Radical Cations
Radical Cations
Radical Cations
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π-C-X •+ Bond Dissociation<br />
� R 3 Si– and R 3 Sn– moieties can be used as “super protons”<br />
� The dependence of k on MeOH, H 2 O,<br />
Bu 4 NF indicates Nu-assisted Si-bond<br />
cleavage<br />
SiMe 3<br />
anode, Et 4NOTs<br />
MeOH, 91%<br />
OMe<br />
J. Yoshida et al. Tetrahedron Lett. 1986, 27, 3373.<br />
P. S. Mariano et al. J. Am. Chem. Soc. 1984, 106, 6439.
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