EU-SICHERHEITSDATENBLATT CLO (Claryfied Oil) ABSCHNITT 1 ...

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Heavy Fuel Oil Components9.5. Uses of Heavy Fuel Oil in Coatings – Industrial9.5.1. Exposure ScenarioSection 1 Exposure Scenario Title Heavy Fuel OilTitleUses in CoatingsUse DescriptorSector(s) of Use 3Process Categories 1, 2, 3, 8a, 8b, 15Further information on the mapping and allocation ofPROC codes is contained in Table 9.1Environmental Release Categories 4Specific Environmental Release Category ESVOC SpERC 4.3a.v1Processes, tasks, activities coveredCovers the use in coatings (paints, inks, adhesives, etc) within closed or contained systems includingincidental exposures during use (including materials receipt, storage, preparation and transfer frombulk and semi-bulk, application activities and film formation) and equipment cleaning, maintenanceand associated laboratory activities.Assessment MethodSee Section 3.Section 2 Operational conditions and risk management measuresSection 2.1 Control of worker exposureProduct characteristicsPhysical form of product LiquidVapour pressure (kPa) Liquid, vapour pressure
Heavy Fuel Oil Componentscontrolled ventilation (10 to 15 air changes per hour) E40. Wearchemically resistant gloves (tested to EN374) in combination with ‘basic’employee training PPE16.CS3 Material transfers Provide a good standard of controlled ventilation (10 to 15 air changesper hour) E40. Wear chemically resistant gloves (tested to EN374) incombination with ‘basic’ employee training PPE16. Ensure materialtransfers are under containment or extract ventilation E66.CS36 Laboratory activities. Handle within a fume cupboard or implement suitable equivalent methodsCS39 Equipment cleaningand maintenanceCS67 Storage.to minimise exposure E12. Wear suitable gloves tested to EN374 PPE15.Drain down and flush system prior to equipment break-in or maintenanceE55. Wear chemically resistant gloves (tested to EN374) in combinationwith specific activity training PPE17. Retain drain downs in sealed storagepending disposal or for subsequent recycle ENVT4.Store substance within a closed system E84. Wear chemically resistantgloves (tested to EN374) in combination with ‘basic’ employee trainingPPE16.Additional information on the basis for the allocation of the identified OCs and RMMs iscontained in Appendices 2 to 3Section 2.2 Control of environmental exposureProduct characteristicsSubstance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a].Amounts usedFraction of EU tonnage used in region 0.1Regional use tonnage (tonnes/year) 1.0e2Fraction of Regional tonnage used locally 1Annual site tonnage (tonnes/year) 1.0e2Maximum daily site tonnage (kg/day) 5.0e3Frequency and duration of useContinuous release [FD2].Emission days (days/year) 20Environmental factors not influenced by risk managementLocal freshwater dilution factor 10Local marine water dilution factor 100Other given operational conditions affecting environmental exposureRelease fraction to air from process (initial release prior to RMM) 0.98Release fraction to wastewater from process (initial release prior to 2.0e-5RMM)Release fraction to soil from process (initial release prior to RMM) 0Technical conditions and measures at process level (source) to prevent releaseCommon practices vary across sites thus conservative process release estimates used [TCS1].Technical onsite conditions and measures to reduce or limit discharges, air emissions andreleases to soilRisk from environmental exposure is driven by humans via indirect exposure [TCR1j].No wastewater treatment required [TCR6]. Prevent discharge of undissolved substance to or recoverfrom onsite wastewater [TRC14].Treat air emission to provide a typical removal efficiency of (%) 90Treat onsite wastewater (prior to receiving water discharge) to provide 0the required removal efficiency (%)If discharging to domestic sewage treatment plant, provide the required 0onsite wastewater removal efficiency of (%)Organisation measures to prevent/limit release from siteDo not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained orreclaimed [OMS3].Conditions and measures related to municipal sewage treatment plant2010-08-10 CSR 135
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Heavy Fuel Oil Components2010-08-10
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Heavy Fuel Oil ComponentsReference
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Industrial: SU3 Industrial:
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ES4-W1 Industrial: SU3
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Heavy Fuel Oil ComponentsThere is a
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Heavy Fuel Oil Components2010-08-10
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Heavy Fuel Oil ComponentsReference
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Industrial: S
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ES4-W1 Industrial:
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Heavy Fuel Oil ComponentsA quantita
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Heavy Fuel Oil Componentsfor subseq
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Heavy Fuel Oil ComponentsThe Petror
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Heavy Fuel Oil Componentsanalysis o
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An Evaluation of the Persistence, B
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Table of ContentsExecutive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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Figure 2. BioHCwin (Y-axis) vs. exp
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2,3-dimethylheptane 9 7.7 6.2 7.42,
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Figure 5. Half-life predictions for
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criterion. It can be concluded that
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Figure 9. Half-life predictions for
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HydrocarbonC nrBioHCwinPredictedHal
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Figure 13. Half-life predictions fo
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Figure 15. Half-life predictions fo
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HydrocarbonC nrBioHCwinPredictedHal
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enzo[a]pyrene 20 421.6 16.5Table 10
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(see Appendix 2). Since BCF predict
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100001000100101n-ParaffinsBvB00 5 1
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8-heptamethyl nonane16
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Hydrocarbon C BMFBCF(Arnot)DietaryB
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10000010000100010010DinaphthenicsBv
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4.5 Polynaphthenic hydrocarbonsRegr
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101Polynaphth. Dietary BMFBMF = 10.
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enzenen-octylbenzene 14 0.034 403 4
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100001000100101NMArBvB05 10 15 20 2
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 CYakata
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10000010000100010010NDiArBvB110 15
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1010.1NDiAr Dietary BMFBMF = 10.011
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Hydrocarbon C BMFArnotBCFDietaryBCF
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Hydrocarbon C BMFArnotBCFDietaryBCF
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AcenaphtheneAcenaphthyleneBenz(a)an
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 ReferencesAnonymous (2004). Fis
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29MN 29MN 30 n-Tetracosylcyclohe
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hexahydroindaneDN 20 2,4-dimethyloc
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PN 27Phenanthrene2,6-dimethylheptyl
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24c1cc(CC(C)CCCC(C)CCCCC)c2CC(
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NMAr 29NMAr 29NMAr 29NMAr 29NMAr 29
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26Dimethyloctyl-1,2,3,6,7,8-he
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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SummaryIn conducting a PBT assessme
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment ofC15 stru
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWEAQUATIC TOXICITY PREDICTIONS
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CONTENTS (Continued)SectionPage15 S
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1-2The model predictions include me
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2-1SECTION 22 SUMMARY OF COMPOSITIO
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10-1SECTION 1010 SUMMARY OF COMPOSI
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