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Issue 1/2005<br />

Baydur ® / Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality


Editorial<br />

Dear Readers,<br />

In 1835, Charles Darwin discovered 14<br />

different species of finch in the Galapagos<br />

Islands, all of which had evolved from a<br />

single finch species. Darwin later developed<br />

his theory of evolution on the basis of this<br />

discovery.<br />

We might ask ourselves: what is the<br />

equivalent of Darwin’s finches in the world<br />

of plastics? In my opinion, it’s polyurethanes.<br />

Their versatile structure has enabled them<br />

to undergo such a process of “evolution” that<br />

they are now found in a number of different<br />

rail transport applications.<br />

Let’s start by considering the driver’s cab in<br />

a train. <strong>Here</strong>, the use of Baydur 110 FRS and<br />

Baydur 60 FRS allows the interior to be<br />

designed in a functional and modern style –<br />

with impressive looking, high-quality<br />

materials and a level of fire performance that<br />

meets the requirements of DIN 5510. Rail<br />

damping with Bayflex ® effectively reduces<br />

vibration, allowing trains to run more quietly<br />

over the track.<br />

When conventional railway sleepers fail,<br />

concrete suffers frost damage and wood rots<br />

away, glass fibre-reinforced Baydur sleepers<br />

are still going strong. They maintain their<br />

high mechanical strength for an estimated<br />

lifetime of over 50 years. That’s what a highly<br />

envolved material called polyurethane can do!<br />

Sincerely,<br />

Dr. Stephan Schleiermacher<br />

<strong>Polyurethanes</strong> Business Unit<br />

Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

IS FLYING REALLY BETTER?<br />

If you want to get from A to B in Germany quickly and in comfort, taking a plane is by no means<br />

your only option. These days, Deutsche Bahn’s high-speed trains offer a standard of service<br />

which, until recently, could only be experienced above the clouds. And it’s not just in the<br />

passenger facilities that you can draw this parallel. The driver’s cab in the ICE ® 3 looks just<br />

like the cockpit of a plane. It is only divided from the passenger carriages by a glass screen,<br />

so anyone who’s interested can see their “pilot” at work at any time during the journey !<br />

Featuring soft contours, a clear layout and<br />

quality-finish surfaces, large areas of the<br />

driver’s control panel in the ICE ® 3 are made up<br />

of large, lightweight molded parts produced by<br />

polyurethane specialist Thieme GmbH & Co. KG<br />

of Teningen, Germany, using the Baydur ® 60<br />

and Baydur ® 110 systems.<br />

Thieme designs cladding<br />

for the cockpit of the ICE ® 3<br />

Thieme supplies the molded parts to Dornier<br />

GmbH, which in turn supplies them to the<br />

ICE ® Siemens/Bombardier consortium. This<br />

consortium has developed and built the ICE ® 3<br />

in a project led by the Transportation Systems<br />

Division of Siemens AG and run in cooperation<br />

with Deutsche Bahn AG.<br />

The advantages of using<br />

polyurethane in rail transport<br />

When it comes to implementing ambitious<br />

design concepts, polyurethane has repeatedly<br />

proven itself to be an excellent material in<br />

many fields. The railway sector is no exception.<br />

A total of 27 different parts are produced for<br />

the ICE ® 3 cockpit.<br />

They include everything from cladding sections<br />

to high-quality panels fitted with recesses<br />

for switches and levers. They can also be<br />

screen-printed. It is vital that the materials<br />

used in this project meet the strict guidelines<br />

of Deutsche Bahn and other national and<br />

international fire safety standards. Baydur ®<br />

complies with the required classifications S4,<br />

SR2 and ST2 of DIN standard 5510.<br />

(For information about fire protection standards<br />

in the rail sector, see the final article in this<br />

edition of InForm, which is entitled “Guide to<br />

<strong>Polyurethanes</strong>”)


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

The cockpit of the ICE ® 3 generation of trains is another example of how polyurethanes<br />

can be used to combine design with functionality and cost-effectiveness.<br />

Why use polyurethane?<br />

Polyurethane offers advantages over other<br />

plastics which are particularly relevant when<br />

designing trains.<br />

Materials are required to be:<br />

- Light<br />

- Easy to clean<br />

- Robust<br />

- Distortion-free<br />

Polyurethane meets all these requirements.<br />

This material also gives designers and<br />

engineers a great deal of room for manoeuvre<br />

in developing their ideas. For example, inserts<br />

or threaded bushings can be integrated directly<br />

at the time of manufacture while sound<br />

absorption holes and grille openings can also<br />

be molded into the design. Geometries can<br />

be selected at will. Thanks to their excellent<br />

flow properties, Baydur ® 60 and 110 make it<br />

possible to design even very complex molded<br />

parts. Even when the walls of components are<br />

very thin, the parts retain excellent rigidity and<br />

their integral skin foam (Baydur ® 60) or microcellular<br />

structure (Baydur ® 110) makes them<br />

light yet stable. Moreover, both materials offer<br />

an excellent surface finish to which high-quality<br />

coatings can be applied. They are thus ideally<br />

suited to the cutting-edge design of the cockpit.<br />

Since Baydur is processed using aluminum<br />

tools, it is cost-effective to produce small and<br />

medium-sized series.<br />

So far, over 150 ICE ® trains featuring cockpits<br />

produced by Thieme have already been brought<br />

into service. One place you’re guaranteed to see<br />

them is on the new ICE ® line between Frankfurt<br />

and Cologne, where they run regularly.<br />

For further information about Thieme go to:<br />

www.thieme-products.com


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

A MATERIAL THAT<br />

POINTS THE WAY FORWARD<br />

Wood, one of the oldest materials known to man, is also one of the most fascinating.<br />

However, this popular material does have its limits in terms of what it can be used for.<br />

Being a natural raw material, wood is not resistant to weathering. Its high tendency<br />

to warp has also forced engineers to look for alternatives in some areas where wood is<br />

traditionally used.<br />

“Eslon Neo Lumber FFU” is an extremely dimensionally<br />

stable composite material based on<br />

Baydur ® 60 reinforced with long glass fibers. It<br />

is produced by Sumika <strong>Bayer</strong> Urethane Co. Ltd.,<br />

a subsidiary of <strong>Bayer</strong> MaterialScience AG.<br />

The Japanese company Sekisui Chemical has<br />

been successfully selling this product for over<br />

20 years as a construction material for the<br />

Asian market. There, the sophisticated composite<br />

material has proved its worth in a wide<br />

variety of applications, particularly where<br />

technical considerations mean that it is not<br />

practical to use wood, but where the engineers<br />

would still like to benefit from the ease of<br />

processing associated with wood. Common<br />

applications include pools for fish farming,<br />

silos, walkways, soil anchors (where it is used<br />

as a substitute for concrete) and, above all,<br />

railway sleepers.<br />

European debut: The Zollamt bridge<br />

in Vienna has been fitted with<br />

polyurethane railway sleepers<br />

Now, this versatile material has made its debut<br />

in Europe. As part of a renovation project, the<br />

tracks on the Zollamt bridge in Vienna have<br />

been laid on sleepers made from polyurethane.<br />

“Eslon Neo Lumber is particularly well suited to<br />

use on bridges as it offers clear advantages over<br />

wood,” says Max Nakai from Sekisui Chemical<br />

Deutschland. “Changes in temperature, UV radiation<br />

and in particular the fact that the air is<br />

always humid mean that wooden sleepers<br />

weather more quickly here than in other<br />

applications. The problem is that carrying out<br />

structural repairs to railway tracks not only<br />

involves considerable inconvenience but is<br />

also very expensive.”<br />

The Zollamt bridge in Vienna<br />

This is also the case with the Zollamt bridge,<br />

which was designed by the Viennese art<br />

nouveau architect Otto Wagner and was<br />

constructed in 1898 when the Viennese city<br />

rail network was built. Materials with a long<br />

service life quickly pay for themselves in<br />

applications like this. Sekisui produces the<br />

polyurethane-glass fiber compound FFU (FFU


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

stands for fiber-reinforced foamed urethane)<br />

using the pultrusion process. The material can<br />

be produced to almost any length, it looks like<br />

wood and combines all the positive attributes<br />

of the natural product with those of a modern<br />

composite material.<br />

Eslon Neo Lumber sleepers can be screwed<br />

together, nailed or sawn using conventional<br />

woodworking tools, and also adhere together<br />

superbly, achieving an even stronger bond<br />

than wood. Other positive features of the material<br />

include its low coefficient of linear thermal<br />

expansion and low thermal conductivity.<br />

Thanks to the closed-cell structure of the lightweight<br />

polyurethane-glass fiber compound,<br />

the sleepers absorb only a minimal amount of<br />

water. The fiber reinforcement provides the<br />

material with high compressive and tensile<br />

strength, making it one of today’s leading hightech<br />

construction materials. The material’s<br />

excellent resistance to hydrolysis, greases and<br />

oils is another quality which makes the “polyurethane<br />

wood” a very reliable material, even<br />

when exposed to long-term weathering.<br />

Unlike natural wood, Eslon Neo Lumber FFU<br />

loses none of its favorable mechanical properties,<br />

even after prolonged service in the open<br />

air. Being light in weigthand simple to process<br />

on site, it is also superior to concrete. Special<br />

techniques for installing sleepers are often<br />

required when working on old bridges. Moreover,<br />

the statics of these bridges normally<br />

mean that only lightweight materials can be<br />

used. In Japan, polyurethane sleepers are not<br />

only used on bridges but also on stretches that<br />

are frequently washed by seawater and exposed<br />

to an aggressive microclimate. In tunnels,<br />

due to the limited amount of space available,<br />

work is very difficult and costly, which is why<br />

in tunnels situated close to the sea, polyurethane,<br />

which is light and resistant to salt water,<br />

is generally preferred.<br />

Stable and weather-resistant<br />

alternative to wood<br />

Sleepers of varying length are used for the<br />

manufacture of points. When concrete sleepers<br />

are cast, a separate mold is needed for each<br />

length. With the pultrusion process, on the<br />

other hand, it is easy to make any individual<br />

length. Polyurethane sleepers are significantly<br />

lighter than concrete ones. This is a particular<br />

advantage with points sleepers, which can be<br />

up to 10 meters long. In addition, polyurethane<br />

sleepers do not break as easily as concrete<br />

ones.<br />

The excellent electrical insulation properties<br />

of the plastic sleepers is particularly effective<br />

in winter when the points have to be heated<br />

in order to prevent them from freezing solid.<br />

The material is also resistant to frost and deicing<br />

salt.<br />

For further information go to:<br />

www.sekisui.de


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

THE WHISPERING<br />

STREETCAR<br />

Streetcar systems are a wonderful thing.<br />

Many city centers are much easier to reach<br />

by streetcar than by car. The streetcar takes<br />

you straight to where the action is, and<br />

there’s no need to worry about finding somewhere<br />

to park. Unfortunately, however,<br />

streetcars have their downside too. It’s not<br />

uncommon for people living along the<br />

routes to be bothered by the noise of streetcars<br />

squeaking and rumbling past their<br />

homes, particularly at night, and stray current<br />

from the tracks can cause corrosion damage<br />

to water and gas pipes.<br />

Fortunately, there’s an effective means of solving<br />

these problems. The underside of the tracks can<br />

be encased in an elastic, non-conducting plastic<br />

foam, a technique mastered by Polyplan GmbH<br />

of Strasslach, Germany. The materials used are<br />

polyurethane systems with tailor-made cell<br />

structures formulated specially for this application<br />

by Büfa Polyurethane GmbH & Co. KG<br />

of Oldenburg, Germany, a systems house of<br />

<strong>Bayer</strong> MaterialScience AG. They boast outstanding<br />

mechanical performance in long-term<br />

use and are very easy to work with.<br />

“There are two main sources of noise from streetcars,”<br />

says Lutz Ohmstede, who was part of the<br />

team at Büfa which developed the polyurethane<br />

system for this unusual application. “Firstly,<br />

there’s the rolling noise from the wheels and<br />

secondly, there’s the impact noise produced<br />

when the streetcar hits weld joints and points<br />

on the track. Both sources of noise can be re-<br />

duced by dampening the rail webs which emit<br />

the noise to provide effective acoustic insulation.<br />

Elastic plastics are perfect for the job.”<br />

Compared to conventional solutions using filled<br />

solid plastics, rigid polyurethane foams offer<br />

particular advantages. “Instead of controlling<br />

the dampening effect, and in turn the noise<br />

reduction performance of the grouting material<br />

by altering its hardness, we can optimize both<br />

properties using a tailor-made pore structure<br />

that literally swallows up sound,” continues<br />

Lutz Ohmstede “Moreover, using polyurethanes<br />

here means that we can completely do<br />

away with plasticizers. That’s particularly<br />

important, since these auxiliary substances<br />

are known to leach out of many other noisereducing<br />

materials over time, which can cause<br />

the material to become brittle.” The Büfaflex ®<br />

systems, which are based on Bayflex ® systems<br />

from <strong>Bayer</strong> MaterialScience AG, boast excellent<br />

long-term stability and maintain their vital<br />

dampening properties very well. Foams produced<br />

using these systems are highly weatherresistant<br />

and are also suitable for use in<br />

groundwater protection zones. Even adverse<br />

environmental conditions don’t affect them.<br />

Foam-coated rails minimize running<br />

noise and problems with stray current<br />

Büfaflex ® is also more cost-effective to process<br />

than conventional rail grouting systems. The<br />

rail is simply “floated” in a special framework<br />

on site and then encased in the foamed polymer<br />

material using a mobile, computer-controlled<br />

polyurethane grouting system so that the grout<br />

comes up to the lower edge of the rail head.<br />

The foam automatically expands to fill any space.<br />

“Grouting the rail in this way provides it with<br />

complete support,” explains Jürgen Huber from<br />

Polyplan GmbH, which specializes in rail grouting.


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

Another advantage is the fact that the polyurethane<br />

grouting system allows continuous<br />

operation, which is far quicker and more costeffective<br />

than the “bucket-by-bucket” approach<br />

used with conventional systems.<br />

“However, the elastic mounting does more than<br />

just significantly reduce structure-borne noise,”<br />

says Huber. “The complete, seamless coating<br />

also ensures that the rail is electrically isolated<br />

from the ground below. That provides the best<br />

possible protection against stray current.”<br />

To ensure that the rail fasteners do not conduct<br />

electricity into the ground, both elements can<br />

additionally be electrically isolated from one<br />

another by inserting plastic plates or anchor<br />

screws with plastic inserts.<br />

The whispering rail SILENCE is already ensuring<br />

peace and quiet on test tracks in major cities<br />

like Munich, Frankfurt and Zurich, and further<br />

projects are on the agenda – not least because<br />

new legislation to combat the problem of stray<br />

current is in the pipeline. “We believe that our<br />

role involves far more than simply providing<br />

the engineering technology on the ground,”<br />

continues Huber “We also intend to develop<br />

special frameworks and components and come<br />

up with cost-reducing strategies. We will in<br />

particular be working with our partner Büfa to<br />

adapt the polyurethane material to the specific<br />

needs of transport companies, which may vary<br />

greatly from one region to the next.”<br />

Once again, the versatility of polyurethane<br />

is really paying off – making<br />

streetcars an even more environmentally<br />

friendly mode of transport<br />

than they already are.<br />

For further information go to:<br />

lutz.ohmstede@buefa.de / www.buefa.com<br />

or visit www.fluesterschiene.de<br />

contact@polyplangmbh.de


Baydur ®/Bayflex ® – <strong>Polyurethanes</strong> for Design and Functionality<br />

ELECTRONIC EYES FOR<br />

FLOATING TRAINS<br />

Regardless of whether or not it comes into<br />

service in Germany in the foreseeable future,<br />

the Transrapid is internationally recognized<br />

as an outstanding achievement of German<br />

engineering. As with all modes of mass<br />

transportation, it is vital that all the system<br />

components in this “maglev” (magnetic<br />

levitation) train be totally reliable. That goes<br />

for the moving parts as well as the fixed<br />

system components, which also require<br />

effective protection from the specific environmental<br />

conditions they will encounter when<br />

the train goes into service in China.<br />

The GST 24 VT voltage sensors in the Transrapid<br />

linear motor produced by Duromer Kunststoffverarbeitungs-GmbH<br />

of Ottendorf-Okrilla,<br />

Germany, on behalf of the Transrapid Consortium<br />

are encapsulated in Baydur ® E, a<br />

specially designed polyurethane molding<br />

system using two liquid components. Despite<br />

its appearance, the Transrapid has little in<br />

common with a conventional high-speed train.<br />

Rather than running on rails, it “floats” to its<br />

destination on strong magnetic fields without<br />

coming into contact with the ground. This makes<br />

for a very smooth, energy-efficient action.<br />

Unlike conventional trains, the drive assembly<br />

on the maglev train is located in the track rather<br />

than in the train itself. The magnetic fields<br />

which “carry” the train are switched on and off<br />

in a fraction of a second by a system of linear<br />

motors. To ensure that the control electronics<br />

in these motors have an accurate picture of<br />

the condition of the railway track at all times,<br />

high-performance sensors are built into the<br />

track at regular intervals to relay vital information<br />

about factors such as the voltage and<br />

current conditions. “These sensors play a<br />

key role in the drive assembly of the Transrapid,<br />

so it’s vital that they are totally reliable,” says<br />

Dr. Axel Georgi, Managing Director of Duromer<br />

Kunststoffverarbeitungs-GmbH. “That’s why<br />

these modules are encased in polyurethane<br />

cast resin. This material not only isolates the<br />

electrical components, it also prevents dust,<br />

dirt and water penetrating the modules under<br />

sub-tropical conditions, thereby ensuring high<br />

operating reliability.” The casting compounds<br />

used are extremely resistant to hydrolysis, a<br />

factor which is important in the often warm,<br />

humid climate of Asian countries, and offers some<br />

clear technical advantages over epoxy resins.<br />

Polyurethane molding systems:<br />

Reliability is key to the drive concept<br />

“Polyurethane cast resins can be processed at<br />

comparatively low temperatures of around 100<br />

degrees Celsius,” explains Friedhelm Fähling,<br />

an expert in electrical casting compounds at<br />

<strong>Bayer</strong> MaterialScience AG. “That allows even<br />

large parts like the cylindrical sensor, which<br />

measures around 150 x 250 mm, to be produced<br />

quickly without lengthy heating uptimes.”<br />

Vacuum technology is used to create a bubblefree<br />

casting which will not cause any unevenness<br />

in the magnetic field. There is no need to anneal<br />

the casting compound afterwards. The moderate<br />

casting temperature also means that only<br />

slight shrinkage pressure is exerted on the<br />

delicate sensor electronics. This allows even<br />

components made of electrical conductors and<br />

semi-conductors with widely divergent thermal<br />

expansion coefficients to be sealed without<br />

sustaining any damage. The excellent flow<br />

properties of the polyurethane and the fact<br />

that it will adhere to a wide range of materials<br />

also ensure gap-free bonding. Moreover, when<br />

used with the appropriate fillers, these<br />

polyurethane resins conduct heat away very<br />

effectively.<br />

<strong>Polyurethanes</strong> have significant economic<br />

advantages over epoxy resins, shorter cycle<br />

times, lower energy costs and easier storage<br />

because different degrees of hardness can be<br />

achieved using one and the same raw material<br />

system.<br />

Foto: Transrapid Int. GmbH & Co. KG<br />

For further information go to:<br />

www.duromer.de


<strong>Bayer</strong> and its Partners<br />

BÜSING & FASCH GMBH & CO.<br />

Founded more than 120 years ago, Büsing & Fasch is an outstanding example of<br />

how entrepreneurial spirit, innovation and perseverance combined with an eye for the<br />

future and a willingness to embrace change can turn a modest regional business<br />

into an international enterprise.<br />

In 1883, Ludwig Büsing and Friedrich Fasch<br />

founded their dye, chemical and oil wholesale<br />

business in Oldenburg. Before the turn of the<br />

century, the dyewoods, plant dyes and tree<br />

oils which the company started out importing<br />

were joined by new products from Germany’s<br />

burgeoning chemical industry. These included<br />

synthetic dyes, mineral oils and all kinds of<br />

liquid and solid chemicals.<br />

New ideas for over 120 years<br />

In 1935, Johann Dietrich Kolwey became the<br />

sole owner of the firm, and a new era in the<br />

company’s history began under his leadership.<br />

He commenced production of dry dyes, coatings<br />

and textile auxiliaries in an effort to produce<br />

a portfolio which would allow him to serve his<br />

customers better, faster and more cost-effectively.<br />

In the 1960s, the company also began<br />

producing reactive resins and polyurethanes.<br />

Today, the BÜFA Group is majority-owned by<br />

the Wuppermann family (the grandchildren<br />

and great-grandchildren of J. D. Kolwey).<br />

Progress is a corporate goal<br />

BÜFA has always insisted on remaining a midsize<br />

company. The BÜFA Group has a modern<br />

structure with a strategic holding company<br />

comprising five independent subsidiaries at 11<br />

sites in Germany and overseas. It employs<br />

more than 500 people and records annual sales<br />

of approximately 150 million Euros. Operational<br />

business is led by the subsidiaries.<br />

The Group’s business activities include:<br />

- Chemical trading<br />

- Cleaning systems<br />

- Specialty glass<br />

- Reactive resins<br />

- Polyurethane systems.<br />

BÜFA Polyurethane & und Co. KG of Oldenburg-Etzhorn<br />

is a specialist in the field of<br />

formulating polyurethane system components.<br />

Since 2003, it has been a joint-venture under-<br />

taking of Büsing & Fasch GmbH & Co. KG and<br />

<strong>Bayer</strong> MaterialScience AG of Leverkusen, the<br />

inventor and market leader in the field of polyurethanes.<br />

<strong>Bayer</strong> and BÜFA have been cooperating<br />

for much longer than that, however.<br />

<strong>Bayer</strong> has been a supplier of raw materials and<br />

a strategic partner ever since polyurethane<br />

activities began in Oldenburg in 1969. <strong>Bayer</strong><br />

MaterialScience AG appreciates the flexible<br />

approach which small and midsize companies<br />

take to business, and therefore sees BÜFA<br />

Polyurethane as an important building block<br />

for central and northern Europe in the worldwide<br />

BaySystems systems house network<br />

which it is developing.<br />

Polyurethane processors require customized<br />

solutions. BÜFA Polyurethane is therefore an<br />

active partner during the development stage<br />

of these materials. It assists its customers in<br />

optimizing process technology, tools and all<br />

the processes which lead up to the start of<br />

series production. The company boasts laboratories<br />

and cutting-edge application technology<br />

with a full range of machinery for this purpose.<br />

The systems are produced in a high-tech automated<br />

formulation plant, tested to the very<br />

highest quality standards and delivered to the<br />

customer in drums, IBCs or tankers. It goes<br />

without saying that BÜFA Polyurethane also<br />

holds ISO 9001 and 14001 certification.<br />

Combining expertise and flexibility for<br />

the benefit of the customer is the stated<br />

objective of the company.<br />

For further information go to:<br />

www.buefa.com


Guide To <strong>Polyurethanes</strong><br />

Fire protection standards (part 2)<br />

RAILWAY VEHICLES<br />

A variety of national fire protection standards for railway vehicles is in force across<br />

Europe (see table for examples). These have developed as a result of differing historical<br />

experiences, evolving concepts of protection and different vehicle designs. Different<br />

countries still use different types of track. This is a reflection of their geography and degree<br />

of urbanization. The passenger evacuation conditions where railway routes feature<br />

large numbers of tunnels or bridges differ from those running across wide open spaces.<br />

Because of these differences, individual countries have different ways of assessing the<br />

various fire risks.<br />

These risks can best be explored from the<br />

point of view of the passenger. When a fire<br />

breaks out on a train, passengers may be<br />

endangered in a variety of ways.<br />

It may be difficult for them to escape or be<br />

rescued if the fire spreads rapidly and there is<br />

a lot of smoke. Smoke gases can have a toxic<br />

effect. In the worst-case scenario, heat may<br />

cause flammable gases to vaporize and collect<br />

under the roof of the train. This gas can spontaneously<br />

ignite in what is known as a “flashover”,<br />

spreading the fire to other parts of the<br />

train.<br />

Different countries use different fire testing<br />

procedures to assess these potential risks.<br />

Our assessment shows that different countries<br />

have independently identified similar types of<br />

risk. In general, flammability, flame spread<br />

patterns and smoke gas density are assessed.<br />

Some testing procedures also assess heat<br />

development and the toxic potential of smoke<br />

gases.<br />

The testing methods used vary widely.<br />

In France and Spain, for example, flame spread<br />

patterns are assessed by looking at the effect<br />

of heat radiation on materials using the<br />

Epiradiateur test. In Germany, on the other<br />

hand, the materials are subjected to a direct<br />

flame in a large test chamber in accordance<br />

with DIN standard 54837 (see photo).<br />

Fire protection standards specify which of the<br />

aforementioned tests a material must pass<br />

and what performance criteria apply to it.<br />

They take account of where a component will<br />

be installed in the vehicle and how large it is.<br />

Additional requirements are also set out for<br />

specific parts such as electrical encapsulation<br />

components.<br />

Based on the fire protection categories of the<br />

vehicle, different material requirements may<br />

be applied to reflect different levels of risk<br />

associated with ease of escape from the vehicle<br />

in question.<br />

For example, passengers can escape more<br />

quickly from a streetcar than they can from<br />

a high-speed train or a vehicle that passes<br />

through tunnels. In Germany, all these factors<br />

are taken into account by fire protection standard<br />

DIN 5510. This standard covers all finished<br />

components and divides trains into four fire<br />

protection categories.<br />

Test results are translated into classes based<br />

on one or more criteria. In Germany, materials<br />

are classified according to three criteria:<br />

A Flammability Class (S1 to S5), a Smoke Development<br />

Class (“SR1 not achieved”, “SR 1” or<br />

“SR2”) and a Drip Class (ST1 or ST2). The fire<br />

protection standard determines the classification<br />

of a material, which in turn governs<br />

the applications for which it can be used. The<br />

This information and our technical advice – whether verbal‚ in writing or by way of trials – are given in good faith but without warranty‚ and this also<br />

applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the information currently<br />

provided – especially that contained in our safety data and technical information sheets – and to test our products as to their suitability for the intended<br />

processes and uses. The application‚ use and processing of our products and the products manufactured by you on the basis of our technical advice<br />

are beyond our control and‚ therefore‚ entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />

Conditions of Sale and Delivery.<br />

Bestell-Nr.: MS 006045, Printed in Germany KL<br />

<strong>Bayer</strong> MaterialScience AG<br />

51368 Leverkusen, Germany<br />

www.bayermaterialscience.com<br />

Baydur 60 FRS in a DIN 54837 testing chamber<br />

standard lists the class ratings which must be<br />

fulfilled for specific applications.<br />

In an effort to ensure uniform assessment of<br />

materials throughout the European Union,<br />

standard EN 45545 “Fire protection on railway<br />

vehicles” has been drafted.<br />

Objections to Part 2 of this draft standard are<br />

currently being filed, and will be assessed soon.<br />

Part 2 deals with the issue of assessing the<br />

fire behavior of materials and components,<br />

and will probably set out four main tests.<br />

These will involve determining the amount of<br />

heat released, the flame spread, the smoke<br />

gas density and the toxicity of the combustion<br />

gases.<br />

Fire protection standard<br />

DIN 5510 1)<br />

AFNOR NF F 16-101<br />

DT-PCI/5A<br />

BS 6853<br />

UNIFER E 10.02.977.3<br />

prEN 45455<br />

Country<br />

Germany<br />

France<br />

Spain<br />

United Kingdom<br />

Italy<br />

European Union<br />

1) also applies in Austria, Switzerland and China<br />

Contact:<br />

Dr. Stephan Schleiermacher<br />

<strong>Polyurethanes</strong> Business Unit<br />

Tel.: ++ 49 214 30 - 3 94 95<br />

stephan.schleiermacher@bayerbms.com<br />

If you have any questions or suggestions,<br />

please contact:<br />

Martin Sixsmith<br />

Tel. +44 1635 563 811<br />

Fax +44 1635 563 272<br />

ukqueries@bayermaterialscience.com


Guide To <strong>Polyurethanes</strong><br />

Fire protection standards (part 2)<br />

RAILWAY VEHICLES<br />

A variety of national fire protection standards for railway vehicles is in force across<br />

Europe (see table for examples). These have developed as a result of differing historical<br />

experiences, evolving concepts of protection and different vehicle designs. Different<br />

countries still use different types of track. This is a reflection of their geography and degree<br />

of urbanization. The passenger evacuation conditions where railway routes feature<br />

large numbers of tunnels or bridges differ from those running across wide open spaces.<br />

Because of these differences, individual countries have different ways of assessing the<br />

various fire risks.<br />

These risks can best be explored from the<br />

point of view of the passenger. When a fire<br />

breaks out on a train, passengers may be<br />

endangered in a variety of ways.<br />

It may be difficult for them to escape or be<br />

rescued if the fire spreads rapidly and there is<br />

a lot of smoke. Smoke gases can have a toxic<br />

effect. In the worst-case scenario, heat may<br />

cause flammable gases to vaporize and collect<br />

under the roof of the train. This gas can spontaneously<br />

ignite in what is known as a “flashover”,<br />

spreading the fire to other parts of the<br />

train.<br />

Different countries use different fire testing<br />

procedures to assess these potential risks.<br />

Our assessment shows that different countries<br />

have independently identified similar types of<br />

risk. In general, flammability, flame spread<br />

patterns and smoke gas density are assessed.<br />

Some testing procedures also assess heat<br />

development and the toxic potential of smoke<br />

gases.<br />

The testing methods used vary widely.<br />

In France and Spain, for example, flame spread<br />

patterns are assessed by looking at the effect<br />

of heat radiation on materials using the<br />

Epiradiateur test. In Germany, on the other<br />

hand, the materials are subjected to a direct<br />

flame in a large test chamber in accordance<br />

with DIN standard 54837 (see photo).<br />

Fire protection standards specify which of the<br />

aforementioned tests a material must pass<br />

and what performance criteria apply to it.<br />

They take account of where a component will<br />

be installed in the vehicle and how large it is.<br />

Additional requirements are also set out for<br />

specific parts such as electrical encapsulation<br />

components.<br />

Based on the fire protection categories of the<br />

vehicle, different material requirements may<br />

be applied to reflect different levels of risk<br />

associated with ease of escape from the vehicle<br />

in question.<br />

For example, passengers can escape more<br />

quickly from a streetcar than they can from<br />

a high-speed train or a vehicle that passes<br />

through tunnels. In Germany, all these factors<br />

are taken into account by fire protection standard<br />

DIN 5510. This standard covers all finished<br />

components and divides trains into four fire<br />

protection categories.<br />

Test results are translated into classes based<br />

on one or more criteria. In Germany, materials<br />

are classified according to three criteria:<br />

A Flammability Class (S1 to S5), a Smoke Development<br />

Class (“SR1 not achieved”, “SR 1” or<br />

“SR2”) and a Drip Class (ST1 or ST2). The fire<br />

protection standard determines the classification<br />

of a material, which in turn governs<br />

the applications for which it can be used. The<br />

This information and our technical advice – whether verbal‚ in writing or by way of trials – are given in good faith but without warranty‚ and this also<br />

applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the information currently<br />

provided – especially that contained in our safety data and technical information sheets – and to test our products as to their suitability for the intended<br />

processes and uses. The application‚ use and processing of our products and the products manufactured by you on the basis of our technical advice<br />

are beyond our control and‚ therefore‚ entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />

Conditions of Sale and Delivery.<br />

Bestell-Nr.: MS 006045, Printed in Germany KL<br />

<strong>Bayer</strong> MaterialScience AG<br />

51368 Leverkusen, Germany<br />

www.bayermaterialscience.com<br />

Baydur 60 FRS in a DIN 54837 testing chamber<br />

standard lists the class ratings which must be<br />

fulfilled for specific applications.<br />

In an effort to ensure uniform assessment of<br />

materials throughout the European Union,<br />

standard EN 45545 “Fire protection on railway<br />

vehicles” has been drafted.<br />

Objections to Part 2 of this draft standard are<br />

currently being filed, and will be assessed soon.<br />

Part 2 deals with the issue of assessing the<br />

fire behavior of materials and components,<br />

and will probably set out four main tests.<br />

These will involve determining the amount of<br />

heat released, the flame spread, the smoke<br />

gas density and the toxicity of the combustion<br />

gases.<br />

Fire protection standard<br />

DIN 5510 1)<br />

AFNOR NF F 16-101<br />

DT-PCI/5A<br />

BS 6853<br />

UNIFER E 10.02.977.3<br />

prEN 45455<br />

1) also applies in Austria, Switzerland and China<br />

Contact:<br />

Dr. Stephan Schleiermacher<br />

<strong>Polyurethanes</strong> Business Unit<br />

Tel.: ++ 49 214 30 - 3 94 95<br />

stephan.schleiermacher@bayerbms.com<br />

If you have any questions or suggestions,<br />

please contact:<br />

Monika Brandt<br />

Tel. ++ 49 214 30 - 3 30 13<br />

Fax ++ 49 214 30 - 5 53 52<br />

monika.brandt@bayerbms.com<br />

Country<br />

Germany<br />

France<br />

Spain<br />

United Kingdom<br />

Italy<br />

European Union

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