LANGE'S HANDBOOK OF CHEMISTRY

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3.13 TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent Actinium-227 Ac 227.0278 10.07 1050(50)ca. 3200 d aq; s acids bromide Aluminum acetylacetonate ammonium bis(sulfate) AcBr3 Al Al(C5H7O2) 3 AlNH4(SO4) 2 · 12H2O 466.74 26.981539 324.31 453.33 5.85 2.70 1.27 1.65 subl 800 660.323 190–193 anhyd 280 2518 315 s aq s HCl, H2SO4, alk i aq; v s alc; s bz, eth 14.3 g/100 mL aq; s glyc; i alc 12-water antimonide AlSb 148.74 4.26 1060 arsenide AlAs 101.90 3.76 1740 bis(acetylsalicylate)Al(OOCC6H4OCOCH3) 2OH 402.30 v sl s aq, alc, eth borate (2/1)2Al2O3 ·B2O3 273.54 ca. 1050 i aq bromide AlBr3 266.69 3.20518 0 97.5 subl 253 d (viol)aq; s alc, acet, bz, CS2 butoxide, sec- Al(C 4H 9O) 3 246.33 0.967 200–206 30mm FP 27; v s org solv butoxide, tert- Al(C 4H 9O) 3 246.33 1.025 20 0 subl 180 v s org solv carbide (4/3)Al 4C 3 143.96 2.360 2100 d 2200 400mm d aq; fire hazard chlorate Al(ClO 3) 3 277.35 v s aq; s alc chloride AlCl 3 133.34 2.440 25 192.6 subl 181.1 g/100 mL: 70 aq (viol), 100 12 abs alc; s CCl 4, eth; sl s bz ethoxide Al(C2H5O) 3 162.16 1.14220 0 140 20514mm s hot aq d; v sl s alc, eth fluoride AlF3 83.98 2.88225 4 1090 subl 1272 0.56 aq; i a, alk, alc, acet hydroxide Al(OH) 3 78.01 2.42 to Al2O3, 300 i aq; s acids, alkalis iodide AlI 3 407.69 3.98 17 191.0 382 d aq; s alc, eth, CS 2 isopropoxide Al(C 3H 7O) 3 204.25 1.0346 20 0 118.5 135 10mm d aq; s alc, bz, chl, PE methoxide Al(CH 3O) 3 72.07 0 130 nitrate 9-water Al(NO 3) 3 ·9H 2O 375.13 1.72 73 d 135 g/100 mL: 64 aq, 100 alc; s acet nitride AlN 40.99 3.05 d 2517 d aq, acid, alkali oxide (alpha-)AlO 3 101.96 3.97 2054(6)2980 i aq; v sl s a, alk perchlorate 6-water Al(ClO 4) 3 ·6H 2O 433.43 2.020 120.8 anhyd 178 133 g/100 mL 20 aq phenoxide Al(C 6H 5O) 3 306.27 1.23 d 265 d aq; s alc, chl, eth phosphate AlPO 4 121.95 2.56 1460 i aq; sl s a phosphide AlP 57.96 2.8515 4 2550 d aq phosphinate (hypophos- Al(H2PO2) 3 221.94 d to PH3, 220 i aq; s HCl, warm alkali phite)
TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent Aluminum (continued) potassium bis(sulfate) 12-water AlK(SO4) 2 · 12H2O 474.39 1.75720 9H2O, 92 anhyd, 200 11.4 g/100 mL aq; v s glyc; i alc propoxide Al(C3H7O) 3 204.25 1.057820 0 106 24814mm selenide Al2Se3 290.84 3.437 daq;salc 20 silicon oxide (1/1)Al2O3 · SiO2 sodium bis(sulfate) AlNa(SO4) 2 · 12H2O 12-water 162.05 458.28 4 3.247 1.675 947 d aq, acid i aq; d HF; s fused alkali 20 61 110 g/100 mL15 aq; i alc stearate sulfate Al(C18H35O2) 3 Al2(SO4) 3 877.41 342.15 1.070 1.61 117–120 770 d i aq, alc; s bz, alk 36.4 g/100 mL20 sulfate 18-water Al2(SO4) 3 · 18H2O 666.46 1.69 aq; sl s alc 17 d 86.5 87 g/100 mL0 sulfide Al2S3 150.16 2.20 aq; i alc 13 tetrahydridoborate Americium Al(BH4) 3 Am 71.53 243 12 1097 64.5 1176 subl 1500 44.5 2011 hyd aq; s acid d aq; ign air; expl in O2,20 s a Ammonia NH3 17.03 lq: 0.6818 at bp 15, 7.2atm g: 0.6175 77.75 33.35 g/100 mL: 34 aq; 13.2 alc; s eth, organic solvents Ammonium acetate NH4C2H3O2 77.08 1.1720 114 d g/100 mL: 1484 aq, 7.915 MeOH; s alc amidosulfate benzoate NH4SO3NH2 NH4C6H5O2 114.13 139.15 1.260 131 198 d 160 subl 160 v s aq; sl s alc g/100 mL: 2015 bromide NH4Br 97.94 2.429 452 (subl under pressure) d 397 vacuo aq, 2.8 alc; s glyc 76 g/100 mL20 aq; v s acet, alc, eth calcium arsenate 6-water NH4CaAsO4 ·6H2O 305.13 1.90515 carbamate carbonate 1-water chloride NH4COONH2 (NH4) 2CO3 ·H2O NH4Cl 78.07 114.10 53.49 1.5274 d 140 subl 60 volatilizes 60 0.02 aq; s NH4Cl v s aq; sl s alc; i eth v s aq; i alc 25 237.8 520 g/100 mL: 2615 aq, 0.619 abs alc; i acet, eth chromate(VI)(NH4) 2CrO4 152.07 1.9112 d 185 34 g/100 mL20 aq; sl s MeOH chromium(III)bissulfate 12-water NH4Cr(SO4) 2 · 12H2O 478.34 1.72 94 d 7.2 g/100 mL0 aq copper(II)tetrachloride 2-water (NH4) 2CuCl4 ·2H2O 277.46 1.993 anhyd, 110 d 120 40.3 g/100 mL20 aq; s alc 3.14
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. To find t
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Molar Equ
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2.92 SECTION 2 TABLE 2.19 Factors f
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2.94 SECTION 2 TABLE 2.19 Factors f
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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4.5 Silver (argentum) Ag 47 [Kr] 4d
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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TABLE 4.5 Electronegativities of th
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TABLE 4.11 Bond Dissociation Energi
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TABLE 4.16 Table of Nuclides (Conti
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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5.1 SOLUBILITIES PHYSICAL PROPERTIE
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO2) 2 26.2 28.0 29.9 31
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(III) sulfateCe2(SO4) 3 ·9H2O 21.4
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iodidePbI2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO4 ·6H2O (pale bl
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Praseodymium bromatePr(BrO 3) 3 55.
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2(NO 3) 2 98 107
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TABLE 5.3 Vapor Pressure of Mercury
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TABLE 5.4 Vapor Pressure of Ice in
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TABLE 5.6 Vapor Pressure of Water (
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TABLE 5.8 Vapor Pressures of Variou
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PHYSICAL PROPERTIES 5.33 TABLE 5.8
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5.3 BOILING POINTS TABLE 5.10 Boili
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TABLE 5.11 Binary Azeotropic (Const
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TABLE 5.12 Ternary Azeotropic Mixtu
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5.4 FREEZING MIXTURES TABLE 5.13 Co
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TABLE 5.13 Compositions of Aqueous
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5.5 DENSITY AND SPECIFIC GRAVITY TA
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PHYSICAL PROPERTIES 5.89 d D t t
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5.6.1 Refractive Index PHYSICAL PRO
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PHYSICAL PROPERTIES 5.137 where the
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5.7 COMBUSTIBLE MIXTURES TABLE 5.23
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TABLE 5.23 Properties of Combustibl
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Deuterium 1150 1222 1297 1372 1448
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TABLE 5.25 Liquid Thermal Conductiv
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TABLE 5.26 Thermal Conductivity of
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TABLE 5.29 Van der Waals’ Constan
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TABLE 5.30 Triple Points of Various
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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PClF 3 THERMODYNAMIC PROPERTIES 6.1
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THERMODYNAMIC PROPERTIES 6.143 The
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TABLE 6.5 Critical Properties (Cont
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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TABLE 7.1 Wavelengths of X-Ray Emis
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SPECTROSCOPY 7.5 TABLE 7.1 Waveleng
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TABLE 7.2 Wavelengths of Absorption
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TABLE 7.3 Critical X-Ray Absorption
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TABLE 7.4 X-Ray Emission Energies i
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SPECTROSCOPY 7.13 Emission line K 1
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TABLE 7.7 Analyzing Crystals for X-
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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TABLE 7.9 Electronic Absorption Ban
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TABLE 7.11 Absorption Wavelength of
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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7.3 FLUORESCENCE TABLE 7.16 Fluores
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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TABLE 7.18 Detection Limits in ng/m
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TABLE 7.19 Sensitive Lines of the E
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TABLE 7.19 Sensitive Lines of the E
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In terms of m, the wavenumber of m
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The ionization constant can be calc
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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TABLE 7.22 Absorption Frequencies o
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TABLE 7.27 Absorption Frequencies i
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TABLE 7.28 Infrared Transmitting Ma
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7.69
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7.6 RAMAN SPECTROSCOPY SPECTROSCOPY
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.75 TABLE 7.30 Raman
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TABLE 7.32 Raman Frequencies of Cum
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TABLE 7.33 Raman Frequencies of Car
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TABLE 7.34 Raman Frequencies of Oth
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TABLE 7.35 Raman Frequencies of Aro
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TABLE 7.36 Raman Frequencies of Sul
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TABLE 7.39 Raman Frequencies of Mis
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7.7 NUCLEAR MAGNETIC RESONANCE TABL
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TABLE 7.41 Nuclear Properties of th
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TABLE 7.42 Proton Chemical Shifts (
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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TABLE 7.46 Proton Spin Coupling Con
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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TABLE 7.49 Carbon-13 Chemical Shift
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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TABLE 7.54 Carbon-13 Chemical Shift
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TABLE 7.56 One-Bond Carbon-Hydrogen
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TABLE 7.58 Carbon-Carbon Spin Coupl
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7 Li CH3Li 15 SPECTROSCOPY 7.111 TA
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TABLE 7.63 Nitrogen-15 (or Nitrogen
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TABLE 7.64 Nitrogen-15 Chemical Shi
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TABLE 7.69 Fluorine-19 Chemical Shi
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TABLE 7.72 Silicon-29 Chemical Shif
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TABLE 7.73 Phosphorus-31 Chemical S
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TABLE 7.74 Phosphorus-31 Spin Coupl
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when z 3 and y 1. The empirical f
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Masses 19 and 31 Alcohol Mass 66
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TABLE 7.76 Condensed Table of Mass
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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TABLE 8.25 Fluorescent Indicators (
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3,3-Dimethoxybenzidine dihydrochlor
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8.7 CONDUCTANCE ELECTROLYTES, EMF,
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Conductance of an Electrolyte Solut
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pKa and Rho
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.1 COOLING TABLE 11.1 Cooling Mix
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11.2 DRYING AND HUMIDIFICATION TABL
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PRACTICAL LABORATORY INFORMATION 11
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TABLE 11.7 Relative Humidity from D
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3-Methyl-1-butanol 132.0 Cyclohexyl
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TABLE 11.9 Molecular Elevation of t
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TABLE 11.11 Solvents of Chromatogra
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TABLE 11.13 McReynolds’ Constants
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FIGURE 11.1 Profile of a solute ban
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TABLE 11.16 Guide to Ion-Exchange R
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TABLE 11.16 Guide to Ion-Exchange R
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11.5 GRAVIMETRIC ANALYSIS TABLE 11.
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TABLE 11.19 Gravimetric Factors (Co
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Sodium tetraphenylborate, NaB(C 6H
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TABLE 11.24 Porosities of Fritted G
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TABLE 11.26 HeatingTemperatures, Co
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TABLE 11.28 Titrimetric (Volumetric
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HN 3 PRACTICAL LABORATORY INFORMATI
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11.6.5 Precipitation Titrations PRA
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TABLE 11.31 Indicators for Precipit
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TABLE 11.33 Variation of 4 with pH
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TABLE 11.38 Common Demasking Agents
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TABLE 11.41 Pipet Capacity Toleranc
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TABLE 11.45 Cubical Coefficients of
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TABLE 11.48 Standard Stock Solution
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TABLE 11.48 Standard Stock Solution
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11.8 SIEVES AND SCREENS TABLE 11.53
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.57 Type E Thermocouples: N
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TABLE 11.59 Type K Thermocouples: N
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TABLE 11.61 Type R Thermocouples: P
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TABLE 11.63 Type T Thermocouples: C
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Index Terms Links Abbreviations: of
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Index Terms Links Aggregation, stat
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Index Terms Links Anions, inorganic
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Index Terms Links Benzoylacetone, f
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Index Terms Links Carbon-carbon: bo
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Index Terms Links Chemical shifts:
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Index Terms Links Correction for so
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Index Terms Links Dielectric streng
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Index Terms Links Emergent stem cor
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Index Terms Links Excitation wavele
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Index Terms Links Gases: equations
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Index Terms Links Hydrogen: binary
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Index Terms Links Iodine: bond diss
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Index Terms Links Lithium: bond dis
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Index Terms Links Mode for set of n
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Index Terms Links Nitrogen-oxygen d
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Index Terms Links Peak asymmetry fa
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Index Terms Links Polybutylene poly
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Index Terms Links Precipitates, hea
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Index Terms Links Rankine scale, co
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Index Terms Links Selection rules:
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Index Terms Links Specific gravity:
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Index Terms Links Sulfuric acid sol
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Index Terms Links Thiosulfate: form
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Index Terms Links Vaporization: ent
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Index Terms Links Zincon, formation
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LANGE'S HANDBOOK OF CHEMISTRY

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