LANGE'S HANDBOOK OF CHEMISTRY

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10.4.12 Polysulfide Rubbers Polysulfide rubbers are prepared as follows: POLYMERS, RUBBERS, FATS, OILS, AND WAXES 10.61 Cl9R9Cl Na9S9S9S9S9Na : HS[9R9S9S9S9S9] nR9SH where R can be 9CH 2CH 29, 9CH 2CH 29O9CH 2CH 29, or 9CH 2CH 29O9CH 29O9CH 2CH 29. Polysulfide rubbers possess excellent resistance to weathering and oils and have very good electrical properties. 10.4.13 Poly(vinyl Chloride) (PVC) Poly(vinyl chloride) as previously discussed in Sec. 10.3, Formulas and Key Properties ofPlastic Materials, has the following structures: PVC polymer plus special plasticizers are used to produce flexible tubing which has good chemical resistance. 10.4.14 Silicone Rubbers Silicone rubbers are prepared as follows: Other groups may replace the methyl groups. Silicone rubbers have excellent ozone and weathering resistance, good electrical properties, and good adhesion to metal. 10.4.15 Styrene-Butadiene Rubber (GRS, SBR, Buna S) Styrene-butadiene rubber is prepared from the free-radical copolymerization of one part by weight ofstyrene and three parts by weight of1,3-butadiene. The butadiene is incorporated by both 1,4addition (80%) and 1,2-addition (20%). The configuration around the double bond ofthe 1,4-adduct is about 80% trans. The product is a random copolymer with these general features:
10.62 SECTION 10 Styrene-butadiene rubber (SBR) is also known as government rubber styrene (GRS) and Buna S. 10.4.16 Urethane See Table 10.3.
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. To find t
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Molar Equ
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2.92 SECTION 2 TABLE 2.19 Factors f
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2.94 SECTION 2 TABLE 2.19 Factors f
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.16 TABLE 3.2 Physical Constants o
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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4.5 Silver (argentum) Ag 47 [Kr] 4d
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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TABLE 4.5 Electronegativities of th
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TABLE 4.11 Bond Dissociation Energi
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TABLE 4.16 Table of Nuclides (Conti
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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5.1 SOLUBILITIES PHYSICAL PROPERTIE
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO2) 2 26.2 28.0 29.9 31
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(III) sulfateCe2(SO4) 3 ·9H2O 21.4
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iodidePbI2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO4 ·6H2O (pale bl
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Praseodymium bromatePr(BrO 3) 3 55.
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2(NO 3) 2 98 107
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TABLE 5.3 Vapor Pressure of Mercury
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TABLE 5.4 Vapor Pressure of Ice in
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TABLE 5.6 Vapor Pressure of Water (
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TABLE 5.8 Vapor Pressures of Variou
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PHYSICAL PROPERTIES 5.33 TABLE 5.8
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5.3 BOILING POINTS TABLE 5.10 Boili
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TABLE 5.11 Binary Azeotropic (Const
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TABLE 5.12 Ternary Azeotropic Mixtu
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5.4 FREEZING MIXTURES TABLE 5.13 Co
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TABLE 5.13 Compositions of Aqueous
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5.5 DENSITY AND SPECIFIC GRAVITY TA
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PHYSICAL PROPERTIES 5.89 d D t t
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5.6.1 Refractive Index PHYSICAL PRO
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PHYSICAL PROPERTIES 5.137 where the
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5.7 COMBUSTIBLE MIXTURES TABLE 5.23
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TABLE 5.23 Properties of Combustibl
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Deuterium 1150 1222 1297 1372 1448
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TABLE 5.25 Liquid Thermal Conductiv
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TABLE 5.26 Thermal Conductivity of
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TABLE 5.29 Van der Waals’ Constan
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TABLE 5.30 Triple Points of Various
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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PClF 3 THERMODYNAMIC PROPERTIES 6.1
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THERMODYNAMIC PROPERTIES 6.143 The
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TABLE 6.5 Critical Properties (Cont
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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TABLE 7.1 Wavelengths of X-Ray Emis
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SPECTROSCOPY 7.5 TABLE 7.1 Waveleng
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TABLE 7.2 Wavelengths of Absorption
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TABLE 7.3 Critical X-Ray Absorption
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TABLE 7.4 X-Ray Emission Energies i
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SPECTROSCOPY 7.13 Emission line K 1
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TABLE 7.7 Analyzing Crystals for X-
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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TABLE 7.9 Electronic Absorption Ban
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TABLE 7.11 Absorption Wavelength of
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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7.3 FLUORESCENCE TABLE 7.16 Fluores
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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TABLE 7.18 Detection Limits in ng/m
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TABLE 7.19 Sensitive Lines of the E
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TABLE 7.19 Sensitive Lines of the E
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In terms of m, the wavenumber of m
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The ionization constant can be calc
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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TABLE 7.22 Absorption Frequencies o
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TABLE 7.27 Absorption Frequencies i
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TABLE 7.28 Infrared Transmitting Ma
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7.69
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7.6 RAMAN SPECTROSCOPY SPECTROSCOPY
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.75 TABLE 7.30 Raman
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TABLE 7.32 Raman Frequencies of Cum
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TABLE 7.33 Raman Frequencies of Car
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TABLE 7.34 Raman Frequencies of Oth
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TABLE 7.35 Raman Frequencies of Aro
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TABLE 7.36 Raman Frequencies of Sul
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TABLE 7.39 Raman Frequencies of Mis
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7.7 NUCLEAR MAGNETIC RESONANCE TABL
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TABLE 7.41 Nuclear Properties of th
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TABLE 7.42 Proton Chemical Shifts (
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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TABLE 7.46 Proton Spin Coupling Con
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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TABLE 7.49 Carbon-13 Chemical Shift
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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TABLE 7.54 Carbon-13 Chemical Shift
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TABLE 7.56 One-Bond Carbon-Hydrogen
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TABLE 7.58 Carbon-Carbon Spin Coupl
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7 Li CH3Li 15 SPECTROSCOPY 7.111 TA
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TABLE 7.63 Nitrogen-15 (or Nitrogen
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TABLE 7.64 Nitrogen-15 Chemical Shi
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TABLE 7.69 Fluorine-19 Chemical Shi
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TABLE 7.72 Silicon-29 Chemical Shif
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TABLE 7.73 Phosphorus-31 Chemical S
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TABLE 7.74 Phosphorus-31 Spin Coupl
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when z 3 and y 1. The empirical f
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Masses 19 and 31 Alcohol Mass 66
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TABLE 7.76 Condensed Table of Mass
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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TABLE 8.25 Fluorescent Indicators (
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3,3-Dimethoxybenzidine dihydrochlor
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8.7 CONDUCTANCE ELECTROLYTES, EMF,
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Conductance of an Electrolyte Solut
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pKa and Rho
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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Page 1037 and 1038: 10.20 SECTION 10 10.3.22 Sulfones B
Page 1039 and 1040: TABLE 10.2 Properties of Commercial
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Page 1077: 10.60 SECTION 10 10.4.8 Polychlorop
Page 1081 and 1082: 10.5 CHEMICAL RESISTANCE TABLE 10.4
Page 1083 and 1084: 10.6 GAS PERMEABILITY TABLE 10.5 Ga
Page 1085 and 1086: TABLE 10.5 Gas Permeability Constan
Page 1087 and 1088: TABLE 10.7 Constants ofFats and Oil
Page 1089 and 1090: TABLE 10.8 Constants ofWaxes Wax Me
Page 1091 and 1092: SECTION 11 PRACTICAL LABORATORY INF
Page 1093 and 1094: 11.1 COOLING TABLE 11.1 Cooling Mix
Page 1095 and 1096: 11.2 DRYING AND HUMIDIFICATION TABL
Page 1097 and 1098: PRACTICAL LABORATORY INFORMATION 11
Page 1099 and 1100: TABLE 11.7 Relative Humidity from D
Page 1101 and 1102: 3-Methyl-1-butanol 132.0 Cyclohexyl
Page 1103 and 1104: TABLE 11.9 Molecular Elevation of t
Page 1107 and 1108: TABLE 11.11 Solvents of Chromatogra
Page 1111 and 1112: TABLE 11.13 McReynolds’ Constants
Page 1119 and 1120: FIGURE 11.1 Profile of a solute ban
Page 1123 and 1124: TABLE 11.16 Guide to Ion-Exchange R
Page 1125 and 1126: TABLE 11.16 Guide to Ion-Exchange R
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PRACTICAL LABORATORY INFORMATION 11
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11.5 GRAVIMETRIC ANALYSIS TABLE 11.
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TABLE 11.19 Gravimetric Factors (Co
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Sodium tetraphenylborate, NaB(C 6H
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TABLE 11.24 Porosities of Fritted G
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TABLE 11.26 HeatingTemperatures, Co
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TABLE 11.28 Titrimetric (Volumetric
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HN 3 PRACTICAL LABORATORY INFORMATI
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11.6.5 Precipitation Titrations PRA
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TABLE 11.31 Indicators for Precipit
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TABLE 11.33 Variation of 4 with pH
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TABLE 11.38 Common Demasking Agents
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TABLE 11.41 Pipet Capacity Toleranc
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TABLE 11.45 Cubical Coefficients of
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TABLE 11.48 Standard Stock Solution
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TABLE 11.48 Standard Stock Solution
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11.8 SIEVES AND SCREENS TABLE 11.53
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.57 Type E Thermocouples: N
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TABLE 11.59 Type K Thermocouples: N
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TABLE 11.61 Type R Thermocouples: P
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TABLE 11.63 Type T Thermocouples: C
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Index Terms Links Abbreviations: of
Page 1243 and 1244:
Index Terms Links Aggregation, stat
Page 1245 and 1246:
Index Terms Links Anions, inorganic
Page 1247 and 1248:
Index Terms Links Benzoylacetone, f
Page 1249 and 1250:
Index Terms Links Carbon-carbon: bo
Page 1251 and 1252:
Index Terms Links Chemical shifts:
Page 1253 and 1254:
Index Terms Links Correction for so
Page 1255 and 1256:
Index Terms Links Dielectric streng
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Index Terms Links Emergent stem cor
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Index Terms Links Excitation wavele
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Index Terms Links Gases: equations
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Index Terms Links Hydrogen: binary
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Index Terms Links Iodine: bond diss
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Index Terms Links Lithium: bond dis
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Index Terms Links Mode for set of n
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Index Terms Links Nitrogen-oxygen d
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Index Terms Links Peak asymmetry fa
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Index Terms Links Polybutylene poly
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Index Terms Links Precipitates, hea
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Index Terms Links Rankine scale, co
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Index Terms Links Selection rules:
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Index Terms Links Specific gravity:
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Index Terms Links Sulfuric acid sol
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Index Terms Links Thiosulfate: form
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Index Terms Links Vaporization: ent
Page 1291:
Index Terms Links Zincon, formation
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LANGE'S HANDBOOK OF CHEMISTRY

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