- Page 2: Walter R. Johnson Atomic Structure
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- Page 12: VIII Preface derivation of the Hart
- Page 16: X Contents 2.8 NumericalSolutiontoD
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- Page 24: 2 1 Angular Momentum one easily est
- Page 28: 4 1 Angular Momentum The value of j
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18 1 Angular Momentum [Jz,T k q ]=q
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20 1 Angular Momentum required calc
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22 1 Angular Momentum 1.5 Spinor an
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24 1 Angular Momentum Now, let us c
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26 1 Angular Momentum The following
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28 1 Angular Momentum 1.16. Derive
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30 2 Central-Field Schrödinger Equ
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32 2 Central-Field Schrödinger Equ
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34 2 Central-Field Schrödinger Equ
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36 2 Central-Field Schrödinger Equ
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38 2 Central-Field Schrödinger Equ
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40 2 Central-Field Schrödinger Equ
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42 2 Central-Field Schrödinger Equ
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44 2 Central-Field Schrödinger Equ
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46 2 Central-Field Schrödinger Equ
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48 2 Central-Field Schrödinger Equ
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50 2 Central-Field Schrödinger Equ
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52 2 Central-Field Schrödinger Equ
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54 2 Central-Field Schrödinger Equ
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56 2 Central-Field Schrödinger Equ
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58 2 Central-Field Schrödinger Equ
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60 2 Central-Field Schrödinger Equ
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62 2 Central-Field Schrödinger Equ
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64 2 Central-Field Schrödinger Equ
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66 2 Central-Field Schrödinger Equ
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68 2 Central-Field Schrödinger Equ
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70 2 Central-Field Schrödinger Equ
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72 3 Self-Consistent Fields The two
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74 3 Self-Consistent Fields v0(1s,
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76 3 Self-Consistent Fields − 1 2
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78 3 Self-Consistent Fields Ψ(r1,
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80 3 Self-Consistent Fields Rule 6
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82 3 Self-Consistent Fields I(nala)
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84 3 Self-Consistent Fields gabba
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86 3 Self-Consistent Fields The off
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88 3 Self-Consistent Fields Thus, w
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90 3 Self-Consistent Fields gives
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92 3 Self-Consistent Fields Normali
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4 2 24 16 8 0 94 3 Self-Consistent
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96 3 Self-Consistent Fields Eab··
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98 3 Self-Consistent Fields As in t
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100 3 Self-Consistent Fields where
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102 3 Self-Consistent Fields The (r
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104 3 Self-Consistent Fields of rad
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4 Atomic Multiplets In this chapter
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4.1 Second-Quantization 109 |ab ·
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Schrödinger Hamiltonian: 4.2 6-j S
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j1 j2 J12 j3 J J23 The quantity j
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4.3 Two-Electron Atoms 115 states c
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4.3 Two-Electron Atoms 117 E (1) 1s
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4.4 Atoms with One or Two Valence E
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4.4 Atoms with One or Two Valence E
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R = 4.5 Particle-Hole Excited State
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4.5 Particle-Hole Excited States 12
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4.6 9-j Symbols 127 charge where re
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4.7 Relativity and Fine Structure 1
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4.7 Relativity and Fine Structure 1
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E (1) J = vw,xy 4.7 Relativity and
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4.7 Relativity and Fine Structure 1
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138 5 Hyperfine Interaction & Isoto
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140 5 Hyperfine Interaction & Isoto
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142 5 Hyperfine Interaction & Isoto
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144 5 Hyperfine Interaction & Isoto
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146 5 Hyperfine Interaction & Isoto
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148 5 Hyperfine Interaction & Isoto
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150 5 Hyperfine Interaction & Isoto
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152 5 Hyperfine Interaction & Isoto
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154 5 Hyperfine Interaction & Isoto
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156 5 Hyperfine Interaction & Isoto
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158 6 Radiative Transitions E(r,t)=
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160 6 Radiative Transitions space o
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162 6 Radiative Transitions From (6
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164 6 Radiative Transitions U(t, t0
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166 6 Radiative Transitions d 2 wfi
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168 6 Radiative Transitions Substit
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170 6 Radiative Transitions to the
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172 6 Radiative Transitions ∞ 0
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174 6 Radiative Transitions Table 6
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176 6 Radiative Transitions 2zpxɛ
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178 6 Radiative Transitions As a sp
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180 6 Radiative Transitions Here, w
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182 6 Radiative Transitions 6.2.8 N
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184 6 Radiative Transitions Let us
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186 6 Radiative Transitions Oscilla
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188 6 Radiative Transitions where n
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190 6 Radiative Transitions The res
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192 6 Radiative Transitions Problem
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7 Introduction to MBPT In this chap
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7.1 Closed-Shell Atoms 7.1 Closed-S
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Closed-Shell: Third-Order Energy 7.
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Again, we write gmnab = where in t
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7.2 B-Spline Basis Sets 7.2 B-Splin
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The matrices A and B are given by A
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7.2 B-Spline Basis Sets 207 If we l
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7.3 Atoms with One Valence Electron
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7.3.2 Angular Momentum Decompositio
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7.3 Atoms with One Valence Electron
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7.3 Atoms with One Valence Electron
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7.4 Relativistic Calculations 217 s
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The radial matrix elements ML(ijkl)
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7.4 Relativistic Calculations 221 o
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7.4 Relativistic Calculations 223 2
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where ηkl is a symmetry factor def
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7.6 MBPT for Divalent Atoms and Ion
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7.6 MBPT for Divalent Atoms and Ion
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7.7 Second-Order Perturbation Theor
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7.7 Second-Order Perturbation Theor
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(b) 7.2. Prove: (a) (b) 0c mambmmm
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8 MBPT for Matrix Elements In Chapt
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8.1 Second-Order Corrections 239 Ta
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t RPA am = tam + bn t RPA ma = tma
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8.2 Random-Phase Approximation 243
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8.3 Third-Order Matrix Elements 245
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8.4 Matrix Elements of Two-Particle
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Energy (a.u.) 10 1 10 0 10 -1 10 -2
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8.5 CI Calculations for Two-Electro
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8.6 Second-Order Matrix Elements in
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8.6 Second-Order Matrix Elements in
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T (2) deriv (−1)J [JI][JF ] v≤
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8.7 Summary Remarks 259 8.2. Consid
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262 Solutions From the above, it fo
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264 Solutions l = 4 t := Table[(-1)
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266 Solutions This, in turn, can be
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268 Solutions top := top*(a+k-1); b
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270 Solutions P[n_, l_, r_] = Sqrt[
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272 Solutions Energies for Na from
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274 Solutions One finds [H, rk] =[c
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276 Solutions The S = 1 eigenstates
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278 Solutions (3s1/2 3s1/2) → [0]
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280 Solutions Thesumsoverµ’s ass
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282 Solutions 〈F |VI|I〉 = 1 gi
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284 Solutions δν =5× 3 4 × 0.91
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286 Solutions 5.5 Normal Mass Shift
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288 Solutions Extracting the coeffi
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290 Solutions 6.3 The Al ground sta
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292 Solutions 6.4 Heliumlike B: (a)
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294 Solutions (d) The 5d 3/2 state
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296 Solutions (c) He (1s2s) 3 S1- T
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298 Solutions where, χ (1) ma =
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300 Solutions Problems of Chapter 8
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302 Solutions i∆T (2) wv = χam
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304 References [17] A. R. Edmonds.
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Index LS coupled states first-order
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graphical rules 3j symbols, 20 arro
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second quantization, 107 second-ord