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20030032186 NASA Marshall Space Flight Center, Huntsville, AL, USA<br />

Magnetic Flux Compression Experiments Using Plasma Armatures<br />

Turner, M. W.; Hawk, C. W.; Litchford, R. J.; March 2003; 37 pp.; In English; Original contains black and white illustrations<br />

Report No.(s): NASA/TP-2003-212341; NAS 1.60:212341; M-1069; No Copyright; Avail: CASI; A03, Hardcopy<br />

Magnetic flux compression reaction chambers offer considerable promise for controlling the plasma flow associated with<br />

various micronuclear/chemical pulse propulsion and power schemes, primarily because they avoid thermalization with wall<br />

structures and permit multicycle operation modes. The major physical effects of concern are the diffusion of magnetic flux into<br />

the rapidly expanding plasma cloud and the development of Rayleigh-Taylor instabilities at the plasma surface, both of which<br />

can severely degrade reactor efficiency and lead to plasma-wall impact. A physical parameter of critical importance to these<br />

underlying magnetohydrodynamic (MHD) processes is the magnetic Reynolds number (R(sub m), the value of which depends<br />

upon the product of plasma electrical conductivity and velocity. Efficient flux compression requires R(sub m) less than 1, and<br />

a thorough understanding of MHD phenomena at high magnetic Reynolds numbers is essential to the reliable design and<br />

operation of practical reactors. As a means of improving this understanding, a simplified laboratory experiment has been<br />

constructed in which the plasma jet ejected from an ablative pulse plasma gun is used to investigate plasma armature<br />

interaction with magnetic fields. As a prelude to intensive study, exploratory experiments were carried out to quantify the<br />

magnetic Reynolds number characteristics of the plasma jet source. Jet velocity was deduced from time-of-flight<br />

measurements using optical probes, and electrical conductivity was measured using an inductive probing technique. Using air<br />

at 27-inHg vacuum, measured velocities approached 4.5 km/s and measured conductivities were in the range of 30 to 40 kS/m.<br />

Author<br />

Electrical Resistivity; Plasma Compression; Magnetic Flux; Reynolds Number; Plasma Jets; Plasma Dynamics; Stability;<br />

Chemical Propulsion<br />

23<br />

CHEMISTRY AND MATERIALS (GENERAL)<br />

Includes general research topics related to the composition, properties, structure, and use of chemical compounds and materials as they<br />

relate to aircraft, launch vehicles, and spacecraft. For specific topics in chemistry and materials see categories 25 through 29. For<br />

astrochemistry see category 90 Astrophysics.<br />

20030020946 NASA Glenn Research Center, Cleveland, OH, USA<br />

The Effect of Film Composition on the Texture and Grain Size of CuInS2 Prepared by Spray Pyrolysis<br />

Jin, Michael H.-C.; Banger, Kulbinder K.; Harris, Jerry D.; Hepp, Aloysius F.; May 12, 2003; 3 pp.; In English; 3rd World<br />

Conference on Photovoltaic Energy Conversion, 12-16 May 2003, Osaka, Japan; Copyright; Avail: CASI; A01, Hardcopy<br />

CuInS2 was deposited by spray pyrolysis using single-source precursors synthesized in-house. Films with either (112) or<br />

(204/220) preferred orientation always showed Cu-rich and In-rich composition respectively. The In-rich (204/220)-oriented<br />

films always contained a secondary phase evaluated as an In-rich compound, and the hindrance of (112)-oriented grain growth<br />

was confirmed by glancing angle X-ray diffraction. In conclusion, only the Cu-rich (112)-oriented films with dense columnar<br />

grains can be prepared without the secondary In-rich compound. The effect of extra Cu on the grain size and the solar cell<br />

results will be also presented.<br />

Author<br />

Films; Textures; Grain Size; Copper Sulfides; Indium Sulfides; Pyrolysis<br />

20030025233 Iowa Univ., Iowa City, IA, USA<br />

Rejuvenation of Spent Media via Supported Emulsion Liquid Membranes<br />

Wiencek, John M.; [2002]; 4 pp.; In English; Original contains black and white illustrations<br />

Contract(s)/Grant(s): NAG8-1588; No Copyright; Avail: CASI; A01, Hardcopy<br />

The overall goal of this project was to maximize the reuseability of spent fermentation media. Supported emulsion liquid<br />

membrane separation, a highly efficient extraction technique, was used to remove inhibitory byproducts during fermentation;<br />

thus, improve the yield while reducing the need for fresh water. The key objectives of this study were: (1) Develop an emulsion<br />

liquid membrane system targeting low molecular weight organic acids which has minimal toxicity on a variety of microbial<br />

systems. (2) Conduct mass transfer studies to allow proper modeling and design of a supported emulsion liquid membrane<br />

system. (3) Investigate the effect of gravity on emulsion coalescence within the membrane unit. (4) Access the effect of water<br />

re-use on fermentation yields in a model microbial system. and (5) Develop a perfusion-type fermentor utilizing a supported<br />

32

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