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R&D on Hydrogen Production by Autothermal Reforming

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4. Synopsis<br />

Catalyst C-1 Catalyst C-2 Catalyst C-3 Catalyst C-4<br />

Figure 3.5.2: Evaluative Tests of Hydrodesulfurizati<strong>on</strong> Reacti<strong>on</strong> Life<br />

Catalyst C-2 Catalyst C-4<br />

Figure 3.5.3: Impact of H2/Oil Ratio <strong>on</strong> <strong>Hydrogen</strong>ati<strong>on</strong> Desulfurizati<strong>on</strong><br />

Reacti<strong>on</strong><br />

4.1 Design of <strong>Autothermal</strong> <strong>Reforming</strong> Process<br />

(1) Basic Establishment of <strong>Autothermal</strong> <strong>Reforming</strong> Type <strong>Hydrogen</strong> Producti<strong>on</strong> System<br />

An autothermal reforming - fuel processing system (ATR-FPS) was set up from supply of<br />

raw materials to after selective removal of CO. On the assumpti<strong>on</strong> that there is no<br />

discharge heat loss, a method was established for calculating reacti<strong>on</strong> c<strong>on</strong>diti<strong>on</strong>s so that<br />

the system as a whole achieves heat balance.<br />

(2) Investigati<strong>on</strong> of <strong>Hydrogen</strong> Producti<strong>on</strong> <strong>on</strong> 1 Nm 3 /hr Scale<br />

<strong>Hydrogen</strong> producti<strong>on</strong> <strong>on</strong> the 1 Nm 3 /hr scale <strong>by</strong> the autothermal reforming method was<br />

c<strong>on</strong>firmed, as was the impact of reacti<strong>on</strong> temperature <strong>on</strong> the autothermal reforming<br />

reacti<strong>on</strong>.<br />

4.2 Basic Design of <strong>Autothermal</strong> <strong>Reforming</strong> - Fuel Processing System<br />

The basic design of the autothermal reforming - fuel processing system (ATR-FPS) was<br />

completed in c<strong>on</strong>siderati<strong>on</strong> of raw material specificati<strong>on</strong>s, substance balance and heat balance.<br />

16

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