers are under containment or extractventilation E66.Ensure material transfers are under containment or extract ventilationE66. Wear chemically resistant gloves (tested to EN374) in combinationwith ‘basic’ employee training PPE16. Avoid carrying out activitiesinvolving exposure for more than 1 hour OC27.Wear chemically resistant gloves (tested to EN374) in combination with‘basic’ employee training PPE16.Provide a good standard of general ventilation (not less than 3 to 5 airchanges per hour) E11. Wear chemically resistant gloves (tested toEN374) in combination with specific activity training PPE17. Drain downsystem prior to equipment break-in or maintenance E65. Retain draindowns in sealed storage pending disposal or for subsequent recycleENVT4. Clear spills immediately C&H13.Additional information on the basis for the allocation of the identified OCs and RMMs iscontained in Appendices 2 to 3Section 2.2 Control of environmental exposureProduct characteristicsSubstance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a].Amounts usedFraction of EU tonnage used in region 0.1Regional use tonnage (tonnes/year) 3.3e5Fraction of Regional tonnage used locally5.0e-4Annual site tonnage (tonnes/year) 1.7e2Maximum daily site tonnage (kg/day) 4.6e2Frequency and duration of useContinuous release [FD2].Emission days (days/year) 365Environmental factors not influenced by risk managementLocal freshwater dilution factor 10Local marine water dilution factor 100Other given operational conditions affecting environmental exposureRelease fraction to air from wide dispersive use (regional only)1.0e-4Release fraction to wastewater from wide dispersive use 0.00001Release fraction to soil from wide dispersive use (regional only) 0.00001Technical conditions and measures at process level (source) to prevent releaseCommon practices vary across sites thus conservative process release estimates used [TCS1].Technical onsite conditions and measures to reduce or limit discharges, air emissions andreleases to soilRisk from environmental exposure is driven by humans via indirect exposure [TCR1j].2010-08-10 CSR 145
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Heavy Fuel Oil Components2010-08-10
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Heavy Fuel Oil ComponentsReference
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Industrial: S
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ES4-W1 Industrial:
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Heavy Fuel Oil ComponentsA quantita
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Heavy Fuel Oil Componentsfor subseq
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Heavy Fuel Oil ComponentsThe Petror
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Heavy Fuel Oil Componentsanalysis o
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An Evaluation of the Persistence, B
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Table of ContentsExecutive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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Figure 2. BioHCwin (Y-axis) vs. exp
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2,3-dimethylheptane 9 7.7 6.2 7.42,
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Figure 5. Half-life predictions for
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criterion. It can be concluded that
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Figure 9. Half-life predictions for
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HydrocarbonC nrBioHCwinPredictedHal
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Figure 13. Half-life predictions fo
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Figure 15. Half-life predictions fo
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HydrocarbonC nrBioHCwinPredictedHal
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enzo[a]pyrene 20 421.6 16.5Table 10
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(see Appendix 2). Since BCF predict
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100001000100101n-ParaffinsBvB00 5 1
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8-heptamethyl nonane16
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Hydrocarbon C BMFBCF(Arnot)DietaryB
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10000010000100010010DinaphthenicsBv
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4.5 Polynaphthenic hydrocarbonsRegr
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101Polynaphth. Dietary BMFBMF = 10.
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enzenen-octylbenzene 14 0.034 403 4
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100001000100101NMArBvB05 10 15 20 2
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 CYakata
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10000010000100010010NDiArBvB110 15
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1010.1NDiAr Dietary BMFBMF = 10.011
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Hydrocarbon C BMFArnotBCFDietaryBCF
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Hydrocarbon C BMFArnotBCFDietaryBCF
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AcenaphtheneAcenaphthyleneBenz(a)an
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 ReferencesAnonymous (2004). Fis
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29MN 29MN 30 n-Tetracosylcyclohe
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hexahydroindaneDN 20 2,4-dimethyloc
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PN 27Phenanthrene2,6-dimethylheptyl
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24c1cc(CC(C)CCCC(C)CCCCC)c2CC(
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NMAr 29NMAr 29NMAr 29NMAr 29NMAr 29
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26Dimethyloctyl-1,2,3,6,7,8-he
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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SummaryIn conducting a PBT assessme
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment ofC15 stru
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWEAQUATIC TOXICITY PREDICTIONS
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CONTENTS (Continued)SectionPage15 S
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1-2The model predictions include me
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2-1SECTION 22 SUMMARY OF COMPOSITIO
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10-1SECTION 1010 SUMMARY OF COMPOSI
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