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Fuels & Lubricants Magazine

Issue 1, October 2017

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excellent low temperature characteristics<br />

of RmB.<br />

Stable crumb rubber quality and<br />

its particle size distribution are one<br />

of the most important criterion for<br />

rubber bitumen production process.<br />

During crumb rubber production<br />

waste tyres are shredded, fabric and<br />

steel used as reinforcement material<br />

are removed. Used tyres should be<br />

cleaned and impurities have to be<br />

removed before shredding (e.g. clay,<br />

sand and gravel).<br />

The most valuable component of<br />

crumb rubber is the polyisoprene<br />

content. Crumb rubber derived<br />

from tyres of passenger cars contains<br />

10-20% polyisoprene, this value<br />

is around 35-45% in truck tyres.<br />

Further constituents of crumb rubbers<br />

are synthetic rubber (15-45%),<br />

carbon black (25-30%), inorganic<br />

additives (5-15%) and plasticisers (5-<br />

15%) measured according to ASTM<br />

D297-15 standard (16).<br />

Asphalt mechanical tests were<br />

also carried out in the development<br />

phase using different bitumen<br />

products produced in Zala Refinery.<br />

The properties of binders applied<br />

for asphalt tests are summarised in<br />

Table 3. The softening point of RmB<br />

is between the values of other two<br />

commercial products. The highest<br />

penetration ensures good workability<br />

in asphalt mixing and compaction.<br />

RmB has the best breaking point.<br />

Dynamic viscosity of RmB is near to<br />

those value of PmB 25/55-65.<br />

Significantly better results were<br />

measured in asphalt mixtures (Table<br />

4). It has almost the same characteristics<br />

as PmB and far better than<br />

50/70 road bitumen.<br />

It has to be mentioned that fatigue<br />

character of different asphalt types<br />

produced with RmB has been furher<br />

improved last years. Recently this<br />

performance character is on the<br />

same level than that of asphalt mixtures<br />

produced with PmB. Other favourable<br />

properties like traffic noise<br />

reduction (-3.2 dB), better adhesion<br />

Property Test method RmB<br />

50/70 road<br />

bitumen<br />

Softening point, °C EN 1427 59 51 74<br />

Penetration at 25 °C,<br />

0.1mm<br />

EN 1426 65 56 45<br />

Fraass breaking point, °C EN 12593 -24 -12 -14<br />

Dynamic viscosity at 180<br />

°C, mPas<br />

Table 3<br />

EN 13702-2 480 90 410<br />

Requirement RmB<br />

50/70 road<br />

bitumen<br />

PmB<br />

25/55-65<br />

Binder content, % 5.1 5.1 5.1<br />

Permanent deformation/Wheel tracking (EN 12687-22)<br />

Relative deformation, % Max, 5.0 1 3.6 1<br />

Resistance to fatigue (EN 12687-24)<br />

Ehhmax, (N=106), microstrain To be reported 160 143 201<br />

PmB<br />

25/55-65<br />

Asphalt cracking*<br />

Cracking temperature, °C Max, -18.0 -31 -18 -24.8<br />

Table 4: AC-11 type of asphalts produced with different bitumen binders<br />

properties (Fig. 2, tested in 60°C<br />

after 36 hours based on the method<br />

developed by the National Road and<br />

Traffic Research Institute, Sweden)<br />

and stopping distance lowering (-5%<br />

at 50 km/h and -10% at 100 km/h)<br />

were also proved comparing RmB<br />

and 50/70 road bitumen based<br />

asphalts (14).<br />

Based on a recent lifecycle analysis<br />

(17) the complex comparison of asphalt<br />

wearing courses made by RmB<br />

45/80-55 and by normal (unmodified)<br />

road construction bitumen<br />

50/70 were compared. The calculation<br />

resulted + 50% lifetime expectation<br />

and - 29-32% lifetime cost for<br />

the whole lifecycle of the wearing<br />

course.<br />

Among several test road construction<br />

the main road of the Danube<br />

Refinery was also reconstructed in<br />

2012. No fatigue cracks, thermal<br />

cracks and rutting can be observed<br />

after 5 years of heav traffic on the<br />

road (Fig. 3).<br />

In 2015 the Hungarian Standards<br />

Institution published the MSZ<br />

930:2015 standard entitled Bitumen<br />

and bituminous binders. Rubber<br />

modified bitumen. Requirements<br />

(18). This specifies the main quality<br />

requirements of the RmB product<br />

(Table 5).<br />

MOL rubber modified bitumen<br />

won the following awards during the<br />

last years:<br />

• Innovative Product Award of<br />

Institution of Chemical Engineers,<br />

UK (IChemE), 2016,<br />

• Environmental Innovation Award<br />

2014 of Hungarian Ministry of<br />

Agriculture,<br />

• To prove its eco-friendly nature<br />

MOL rubber modified bitumen<br />

gained ECO-label in November,<br />

2014 from Hungarian ECO-labelling<br />

Organisation,<br />

• House of the Hungarian Quality<br />

Award 2013 for MOL rubber<br />

modified bitumen process from<br />

Hungarian Society for Quality,<br />

2013.<br />

<strong>Fuels</strong>&<strong>Lubricants</strong> No. 1 OCTOBER 2017 21

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