Here - Polyurethanes - Bayer
Here - Polyurethanes - Bayer
Here - Polyurethanes - Bayer
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Issue 1/2005<br />
Baydur ® / Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality
Editorial<br />
Dear Readers,<br />
In 1835, Charles Darwin discovered 14<br />
different species of finch in the Galapagos<br />
Islands, all of which had evolved from a<br />
single finch species. Darwin later developed<br />
his theory of evolution on the basis of this<br />
discovery.<br />
We might ask ourselves: what is the<br />
equivalent of Darwin’s finches in the world<br />
of plastics? In my opinion, it’s polyurethanes.<br />
Their versatile structure has enabled them<br />
to undergo such a process of “evolution” that<br />
they are now found in a number of different<br />
rail transport applications.<br />
Let’s start by considering the driver’s cab in<br />
a train. <strong>Here</strong>, the use of Baydur 110 FRS and<br />
Baydur 60 FRS allows the interior to be<br />
designed in a functional and modern style –<br />
with impressive looking, high-quality<br />
materials and a level of fire performance that<br />
meets the requirements of DIN 5510. Rail<br />
damping with Bayflex ® effectively reduces<br />
vibration, allowing trains to run more quietly<br />
over the track.<br />
When conventional railway sleepers fail,<br />
concrete suffers frost damage and wood rots<br />
away, glass fibre-reinforced Baydur sleepers<br />
are still going strong. They maintain their<br />
high mechanical strength for an estimated<br />
lifetime of over 50 years. That’s what a highly<br />
envolved material called polyurethane can do!<br />
Sincerely,<br />
Dr. Stephan Schleiermacher<br />
<strong>Polyurethanes</strong> Business Unit<br />
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
IS FLYING REALLY BETTER?<br />
If you want to get from A to B in Germany quickly and in comfort, taking a plane is by no means<br />
your only option. These days, Deutsche Bahn’s high-speed trains offer a standard of service<br />
which, until recently, could only be experienced above the clouds. And it’s not just in the<br />
passenger facilities that you can draw this parallel. The driver’s cab in the ICE ® 3 looks just<br />
like the cockpit of a plane. It is only divided from the passenger carriages by a glass screen,<br />
so anyone who’s interested can see their “pilot” at work at any time during the journey !<br />
Featuring soft contours, a clear layout and<br />
quality-finish surfaces, large areas of the<br />
driver’s control panel in the ICE ® 3 are made up<br />
of large, lightweight molded parts produced by<br />
polyurethane specialist Thieme GmbH & Co. KG<br />
of Teningen, Germany, using the Baydur ® 60<br />
and Baydur ® 110 systems.<br />
Thieme designs cladding<br />
for the cockpit of the ICE ® 3<br />
Thieme supplies the molded parts to Dornier<br />
GmbH, which in turn supplies them to the<br />
ICE ® Siemens/Bombardier consortium. This<br />
consortium has developed and built the ICE ® 3<br />
in a project led by the Transportation Systems<br />
Division of Siemens AG and run in cooperation<br />
with Deutsche Bahn AG.<br />
The advantages of using<br />
polyurethane in rail transport<br />
When it comes to implementing ambitious<br />
design concepts, polyurethane has repeatedly<br />
proven itself to be an excellent material in<br />
many fields. The railway sector is no exception.<br />
A total of 27 different parts are produced for<br />
the ICE ® 3 cockpit.<br />
They include everything from cladding sections<br />
to high-quality panels fitted with recesses<br />
for switches and levers. They can also be<br />
screen-printed. It is vital that the materials<br />
used in this project meet the strict guidelines<br />
of Deutsche Bahn and other national and<br />
international fire safety standards. Baydur ®<br />
complies with the required classifications S4,<br />
SR2 and ST2 of DIN standard 5510.<br />
(For information about fire protection standards<br />
in the rail sector, see the final article in this<br />
edition of InForm, which is entitled “Guide to<br />
<strong>Polyurethanes</strong>”)
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
The cockpit of the ICE ® 3 generation of trains is another example of how polyurethanes<br />
can be used to combine design with functionality and cost-effectiveness.<br />
Why use polyurethane?<br />
Polyurethane offers advantages over other<br />
plastics which are particularly relevant when<br />
designing trains.<br />
Materials are required to be:<br />
- Light<br />
- Easy to clean<br />
- Robust<br />
- Distortion-free<br />
Polyurethane meets all these requirements.<br />
This material also gives designers and<br />
engineers a great deal of room for manoeuvre<br />
in developing their ideas. For example, inserts<br />
or threaded bushings can be integrated directly<br />
at the time of manufacture while sound<br />
absorption holes and grille openings can also<br />
be molded into the design. Geometries can<br />
be selected at will. Thanks to their excellent<br />
flow properties, Baydur ® 60 and 110 make it<br />
possible to design even very complex molded<br />
parts. Even when the walls of components are<br />
very thin, the parts retain excellent rigidity and<br />
their integral skin foam (Baydur ® 60) or microcellular<br />
structure (Baydur ® 110) makes them<br />
light yet stable. Moreover, both materials offer<br />
an excellent surface finish to which high-quality<br />
coatings can be applied. They are thus ideally<br />
suited to the cutting-edge design of the cockpit.<br />
Since Baydur is processed using aluminum<br />
tools, it is cost-effective to produce small and<br />
medium-sized series.<br />
So far, over 150 ICE ® trains featuring cockpits<br />
produced by Thieme have already been brought<br />
into service. One place you’re guaranteed to see<br />
them is on the new ICE ® line between Frankfurt<br />
and Cologne, where they run regularly.<br />
For further information about Thieme go to:<br />
www.thieme-products.com
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
A MATERIAL THAT<br />
POINTS THE WAY FORWARD<br />
Wood, one of the oldest materials known to man, is also one of the most fascinating.<br />
However, this popular material does have its limits in terms of what it can be used for.<br />
Being a natural raw material, wood is not resistant to weathering. Its high tendency<br />
to warp has also forced engineers to look for alternatives in some areas where wood is<br />
traditionally used.<br />
“Eslon Neo Lumber FFU” is an extremely dimensionally<br />
stable composite material based on<br />
Baydur ® 60 reinforced with long glass fibers. It<br />
is produced by Sumika <strong>Bayer</strong> Urethane Co. Ltd.,<br />
a subsidiary of <strong>Bayer</strong> MaterialScience AG.<br />
The Japanese company Sekisui Chemical has<br />
been successfully selling this product for over<br />
20 years as a construction material for the<br />
Asian market. There, the sophisticated composite<br />
material has proved its worth in a wide<br />
variety of applications, particularly where<br />
technical considerations mean that it is not<br />
practical to use wood, but where the engineers<br />
would still like to benefit from the ease of<br />
processing associated with wood. Common<br />
applications include pools for fish farming,<br />
silos, walkways, soil anchors (where it is used<br />
as a substitute for concrete) and, above all,<br />
railway sleepers.<br />
European debut: The Zollamt bridge<br />
in Vienna has been fitted with<br />
polyurethane railway sleepers<br />
Now, this versatile material has made its debut<br />
in Europe. As part of a renovation project, the<br />
tracks on the Zollamt bridge in Vienna have<br />
been laid on sleepers made from polyurethane.<br />
“Eslon Neo Lumber is particularly well suited to<br />
use on bridges as it offers clear advantages over<br />
wood,” says Max Nakai from Sekisui Chemical<br />
Deutschland. “Changes in temperature, UV radiation<br />
and in particular the fact that the air is<br />
always humid mean that wooden sleepers<br />
weather more quickly here than in other<br />
applications. The problem is that carrying out<br />
structural repairs to railway tracks not only<br />
involves considerable inconvenience but is<br />
also very expensive.”<br />
The Zollamt bridge in Vienna<br />
This is also the case with the Zollamt bridge,<br />
which was designed by the Viennese art<br />
nouveau architect Otto Wagner and was<br />
constructed in 1898 when the Viennese city<br />
rail network was built. Materials with a long<br />
service life quickly pay for themselves in<br />
applications like this. Sekisui produces the<br />
polyurethane-glass fiber compound FFU (FFU
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
stands for fiber-reinforced foamed urethane)<br />
using the pultrusion process. The material can<br />
be produced to almost any length, it looks like<br />
wood and combines all the positive attributes<br />
of the natural product with those of a modern<br />
composite material.<br />
Eslon Neo Lumber sleepers can be screwed<br />
together, nailed or sawn using conventional<br />
woodworking tools, and also adhere together<br />
superbly, achieving an even stronger bond<br />
than wood. Other positive features of the material<br />
include its low coefficient of linear thermal<br />
expansion and low thermal conductivity.<br />
Thanks to the closed-cell structure of the lightweight<br />
polyurethane-glass fiber compound,<br />
the sleepers absorb only a minimal amount of<br />
water. The fiber reinforcement provides the<br />
material with high compressive and tensile<br />
strength, making it one of today’s leading hightech<br />
construction materials. The material’s<br />
excellent resistance to hydrolysis, greases and<br />
oils is another quality which makes the “polyurethane<br />
wood” a very reliable material, even<br />
when exposed to long-term weathering.<br />
Unlike natural wood, Eslon Neo Lumber FFU<br />
loses none of its favorable mechanical properties,<br />
even after prolonged service in the open<br />
air. Being light in weigthand simple to process<br />
on site, it is also superior to concrete. Special<br />
techniques for installing sleepers are often<br />
required when working on old bridges. Moreover,<br />
the statics of these bridges normally<br />
mean that only lightweight materials can be<br />
used. In Japan, polyurethane sleepers are not<br />
only used on bridges but also on stretches that<br />
are frequently washed by seawater and exposed<br />
to an aggressive microclimate. In tunnels,<br />
due to the limited amount of space available,<br />
work is very difficult and costly, which is why<br />
in tunnels situated close to the sea, polyurethane,<br />
which is light and resistant to salt water,<br />
is generally preferred.<br />
Stable and weather-resistant<br />
alternative to wood<br />
Sleepers of varying length are used for the<br />
manufacture of points. When concrete sleepers<br />
are cast, a separate mold is needed for each<br />
length. With the pultrusion process, on the<br />
other hand, it is easy to make any individual<br />
length. Polyurethane sleepers are significantly<br />
lighter than concrete ones. This is a particular<br />
advantage with points sleepers, which can be<br />
up to 10 meters long. In addition, polyurethane<br />
sleepers do not break as easily as concrete<br />
ones.<br />
The excellent electrical insulation properties<br />
of the plastic sleepers is particularly effective<br />
in winter when the points have to be heated<br />
in order to prevent them from freezing solid.<br />
The material is also resistant to frost and deicing<br />
salt.<br />
For further information go to:<br />
www.sekisui.de
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
THE WHISPERING<br />
STREETCAR<br />
Streetcar systems are a wonderful thing.<br />
Many city centers are much easier to reach<br />
by streetcar than by car. The streetcar takes<br />
you straight to where the action is, and<br />
there’s no need to worry about finding somewhere<br />
to park. Unfortunately, however,<br />
streetcars have their downside too. It’s not<br />
uncommon for people living along the<br />
routes to be bothered by the noise of streetcars<br />
squeaking and rumbling past their<br />
homes, particularly at night, and stray current<br />
from the tracks can cause corrosion damage<br />
to water and gas pipes.<br />
Fortunately, there’s an effective means of solving<br />
these problems. The underside of the tracks can<br />
be encased in an elastic, non-conducting plastic<br />
foam, a technique mastered by Polyplan GmbH<br />
of Strasslach, Germany. The materials used are<br />
polyurethane systems with tailor-made cell<br />
structures formulated specially for this application<br />
by Büfa Polyurethane GmbH & Co. KG<br />
of Oldenburg, Germany, a systems house of<br />
<strong>Bayer</strong> MaterialScience AG. They boast outstanding<br />
mechanical performance in long-term<br />
use and are very easy to work with.<br />
“There are two main sources of noise from streetcars,”<br />
says Lutz Ohmstede, who was part of the<br />
team at Büfa which developed the polyurethane<br />
system for this unusual application. “Firstly,<br />
there’s the rolling noise from the wheels and<br />
secondly, there’s the impact noise produced<br />
when the streetcar hits weld joints and points<br />
on the track. Both sources of noise can be re-<br />
duced by dampening the rail webs which emit<br />
the noise to provide effective acoustic insulation.<br />
Elastic plastics are perfect for the job.”<br />
Compared to conventional solutions using filled<br />
solid plastics, rigid polyurethane foams offer<br />
particular advantages. “Instead of controlling<br />
the dampening effect, and in turn the noise<br />
reduction performance of the grouting material<br />
by altering its hardness, we can optimize both<br />
properties using a tailor-made pore structure<br />
that literally swallows up sound,” continues<br />
Lutz Ohmstede “Moreover, using polyurethanes<br />
here means that we can completely do<br />
away with plasticizers. That’s particularly<br />
important, since these auxiliary substances<br />
are known to leach out of many other noisereducing<br />
materials over time, which can cause<br />
the material to become brittle.” The Büfaflex ®<br />
systems, which are based on Bayflex ® systems<br />
from <strong>Bayer</strong> MaterialScience AG, boast excellent<br />
long-term stability and maintain their vital<br />
dampening properties very well. Foams produced<br />
using these systems are highly weatherresistant<br />
and are also suitable for use in<br />
groundwater protection zones. Even adverse<br />
environmental conditions don’t affect them.<br />
Foam-coated rails minimize running<br />
noise and problems with stray current<br />
Büfaflex ® is also more cost-effective to process<br />
than conventional rail grouting systems. The<br />
rail is simply “floated” in a special framework<br />
on site and then encased in the foamed polymer<br />
material using a mobile, computer-controlled<br />
polyurethane grouting system so that the grout<br />
comes up to the lower edge of the rail head.<br />
The foam automatically expands to fill any space.<br />
“Grouting the rail in this way provides it with<br />
complete support,” explains Jürgen Huber from<br />
Polyplan GmbH, which specializes in rail grouting.
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
Another advantage is the fact that the polyurethane<br />
grouting system allows continuous<br />
operation, which is far quicker and more costeffective<br />
than the “bucket-by-bucket” approach<br />
used with conventional systems.<br />
“However, the elastic mounting does more than<br />
just significantly reduce structure-borne noise,”<br />
says Huber. “The complete, seamless coating<br />
also ensures that the rail is electrically isolated<br />
from the ground below. That provides the best<br />
possible protection against stray current.”<br />
To ensure that the rail fasteners do not conduct<br />
electricity into the ground, both elements can<br />
additionally be electrically isolated from one<br />
another by inserting plastic plates or anchor<br />
screws with plastic inserts.<br />
The whispering rail SILENCE is already ensuring<br />
peace and quiet on test tracks in major cities<br />
like Munich, Frankfurt and Zurich, and further<br />
projects are on the agenda – not least because<br />
new legislation to combat the problem of stray<br />
current is in the pipeline. “We believe that our<br />
role involves far more than simply providing<br />
the engineering technology on the ground,”<br />
continues Huber “We also intend to develop<br />
special frameworks and components and come<br />
up with cost-reducing strategies. We will in<br />
particular be working with our partner Büfa to<br />
adapt the polyurethane material to the specific<br />
needs of transport companies, which may vary<br />
greatly from one region to the next.”<br />
Once again, the versatility of polyurethane<br />
is really paying off – making<br />
streetcars an even more environmentally<br />
friendly mode of transport<br />
than they already are.<br />
For further information go to:<br />
lutz.ohmstede@buefa.de / www.buefa.com<br />
or visit www.fluesterschiene.de<br />
contact@polyplangmbh.de
Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />
ELECTRONIC EYES FOR<br />
FLOATING TRAINS<br />
Regardless of whether or not it comes into<br />
service in Germany in the foreseeable future,<br />
the Transrapid is internationally recognized<br />
as an outstanding achievement of German<br />
engineering. As with all modes of mass<br />
transportation, it is vital that all the system<br />
components in this “maglev” (magnetic<br />
levitation) train be totally reliable. That goes<br />
for the moving parts as well as the fixed<br />
system components, which also require<br />
effective protection from the specific environmental<br />
conditions they will encounter when<br />
the train goes into service in China.<br />
The GST 24 VT voltage sensors in the Transrapid<br />
linear motor produced by Duromer Kunststoffverarbeitungs-GmbH<br />
of Ottendorf-Okrilla,<br />
Germany, on behalf of the Transrapid Consortium<br />
are encapsulated in Baydur ® E, a<br />
specially designed polyurethane molding<br />
system using two liquid components. Despite<br />
its appearance, the Transrapid has little in<br />
common with a conventional high-speed train.<br />
Rather than running on rails, it “floats” to its<br />
destination on strong magnetic fields without<br />
coming into contact with the ground. This makes<br />
for a very smooth, energy-efficient action.<br />
Unlike conventional trains, the drive assembly<br />
on the maglev train is located in the track rather<br />
than in the train itself. The magnetic fields<br />
which “carry” the train are switched on and off<br />
in a fraction of a second by a system of linear<br />
motors. To ensure that the control electronics<br />
in these motors have an accurate picture of<br />
the condition of the railway track at all times,<br />
high-performance sensors are built into the<br />
track at regular intervals to relay vital information<br />
about factors such as the voltage and<br />
current conditions. “These sensors play a<br />
key role in the drive assembly of the Transrapid,<br />
so it’s vital that they are totally reliable,” says<br />
Dr. Axel Georgi, Managing Director of Duromer<br />
Kunststoffverarbeitungs-GmbH. “That’s why<br />
these modules are encased in polyurethane<br />
cast resin. This material not only isolates the<br />
electrical components, it also prevents dust,<br />
dirt and water penetrating the modules under<br />
sub-tropical conditions, thereby ensuring high<br />
operating reliability.” The casting compounds<br />
used are extremely resistant to hydrolysis, a<br />
factor which is important in the often warm,<br />
humid climate of Asian countries, and offers some<br />
clear technical advantages over epoxy resins.<br />
Polyurethane molding systems:<br />
Reliability is key to the drive concept<br />
“Polyurethane cast resins can be processed at<br />
comparatively low temperatures of around 100<br />
degrees Celsius,” explains Friedhelm Fähling,<br />
an expert in electrical casting compounds at<br />
<strong>Bayer</strong> MaterialScience AG. “That allows even<br />
large parts like the cylindrical sensor, which<br />
measures around 150 x 250 mm, to be produced<br />
quickly without lengthy heating uptimes.”<br />
Vacuum technology is used to create a bubblefree<br />
casting which will not cause any unevenness<br />
in the magnetic field. There is no need to anneal<br />
the casting compound afterwards. The moderate<br />
casting temperature also means that only<br />
slight shrinkage pressure is exerted on the<br />
delicate sensor electronics. This allows even<br />
components made of electrical conductors and<br />
semi-conductors with widely divergent thermal<br />
expansion coefficients to be sealed without<br />
sustaining any damage. The excellent flow<br />
properties of the polyurethane and the fact<br />
that it will adhere to a wide range of materials<br />
also ensure gap-free bonding. Moreover, when<br />
used with the appropriate fillers, these<br />
polyurethane resins conduct heat away very<br />
effectively.<br />
<strong>Polyurethanes</strong> have significant economic<br />
advantages over epoxy resins, shorter cycle<br />
times, lower energy costs and easier storage<br />
because different degrees of hardness can be<br />
achieved using one and the same raw material<br />
system.<br />
Foto: Transrapid Int. GmbH & Co. KG<br />
For further information go to:<br />
www.duromer.de
<strong>Bayer</strong> and its Partners<br />
BÜSING & FASCH GMBH & CO.<br />
Founded more than 120 years ago, Büsing & Fasch is an outstanding example of<br />
how entrepreneurial spirit, innovation and perseverance combined with an eye for the<br />
future and a willingness to embrace change can turn a modest regional business<br />
into an international enterprise.<br />
In 1883, Ludwig Büsing and Friedrich Fasch<br />
founded their dye, chemical and oil wholesale<br />
business in Oldenburg. Before the turn of the<br />
century, the dyewoods, plant dyes and tree<br />
oils which the company started out importing<br />
were joined by new products from Germany’s<br />
burgeoning chemical industry. These included<br />
synthetic dyes, mineral oils and all kinds of<br />
liquid and solid chemicals.<br />
New ideas for over 120 years<br />
In 1935, Johann Dietrich Kolwey became the<br />
sole owner of the firm, and a new era in the<br />
company’s history began under his leadership.<br />
He commenced production of dry dyes, coatings<br />
and textile auxiliaries in an effort to produce<br />
a portfolio which would allow him to serve his<br />
customers better, faster and more cost-effectively.<br />
In the 1960s, the company also began<br />
producing reactive resins and polyurethanes.<br />
Today, the BÜFA Group is majority-owned by<br />
the Wuppermann family (the grandchildren<br />
and great-grandchildren of J. D. Kolwey).<br />
Progress is a corporate goal<br />
BÜFA has always insisted on remaining a midsize<br />
company. The BÜFA Group has a modern<br />
structure with a strategic holding company<br />
comprising five independent subsidiaries at 11<br />
sites in Germany and overseas. It employs<br />
more than 500 people and records annual sales<br />
of approximately 150 million Euros. Operational<br />
business is led by the subsidiaries.<br />
The Group’s business activities include:<br />
- Chemical trading<br />
- Cleaning systems<br />
- Specialty glass<br />
- Reactive resins<br />
- Polyurethane systems.<br />
BÜFA Polyurethane & und Co. KG of Oldenburg-Etzhorn<br />
is a specialist in the field of<br />
formulating polyurethane system components.<br />
Since 2003, it has been a joint-venture under-<br />
taking of Büsing & Fasch GmbH & Co. KG and<br />
<strong>Bayer</strong> MaterialScience AG of Leverkusen, the<br />
inventor and market leader in the field of polyurethanes.<br />
<strong>Bayer</strong> and BÜFA have been cooperating<br />
for much longer than that, however.<br />
<strong>Bayer</strong> has been a supplier of raw materials and<br />
a strategic partner ever since polyurethane<br />
activities began in Oldenburg in 1969. <strong>Bayer</strong><br />
MaterialScience AG appreciates the flexible<br />
approach which small and midsize companies<br />
take to business, and therefore sees BÜFA<br />
Polyurethane as an important building block<br />
for central and northern Europe in the worldwide<br />
BaySystems systems house network<br />
which it is developing.<br />
Polyurethane processors require customized<br />
solutions. BÜFA Polyurethane is therefore an<br />
active partner during the development stage<br />
of these materials. It assists its customers in<br />
optimizing process technology, tools and all<br />
the processes which lead up to the start of<br />
series production. The company boasts laboratories<br />
and cutting-edge application technology<br />
with a full range of machinery for this purpose.<br />
The systems are produced in a high-tech automated<br />
formulation plant, tested to the very<br />
highest quality standards and delivered to the<br />
customer in drums, IBCs or tankers. It goes<br />
without saying that BÜFA Polyurethane also<br />
holds ISO 9001 and 14001 certification.<br />
Combining expertise and flexibility for<br />
the benefit of the customer is the stated<br />
objective of the company.<br />
For further information go to:<br />
www.buefa.com
Guide To <strong>Polyurethanes</strong><br />
Fire protection standards (part 2)<br />
RAILWAY VEHICLES<br />
A variety of national fire protection standards for railway vehicles is in force across<br />
Europe (see table for examples). These have developed as a result of differing historical<br />
experiences, evolving concepts of protection and different vehicle designs. Different<br />
countries still use different types of track. This is a reflection of their geography and degree<br />
of urbanization. The passenger evacuation conditions where railway routes feature<br />
large numbers of tunnels or bridges differ from those running across wide open spaces.<br />
Because of these differences, individual countries have different ways of assessing the<br />
various fire risks.<br />
These risks can best be explored from the<br />
point of view of the passenger. When a fire<br />
breaks out on a train, passengers may be<br />
endangered in a variety of ways.<br />
It may be difficult for them to escape or be<br />
rescued if the fire spreads rapidly and there is<br />
a lot of smoke. Smoke gases can have a toxic<br />
effect. In the worst-case scenario, heat may<br />
cause flammable gases to vaporize and collect<br />
under the roof of the train. This gas can spontaneously<br />
ignite in what is known as a “flashover”,<br />
spreading the fire to other parts of the<br />
train.<br />
Different countries use different fire testing<br />
procedures to assess these potential risks.<br />
Our assessment shows that different countries<br />
have independently identified similar types of<br />
risk. In general, flammability, flame spread<br />
patterns and smoke gas density are assessed.<br />
Some testing procedures also assess heat<br />
development and the toxic potential of smoke<br />
gases.<br />
The testing methods used vary widely.<br />
In France and Spain, for example, flame spread<br />
patterns are assessed by looking at the effect<br />
of heat radiation on materials using the<br />
Epiradiateur test. In Germany, on the other<br />
hand, the materials are subjected to a direct<br />
flame in a large test chamber in accordance<br />
with DIN standard 54837 (see photo).<br />
Fire protection standards specify which of the<br />
aforementioned tests a material must pass<br />
and what performance criteria apply to it.<br />
They take account of where a component will<br />
be installed in the vehicle and how large it is.<br />
Additional requirements are also set out for<br />
specific parts such as electrical encapsulation<br />
components.<br />
Based on the fire protection categories of the<br />
vehicle, different material requirements may<br />
be applied to reflect different levels of risk<br />
associated with ease of escape from the vehicle<br />
in question.<br />
For example, passengers can escape more<br />
quickly from a streetcar than they can from<br />
a high-speed train or a vehicle that passes<br />
through tunnels. In Germany, all these factors<br />
are taken into account by fire protection standard<br />
DIN 5510. This standard covers all finished<br />
components and divides trains into four fire<br />
protection categories.<br />
Test results are translated into classes based<br />
on one or more criteria. In Germany, materials<br />
are classified according to three criteria:<br />
A Flammability Class (S1 to S5), a Smoke Development<br />
Class (“SR1 not achieved”, “SR 1” or<br />
“SR2”) and a Drip Class (ST1 or ST2). The fire<br />
protection standard determines the classification<br />
of a material, which in turn governs<br />
the applications for which it can be used. The<br />
This information and our technical advice – whether verbal‚ in writing or by way of trials – are given in good faith but without warranty‚ and this also<br />
applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the information currently<br />
provided – especially that contained in our safety data and technical information sheets – and to test our products as to their suitability for the intended<br />
processes and uses. The application‚ use and processing of our products and the products manufactured by you on the basis of our technical advice<br />
are beyond our control and‚ therefore‚ entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />
Conditions of Sale and Delivery.<br />
Bestell-Nr.: MS 006045, Printed in Germany KL<br />
<strong>Bayer</strong> MaterialScience AG<br />
51368 Leverkusen, Germany<br />
www.bayermaterialscience.com<br />
Baydur 60 FRS in a DIN 54837 testing chamber<br />
standard lists the class ratings which must be<br />
fulfilled for specific applications.<br />
In an effort to ensure uniform assessment of<br />
materials throughout the European Union,<br />
standard EN 45545 “Fire protection on railway<br />
vehicles” has been drafted.<br />
Objections to Part 2 of this draft standard are<br />
currently being filed, and will be assessed soon.<br />
Part 2 deals with the issue of assessing the<br />
fire behavior of materials and components,<br />
and will probably set out four main tests.<br />
These will involve determining the amount of<br />
heat released, the flame spread, the smoke<br />
gas density and the toxicity of the combustion<br />
gases.<br />
Fire protection standard<br />
DIN 5510 1)<br />
AFNOR NF F 16-101<br />
DT-PCI/5A<br />
BS 6853<br />
UNIFER E 10.02.977.3<br />
prEN 45455<br />
Country<br />
Germany<br />
France<br />
Spain<br />
United Kingdom<br />
Italy<br />
European Union<br />
1) also applies in Austria, Switzerland and China<br />
Contact:<br />
Dr. Stephan Schleiermacher<br />
<strong>Polyurethanes</strong> Business Unit<br />
Tel.: ++ 49 214 30 - 3 94 95<br />
stephan.schleiermacher@bayerbms.com<br />
If you have any questions or suggestions,<br />
please contact:<br />
Martin Sixsmith<br />
Tel. +44 1635 563 811<br />
Fax +44 1635 563 272<br />
ukqueries@bayermaterialscience.com
Guide To <strong>Polyurethanes</strong><br />
Fire protection standards (part 2)<br />
RAILWAY VEHICLES<br />
A variety of national fire protection standards for railway vehicles is in force across<br />
Europe (see table for examples). These have developed as a result of differing historical<br />
experiences, evolving concepts of protection and different vehicle designs. Different<br />
countries still use different types of track. This is a reflection of their geography and degree<br />
of urbanization. The passenger evacuation conditions where railway routes feature<br />
large numbers of tunnels or bridges differ from those running across wide open spaces.<br />
Because of these differences, individual countries have different ways of assessing the<br />
various fire risks.<br />
These risks can best be explored from the<br />
point of view of the passenger. When a fire<br />
breaks out on a train, passengers may be<br />
endangered in a variety of ways.<br />
It may be difficult for them to escape or be<br />
rescued if the fire spreads rapidly and there is<br />
a lot of smoke. Smoke gases can have a toxic<br />
effect. In the worst-case scenario, heat may<br />
cause flammable gases to vaporize and collect<br />
under the roof of the train. This gas can spontaneously<br />
ignite in what is known as a “flashover”,<br />
spreading the fire to other parts of the<br />
train.<br />
Different countries use different fire testing<br />
procedures to assess these potential risks.<br />
Our assessment shows that different countries<br />
have independently identified similar types of<br />
risk. In general, flammability, flame spread<br />
patterns and smoke gas density are assessed.<br />
Some testing procedures also assess heat<br />
development and the toxic potential of smoke<br />
gases.<br />
The testing methods used vary widely.<br />
In France and Spain, for example, flame spread<br />
patterns are assessed by looking at the effect<br />
of heat radiation on materials using the<br />
Epiradiateur test. In Germany, on the other<br />
hand, the materials are subjected to a direct<br />
flame in a large test chamber in accordance<br />
with DIN standard 54837 (see photo).<br />
Fire protection standards specify which of the<br />
aforementioned tests a material must pass<br />
and what performance criteria apply to it.<br />
They take account of where a component will<br />
be installed in the vehicle and how large it is.<br />
Additional requirements are also set out for<br />
specific parts such as electrical encapsulation<br />
components.<br />
Based on the fire protection categories of the<br />
vehicle, different material requirements may<br />
be applied to reflect different levels of risk<br />
associated with ease of escape from the vehicle<br />
in question.<br />
For example, passengers can escape more<br />
quickly from a streetcar than they can from<br />
a high-speed train or a vehicle that passes<br />
through tunnels. In Germany, all these factors<br />
are taken into account by fire protection standard<br />
DIN 5510. This standard covers all finished<br />
components and divides trains into four fire<br />
protection categories.<br />
Test results are translated into classes based<br />
on one or more criteria. In Germany, materials<br />
are classified according to three criteria:<br />
A Flammability Class (S1 to S5), a Smoke Development<br />
Class (“SR1 not achieved”, “SR 1” or<br />
“SR2”) and a Drip Class (ST1 or ST2). The fire<br />
protection standard determines the classification<br />
of a material, which in turn governs<br />
the applications for which it can be used. The<br />
This information and our technical advice – whether verbal‚ in writing or by way of trials – are given in good faith but without warranty‚ and this also<br />
applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the information currently<br />
provided – especially that contained in our safety data and technical information sheets – and to test our products as to their suitability for the intended<br />
processes and uses. The application‚ use and processing of our products and the products manufactured by you on the basis of our technical advice<br />
are beyond our control and‚ therefore‚ entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />
Conditions of Sale and Delivery.<br />
Bestell-Nr.: MS 006045, Printed in Germany KL<br />
<strong>Bayer</strong> MaterialScience AG<br />
51368 Leverkusen, Germany<br />
www.bayermaterialscience.com<br />
Baydur 60 FRS in a DIN 54837 testing chamber<br />
standard lists the class ratings which must be<br />
fulfilled for specific applications.<br />
In an effort to ensure uniform assessment of<br />
materials throughout the European Union,<br />
standard EN 45545 “Fire protection on railway<br />
vehicles” has been drafted.<br />
Objections to Part 2 of this draft standard are<br />
currently being filed, and will be assessed soon.<br />
Part 2 deals with the issue of assessing the<br />
fire behavior of materials and components,<br />
and will probably set out four main tests.<br />
These will involve determining the amount of<br />
heat released, the flame spread, the smoke<br />
gas density and the toxicity of the combustion<br />
gases.<br />
Fire protection standard<br />
DIN 5510 1)<br />
AFNOR NF F 16-101<br />
DT-PCI/5A<br />
BS 6853<br />
UNIFER E 10.02.977.3<br />
prEN 45455<br />
1) also applies in Austria, Switzerland and China<br />
Contact:<br />
Dr. Stephan Schleiermacher<br />
<strong>Polyurethanes</strong> Business Unit<br />
Tel.: ++ 49 214 30 - 3 94 95<br />
stephan.schleiermacher@bayerbms.com<br />
If you have any questions or suggestions,<br />
please contact:<br />
Monika Brandt<br />
Tel. ++ 49 214 30 - 3 30 13<br />
Fax ++ 49 214 30 - 5 53 52<br />
monika.brandt@bayerbms.com<br />
Country<br />
Germany<br />
France<br />
Spain<br />
United Kingdom<br />
Italy<br />
European Union