BURMASTIC ADHESIVE SF - 5 GAL

Material Safety Data SheetBURMASTIC ADHESIVE SF - 5 GALVersion 5.0 Print Date 07/09/2012REVISION DATE: 07/08/2012SECTION 1 - PRODUCT IDENTIFICATIONTrade name : BURMASTIC ADHESIVE SF - 5 GALProduct code : 365600 805COMPANY : Tremco Incorporated3735 Green RoadCleveland, OH 44122Telephone : (216) 292-5000 8:30 - 5:00 ESTEmergency Phone: : (216) 765-6727 8:30 - 5:00 ESTAfter Hours: Chemtrec 1-800-424-9300Product use : AdhesiveSECTION 2 - HAZARDS IDENTIFICATIONEmergency OverviewBlack. Liquid. May cause slight irritation to the respiratory system. May cause nausea, headaches, anddizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization. Leavearea to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Move to freshair. If required, artificial respiration or administration of oxygen can be performed by trained personnel.Acute Potential Health Effects/ Routes of EntryInhalation : May cause slight irritation to the respiratory system. May cause nausea, headaches, anddizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratorysensitization.Eyes : Direct contact may cause mild irritation.Ingestion : May cause gastrointestinal irritation, nausea, and vomiting.Skin : May cause sensitization resulting in irritation, itching and redness.Aggravated Medical ConditionsPre-existing eye, skin and respiratory disorders may be aggravated by exposure.Chronic Health EffectsOverexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, andirritation of the skin, dermatitis, and central nervous system (CNS) effects. Prolonged or repeated exposure tobutyl benzyl phthalate may cause reduced body weights and adverse effects on the liver, kidney, spleen,pancreas, and reproductive organs. Overexposure to maleic anhydride can cause allergic asthmatic responsesand, after long-term exposure, bronchitis. Diphenylmethane diisocyanate (methylene bisphenyl isocyanate)caused an increased incidence of lung tumors in experimental animals following long term inhalation atconcentrations in excess of 100 times the exposure limit. Fillers are encapsulated and not expected to bereleased from product under normal conditions of use.Target Organs: Skin, Eye, Ingestion, LungSECTION 3 - PRODUCT COMPOSITIONChemical Name CAS-No. Weight %Polyurethane Polymer NJ TSRN# 51721300-5386P 30.0 - 60.01/6 365600 805

Material Safety Data SheetBURMASTIC ADHESIVE SF - 5 GALVersion 5.0 Print Date 07/09/2012REVISION DATE: 07/08/2012SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONPersonal protection equipmentRespiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor orsupplied air respirator when airborne contaminant level(s) are expected toexceed exposure limits indicated on the MSDS. Follow manufacturer'sdirections for respirator use.Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel toreduce exposure.Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely.Remove and wash contaminated clothing before reuse.Protective measures : Use professional judgment in the selection, care, and use.Engineering measures : Use general ventilation and/ or local exhaust to reduce the airbornecontaminant concentration below the exposure limit listed in the MSDSExposure LimitsChemical Name CAS Number Regulation Limit FormAsphalt 8052-42-4 ACGIH TWA: 0.5 mg/m3 Inhalable fraction.asbenzene solubles4,4'-Methylenebis(phenylisocyanate)101-68-8 ACGIH TWA: 0.005 ppmSECTION 9 - PHYSICAL AND CHEMICAL PROPERTIESForm: LiquidColor: BlackOdor: PetroleumpH: Not available.Vapour pressure: Not available.Vapor density: Heavier than airMelting point/range: Not available.Freezing point: Not available.Boiling point/range: Not available.Water solubility: InsolubleSpecific Gravity : 1.066% Volatile Weight : 1 %SECTION 10 - REACTIVITY / STABILITYSubstances to avoid: Amines.Water or moisture and oxidizing agents.Alcohols.Strongacids.Strong bases.3/6 365600 805

Material Safety Data SheetBURMASTIC ADHESIVE SF - 5 GALVersion 5.0 Print Date 07/09/2012REVISION DATE: 07/08/2012StabilityHazardous polymerization: Material is stable under normal storage, handling, and use.: Will not occur.SECTION 11 - TOXICOLOGICAL INFORMATIONButyl benzyl phthalate, CAS-No.: 85-68-7Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8Acute inhalation toxicity (LC-50) 0.369 mg/l for 4 h ( Rat ) 0.38 mg/l for 4 h ( Rat )SECTION 12 - ECOLOGICAL INFORMATIONNo Data AvailableSECTION 13 - DISPOSAL CONSIDERATIONSDisposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose ofwaste in compliance with state and local regulations.SECTION 14 - TRANSPORTATION / SHIPPING DATACFR / DOT:Not RegulatedTDG:Not RegulatedIMDG:UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Butyl Benzyl Phthalate), 9, PGIII, MARINE POLLUTANTFurther Information:The above shipping description may not be accurate for all container sizes and all modes of transportation.Please refer to Bill of Lading.SECTION 15 - REGULATORY INFORMATIONNorth American Inventories:All components are listed or exempt from the TSCA inventory.This product or its components are listed on, or exempt from the Canadian Domestic Substances List.4/6 365600 805

Material Safety Data SheetBURMASTIC ADHESIVE SF - 5 GALVersion 5.0 Print Date 07/09/2012REVISION DATE: 07/08/2012U.S. Federal Regulations:SARA 313 Components : 4,4'-Methylene bis(phenylisocyanate) 101-68-8SARA 311/312 Hazards : Acute Health HazardOSHA Hazardous Components :Asphalt 8052-42-4Butyl benzyl phthalate 85-68-74,4'-Methylene bis(phenylisocyanate) 101-68-8OSHA Status: Consideredhazardous based on thefollowing criteria:: IrritantSensitizerOSHA Flammability : IIIBRegulatory VOC (less water andexempt solvent): 21 g/lVOC Method 310 : 1 %U.S. State Regulations:MASS RTK Components : Asphalt 8052-42-4Butyl benzyl phthalate 85-68-74,4'-Methylene bis(phenylisocyanate) 101-68-8Crystalline Silica (Quartz)/ Silica Sand 14808-60-7Penn RTK Components : Polyurethane Polymer NJ TSRN# 51721300-5386PAsphalt 8052-42-4Butyl benzyl phthalate 85-68-7Heavy aromatic naphtha 64742-94-54,4'-Methylene bis(phenylisocyanate) 101-68-8NJ RTK Components : Polyurethane Polymer NJ TSRN# 51721300-5386PAsphalt 8052-42-4Butyl benzyl phthalate 85-68-7Heavy aromatic naphtha 64742-94-54,4'-Methylene bis(phenylisocyanate) 101-68-8Components under California Proposition 65:WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or otherreproductive harmSECTION 16 - OTHER INFORMATIONHMIS Rating :Health 2 0 = MinimumFlammability 11 = SlightReactivityPPE12 = Moderate3 = Serious4 = Severe5/6 365600 805

Material Safety Data SheetBURMASTIC ADHESIVE SF - 5 GALVersion 5.0 Print Date 07/09/2012REVISION DATE: 07/08/2012Further information:For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for theconsideration of the user, subject to their own investigation of compliance with applicable regulations, includingthe safe use of the product under every foreseeable condition.Prepared by: Rich MikolLegendACGIH - American Conference of Governmental HygienistsCERCLA - Comprehensive Environmental Response, Compensation, andLiability ActDOT - Department of TransportationDSL - Domestic Substance ListEPA - Environmental Protection AgencyHMIS - Hazardous Materials Information SystemIARC - International Agency for Research on CancerMSHA - Mine Safety Health AdministrationNDSL - Non-Domestic Substance ListNIOSH - National Institute for Occupational Safety and HealthNTP - National Toxicology ProgramOSHA - Occupational Safety and Health AdministrationPEL - Permissible Exposure LimitRCRA - Resource Conservation and Recovery ActRTK - Right To KnowSARA - Superfund Amendments and Reauthorization ActSTEL - Short Term Exposure LimitTLV - Threshold Limit ValueTSCA - Toxic Substances Control ActTWA - Time Weighted AverageV - VolumeVOC - Volatile Organic CompoundWHMIS - Workplace Hazardous Materials InformationSystem6/6 365600 805