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REVIEW OF LITERATURE

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35<br />

included. Approximately 40% of all Picea taxa and one-third of Larix taxa<br />

have been analyzed so far for their seed FA compositions. Qualitatively,<br />

the seed FA compositions in the three genera studied are the same as in<br />

Pinus spp., including in particular the same delta 5-olefinic acids.<br />

Considerably lower variability in Larix and Picea spp. than in Pinus spp.<br />

An assessment of geographical variations in the seed FA compositions of<br />

P. abies was made. This observation supports the use of seed FA<br />

compositions as chemotaxonomic markers, as they practically do not<br />

depend on climatic conditions. The main FA is linoleic acid, followed by<br />

pinoleic and oleic acids. A maximum of 34% of total delta 5-olefinic acids<br />

is reahced in L. sibirica seeds, which appears to be the highest value<br />

found in Pinaceae seed FA. In most Pinus spp., the C18 delta 5-olefinic<br />

acids are present in considerably higher amounts than the C20 delta5-<br />

olefinic acids.<br />

Destaillats et al. (2002) reported about saturated and unsaturated<br />

anteiso-C19 acids in the seed lipids from Hesperopeuce mertensiana<br />

(Pinaceae). Minor uncommon FA from Hesperopeuce mertensiana (a<br />

gymnosperm species of the Pinaceae family) seed oil were characterized<br />

through a combination of silver ion TLC, and GLC coupled with MS of<br />

their picolinyl derivatives. These uncommon components have the<br />

structure 16-methyloctadecanoic, 16-methyl-cis-9-octadecenoic and 16-<br />

metyl-cis-9,cis-12-octadecadienoic acids. These branched C19 acids<br />

were identified earlier in the wood of Picea abies, which would indicate

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