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2-27 oxide (pitchblende) sulfate (ous) U3O8 U(SO4) 24H2O olive gn. gn., rhb. 7.31 d. −4H2O, 300 i. 23 i. s. HNO3, H2SO4 11° 963° Uranyl acetate UO2(C2H3O2) 22H2O yel., rhb. 2.89 s. dil. a. 15° −2H2O, 110 9.217° carbonate (rutherfordine) nitrate UO2CO3 UO2(NO3) 26H2O tet. yel., rhb., 1.4967 5.6 2.807 60.2 118 170.3 d. s. al., act. 0° ∞60° sulfate UO2SO43H2O yel. cr. 3.28 v. s. ac., al., et.; i. dil., alk. 16.5° d. 100 18.913.2° 23025° Vanadic acid, meta- Vanadic acid, pyro- Vanadium chloride, di- HVO3 H4V2O7 V VCl2 yel. scales pa. yel., amor. lt. gray, cb. gn., hex., delq. 5.96 3.23 1710 3000 i. i. i. i. 4 al.; s. a. s. a., alk.; i. NH3 s. a., alk., NH4OH s. HNO3, H2SO4; i. aq., alk. 18° chloride, tri- VCl3 pink, tabular, delq. 3.00 s. d. s. al., et. 18° chloride, tetra- VCl4 red lq. 1.816 d. s. d. s. abs. al., et. 30° −109 148.5755mm oxide, di- V2O2 lt. gray cr. 3.64 ign. s. d. i. i. s. abs. al., et., chl., ac. s. a. oxide, tri- V2O3 bk. cr. 4.87 18° 4 1970 sl. s. s. s. HNO3, HF, alk. oxide, tetra- V2O4 blue cr. 4.399 1967 i. i. s. a., alk. oxide, penta- V2O5 red-yel., rhb. 3.357 18° 4 800 d. 1750 0.820° s. a., alk.; i. abs. al. oxychloride, mono- Vanadyl chloride chloride, di- VOCl (VO)2Cl VOCl2 brn. pd. yel. cr. gn., delq. 2.824 3.64 2.88 d. in air i. i. v. s. HNO3 s. HNO3 13° chloride, tri- Water† VOCl3 H2O yel. lq. col. lq., 1.33300 1.829 1800 0.0004218° oxide ZnO wh., amor. 5.47 >1800 0.00042 s. a., alk., NH4Cl; i. NH3 18° peroxide ZnO2 yel. 1.571 expl. 212 0.0022 i. NH4OH; d. a. phosphide Zn3P2 steel gray, cb. 4.55 13° 4 >420 1100 i. s. dil. a. silicate sulfate (zincosite) ZnSiO3 ZnSO4 hex. or rhb.; glass, 1.650 wh., rhb., 1.669 3.52 3.74 1437 i. 15° 4 d. 740 420° 61100° sl. s. al.; s. gly. sulfate ZnSO4H2O col. 3.28 15° 4 d. 238 s. 89.5100° sulfate ZnSO46H2O mn. 2.072 15° 4 −5H2O, 70 s. s. sl. s. al.; i. act.; NH3 sulfate (goslarite) ZnSO47H2O* rhb., 1.4801 1.96616.5° tr. 39 −7H2O, 280 115.20° 653.6100° sulfide (α) (wurzite) ZnS wh., hex., 2.356 4.087 1850 sl. s. al.; i. act.; NH3 150atm subl. 1185 0.0006918° sulfide (β) (sphalerite) ZnS wh., cb.; glass (?) 4.102 i. v. s. a.; i. ac. 25° 2.18–2.25 4 tr. 1020 i. i. s. a. sulfide (blende) ZnS wh., granular 4.04 i. i. v. s. a.; i. ac. sulfite Zirconium ZnSO32aH2O Zr mn. cb., pd. ign. easily 6.4 −2aH2O, 100 1700 d. 200 >2900 0.16 i. d. i. s. H2SO3, NH4OH; i. al. s. HF, aq. reg.; sl. s. a. oxide, di- (baddeleyite) oxide, di- (free from Hf) *Usual commercial form. ZrO2 ZrO2 yel. or brn., mn., 2.19 wh., mn. 5.49 5.73 2700 4300 i. i. i. i. s. H2SO4, HF s. H2SO4, HF †Cf. special tables on water and steam, Tables 2-3, 2-4, 2-5, 2-185, 2-186 and 2-351 through 2-357. NOTE: °F = 9 842.08 502.22 424.15 330.04 502.13 420.14 99.95 217.91 50.94 121.85 157.30 192.75 133.88 149.88 165.88 181.88 86.39 169.33 137.85 173.30 18.02 20.029 131.29 173.04 88.91 65.41 183.50 219.53 225.22 125.42 136.32 117.44 99.42 319.22 297.51 81.41 81.41 97.41 258.17 141.49 161.47 179.49 269.56 287.58 97.47 97.47 97.47 190.51 91.22 123.22 123.22 ⁄5 °C + 32.
2-28 TABLE 2-2 Physical Properties of Organic Compounds* (A), density referred to air al., ethyl alcohol amor., amorphous aq., aqua, water brn., brown bz., benzene c., cubic cc., cubic centimeter chl., chloroform col., colorless cr., crystalline d., decomposes d-, dextrorotatory dl-, dextro-laevorotatory et., ethyl ether expl., explodes gn., green h., hot hex., hexagonal i-, iso-, containing the group (CH 3)2CHi., insoluble ign., ignites l-, laevorotatory lf., leaflets lq., liquid m-, meta mn., monoclinic n-, normal This table of the physical properties includes the organic compounds of most general interest. For the properties of other organic compounds, reference must be made to larger tables in Lange’s Handbook of Chemistry (Handbook Publishers), Handbook of Chemistry and Physics (Chemical Rubber Publishing Co.), Van Nostrand’s Chemical Annual, International Critical Tables (McGraw-Hill), and similar works. The molecular weights are based on the atomic weight values in “Atomic weights of the Elements 2001,” PURE Appl. Chem., 75, 1107, 2003. The densities are given for the temperature indicated and Abbreviations Used in the Table nd., needles o-, ortho or., orange p-, para pd., powder pet., petroleum ether pl., plates pr., prisms rhb., rhombic s., soluble s-, sec-, secondary silv., silvery sl., slightly subl., sublimes sym., symmetrical t-, tertiary tet., tetragonal tri., triclinic uns., unsymmetrical v., very v. s., very soluble v. sl. s., very slightly soluble wh., white yel., yellow (+), right rotation >, greater than 250 296 i. sl. s. 0.86 s. s. 19 (p-) N-tolylacetamide CH3C6H4NHCOCH3 rhb. or mn. 15 1.212 153 306–7 0.09 s. s. 22 1025 Acetic acid anhydride nitrile Acetone Acetonyl urea Acetophenone benzoyl hydride ethanoic acid, vinegar acid acetyl oxide, acetic oxide methyl cyanide propanone, dimethyl ketone dimethyl hydantoin methyl-phenyl ketone CH3CO2H (CH3CO)2O CH3CN CH3COCH3 (CH3)2 CH3COC6H5 col. lq. col. lq. col. lq. col. lq. tri./al. lf. 20/4 1.049 20/4 1.082 20/4 0.783 20/4 0.792 15/15 1.033 16.7 −73 −41 −94.6 175 20.5 118.1 139.6 81.6–2.0 56.5 subl. 202.3 ∞ 12 c. ∞ ∞ s. ∞ ∞ ∞ ∞ s. s. ∞ ∞ ∞ ∞ s. 749 Acetyl-chloride -phenylenediamine (-p) Acetylene ethanoyl chloride amino-acetanilide (p) ethyne; ethine CH3COCl C2H3ONHC6H4NH2 HCCH col. lq. nd./aq. col. gas 20/4 1.105 (A) 0.906 −112.0 162 −81.5 51–2 i. d. s. h. s. d. v. s. s. ∞ v. s. 891 −84760 100 cc. 18 600 cc. 18 dichloride (cis) 1,2-dichloroethene CHCl:CHCl col. lq. 1.29115/4 −80.5 60.3 0.3520 ∞ ∞ (trans) dioform CHCl:CHCl col. lq. 1.26515/4 −50 48.4 0.6320 ∞ ∞ Aconitic acid Acridine Acrolein ethylene aldehyde Acrylic acid nitrile Adipic acid equisetic acid; citridic acid acrylic aldehyde, propenal propenoic acid vinyl cyanide hexandioc acid, adipinic acid C3H3(CO2H)3 C6H4 < (CH)(N) > C6H4 CH2:CHCHO CH2:CHCO2H CH2:CHCN (CH2CH2CO2H)2 cr./aq. rhb./aq. al. col. lq. col. lq. col. lq. mn. pr. 20/4 0.841 16/4 1.062 20 0.811 25/4 1.360 192 d. 110–1 −87.7 12–13 −82 151–3 346 52.5 141–2 78–9 265 15 33 sl. s. h. 40 ∞ s. sl. s. s. s. ∞ v. sl. s. s. s. 10 1.415 v. s. 0.615 amide nitrile Adrenaline (1-) (3,4,1) Alanine (α) (dl-) Aldol acetaldol tetramethylene 1-suprarenine 2-hydroxybutyraldehyde (CH2CH2CONH2)2 (CH2CH2CN)2 C6H3(OH)2(CHOHCH2NHCH3) CH3CH(NH2)CO2H CH3CH(OH)CH2COH cr. pd. col. oil col. pd. nd./aq. col. lq. 19/19 0.951 20/4 1.103 226–7 1 d. 207–11 295 d. 295 subl. >200 83 12 0.4 v. sl. s. 20 0.03 17 22 s. v. sl. s. v. sl. s. v. sl. s. i. i. 20 Alizarin Allyl alcohol bromide Anthraquinoic acid propen-1-ol-3,propenyl alcohol 3-bromo-propene-1 C6H4(CO)2C6H2(OH)2 CH2:CHCH2OH CH2:CHCH2Br red rhb. col. lq. lq. 20/4 0.854 20/4 1.398 289–90 −129 −119.4 430 96.6 70–1 ∞ 100 0.03 ∞ ∞ v. s. ∞ s. v. s. ∞ 753 chloride thiocyanate (i) thiourea 3-chloro-propene-1 mustard oil thiosinamide CH2:CHCH2Cl CH2:CHCH2NCS CH2:CHCH2NHCSNH2 col. lq. col. oil col. pr. 20/4 0.938 20/4 1.013 20/20 1.219 −136.4 −80 77–8 44.6 152 i.
Page 2 and 3: Copyright © 2008, 1997, 1984, 1973
Page 4 and 5: Bruce E. Poling Department of Chemi
Page 6 and 7: 2-132 Hydrogen Chloride (HCl) . . .
Page 8 and 9: TRANSPORT PROPERTIES Introduction .
Page 10 and 11: 2-7 TABLE 2-1 Physical Properties o
Page 12 and 13: 2-9 phosphate, dibasic (NH4) 2HPO4
Page 14 and 15: 2-11 chloride CdCl22aH2O col., mn.,
Page 16 and 17: 2-13 Chromium trioxide (chromic aci
Page 18 and 19: 2-15 phosphate (vivianite) silicate
Page 20 and 21: 2-17 oxide, monooxide, red (minium)
Page 22 and 23: 2-19 chloride (calomel) HgCl wh., t
Page 24 and 25: 2-21 Phosphoric acid, hypo- H4P2O6
Page 26 and 27: 2-23 Selenium Se8 steel gray 4.825
Page 28 and 29: 2-25 sulfate Na2SO4 col., hex. 884
Page 32 and 33: 2-29 Amino-diphenylamine (p-) H2NC6
Page 34 and 35: 2-31 768 Benzoin (dl-) C6H5COCHOHC6
Page 36 and 37: 2-33 20 Carvacrylamine (2-,1-,4-) H
Page 38 and 39: 2-35 Dibenzothiazyl-disulfide (2-,2
Page 40 and 41: 2-37 73/4 Diphenyl C6H5C6H5 col. mn
Page 42 and 43: 2-39 15 Glutaric acid CH2(CH2CO2H)2
Page 44 and 45: 2-41 25 Methoxy-methoxyethanol CH3(
Page 46 and 47: 2-43 62 -naphthalene (α-) C10H7NO2
Page 48 and 49: 2-45 Pulegol (iso-)(d-) C10H17OH co
Page 50 and 51: 2-47 -phenol (2-,3-,6-) (NO2)3C6H2O
Page 52 and 53: Paraffins Name Cmpd. No. Formula Me
Page 54 and 55: VAPOR PRESSURES OF PURE SUBSTANCES
Page 56 and 57: VAPOR PRESSURES OF PURE SUBSTANCES
Page 58 and 59: 2-55 TABLE 2-8 Vapor Pressure of In
Page 60 and 61: 2-57 121 Diphenyl ether C12H10O 101
Page 62 and 63: 2-59 243 -Methyl styrene C9H10 98-8
Page 64 and 65: TABLE 2-9 Vapor Pressures of Inorga
Page 66 and 67: TABLE 2-9 Vapor Pressures of Inorga
Page 68 and 69: TABLE 2-10 Vapor Pressures of Organ
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TABLE 2-10 Vapor Pressures of Organ
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TABLE 2-10 Vapor Pressures of Organ
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FIG. 2-1 Vapor pressures of H 3PO 4
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TABLE 2-14 Water Partial Pressure,
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VAPOR PRESSURES OF SOLUTIONS 2-85 T
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TABLE 2-17 Total Pressure, bar, of
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TABLE 2-19 Partial Pressures of H2O
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2-91 TABLE 2-24 Mole Percentages of
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2-93 TABLE 2-26 Total Vapor Pressur
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CHART FOR GASES AT HIGH PRESSURES T
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TABLE 2-31 Density (kg/m 3 ) of Mer
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2-99 60 o-Cresol C 7H 8O 95-48-7 10
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2-101 182 Hydrazine H 4N 2 302-01-2
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2-103 304 Propylbenzene C9H12 103-6
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TABLE 2-42 Barium Chloride (BaCl2)*
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DENSITIES OF AQUEOUS INORGANIC SOLU
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TABLE 2-73 Potassium Carbonate (K2C
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DENSITIES OF AQUEOUS ORGANIC SOLUTI
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TABLE 2-117 Glycerol* DENSITIES OF
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TABLE 2-119 Densities of Aqueous So
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TABLE 2-120 Approximate Specific Gr
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2-127 1 Calcium bicarbonate Ca(HCO3
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2-129 TABLE 2-122 Solubilities of I
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TABLE 2-125 Henry’s Constant H fo
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UNITS CONVERSIONS For this subsecti
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THERMAL EXPANSION 2-135 TABLE 2-136
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UNITS CONVERSIONS Joule-Thomson coe
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CRITICAL CONSTANTS 2-139 TABLE 2-14
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CRITICAL CONSTANTS 2-141 TABLE 2-14
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INTRODUCTION The compressibility fa
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-149 Heats of Fusion of Orga
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2-151 60 o-Cresol C 7H 8O 95-48-7 1
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2-153 182 Hydrazine H 4N 2 302-01-2
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2-155 303 Propyl amine C3H9N 107-10
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TABLE 2-151 Heat Capacities of the
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2-165 TABLE 2-153 Heat Capacities o
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2-167 117 Dimethyl sulfide C 2H 6S
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2-169 237 2-Methyl-2-propanol C4H10
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TABLE 2-154 Specific Heats of Organ
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TABLE 2-154 Specific Heats of Organ
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2-175 237 2-Methyl-2-propanol C4H10
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2-177 61 p-Cresol C7H8O 106-44-5 10
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2-179 184 Hydrogen bromide HBr 1003
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2-181 304 305 306 307 308 309 310 3
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UNITS CONVERSIONS For this subsecti
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TABLE 2-176 and Solids Specific Hea
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TABLE 2-178 Heats and Free Energies
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2-195 TABLE 2-179 Enthalpies and Gi
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2-197 117 Dimethyl sulfide C 2H 6S
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2-199 238 2-Methyl propene C 4H 8 1
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TABLE 2-180 Ideal Gas Sensible Enth
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Aluminum bromide aq AlBr3 +85.3 chl
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TABLE 2-182 Heats of Solution of In
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EXPLANATION OF TABLES The following
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TABLE 2-185 Thermodynamic Propertie
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2-211 TABLE 2-187 Thermodynamic Pro
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2-213 97 0.44878 0.62667 1.5957 5.4
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2-215 Pressure (MPa) −200 −100
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2-219 Pressure (MPa) −200 0 200 4
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2-223 200.00 100.00 30.368 0.032930
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2-225 0.60 0.04 0.58 0.38 0.0218 0.
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2-227 0.60 0.07 0.56 0.37 0.0457 0.
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TABLE 2-194 Saturated Bromine* THER
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2-233 250.00 1.0000 10.770 0.092855
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2-235 Single-Phase Properties 100.0
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2-243 114.00 1.3517 1.9228 0.52008
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TABLE 2-201 Thermophysical Properti
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2-249 TABLE 2-205 Thermophysical Pr
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TABLE 2-206 Saturated Chloroform (R
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THERMODYNAMIC PROPERTIES 2-267 FIG.
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2-271 200.00 1.0000 0.61498 1.6261
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TABLE 2-232 Saturated Mercury* THER
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FIG. 2-12 Enthalpy-log-pressure dia
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2-309 Pressure (MPa) −200 −100
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FIG. 2-14 Mollier diagram for nitro
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2-333 Pressure (MPa) 150 200 250 30
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TABLE 2-253 Saturated Refrigerant 1
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2-347 Pressure (MPa) 0 100 200 300
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TABLE 2-261 Thermodynamic Propertie
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Pressure, bar 30 20 15 10 8 6 4 2 1
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TABLE 2-265 Saturated R-401B (SUVA
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2-371 FIG. 2-25 Enthalpy-log-pressu
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2-393 Pressure (MPa) 50 100 150 200
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2-395 305.00 1.9749 1.1138 0.89779
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2-399 310.00 1.7307 0.98768 1.0125
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2-401 TABLE 2-299 Saturated Sodium
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TABLE 2-302 Saturated SUVA AC 9000
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2-415 800 5 0.77805 1.2853 56.576 6
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TABLE 2-308 Surface Tension (N/m) o
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2-421 TABLE 2-312 Vapor Viscosity o
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2-423 119 Dimethyl terephthalate C
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2-425 241 Methylpropyl sulfide C4H1
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2-427 TABLE 2-313 Viscosity of Inor
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2-429 119 Dimethyl terephthalate C
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2-431 241 Methylpropyl sulfide C4H1
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2-433 TABLE 2-314 Vapor Thermal Con
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2-435 117 Dimethyl sulfide C2H6S 75
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2-437 238 2-Methyl propene C 4H 8 1
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2-439 TABLE 2-315 Thermal Conductiv
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2-441 116 Dimethylsilane C 2H 8Si 1
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2-443 237 2-Methyl-2-propanol C 4H
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TABLE 2-316 Transport Properties of
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2-447 Methyl acetate Vinyl acetate
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TRANSPORT PROPERTIES 2-449 FIG. 2-3
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TABLE 2-321 Prandtl Number of Air*
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TRANSPORT PROPERTIES 2-455 TABLE 2-
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TABLE 2-328 Thermal Conductivity of
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PREDICTION AND CORRELATION OF PHYSI
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TABLE 2-336 Ambrose Group a Contrib
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TABLE 2-338 Fedors*Method Atomic an
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Example The vapor pressure of n-dec
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Rg = = 1.505 × 10−10 2π(1.918
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Expected uncertainty: 5 to 10 perce
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Interpolation of the Pr values in T
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method. Although Eqs. (2-33) and (2
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Prog., 69, 7 (1973): 83; Lee, B. I.
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From Eq. (2-52): CP = (307.93) 0.79
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− 0.000607(1.06) 8 =−0.301 B (1
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2-501 Table 2-352 Acentric Deviatio
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Liquids For most liquids, the satur
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Numerous methods have been develope
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Group interactions: m/n αmn group
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TABLE 2-358 Correlation Parameters
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Calculation using Eq. (2-112): k =
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where σm = surface tension of the
Page 520 and 521:
The values recommended in the DIPPR
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