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2-37 73/4 Diphenyl C6H5C6H5 col. mn. 0.992 69–70 254.9 i. 1020 6.620 20/20 -amine C6H5NHC6H5 col. mn. 1.160 52.9 302 0.0325 5619.5 s. 14 carbonate CO(OC6H5)2 nd./al. 1.272 80 302–6 i. v. s. s. 40 -chloroarsine (C6H5)2AsCl rhb. 1.583 43–4 d. 327 0.2 d. 20 s. 50/50 -ethane (C6H5CH2)2 col. pr. 0.978 52–3 284 i. s. v. s. 20 ether C6H5OC6H5 col. rhb. 1.073 27 259 v. sl. s. s. ∞ 20 guanidine (C6H5NH)2C:NH mn./al. 147–8 d. > 170 v. sl. s. 9 sl. s. 26/4 -methane (C6H5)2CH2 col. pr. 1.001 26–7 265 i. v. s. v. s. phenylenediamine (p-) (C6H5NH)2C6H4 cr. 152 i. succinate (CH2CO2C6H5)2 lf./al. 122–3 330 i. s. 15/15 sulfide (C6H5)2S col. lq. 1.119
2-38 TABLE 2-2 <strong>Physical</strong> Properties of Organic Compounds (Continued) Formula Form <strong>and</strong> Specific Melting Boiling Solubility in 100 parts Name Formula weight color gravity point, °C point, °C Water Alcohol Ether laurate mercaptan methacrylate naphthylamine (α-) CH3(CH2)10CO2C2H5 CH3CH2SH CH2:C(CH3)CO2C2H5 C10H7NHC2H5 oil lq. col. lq. oil 13/4 0.868 20/4 0.839 15.6 0.913 20/4 1.060 −10.7 −121 269 36–7 118 303 i. 1.5 i. s. s. s. ∞ s. s. 723 naphthyl ether (α-) nitrate C10H7OC2H5 C2H5ONO2 cr. col. lq. 20/20 1.061 25/4 1.100 5.5 −102 276.4 87–8 i. i. 1.3 s. s. s. s. 55 nitrite oleate C2H5ONO C17H33CO2C2H5 lq. oil 15.5 0.900 25 0.867 290 −127 253.5 267.5 201 201–2 201–2 ign. >150 293–5 14.5 24.9 sl. s. v. sl. s. v. sl. s. sl. s. sl. s. i. v. sl. s. i. v. sl. s. h. i. i. ∞ ∞ ∞ s. s. h. s. h. s. ∞ ∞ ∞ s. s. s. ∞ −20 −92 −21 v. s. v. s. v. s. (m-) (CH2O)3 wh. 65 1.17 64 114.5759 2125 (p-) Formamide Formanilide (CH2O)xxH2O HCONH2 HCONHC6H5 amor. lq. mn. 20/4 1.139 15/15 1.147 150–60 2 47 subl. 193 216 18 20–30 ∞ s. i. ∞ s. i. v. sl. s. 120 Formic acid Fructose HCO2H CH2OH(CHOH)3COCH2OH col. lq. nd./aq. 20/4 1.220 17.5 1.669 8.6 95–105 100.8 sl. s. ∞ v. s. v. s. ∞ 8 s. 18 Fuchsin Fulminic acid C20H19N3HCl C:NOH red 1.22 d. >200 0.3 s. i. Fumaric acid (trans-) HO2CCH:CHCO2H col. pr. 20/4 1.635 286–7 290 0.717 5.830 0.725 Furfural C4H3OCHO lq. 20/4 1.159 −38.7 161.7760 9.113 Furfuran C4H4O col. lq. 20/4 0.937 31–2 ∞ ∞ 756 Furfuryl acetate alcohol CH3CO2CH2C4H3O C4H3OCH2OH col. oil oil 20/4 1.118 25/4 1.129 175–7 169.5 i. i. s. s. s. s. 752 butyrate propionate Furoic acid G-acid, K salt (2-)(6-,8-) Na salt (2-)(6-,8-) Galactose (d-)(α-) C3H7CO2CH2C4H3O C2H5CO2CH2C4H3O C4H3OCO2H HOC10H5(SO3K)2 HOC10H5(SO3Na)2 C5H11O5CHO col. lq. col. lq. mn. pr. cr. cr. pr. 20/4 1.053 20/4 1.109 133–4 165.5 212–3 195–6 230–2 ∞ v. sl. s. v. sl. s. 15 3.6 25 8 20 34 0 10.3 s. s. s. s. 0.6 s. ∞ ∞ s. 40 Gallic acid (3-,4-,5-) (HO) 3C6H2CO2HH2O mn./aq. 4/4 1.694 d. 220 113 2815 2.515 Gamma acid (2-,8-,6-) Geraniol Glucose (d-)(α-) C10H5(NH2)(OH)SO3H C9H15CH2OH C5H11O5CHO cr. col. lq. rhb. 15 0.883 25 1.544
Page 2 and 3: Copyright © 2008, 1997, 1984, 1973
Page 4 and 5: Bruce E. Poling Department of Chemi
Page 6 and 7: 2-132 Hydrogen Chloride (HCl) . . .
Page 8 and 9: TRANSPORT PROPERTIES Introduction .
Page 10 and 11: 2-7 TABLE 2-1 Physical Properties o
Page 12 and 13: 2-9 phosphate, dibasic (NH4) 2HPO4
Page 14 and 15: 2-11 chloride CdCl22aH2O col., mn.,
Page 16 and 17: 2-13 Chromium trioxide (chromic aci
Page 18 and 19: 2-15 phosphate (vivianite) silicate
Page 20 and 21: 2-17 oxide, monooxide, red (minium)
Page 22 and 23: 2-19 chloride (calomel) HgCl wh., t
Page 24 and 25: 2-21 Phosphoric acid, hypo- H4P2O6
Page 26 and 27: 2-23 Selenium Se8 steel gray 4.825
Page 28 and 29: 2-25 sulfate Na2SO4 col., hex. 884
Page 30 and 31: 2-27 oxide (pitchblende) sulfate (o
Page 32 and 33: 2-29 Amino-diphenylamine (p-) H2NC6
Page 34 and 35: 2-31 768 Benzoin (dl-) C6H5COCHOHC6
Page 36 and 37: 2-33 20 Carvacrylamine (2-,1-,4-) H
Page 38 and 39: 2-35 Dibenzothiazyl-disulfide (2-,2
Page 42 and 43: 2-39 15 Glutaric acid CH2(CH2CO2H)2
Page 44 and 45: 2-41 25 Methoxy-methoxyethanol CH3(
Page 46 and 47: 2-43 62 -naphthalene (α-) C10H7NO2
Page 48 and 49: 2-45 Pulegol (iso-)(d-) C10H17OH co
Page 50 and 51: 2-47 -phenol (2-,3-,6-) (NO2)3C6H2O
Page 52 and 53: Paraffins Name Cmpd. No. Formula Me
Page 54 and 55: VAPOR PRESSURES OF PURE SUBSTANCES
Page 56 and 57: VAPOR PRESSURES OF PURE SUBSTANCES
Page 58 and 59: 2-55 TABLE 2-8 Vapor Pressure of In
Page 60 and 61: 2-57 121 Diphenyl ether C12H10O 101
Page 62 and 63: 2-59 243 -Methyl styrene C9H10 98-8
Page 64 and 65: TABLE 2-9 Vapor Pressures of Inorga
Page 66 and 67: TABLE 2-9 Vapor Pressures of Inorga
Page 68 and 69: TABLE 2-10 Vapor Pressures of Organ
Page 84 and 85: FIG. 2-1 Vapor pressures of H 3PO 4
Page 86 and 87: TABLE 2-14 Water Partial Pressure,
Page 88 and 89: VAPOR PRESSURES OF SOLUTIONS 2-85 T
Page 90 and 91:
TABLE 2-17 Total Pressure, bar, of
Page 92 and 93:
TABLE 2-19 Partial Pressures of H2O
Page 94 and 95:
2-91 TABLE 2-24 Mole Percentages of
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2-93 TABLE 2-26 Total Vapor Pressur
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CHART FOR GASES AT HIGH PRESSURES T
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TABLE 2-31 Density (kg/m 3 ) of Mer
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2-99 60 o-Cresol C 7H 8O 95-48-7 10
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2-101 182 Hydrazine H 4N 2 302-01-2
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2-103 304 Propylbenzene C9H12 103-6
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TABLE 2-42 Barium Chloride (BaCl2)*
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DENSITIES OF AQUEOUS INORGANIC SOLU
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TABLE 2-73 Potassium Carbonate (K2C
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DENSITIES OF AQUEOUS ORGANIC SOLUTI
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TABLE 2-117 Glycerol* DENSITIES OF
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TABLE 2-119 Densities of Aqueous So
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TABLE 2-120 Approximate Specific Gr
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2-127 1 Calcium bicarbonate Ca(HCO3
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2-129 TABLE 2-122 Solubilities of I
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TABLE 2-125 Henry’s Constant H fo
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UNITS CONVERSIONS For this subsecti
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THERMAL EXPANSION 2-135 TABLE 2-136
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UNITS CONVERSIONS Joule-Thomson coe
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CRITICAL CONSTANTS 2-139 TABLE 2-14
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CRITICAL CONSTANTS 2-141 TABLE 2-14
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INTRODUCTION The compressibility fa
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-147 Heats of Fusion and Vap
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TABLE 2-149 Heats of Fusion of Orga
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2-151 60 o-Cresol C 7H 8O 95-48-7 1
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2-153 182 Hydrazine H 4N 2 302-01-2
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2-155 303 Propyl amine C3H9N 107-10
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TABLE 2-151 Heat Capacities of the
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2-165 TABLE 2-153 Heat Capacities o
Page 170 and 171:
2-167 117 Dimethyl sulfide C 2H 6S
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2-169 237 2-Methyl-2-propanol C4H10
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TABLE 2-154 Specific Heats of Organ
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TABLE 2-154 Specific Heats of Organ
Page 178 and 179:
2-175 237 2-Methyl-2-propanol C4H10
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2-177 61 p-Cresol C7H8O 106-44-5 10
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2-179 184 Hydrogen bromide HBr 1003
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2-181 304 305 306 307 308 309 310 3
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UNITS CONVERSIONS For this subsecti
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TABLE 2-176 and Solids Specific Hea
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TABLE 2-178 Heats and Free Energies
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2-195 TABLE 2-179 Enthalpies and Gi
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2-197 117 Dimethyl sulfide C 2H 6S
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2-199 238 2-Methyl propene C 4H 8 1
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TABLE 2-180 Ideal Gas Sensible Enth
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Aluminum bromide aq AlBr3 +85.3 chl
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TABLE 2-182 Heats of Solution of In
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EXPLANATION OF TABLES The following
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TABLE 2-185 Thermodynamic Propertie
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2-211 TABLE 2-187 Thermodynamic Pro
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2-213 97 0.44878 0.62667 1.5957 5.4
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2-215 Pressure (MPa) −200 −100
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2-219 Pressure (MPa) −200 0 200 4
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2-223 200.00 100.00 30.368 0.032930
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2-225 0.60 0.04 0.58 0.38 0.0218 0.
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2-227 0.60 0.07 0.56 0.37 0.0457 0.
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TABLE 2-194 Saturated Bromine* THER
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2-233 250.00 1.0000 10.770 0.092855
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2-235 Single-Phase Properties 100.0
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2-243 114.00 1.3517 1.9228 0.52008
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TABLE 2-201 Thermophysical Properti
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2-249 TABLE 2-205 Thermophysical Pr
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TABLE 2-206 Saturated Chloroform (R
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THERMODYNAMIC PROPERTIES 2-267 FIG.
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2-271 200.00 1.0000 0.61498 1.6261
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TABLE 2-232 Saturated Mercury* THER
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FIG. 2-12 Enthalpy-log-pressure dia
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2-309 Pressure (MPa) −200 −100
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FIG. 2-14 Mollier diagram for nitro
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2-333 Pressure (MPa) 150 200 250 30
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TABLE 2-253 Saturated Refrigerant 1
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2-347 Pressure (MPa) 0 100 200 300
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TABLE 2-261 Thermodynamic Propertie
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Pressure, bar 30 20 15 10 8 6 4 2 1
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TABLE 2-265 Saturated R-401B (SUVA
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2-371 FIG. 2-25 Enthalpy-log-pressu
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2-393 Pressure (MPa) 50 100 150 200
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2-395 305.00 1.9749 1.1138 0.89779
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2-399 310.00 1.7307 0.98768 1.0125
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2-401 TABLE 2-299 Saturated Sodium
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TABLE 2-302 Saturated SUVA AC 9000
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2-415 800 5 0.77805 1.2853 56.576 6
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TABLE 2-308 Surface Tension (N/m) o
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2-421 TABLE 2-312 Vapor Viscosity o
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2-423 119 Dimethyl terephthalate C
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2-425 241 Methylpropyl sulfide C4H1
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2-427 TABLE 2-313 Viscosity of Inor
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2-429 119 Dimethyl terephthalate C
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2-431 241 Methylpropyl sulfide C4H1
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2-433 TABLE 2-314 Vapor Thermal Con
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2-435 117 Dimethyl sulfide C2H6S 75
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2-437 238 2-Methyl propene C 4H 8 1
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2-439 TABLE 2-315 Thermal Conductiv
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2-441 116 Dimethylsilane C 2H 8Si 1
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2-443 237 2-Methyl-2-propanol C 4H
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TABLE 2-316 Transport Properties of
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2-447 Methyl acetate Vinyl acetate
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TRANSPORT PROPERTIES 2-449 FIG. 2-3
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TABLE 2-321 Prandtl Number of Air*
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TRANSPORT PROPERTIES 2-455 TABLE 2-
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TABLE 2-328 Thermal Conductivity of
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PREDICTION AND CORRELATION OF PHYSI
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TABLE 2-336 Ambrose Group a Contrib
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TABLE 2-338 Fedors*Method Atomic an
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Example The vapor pressure of n-dec
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Rg = = 1.505 × 10−10 2π(1.918
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Expected uncertainty: 5 to 10 perce
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Interpolation of the Pr values in T
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method. Although Eqs. (2-33) and (2
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Prog., 69, 7 (1973): 83; Lee, B. I.
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From Eq. (2-52): CP = (307.93) 0.79
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− 0.000607(1.06) 8 =−0.301 B (1
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2-501 Table 2-352 Acentric Deviatio
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Liquids For most liquids, the satur
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Numerous methods have been develope
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Group interactions: m/n αmn group
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TABLE 2-358 Correlation Parameters
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Calculation using Eq. (2-112): k =
Page 518 and 519:
where σm = surface tension of the
Page 520 and 521:
The values recommended in the DIPPR
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