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Radical Cations

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� Typical arene oxidation products are observed<br />

H<br />

! donor<br />

N H<br />

anode<br />

n-RH •+ Deprotonation<br />

H<br />

N H<br />

H 2N NH 2<br />

� Observation of these products indicates that the arene is the site of oxiation, not N-lone pairs<br />

H<br />

N<br />

N<br />

N<br />

NH 2<br />

T. Shono et al. J. Am. Chem. Soc. 1982, 104, 5753.

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