Radical Cations
Radical Cations
Radical Cations
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� Typical arene oxidation products are observed<br />
H<br />
! donor<br />
N H<br />
anode<br />
n-RH •+ Deprotonation<br />
H<br />
N H<br />
H 2N NH 2<br />
� Observation of these products indicates that the arene is the site of oxiation, not N-lone pairs<br />
H<br />
N<br />
N<br />
N<br />
NH 2<br />
T. Shono et al. J. Am. Chem. Soc. 1982, 104, 5753.