LANGE'S HANDBOOK OF CHEMISTRY

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TABLE 10.5 Gas Permeability Constants (10 10 P)at25C for Polymers and Rubbers (Continued) Acrylonitrile-styrene copolymer (66 : 34) 0.048 0.21 2 000 Poly(1,3-butadiene) 6.42 41.9 19.0 138.0 5 070 Poly (cis-1,4-butadiene) 32.6 19.2 19.2 (Ne); 41.0 (Ar) Butadiene-acrylonitrile copolymer (80 : 20) 12.2 1.06 15.9 3.85 30.8 24.8 (C 2H 2); 7.7 (propyne) Butadiene-styrene copolymer (80 : 20) 13.4 1.71 5.01 (Ne); 4.49 (Ar) Butadiene-styrene copolymer (92 : 8) 22.9 5.11 9.70 (Ne); 12.7 (Ar) Polychloroprene 1.2 13.6 4.0 25.8 3.79 (Ar); 3.27 (CH 4) Polyethylene, low-density 4.9 0.969 12.0 30 2.88 12.6 90 2.88 (CH 4); 6.81 (C 2H 6); 9.43 (C 3H 8); 1.48 CO); 49 0 (ethylene oxide); 14.4 (propene); 42.2 (propyne); 0.170 (SF 6); 472 60 (CH 3Br) Polyethylene, high-density 1.14 0.143 3.0 20 0.403 0.36 12.0 0.388 (CH 4); 0.590 (C 2H 6); 0.537 (C 3H 8); 0.008 3 (SF 6); 1.69 (Ar); 4.01 (propene) Poly(ethylene terephthalate) Crystalline 1.32 0.006 5 3.70 20 0.035 0.17 130 0.003 2 (CH 4); 0.08 60 (CH 3Br) Amorphous 3.28 0.013 0.059 0.30 0.009 (CH 4) Poly(ethyl methacrylate) 6.82 0.220 1.15 5.00 3 200 2.98 (Ne); 0.565 (Ar); 0.370 (Kr); 3.83 (H 2S); 0.000 001 65 (SF 6) Isobutene-isoprene copolymer (98 : 2) 8.38 0.324 7.20 1.30 5.16 110 38 13.6 50 (C 3H 8) Isoprene-acrylonitrile copolymer (76 : 24) 7.77 0.181 7.41 0.852 4.32 10.67 Polymer or rubber He N 2 H 2 O 2 CO 2 H 2O Other Gas
TABLE 10.5 Gas Permeability Constants (10 10 P)at25C for Polymers and Rubbers (Continued) Polymer or rubber He N 2 H 2 O 2 CO 2 H 2O Other Isoprene-methacrylonitrile copolymer (76 : 24) Methacrylonitrile-styrene- 0.596 13.6 2.34 14.1 butadiene copolymer (88:7:5) 0.004 8 0.014 600 Poly(methylpentene) 101 7.83 136 32.0 92.6 Polypropylene 3820 0.4430 4120 2.330 9.230 51 0.3320 (H2S); 9.220 Silicone rubber, 10% filler 233 (NH3) 0 2270 4640 4890 3 240 43 00035 1910 (Ne); 5500 (Ar); 1 0200 (Kr); 2 5500 (Xe); 19 0000 (butane) Polystyrene 18.7 0.788 23.3 2.63 10.5 1 200 Poly(tetrafluoroethylene) Poly(trifluoroethylene) 6.8 1.4 9.8 4.2 11.7 15.7 (NO2); 37.5 (N2O4) 20 0.003 0.9420 0.02540 0.04840 0.29 1.20 (ethylene oxide); 4.660 (CH3Br) Poly(vinyl acetate) 12.630 8930 0.5030 2.6430 (Ne); 0.1930 (Ar); 0.07830 (Kr); 0.05030 (CH4) Poly(vinyl alcohol) 0.00130 0.00114 0.009 0.008 9 0.00123 0.007 (H2S); 0.0020 (ethylene oxide) Poly(vinyl chloride) 2.05 0.011 8 1.70 0.045 3 0.157 275 3.92 (Ne); 0.011 5 (Ar); 0.028 6 (CH4) Poly(vinylidene chloride) 0.3134 0.000 9430 0.005 330 0.0330 0.5 0.0330 (H2S); 0.00860 (CH3Br) 10.68 Gas
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. To find t
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Molar Equ
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2.92 SECTION 2 TABLE 2.19 Factors f
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2.94 SECTION 2 TABLE 2.19 Factors f
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.16 TABLE 3.2 Physical Constants o
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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4.5 Silver (argentum) Ag 47 [Kr] 4d
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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TABLE 4.5 Electronegativities of th
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TABLE 4.11 Bond Dissociation Energi
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TABLE 4.16 Table of Nuclides (Conti
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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5.1 SOLUBILITIES PHYSICAL PROPERTIE
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO2) 2 26.2 28.0 29.9 31
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(III) sulfateCe2(SO4) 3 ·9H2O 21.4
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iodidePbI2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO4 ·6H2O (pale bl
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Praseodymium bromatePr(BrO 3) 3 55.
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2(NO 3) 2 98 107
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TABLE 5.3 Vapor Pressure of Mercury
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TABLE 5.4 Vapor Pressure of Ice in
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TABLE 5.6 Vapor Pressure of Water (
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TABLE 5.8 Vapor Pressures of Variou
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PHYSICAL PROPERTIES 5.33 TABLE 5.8
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5.3 BOILING POINTS TABLE 5.10 Boili
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TABLE 5.11 Binary Azeotropic (Const
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TABLE 5.12 Ternary Azeotropic Mixtu
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5.4 FREEZING MIXTURES TABLE 5.13 Co
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TABLE 5.13 Compositions of Aqueous
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5.5 DENSITY AND SPECIFIC GRAVITY TA
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PHYSICAL PROPERTIES 5.89 d D t t
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5.6.1 Refractive Index PHYSICAL PRO
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PHYSICAL PROPERTIES 5.137 where the
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5.7 COMBUSTIBLE MIXTURES TABLE 5.23
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TABLE 5.23 Properties of Combustibl
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Deuterium 1150 1222 1297 1372 1448
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TABLE 5.25 Liquid Thermal Conductiv
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TABLE 5.26 Thermal Conductivity of
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TABLE 5.29 Van der Waals’ Constan
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TABLE 5.30 Triple Points of Various
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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PClF 3 THERMODYNAMIC PROPERTIES 6.1
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THERMODYNAMIC PROPERTIES 6.143 The
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TABLE 6.5 Critical Properties (Cont
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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TABLE 7.1 Wavelengths of X-Ray Emis
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SPECTROSCOPY 7.5 TABLE 7.1 Waveleng
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TABLE 7.2 Wavelengths of Absorption
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TABLE 7.3 Critical X-Ray Absorption
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TABLE 7.4 X-Ray Emission Energies i
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SPECTROSCOPY 7.13 Emission line K 1
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TABLE 7.7 Analyzing Crystals for X-
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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TABLE 7.9 Electronic Absorption Ban
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TABLE 7.11 Absorption Wavelength of
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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7.3 FLUORESCENCE TABLE 7.16 Fluores
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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TABLE 7.18 Detection Limits in ng/m
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TABLE 7.19 Sensitive Lines of the E
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TABLE 7.19 Sensitive Lines of the E
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In terms of m, the wavenumber of m
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The ionization constant can be calc
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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TABLE 7.22 Absorption Frequencies o
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TABLE 7.27 Absorption Frequencies i
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TABLE 7.28 Infrared Transmitting Ma
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7.69
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7.6 RAMAN SPECTROSCOPY SPECTROSCOPY
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.75 TABLE 7.30 Raman
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TABLE 7.32 Raman Frequencies of Cum
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TABLE 7.33 Raman Frequencies of Car
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TABLE 7.34 Raman Frequencies of Oth
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TABLE 7.35 Raman Frequencies of Aro
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TABLE 7.36 Raman Frequencies of Sul
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TABLE 7.39 Raman Frequencies of Mis
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7.7 NUCLEAR MAGNETIC RESONANCE TABL
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TABLE 7.41 Nuclear Properties of th
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TABLE 7.42 Proton Chemical Shifts (
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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TABLE 7.46 Proton Spin Coupling Con
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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TABLE 7.49 Carbon-13 Chemical Shift
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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TABLE 7.54 Carbon-13 Chemical Shift
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TABLE 7.56 One-Bond Carbon-Hydrogen
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TABLE 7.58 Carbon-Carbon Spin Coupl
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7 Li CH3Li 15 SPECTROSCOPY 7.111 TA
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TABLE 7.63 Nitrogen-15 (or Nitrogen
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TABLE 7.64 Nitrogen-15 Chemical Shi
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TABLE 7.69 Fluorine-19 Chemical Shi
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TABLE 7.72 Silicon-29 Chemical Shif
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TABLE 7.73 Phosphorus-31 Chemical S
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TABLE 7.74 Phosphorus-31 Spin Coupl
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when z 3 and y 1. The empirical f
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Masses 19 and 31 Alcohol Mass 66
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TABLE 7.76 Condensed Table of Mass
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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TABLE 8.25 Fluorescent Indicators (
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3,3-Dimethoxybenzidine dihydrochlor
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8.7 CONDUCTANCE ELECTROLYTES, EMF,
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Conductance of an Electrolyte Solut
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pKa and Rho
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
Page 1027 and 1028:
10.10 SECTION 10 Key properties of
Page 1029 and 1030:
10.12 SECTION 10 10.3.8 Fluorocarbo
Page 1031 and 1032:
10.14 SECTION 10 10.3.11 Phenolics
Page 1033 and 1034: 10.16 SECTION 10 The resin has the
Page 1035 and 1036: 10.18 SECTION 10 10.3.19 Polyuretha
Page 1037 and 1038: 10.20 SECTION 10 10.3.22 Sulfones B
Page 1039 and 1040: TABLE 10.2 Properties of Commercial
Page 1075 and 1076: 10.58 SECTION 10 10.4 FORMULAS AND
Page 1077 and 1078: 10.60 SECTION 10 10.4.8 Polychlorop
Page 1079 and 1080: 10.62 SECTION 10 Styrene-butadiene
Page 1081 and 1082: 10.5 CHEMICAL RESISTANCE TABLE 10.4
Page 1083: 10.6 GAS PERMEABILITY TABLE 10.5 Ga
Page 1087 and 1088: TABLE 10.7 Constants ofFats and Oil
Page 1089 and 1090: TABLE 10.8 Constants ofWaxes Wax Me
Page 1091 and 1092: SECTION 11 PRACTICAL LABORATORY INF
Page 1093 and 1094: 11.1 COOLING TABLE 11.1 Cooling Mix
Page 1095 and 1096: 11.2 DRYING AND HUMIDIFICATION TABL
Page 1097 and 1098: PRACTICAL LABORATORY INFORMATION 11
Page 1099 and 1100: TABLE 11.7 Relative Humidity from D
Page 1101 and 1102: 3-Methyl-1-butanol 132.0 Cyclohexyl
Page 1103 and 1104: TABLE 11.9 Molecular Elevation of t
Page 1107 and 1108: TABLE 11.11 Solvents of Chromatogra
Page 1111 and 1112: TABLE 11.13 McReynolds’ Constants
Page 1119 and 1120: FIGURE 11.1 Profile of a solute ban
Page 1123 and 1124: TABLE 11.16 Guide to Ion-Exchange R
Page 1125 and 1126: TABLE 11.16 Guide to Ion-Exchange R
Page 1131 and 1132: 11.5 GRAVIMETRIC ANALYSIS TABLE 11.
Page 1133 and 1134: TABLE 11.19 Gravimetric Factors (Co
Page 1135 and 1136:
TABLE 11.19 Gravimetric Factors (Co
Page 1137 and 1138:
Page 1139 and 1140:
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Page 1149 and 1150:
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Page 1155 and 1156:
Page 1157 and 1158:
Page 1159 and 1160:
Sodium tetraphenylborate, NaB(C 6H
Page 1161 and 1162:
TABLE 11.24 Porosities of Fritted G
Page 1163 and 1164:
TABLE 11.26 HeatingTemperatures, Co
Page 1165 and 1166:
PRACTICAL LABORATORY INFORMATION 11
Page 1167 and 1168:
TABLE 11.28 Titrimetric (Volumetric
Page 1169 and 1170:
Page 1171 and 1172:
Page 1173 and 1174:
Page 1175 and 1176:
Page 1177 and 1178:
HN 3 PRACTICAL LABORATORY INFORMATI
Page 1179 and 1180:
11.6.5 Precipitation Titrations PRA
Page 1181 and 1182:
Page 1183 and 1184:
Page 1185 and 1186:
TABLE 11.31 Indicators for Precipit
Page 1187 and 1188:
TABLE 11.33 Variation of 4 with pH
Page 1189 and 1190:
Page 1191 and 1192:
TABLE 11.38 Common Demasking Agents
Page 1193 and 1194:
TABLE 11.41 Pipet Capacity Toleranc
Page 1195 and 1196:
TABLE 11.45 Cubical Coefficients of
Page 1197 and 1198:
TABLE 11.48 Standard Stock Solution
Page 1199 and 1200:
TABLE 11.48 Standard Stock Solution
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Page 1227 and 1228:
11.8 SIEVES AND SCREENS TABLE 11.53
Page 1229 and 1230:
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
Page 1233 and 1234:
TABLE 11.57 Type E Thermocouples: N
Page 1235 and 1236:
TABLE 11.59 Type K Thermocouples: N
Page 1237 and 1238:
TABLE 11.61 Type R Thermocouples: P
Page 1239 and 1240:
TABLE 11.63 Type T Thermocouples: C
Page 1241 and 1242:
Index Terms Links Abbreviations: of
Page 1243 and 1244:
Index Terms Links Aggregation, stat
Page 1245 and 1246:
Index Terms Links Anions, inorganic
Page 1247 and 1248:
Index Terms Links Benzoylacetone, f
Page 1249 and 1250:
Index Terms Links Carbon-carbon: bo
Page 1251 and 1252:
Index Terms Links Chemical shifts:
Page 1253 and 1254:
Index Terms Links Correction for so
Page 1255 and 1256:
Index Terms Links Dielectric streng
Page 1257 and 1258:
Index Terms Links Emergent stem cor
Page 1259 and 1260:
Index Terms Links Excitation wavele
Page 1261 and 1262:
Index Terms Links Gases: equations
Page 1263 and 1264:
Index Terms Links Hydrogen: binary
Page 1265 and 1266:
Index Terms Links Iodine: bond diss
Page 1267 and 1268:
Index Terms Links Lithium: bond dis
Page 1269 and 1270:
Index Terms Links Mode for set of n
Page 1271 and 1272:
Index Terms Links Nitrogen-oxygen d
Page 1273 and 1274:
Index Terms Links Peak asymmetry fa
Page 1275 and 1276:
Index Terms Links Polybutylene poly
Page 1277 and 1278:
Index Terms Links Precipitates, hea
Page 1279 and 1280:
Index Terms Links Rankine scale, co
Page 1281 and 1282:
Index Terms Links Selection rules:
Page 1283 and 1284:
Index Terms Links Specific gravity:
Page 1285 and 1286:
Index Terms Links Sulfuric acid sol
Page 1287 and 1288:
Index Terms Links Thiosulfate: form
Page 1289 and 1290:
Index Terms Links Vaporization: ent
Page 1291:
Index Terms Links Zincon, formation
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LANGE'S HANDBOOK OF CHEMISTRY

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