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2-35 Dibenzothiazyl-disulfide (2-,2′-) (C6H4NSC)2S2 cr. 1.50 180 d. i. 18 Dibensoyl methane (C6H5CO)2CH2 rhb./al. 78 219–21 i. 4.420 s. 25/25 Dibensyl-amine (C6H5CH2)2NH col. oil 1.028 −26 268–71250 i. s. s. -aniline C6H5N(CH2C6H5)2 pr./al. 70–1 >300 i. v. s. h. s. ketone (C6H5CH2)2CO cr. 34–5 330.6 i. 12 phthalate (o-) C6H4(CO2CH2C6H5)2 pr./al. 42–3 274 v. sl. s. s. s. 14 succinate (CH2CO2CH2C6H5)2 lf./al. 45–6 238 i. s. s. 20/4 Dibromo-benzene (o-) C6H4Br2 col. lq. 1.956 1.8 221–2 i. s. s. 20/4 (m-) C6H4Br2 col. lq. 1.952 −6.9 219755 i. s. s. 18 (p-) C6H4Br2 pl./al. 2.261 87–8 218.6758 i. 1.6 7125 -diphenyl (4-,4′-) BrC6H4C6H4Br mn. pr. 1.897 164–5 355–60 i. v. sl. s. h. 20/4 Dibutyl-adipate (n-) (CH2CH2CO2C4H9)2 col. lq. 0.965 −38 18314 i. ∞ ∞ 25 (i-) (CH2CH2CO2C4H9)2 col. lq. 0.950 −20 278–80 i. 20/20 -amine (n-) (C2H5CH2CH2)2NH col. lq. 0.768 159761 ∞ ∞ ∞ 25/4 (i-) [(CH3)2CHCH2]2NH col. lq. 0.741 −70 139–40 v. sl. s. s. s. 10 -p-aminophenol (s-) (C4H9)2NC6H4OH lq. 170 i. -aniline (n-) C6H5N(C4H9)2 lq. 262.8 i. ∞ ∞ 20/4 carbonate (n-) CO(OC4H9)2 col. lq. 0.924 207740 i. s. 15 (i-) CO(OC4H9)2 col. lq. 0.919 190 i. (s-) CO(OC4H9)2 col. lq. 178–80 20/20 ether (n-) (C2H5CH2CH2)2O lq. 0.769 −98 142.4
2-36 TABLE 2-2 <strong>Physical</strong> Properties of Organic Compounds (Continued) Formula Form <strong>and</strong> Specific Melting Boiling Solubility in 100 parts Name Formula weight color gravity point, °C point, °C Water Alcohol Ether 20/4 tartrate (d-) (CHOHCO2C2H5)2 lq. 1.204 17 280 sl. s. ∞ ∞ 755 -toluidine (o-) CH3C6H4N(C2H5)2 lq. 208–9 i. s. s. (m-) CH3C6H4N(C2H5)2 lq. 231–2 i. s. s. 15.5 (p-) CH3C6H4N(C2H5)2 lq. 0.924 228–9 i. 25/4 Diethyleneglycol dinitrate O(CH2CH2ONO2)2 lq. 1.377 −11.3 i. −30 Difluorodichloromethane F2CCl2 gas 1.486 −155 −29.2 5.7 cc. 26 s. s. 10 Diglycerol [(HO) 2C3H5]2O lq. 220–30 s. h. i. Dihydroxy-dinaphthyl (α-) (HOC10H6)2 pl./al. 300 i. s. v. s. (-2,-2′,-1,-1′) (HOC10H6)2 nd./al. 218 subl. i. s. v. s. -diphenyl (4-,4′-) (HOC6H4)2 rhb./al. 1.25 270–2 subl. sl. s. v. s. v. s. 25 -ethyl formal (β-) CH2(OCH2CH2OH)2 lq. 1.154 −5.3 264 ∞ -naphthalene (1-,5-) C10H6(OH)2 pr./aq. 258–60 d. sl. s. s. v. s. (1-,8-) C10H6(OH)2 nd. 140 sl. s. h. v. s. 55/55 Dimethoxy-benzene (p-) (CH3O)2C6H4 lf. 1.053 56 212.6 v. sl. s. v. s. v. s. -diphenylamine (4-,4′-) HN(C6H4OCH3)2 cr. 103 i. 15.6 -ethyl adipate (CH2)4(CO2C2H4OCH3)2 lq. 1.075 145–502 5 20/4 Dimethyl adipate [(CH2)2CO2CH3]2 col. lq. 1.063 10–1 11518 i. 0/4 -amine (CH3)2NH col. lq. 0.680 −96 7.4 v. s. s. s. -aminoasobenzene (p-) C6H5N:NC6H4N(CH3)2 yel./al. 116–7 d. i. s. s. 20/4 -aminoethanol (CH3)2NCH2CH2OH col. lq. 0.887 135756 ∞ -aminophenol (m-) (CH3)2NC6H4OH nd. 85 265–8 sl. s. h. s. s. 20/4 -aniline (CH3)2NC6H5 yel. lq. 0.956 2.5 193 i. s. s. sulfonic acid (m-) (CH3)2NC6H4SO3H cr. d. 266 s. (p-) (CH3)2NC6H4SO3HH2O pr. 257 s. h. v. sl. s. v. sl. s. 20/4 carbonate OC(OCH3)2 col. lq. 1.070 0.5 89–90 i. ∞ ∞ 18 ether CH3OCH3 gas −138.5 −23.7 3700 cc. s. s. 25 -formamide HCON(CH3)2 lq. 0.945 −58.3 152.8 ∞ fumarate (:CHCO2CH3)2 col. tri. 102 192 i. sl. s. sl. s. 15.6 glutarate (CH2)3(CO2CH3)2 lq. 1.089 −37 13050 20 glyoxime (CH3C:NOH)2 col. cr. 240–6 0.06 v. s. v. s. 20/4 -naphthalene (1-,4-) C10H6(CH3)2 lq. 1.016 360 i. 0.8 c. v. s. (β,β′-) (C10H7)2CH2 nd./al. 92 i. s. 20 Dinitro-anisole (1-)(2-,4-) CH3OC6H3(NO2)2 col. mn. 1.341 94–5 sl. s. h. 1.520 18 -benzene (o-) C6H4(NO2)2 col. mn. 1.59 117–8 319774 0.01 c. 1.921 20/4 (m-) C6H4(NO2)2 col. rhb. 1.575 89.8 300–2 0.399 320 18 (p-) C6H4(NO2)2 col. mn. 1.625 173–4 299777 0.18100 0.1821 sulfonic acid (2-,4-)(1-) (NO2)2C6H3SO3H3H2O pr. 106–8 s. s. v. sl. s. 25 -benzoic acid (2-,4-) (NO2)2C6H3CO2H cr./aq. 179–80 1.85 s. (3-,5-) (NO2)2C6H3CO2H mn. pr. 204–5 subl. s h. v. s. sl. s. -benzophenone (4-,4′-) (NO2C6H4)2CO col. nd. 189 i. 20 -diphenyl (4-,4′-) (NO2C6H4)2 nd./al. 1.445 233 i. 1.5 (2-,4′-) (NO2C6H4)2 mn. 1.474 93.5 i. v. s. h. -naphthalene (1-,5-) C10H6(NO2)2 nd. 216 subl. i. (1-,8-) C10H6(NO2)2 rhb. 170–2 d. i. 0.2 c. 20 Dinitro-phenol (2-,3-) (NO2)2C6H3OH yel. mn. 1.681 144–5 sl. s. v. s. h. v. s. 24 (2-,4-) (NO2)2C6H3OH yel. rhb. 1.683 114–5 subl. 0.5 c. 420 v. s. h. (2-,6-) (NO2)2C6H3OH yel. rhb. 63–4 s. h. s. h. s. -salicylic acid (3-,5-) (NO2)2C6H2(OH)CO2HH2O pl./aq. 173 d. s. c. v. s. v. s. -stilbene (4-,4′-) (NO2C6H4CH:)2 yel. lf. 210–6 i. v. sl. s. v. sl. s. 71 -toluene (2-,4-) (NO2)2C6H3CH3 nd. 1.321 70 300 0.0322 1.215 916 206.19 163.26 163.26 163.26 196.12 120.91 166.17 286.32 286.32 186.21 136.15 160.17 160.17 138.16 229.27 262.30 174.19 45.08 225.29 89.14 137.18 121.18 201.24 219.26 90.08 46.07 73.09 144.13 160.17 116.12 156.22 156.22 171.24 171.24 118.09 194.18 126.13 62.13 178.14 110.15 254.33 268.35 268.35 198.13 168.11 168.11 168.11 302.22 212.12 212.12 272.21 244.20 244.20 218.17 218.17 184.11 184.11 184.11 246.13 270.24 182.13 111 (3-,4-) (NO2)2C6H3CH3 182.13 nd. 1.259 60–1 i. 111 (3-,5-) (NO2)2C6H3CH3 182.13 mn. pr. 1.277 92–3 subl. sl. s. s. h. s. 20/4 Dioxane O < (CH2CH2)2 > O 88.11 col. lq. 1.033 9.5–10.5 101.1 ∞ s. s. 18 Dipentene C10H16 136.23 col. lq. 0.865 178 i.
Page 2 and 3: Copyright © 2008, 1997, 1984, 1973
Page 4 and 5: Bruce E. Poling Department of Chemi
Page 6 and 7: 2-132 Hydrogen Chloride (HCl) . . .
Page 8 and 9: TRANSPORT PROPERTIES Introduction .
Page 10 and 11: 2-7 TABLE 2-1 Physical Properties o
Page 12 and 13: 2-9 phosphate, dibasic (NH4) 2HPO4
Page 14 and 15: 2-11 chloride CdCl22aH2O col., mn.,
Page 16 and 17: 2-13 Chromium trioxide (chromic aci
Page 18 and 19: 2-15 phosphate (vivianite) silicate
Page 20 and 21: 2-17 oxide, monooxide, red (minium)
Page 22 and 23: 2-19 chloride (calomel) HgCl wh., t
Page 24 and 25: 2-21 Phosphoric acid, hypo- H4P2O6
Page 26 and 27: 2-23 Selenium Se8 steel gray 4.825
Page 28 and 29: 2-25 sulfate Na2SO4 col., hex. 884
Page 30 and 31: 2-27 oxide (pitchblende) sulfate (o
Page 32 and 33: 2-29 Amino-diphenylamine (p-) H2NC6
Page 34 and 35: 2-31 768 Benzoin (dl-) C6H5COCHOHC6
Page 36 and 37: 2-33 20 Carvacrylamine (2-,1-,4-) H
Page 40 and 41: 2-37 73/4 Diphenyl C6H5C6H5 col. mn
Page 42 and 43: 2-39 15 Glutaric acid CH2(CH2CO2H)2
Page 44 and 45: 2-41 25 Methoxy-methoxyethanol CH3(
Page 46 and 47: 2-43 62 -naphthalene (α-) C10H7NO2
Page 48 and 49: 2-45 Pulegol (iso-)(d-) C10H17OH co
Page 50 and 51: 2-47 -phenol (2-,3-,6-) (NO2)3C6H2O
Page 52 and 53: Paraffins Name Cmpd. No. Formula Me
Page 54 and 55: VAPOR PRESSURES OF PURE SUBSTANCES
Page 56 and 57: VAPOR PRESSURES OF PURE SUBSTANCES
Page 58 and 59: 2-55 TABLE 2-8 Vapor Pressure of In
Page 60 and 61: 2-57 121 Diphenyl ether C12H10O 101
Page 62 and 63: 2-59 243 -Methyl styrene C9H10 98-8
Page 64 and 65: TABLE 2-9 Vapor Pressures of Inorga
Page 66 and 67: TABLE 2-9 Vapor Pressures of Inorga
Page 68 and 69: TABLE 2-10 Vapor Pressures of Organ
Page 84 and 85: FIG. 2-1 Vapor pressures of H 3PO 4
Page 86 and 87: TABLE 2-14 Water Partial Pressure,
Page 88 and 89:
VAPOR PRESSURES OF SOLUTIONS 2-85 T
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TABLE 2-17 Total Pressure, bar, of
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TABLE 2-19 Partial Pressures of H2O
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2-91 TABLE 2-24 Mole Percentages of
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2-93 TABLE 2-26 Total Vapor Pressur
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CHART FOR GASES AT HIGH PRESSURES T
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TABLE 2-31 Density (kg/m 3 ) of Mer
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2-99 60 o-Cresol C 7H 8O 95-48-7 10
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2-101 182 Hydrazine H 4N 2 302-01-2
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2-103 304 Propylbenzene C9H12 103-6
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TABLE 2-42 Barium Chloride (BaCl2)*
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DENSITIES OF AQUEOUS INORGANIC SOLU
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TABLE 2-73 Potassium Carbonate (K2C
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DENSITIES OF AQUEOUS ORGANIC SOLUTI
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TABLE 2-117 Glycerol* DENSITIES OF
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TABLE 2-119 Densities of Aqueous So
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TABLE 2-120 Approximate Specific Gr
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2-127 1 Calcium bicarbonate Ca(HCO3
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2-129 TABLE 2-122 Solubilities of I
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TABLE 2-125 Henry’s Constant H fo
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UNITS CONVERSIONS For this subsecti
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THERMAL EXPANSION 2-135 TABLE 2-136
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UNITS CONVERSIONS Joule-Thomson coe
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CRITICAL CONSTANTS 2-139 TABLE 2-14
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CRITICAL CONSTANTS 2-141 TABLE 2-14
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INTRODUCTION The compressibility fa
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-149 Heats of Fusion of Orga
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2-151 60 o-Cresol C 7H 8O 95-48-7 1
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2-153 182 Hydrazine H 4N 2 302-01-2
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2-155 303 Propyl amine C3H9N 107-10
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TABLE 2-151 Heat Capacities of the
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2-165 TABLE 2-153 Heat Capacities o
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2-167 117 Dimethyl sulfide C 2H 6S
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2-169 237 2-Methyl-2-propanol C4H10
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TABLE 2-154 Specific Heats of Organ
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TABLE 2-154 Specific Heats of Organ
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2-175 237 2-Methyl-2-propanol C4H10
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2-177 61 p-Cresol C7H8O 106-44-5 10
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2-179 184 Hydrogen bromide HBr 1003
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2-181 304 305 306 307 308 309 310 3
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UNITS CONVERSIONS For this subsecti
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TABLE 2-176 and Solids Specific Hea
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TABLE 2-178 Heats and Free Energies
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2-195 TABLE 2-179 Enthalpies and Gi
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2-197 117 Dimethyl sulfide C 2H 6S
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2-199 238 2-Methyl propene C 4H 8 1
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TABLE 2-180 Ideal Gas Sensible Enth
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Aluminum bromide aq AlBr3 +85.3 chl
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TABLE 2-182 Heats of Solution of In
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EXPLANATION OF TABLES The following
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TABLE 2-185 Thermodynamic Propertie
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2-211 TABLE 2-187 Thermodynamic Pro
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2-213 97 0.44878 0.62667 1.5957 5.4
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2-215 Pressure (MPa) −200 −100
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2-219 Pressure (MPa) −200 0 200 4
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2-223 200.00 100.00 30.368 0.032930
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2-225 0.60 0.04 0.58 0.38 0.0218 0.
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2-227 0.60 0.07 0.56 0.37 0.0457 0.
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TABLE 2-194 Saturated Bromine* THER
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2-233 250.00 1.0000 10.770 0.092855
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2-235 Single-Phase Properties 100.0
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2-243 114.00 1.3517 1.9228 0.52008
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TABLE 2-201 Thermophysical Properti
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2-249 TABLE 2-205 Thermophysical Pr
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TABLE 2-206 Saturated Chloroform (R
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THERMODYNAMIC PROPERTIES 2-267 FIG.
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2-271 200.00 1.0000 0.61498 1.6261
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TABLE 2-232 Saturated Mercury* THER
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FIG. 2-12 Enthalpy-log-pressure dia
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2-309 Pressure (MPa) −200 −100
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FIG. 2-14 Mollier diagram for nitro
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2-333 Pressure (MPa) 150 200 250 30
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TABLE 2-253 Saturated Refrigerant 1
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2-347 Pressure (MPa) 0 100 200 300
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TABLE 2-261 Thermodynamic Propertie
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Pressure, bar 30 20 15 10 8 6 4 2 1
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TABLE 2-265 Saturated R-401B (SUVA
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2-371 FIG. 2-25 Enthalpy-log-pressu
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2-393 Pressure (MPa) 50 100 150 200
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2-395 305.00 1.9749 1.1138 0.89779
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2-399 310.00 1.7307 0.98768 1.0125
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2-401 TABLE 2-299 Saturated Sodium
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TABLE 2-302 Saturated SUVA AC 9000
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2-415 800 5 0.77805 1.2853 56.576 6
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TABLE 2-308 Surface Tension (N/m) o
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2-421 TABLE 2-312 Vapor Viscosity o
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2-423 119 Dimethyl terephthalate C
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2-425 241 Methylpropyl sulfide C4H1
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2-427 TABLE 2-313 Viscosity of Inor
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2-429 119 Dimethyl terephthalate C
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2-431 241 Methylpropyl sulfide C4H1
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2-433 TABLE 2-314 Vapor Thermal Con
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2-435 117 Dimethyl sulfide C2H6S 75
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2-437 238 2-Methyl propene C 4H 8 1
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2-439 TABLE 2-315 Thermal Conductiv
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2-441 116 Dimethylsilane C 2H 8Si 1
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2-443 237 2-Methyl-2-propanol C 4H
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TABLE 2-316 Transport Properties of
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2-447 Methyl acetate Vinyl acetate
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TRANSPORT PROPERTIES 2-449 FIG. 2-3
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TABLE 2-321 Prandtl Number of Air*
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TRANSPORT PROPERTIES 2-455 TABLE 2-
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TABLE 2-328 Thermal Conductivity of
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PREDICTION AND CORRELATION OF PHYSI
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TABLE 2-336 Ambrose Group a Contrib
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TABLE 2-338 Fedors*Method Atomic an
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Example The vapor pressure of n-dec
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Rg = = 1.505 × 10−10 2π(1.918
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Expected uncertainty: 5 to 10 perce
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Interpolation of the Pr values in T
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method. Although Eqs. (2-33) and (2
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Prog., 69, 7 (1973): 83; Lee, B. I.
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From Eq. (2-52): CP = (307.93) 0.79
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− 0.000607(1.06) 8 =−0.301 B (1
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2-501 Table 2-352 Acentric Deviatio
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Liquids For most liquids, the satur
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Numerous methods have been develope
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Group interactions: m/n αmn group
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TABLE 2-358 Correlation Parameters
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Calculation using Eq. (2-112): k =
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where σm = surface tension of the
Page 520 and 521:
The values recommended in the DIPPR
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