Nanostructured, electroactive and bioapplicable materials

Figure 7-12. Mass spectrum of aluminum complex 3b. .............................................. 214
Figure 7-13. Mass spectra of aluminum complex sample, 3a, stored under
different conditions. Top: dissolved in acetone for 2 h; Bottom:
powder under nitrogen for 2 weeks......................................................... 215
Figure A-1. Repeating unit in polyphosphazenes....................................................... 242
Figure A-2. Two fundamental routes to synthesize substituted
polyphosphazenes.................................................................................... 243
Figure A-3. Applications of materials modified with stimuli-responsive
polymers for separation/purification, membrane valves, and
bioactive molecules................................................................................. 244
Figure A-4. Release mechanism for grafted stimuli-sensitive polyphosphazene
matrices. .................................................................................................. 245
Figure A-5. Preparation of poly(N-isopropylacrylamide) modified
polyphosphazene as temperature sensitive delivery matrix material...... 246
Figure B-1. Rotating disk (Hg on Au) polarogram (2400 rpm) of ligand 1a in
MeCN. Scan Rate = 50 mV/s.................................................................. 249
Figure B-2. Cyclic voltammogram (Hg on Au, negative potential region) vs.
Ag/Ag + of ligand 1a in MeCN. Scan Rate = 100 mV/s. ......................... 250
Figure B-3. Cyclic voltammogram (Pt wire, negative region) vs. Ag/Ag + of
ligand 1a in MeCN. Scan Rate = 100 mV/s............................................ 251
Figure B-4. Cyclic voltammogram (Pt wire, positive region) vs. Ag/Ag + of
ligand 1a in MeCN. Scan Rate = 100 mV/s............................................ 252
Figure B-5. Rotating disk (Hg on Au) polarogram (2400 rpm) of ligand 2a in
MeCN. Scan Rate = 40 mV/s.................................................................. 253
Figure B-6. Cyclic voltammogram (Hg on Au, negative region) vs. Ag/Ag + of
ligand 2a in MeCN. Scan Rate = 100 mV/s............................................ 254
Figure B-7. Cyclic voltammogram (Pt wire, negative region) vs. Ag/Ag + of
ligand 2a in MeCN. Scan Rate = 100 mV/s............................................ 255
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