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(FINAL) Chemistry Notebook 2016-17

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The Learning Goal for this assignment is:<br />

The students will learn how the interactions between water molecules account for the unique<br />

properties of water and how aqueous solutions form.<br />

Take note over the following chapter. Use the Headings provided to organize your notes. Define and number all highlighted vocabulary (total 22 ) as well<br />

as summarize and take notes over the sections. You may add pictures where needed. The pictures should be an appropriate size. Use Arial 12 for all<br />

text. This document should be 2 pages and should be saved as a pdf before you submit it into Angel.<br />

Chapter 15 Water and Aqueous Systems<br />

Pages 488 - 507<br />

15.1 Water and Its Properties<br />

Water in the Liquid State – Water, H2O, is a polar molecule comprised of two hydrogens on<br />

either side of an oxygen. This polarity results in hydrogen bonding, which attributes water many of its<br />

unique properties (high surface tension, low vapor pressure, high boiling point). Water molecules are<br />

drawn towards the inside of a water droplet, creating a spherical shape, and the force that pulls a<br />

liquid inward and makes liquids have smaller surface areas is called surface tension 1 . Water has a<br />

higher surface tension than most liquids, but its surface tension decreases when you add a<br />

surfactant 2 , which is any substance that interferes with the hydrogen bonding between water<br />

molecules (which causes beads of water to spread out/flatten). That’s why when you add soap (a<br />

surfactant) to water, the droplets are flatter than normal. Hydrogen bonding in water creates a low<br />

vapor pressure because all of the hydrogen bonds keep the liquid connected, so the bonds have to<br />

be broken in order to allow for molecules to escape and evaporate (and the chances of that are low,<br />

so evaporation happens slowly.) Otherwise, a glass of water would start to disappear the moment you<br />

pour it. Hydrogen bonding is also strong enough to keep it from boiling at standard temperature,<br />

otherwise it would be a gas at normal temperatures on Earth.<br />

Water in the Solid State – Water as a solid is less dense than as a liquid, so ice floats in water.<br />

Hydrogen bonds hold water molecules in place at the solid phase, and the structure is arranged<br />

hexagonally with an open framework. The structure of a snowflake is similar to that of an ice crystal.<br />

In liquid water, molecules are more packed together, which makes it denser than ice because ice’s<br />

structural arrangement keeps it spread apart. Ice floating at the top of a body of water acts as an<br />

insulator for the rest of a body of water, meaning that the water at the bottom is above 0 oC , creating<br />

conditions for organisms to live below the water. Ice melts at a relatively high temperature for its low<br />

density, meaning that it takes a lot of energy to get ice to melt, whereas the same amount of energy<br />

raises the temperature of liquid water rapidly. (That’s why ice in your drink keeps your drink cool for<br />

so long. The energy that would heat up water quickly is instead absorbed by ice cubes, keeping your<br />

drink cool.)<br />

15.2 Homogeneous Aqueous Systems<br />

Solutions – You won’t find pure water in nature because water dissolves many substances it comes<br />

in contact with, and water with dissolved substances inside is known as an aqueous solution 3 .<br />

Solutions are comprised of a solvent 4 , which is the substance doing the dissolving, and the dissolved<br />

particles in a solvent are a solute 5 , and they are dispersed in the solvent. Solutions are stable<br />

homogenous mixtures, meaning that they don’t settle out when resting (given that conditions like<br />

temperature are constant), and that both the solvent and solute pass through filters. Ionic and polar<br />

covalent compounds dissolve easily inside of water, but nonpolar covalent compounds do not. Water<br />

molecules are constantly moving, and when an ionic solid is placed inside water, the water molecules<br />

124

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