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American Ceramic Society Bulletin

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esearch briefs<br />

X-ray microtomography and finite element<br />

analysis to examine in each of the<br />

90 specimens how trabecular scaling<br />

changes in relation to size, and how<br />

bone mechanics change in relation to<br />

the scaling. For materials scientists,<br />

here are the key findings (some of<br />

which may be a little counterintuitive):<br />

• From animal to animal, the bone<br />

volume fraction does not substantially<br />

scale with creature size;<br />

• Although the bone volume fraction<br />

does not increase greatly, the trabeculae<br />

in the femur of larger animals<br />

are thicker, farther apart;<br />

• Also in larger animals, the trabeculae<br />

are less densely connected (the<br />

number per unit volume is considerably<br />

fewer than in small animals; and<br />

• Finite element modeling explains<br />

that scaling does not alter the bulk<br />

stiffness of trabecular bone, but probably<br />

mitigates strain on the scale of the<br />

osteocyctes.<br />

The authors suggest that the differences<br />

in how trabeculae grow in various<br />

animals might be “an interspecific<br />

manifestation of bone tissue’s drive to<br />

maintain mechanical homeostasis. It<br />

appears that changes in geometry are<br />

preferred over increased bone mass.”<br />

They and other researchers note that<br />

this preference “may be an adaption<br />

that limits the physiological cost of producing,<br />

maintaining and moving more<br />

tissue.”<br />

So, what are broader implications? If<br />

one is thinking about how to develop a<br />

“smart material” that could adapt to a<br />

changing environment, there is a lesson<br />

in bones: The modeling and remodeling<br />

of trabeculae and surrounding<br />

internal structures seem to be a massefficient<br />

strategy for dealing with strain.<br />

Elephants do not require thick, dense<br />

bones to support their loads. They just<br />

use their internal capacity to alter their<br />

bone structure.<br />

“We can learn a lot from nature,<br />

such as how nature develops these<br />

strong, lightweight structures,” advises<br />

Shefelbine in a story in The Engineer.<br />

“We could adopt this in design. It could<br />

inform how people develop structural<br />

foams.” In particular, the researchers<br />

say, “This may represent a new<br />

approach to designing cellular solids<br />

for engineered structures of different<br />

scales.”<br />

The IC research team also has created<br />

an open-source computer program<br />

(“BoneJ”) for examining the number,<br />

thickness and spacing of trabeculae as<br />

well as analyses of whole bones.<br />

Visit Imperial College, www3.imperial.ac.uk;<br />

and BoneJ, www.bonej.org/ n<br />

Evidence mounts that<br />

‘pseudogap’ is distinct phase in<br />

superconducting materials<br />

Investigators in the field of hightemperature<br />

superconductors have<br />

been stumped for some time about<br />

what is occurring between when the<br />

temperature of a material drops to the<br />

point (T*) where electrons begin to<br />

form Cooper pairs (T c ) and the critical<br />

temperature for full superconductivity.<br />

Heretofore, this odd transitional region<br />

has been dubbed a “pseudogap,” but<br />

now a collaborative research project has<br />

revealed that three different tests suggest<br />

the pseudogap is actually a distinct<br />

phase.<br />

The collaboration included scientists<br />

from the Lawrence Berkeley National<br />

Laboratory, the University of California<br />

at Berkeley, Stanford University and<br />

the SLAC National Accelerator Lab.<br />

Their results were recently published in<br />

Science (doi:10.1126/science.1198415).<br />

Led by Zhi-Xun Shen, director of<br />

the Stanford Institute for Materials and<br />

Energy Science at SLAC and a professor<br />

of physics at Stanford University, the<br />

group focused only on Pb-Bi2201 (a lead<br />

bismuth strontium lanthanum copper<br />

oxide) because of the materials relatively<br />

wide range between T* and T c .<br />

Previous research supported two separate<br />

theories about the odd pseudogap:<br />

One theory is that it is just a range of<br />

gradual transition to superconductivity,<br />

and the other is that it is a state of<br />

material distinct from superconductiv-<br />

ity and normal “metallicity” with a<br />

quantum critical point.<br />

“Promising as the ‘quantum critical’<br />

paradigm is for explaining a wide range<br />

of exotic materials, high-T c superconductivity<br />

in cuprates has stubbornly<br />

refused to fit the mold. For 20 years, the<br />

cuprates managed to conceal any evidence<br />

of a phase-transition line where<br />

the quantum critical point is supposed<br />

to be found,” says Joseph Orenstein in<br />

a news release from the Berkeley Lab.<br />

Orenstein works in the lab’s Materials<br />

Sciences Division and is a professor of<br />

physics at UC Berkeley, whose group<br />

conducted one of the research team’s<br />

three experiments.<br />

According to the release, the hope<br />

is that once researchers can wrap their<br />

thinking around the concept of a quantum<br />

critical point (X c ), new routes<br />

to superconductivity can be found.<br />

“This is a paradigm shift in the way we<br />

understand high-temperature superconductivity,”<br />

says Ruihua He, lead author<br />

with Makoto Hashimoto. “The involvement<br />

of an additional phase, once<br />

fully understood, might open up new<br />

possibilities for achieving superconductivity<br />

at even higher temperatures<br />

in these materials.” These two worked<br />

with Shen at SIMES and also worked<br />

at Stanford’s Department of Applied<br />

Physics and at Berkeley Lab’s Advanced<br />

Light Source.<br />

One of the tests they conducted<br />

involved angle-resolved photoemission<br />

spectroscopy to track the kinetic<br />

energy and momentum of the emitted<br />

electrons over a temperature range. In<br />

another test, investigators measured<br />

changes in rotations of the plane of<br />

polarization light reflected from the<br />

same Pb-Bi2201 sample under a zero<br />

magnetic field (magneto optical Kerr<br />

effects). The rotations are proportional<br />

to the net magnetization of the sample<br />

at various temperatures. Orenstein’s<br />

group performed the third test, a study<br />

of time-resolved reflectivity of the<br />

Pb-Bi2201 sample.<br />

None of these tests were particularly<br />

novel – except that this time they<br />

22 <strong>American</strong> <strong>Ceramic</strong> <strong>Society</strong> <strong>Bulletin</strong>, Vol. 90, No. 4

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