LANGE'S HANDBOOK OF CHEMISTRY

Recommendations

Info

ORGANIC COMPOUNDS 1.31 1.1.3.13 Ethers (R19O9R 2 ). In substitutivenomenclature, oneof thepossibleradicals, R9O9, is stated as the prefix to the parent compound that is senior from among R1 or R2 . Examples are methoxyethane for CH3OCH2CH3 and butoxyethanol for C4H9OCH2CH2OH. When another principal group has precedence and oxygen is linking two identical parent compounds, the prefix oxy- may be used, as with 2,2-oxydiethanol for HOCH2CH2OCH2CH2OH. Compounds of thetypeRO9Y9OR, where the two parent compounds are identical and contain a group having priority over ethers for citation as suffix, are named as assemblies of identical units. For example, HOOC9CH29O9CH2CH29O9CH29COOH is named 2,2-(ethylenedioxy)diacetic acid. Linear polyethers derived from three or more molecules of aliphatic dihydroxy compounds, particularly when the chain length exceeds ten units, are most conveniently named by open-chain replacement nomenclature. For example, CH3CH29O9CH2CH29O9CH2CH3 could be3,6dioxaoctane or (2-ethoxy)ethoxyethane. An oxygen atom directly attached to two carbon atoms already forming part of a ring system or to two carbon atoms of a chain may be indicated by the prefix epoxy-. For example, CH29CH9CH2Cl is named 1-chloro-2,3-epoxypropane. O Symmetrical linear polyethers may be named (1) in terms of the central oxygen atom when there is an odd number of ether oxygen atoms or (2) in terms of the central hydrocarbon group when there is an even number of ether oxygen atoms. For example, C2H59O9C 4H89O9C 4H89O9C 2H5 is bis-(4-ethoxybutyl)ether, and 3,6-dioxaoctane (earlier example) could be named 1,2bis(ethoxy)ethane. Partial ethers of polyhydroxy compounds may be named (1) by substitutive nomenclature or (2) by stating thenameof thepolyhydroxy compound followed by thenameof theetherifying radical(s) followed by the word ether. For example, (1) 3-Butoxy-1,2-propanediol (2) Glycerol 1-butyl ether; also, 1-O-butylglycerol Cyclic ethers are named either as heterocyclic compounds or by specialist rules of heterocyclic nomenclature. Radicofunctional names are formed by citing the names of the radicals R 1 and R 2 followed by the word ether. Thus methoxyethane becomes ethyl methyl ether and ethoxyethane becomes diethyl ether. 1.1.3.14 Halogen Derivatives. Using substitutive nomenclature, names are formed by adding prefixes listed in Table 1.8 to the name of the parent compound. The prefix perhalo- implies the replacement of all hydrogen atoms by the particular halogen atoms. Cations of thetypeR 1 R 2 X are given names derived from the halonium ion, H 2X , by substitution, e.g., diethyliodonium chloride for (C 2H 5) 2I Cl . Retained are these trivial names; bromoform (CHBr 3), chloroform (CHCl 3), fluoroform (CHF 3), iodoform (CHI 3), phosgene (COCl 2), thiophosgene (CSCl 2), and dichlorocarbene radical ( CCl 2). Inorganic nomenclature leads to such names as carbonyl and thiocarbonyl halides (COX 2 and CSX 2) and carbon tetrahalides (CX 4). 1.1.3.15 Hydroxylamines and Oximes. For RNH9OH compounds, prefix the name of the radical R to hydroxylamine. If another substituent has priority as principal group, attach the prefix
1.32 SECTION 1 hydroxyamino- to the parent name. For example, C 6H 5NHOH would benamed N-phenylhydroxylamine, but HOC 6H 4NHOH would be(hydroxyamino)phenol, with thepoint of attachment indicated by a locant preceding the parentheses. Compounds of thetypeR 1 NH9OR 2 are named (1) as alkoxyamino derivatives of compound R 1 H, (2) as N,O-substituted hydroxylamines, (3) as alkoxyamines (even if R 1 is hydrogen), or (4) by the prefix aminooxy- when another substituent has priority for parent name. Examples of each type are 1. 2-(Methoxyamino)-8-naphthalenecarboxylic acid for CH3ONH9C 10H6COOH 2. O-Phenylhydroxylamine for H2N9O9C 6H5 or N-phenylhydroxylamine for C6H5NH9OH 3. Phenoxyamine for H2N9O9C 6H5 (not preferred to O-phenylhydroxylamine) 4. Ethyl (aminooxy)acetate for H2N9O9CH2CO9OC2H5 Acyl derivatives, RCO9NH9OH and H 2N9O9CO9R, arenamed as N-hydroxy derivatives of amides and as O-acylhydroxylamines, respectively. The former may also be named as hydroxamic acids. Examples are N-hydroxyacetamide for CH 3CO9NH9OH and O-acetylhydroxylaminefor H 2N9O9CO9CH 3. Further substituents are denoted by prefixes with O- and/or Nlocants. For example, C 6H 5NH9O9C 2H 5 would be O-ethyl-N-phenylhydroxylamine or N-ethoxylaniline. For oximes, the word oxime is placed after the name of the aldehyde or ketone. If the carbonyl group is not theprincipal group, usetheprefix hydroxyimino-. Compounds with thegroup N9OR are named by a prefix alkyloxyimino- as oxime O-ethers or as O-substituted oximes. Compounds with thegroup C"N(O)R arenamed by adding N-oxideafter thenameof thealkylideneaminc compound. For amineoxides, add theword oxide after thenameof thebase, with locants. For example, C 5H 5N9O is named pyridine N-oxideor pyridine1-oxide. 1.1.3.16Imines. Thegroup C"NH is named either by the suffix -imine or by citing the nameof thebivalent radical R 1 R 2 C as a prefix to amine. For example, CH 3CH 2CH 2CH"NH could be named 1-butanimine or butylideneamine. When the nitrogen is substituted, as in CH 2"N9CH 2CH 3, thenameis N-(methylidene)ethylamine. Quinones are exceptions. When one or more atoms of quinonoid oxygen have been replaced by NH or NR, they arenamed by using thenameof thequinonefollowed by theword imine (and preceded by proper affixes). Substituents on the nitrogen atom are named as prefixes. Examples are p-Benzoquinone monoimine p-Benzoquinone diimine 1.1.3.17 Ketenes. Derivatives of the compound ketene, CH 2"C"O, arenamed by substitutive nomenclature. For example, C 4H 9CH"C"O is butyl ketene. An acyl derivative, such as CH 3CH 29CO9CH 2CH"C"O, may be named as a polyketone, 1-hexene-1,4-dione. Bisketene is used for two to avoid ambiguity with diketene (dimeric ketene). 1.1.3.18 Ketones. Acyclic ketones are named (1) by adding the suffix -one to the name of the hydrocarbon forming theprincipal chain or (2) by citing thenames of theradicals R 1 and R 2 followed
Page 1 and 2: LANGE'S HANDBOOK OF CHEMISTRY John
Page 3 and 4: Grateful acknowledgment is hereby m
Page 5 and 6: PREFACE TO FIFTEENTH EDITION This n
Page 7 and 8: PREFACE TO FIFTEENTH EDITION ix inv
Page 9 and 10: xii PREFACE TO FOURTEENTH EDITION l
Page 11 and 12: PREFACE TO FIRST EDITION This book
Page 13 and 14: For the detailed contents of any se
Page 15 and 16: 1.2 SECTION 1 is derived from the G
Page 17 and 18: 1.4 SECTION 1 rather than methylide
Page 19 and 20: 1.6 SECTION 1 Styrene Toluene Xylen
Page 21 and 22: 1.8 SECTION 1 TABLE 1.2 Fused Polyc
Page 23 and 24: 1.10 SECTION 1 1.1.1.6 Bridged Hydr
Page 25 and 26: 1.12 SECTION 1 TABLE 1.4 Suffixes f
Page 27 and 28: 1.14 SECTION 1 TABLE 1.5 Trivial Na
Page 29 and 30: 1.16 SECTION 1 TABLE 1.6 Trivial Na
Page 31 and 32: 1.18 SECTION 1 Selection of the pri
Page 33 and 34: 1.20 SECTION 1 attached to one anot
Page 35 and 36: 1.22 SECTION 1 When side chains of
Page 37 and 38: 1.24 SECTION 1 heterocyclic structu
Page 39 and 40: 1.26 SECTION 1 Bivalent radicals of
Page 41 and 42: 1.28 SECTION 1 Complex linear polya
Page 43: 1.30 SECTION 1 TABLE 1.11 Names of
Page 47 and 48: 1.34 SECTION 1 may be named (1) by
Page 49 and 50: 1.36 SECTION 1 Examples are methyl
Page 51 and 52: 1.38 SECTION 1 tuted acid, respecti
Page 53 and 54: 1.40 SECTION 1 FIGURE 1.2 Newman pr
Page 55 and 56: 1.42 SECTION 1 from the ring are kn
Page 57 and 58: 1.44 SECTION 1 FIGURE 1.11 Two isom
Page 59 and 60: 1.46 SECTION 1 Chiral Center. The c
Page 61 and 62: 1.48 SECTION 1 FIGURE 1.15 Isomers
Page 63 and 64: 1.50 SECTION 1 entries to bring tog
Page 65 and 66: 1.52 SECTION 1 TABLE 1.13 Names and
Page 73 and 74: 1.60 SECTION 1 TABLE 1.14 Empirical
Page 89 and 90: 2.2 SECTION 2 2.3.6 Student’s Dis
Page 91 and 92: 2.4 SECTION 2 TABLE 2.1 Fundamental
Page 93 and 94: 2.6 SECTION 2 TABLE 2.1 Fundamental
Page 95 and 96:
2.8 SECTION 2 TABLE 2.2 Physical an
Page 97 and 98:
2.10 SECTION 2 TABLE 2.2 Physical a
Page 99 and 100:
Page 101 and 102:
Page 103 and 104:
Page 105 and 106:
Page 107 and 108:
Page 109 and 110:
Page 111 and 112:
2.24 SECTION 2 TABLE 2.3 Mathematic
Page 113 and 114:
2.26 SECTION 2 TABLE 2.6 Abbreviati
Page 115 and 116:
Page 117 and 118:
Page 119 and 120:
Page 121 and 122:
Page 123 and 124:
2.36 SECTION 2 TABLE 2.7 Conversion
Page 125 and 126:
Page 127 and 128:
Page 129 and 130:
Page 131 and 132:
Page 133 and 134:
Page 135 and 136:
Page 137 and 138:
Page 139 and 140:
Page 141 and 142:
2.54 SECTION 2 TABLE 2.8 Temperatur
Page 143 and 144:
Page 145 and 146:
Page 147 and 148:
Page 149 and 150:
Page 151 and 152:
Page 153 and 154:
2.66 SECTION 2 2.1.1 Conversion of
Page 155 and 156:
2.68 SECTION 2 Oleometer. A hydrome
Page 157 and 158:
2.70 SECTION 2 Example 3. To find t
Page 159 and 160:
2.72 SECTION 2 TABLE 2.9 Barometer
Page 161 and 162:
2.74 SECTION 2 TABLE 2.9 Barometer
Page 163 and 164:
2.76 SECTION 2 TABLE 2.10 Barometri
Page 165 and 166:
2.78 SECTION 2 TABLE 2.12 Reduction
Page 167 and 168:
2.80 SECTION 2 TABLE 2.12 Reduction
Page 169 and 170:
2.82 SECTION 2 TABLE 2.13 Viscosity
Page 171 and 172:
2.84 SECTION 2 TABLE 2.14 Conversio
Page 173 and 174:
2.86 SECTION 2 TABLE 2.15 Hydromete
Page 175 and 176:
2.88 SECTION 2 TABLE 2.17 Correctio
Page 177 and 178:
2.90 SECTION 2 TABLE 2.18 Molar Equ
Page 179 and 180:
2.92 SECTION 2 TABLE 2.19 Factors f
Page 181 and 182:
2.94 SECTION 2 TABLE 2.19 Factors f
Page 183 and 184:
2.96 SECTION 2 TABLE 2.20 Values of
Page 185 and 186:
2.98 SECTION 2 TABLE 2.21 Transmitt
Page 187 and 188:
2.100 SECTION 2 TABLE 2.21 Transmit
Page 189 and 190:
2.102 SECTION 2 2.2 MATHEMATICAL TA
Page 191 and 192:
2.104 SECTION 2 TABLE 2.23 Derivati
Page 193 and 194:
2.106 SECTION 2 TABLE 2.24 Integral
Page 195 and 196:
2.108 SECTION 2 TABLE 2.24 Integral
Page 197 and 198:
2.110 SECTION 2 Regular Polygon of
Page 199 and 200:
2.112 SECTION 2 A h[0.4(y y ) 1.
Page 201 and 202:
2.114 SECTION 2 2.2.3.1 Signs of th
Page 203 and 204:
2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
Page 205 and 206:
2.118 SECTION 2 2.3.2 Errors in Qua
Page 207 and 208:
2.120 SECTION 2 The breadth or spre
Page 209 and 210:
2.122 SECTION 2 TABLE 2.26b Areas U
Page 211 and 212:
2.124 SECTION 2 The distribution of
Page 213 and 214:
2.126 SECTION 2 Should there be mor
Page 215 and 216:
2.128 SECTION 2 Example 10 Six samp
Page 217 and 218:
2.130 SECTION 2 2.3.9 The F Statist
Page 219 and 220:
TABLE 2.29 F Distribution (Continue
Page 221 and 222:
2.134 SECTION 2 mathematical treatm
Page 223 and 224:
2.136 SECTION 2 The confidence limi
Page 225 and 226:
2.138 SECTION 2 situation where rel
Page 227 and 228:
3.2 SECTION 3 The alphabetical orde
Page 229 and 230:
3.4 SECTION 3 When it is required t
Page 231 and 232:
3.6 SECTION 3 PO phosphoryl SeO sel
Page 233 and 234:
3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
Page 235 and 236:
3.10 SECTION 3 3.1.6.6 Multiplicati
Page 237 and 238:
3.12 SECTION 3 3.2 PHYSICAL PROPERT
Page 239 and 240:
TABLE 3.2 Physical Constants of Ino
Page 241 and 242:
3.16 TABLE 3.2 Physical Constants o
Page 243 and 244:
Page 245 and 246:
Page 247 and 248:
Page 249 and 250:
Page 251 and 252:
Page 253 and 254:
Page 255 and 256:
Page 257 and 258:
Page 259 and 260:
Page 261 and 262:
Page 263 and 264:
Page 265 and 266:
Page 267 and 268:
Page 269 and 270:
Page 271 and 272:
Page 273 and 274:
Page 275 and 276:
Page 277 and 278:
Page 279 and 280:
Page 281 and 282:
Page 283 and 284:
Page 285 and 286:
Page 287 and 288:
3.62 SECTION 3 TABLE 3.3 Synonyms a
Page 289 and 290:
SECTION 4 PROPERTIES OF ATOMS, RADI
Page 291 and 292:
4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
Page 293 and 294:
4.5 Silver (argentum) Ag 47 [Kr] 4d
Page 295 and 296:
PROPERTIES OF ATOMS,RADICALS,AND BO
Page 297 and 298:
Page 299 and 300:
Page 301 and 302:
Page 303 and 304:
Page 305 and 306:
Page 307 and 308:
Page 309 and 310:
PROPERTIES OF ATOMS, RADICALS, AND
Page 311 and 312:
Page 313 and 314:
Page 315 and 316:
Page 317 and 318:
TABLE 4.5 Electronegativities of th
Page 319 and 320:
Page 321 and 322:
Page 323 and 324:
Page 325 and 326:
Page 327 and 328:
Page 329 and 330:
TABLE 4.11 Bond Dissociation Energi
Page 331 and 332:
Page 333 and 334:
Page 335 and 336:
Page 337 and 338:
Page 339 and 340:
Page 341 and 342:
Page 343 and 344:
Page 345 and 346:
Page 347 and 348:
TABLE 4.16 Table of Nuclides (Conti
Page 349 and 350:
Page 351 and 352:
Page 353 and 354:
Page 355 and 356:
Page 357 and 358:
Page 359 and 360:
Page 361 and 362:
Page 363 and 364:
Page 365 and 366:
Page 367 and 368:
Page 369 and 370:
Page 371 and 372:
Page 373 and 374:
SECTION 5 PHYSICAL PROPERTIES 5.1 S
Page 375 and 376:
5.1 SOLUBILITIES PHYSICAL PROPERTIE
Page 377 and 378:
TABLE 5.1 Solubility of Gases in Wa
Page 379 and 380:
TABLE 5.1 Solubility of Gases in Wa
Page 381 and 382:
TABLE 5.2 Solubilities of Inorganic
Page 383 and 384:
formateBa(CHO2) 2 26.2 28.0 29.9 31
Page 385 and 386:
(III) sulfateCe2(SO4) 3 ·9H2O 21.4
Page 387 and 388:
iodidePbI2 0.044 0.056 0.069 0.090
Page 389 and 390:
Nickel sulfateNiSO4 ·6H2O (pale bl
Page 391 and 392:
Praseodymium bromatePr(BrO 3) 3 55.
Page 393 and 394:
formate NaCHO 2 43.9 62.5 81.2 102
Page 395 and 396:
Uranyl nitrate UO 2(NO 3) 2 98 107
Page 397 and 398:
TABLE 5.3 Vapor Pressure of Mercury
Page 399 and 400:
TABLE 5.4 Vapor Pressure of Ice in
Page 401 and 402:
TABLE 5.6 Vapor Pressure of Water (
Page 403 and 404:
TABLE 5.8 Vapor Pressures of Variou
Page 405 and 406:
PHYSICAL PROPERTIES 5.33 TABLE 5.8
Page 407 and 408:
Page 409 and 410:
Page 411 and 412:
Page 413 and 414:
Page 415 and 416:
Page 417 and 418:
Page 419 and 420:
Page 421 and 422:
Page 423 and 424:
Page 425 and 426:
Page 427 and 428:
Page 429 and 430:
5.3 BOILING POINTS TABLE 5.10 Boili
Page 431 and 432:
TABLE 5.11 Binary Azeotropic (Const
Page 433 and 434:
Page 435 and 436:
Page 437 and 438:
Page 439 and 440:
Page 441 and 442:
Page 443 and 444:
Page 445 and 446:
Page 447 and 448:
Page 449 and 450:
TABLE 5.12 Ternary Azeotropic Mixtu
Page 451 and 452:
Page 453 and 454:
Page 455 and 456:
5.4 FREEZING MIXTURES TABLE 5.13 Co
Page 457 and 458:
TABLE 5.13 Compositions of Aqueous
Page 459 and 460:
5.5 DENSITY AND SPECIFIC GRAVITY TA
Page 461 and 462:
PHYSICAL PROPERTIES 5.89 d D t t
Page 463 and 464:
Page 465 and 466:
Page 467 and 468:
Page 469 and 470:
Page 471 and 472:
Page 473 and 474:
Page 475 and 476:
Page 477 and 478:
Page 479 and 480:
Page 481 and 482:
Page 483 and 484:
Page 485 and 486:
Page 487 and 488:
Page 489 and 490:
Page 491 and 492:
Page 493 and 494:
Page 495 and 496:
Page 497 and 498:
Page 499 and 500:
Page 501 and 502:
Page 503 and 504:
Page 505 and 506:
Page 507 and 508:
5.6.1 Refractive Index PHYSICAL PRO
Page 509 and 510:
PHYSICAL PROPERTIES 5.137 where the
Page 511 and 512:
5.7 COMBUSTIBLE MIXTURES TABLE 5.23
Page 513 and 514:
TABLE 5.23 Properties of Combustibl
Page 515 and 516:
Page 517 and 518:
Page 519 and 520:
Page 521 and 522:
Deuterium 1150 1222 1297 1372 1448
Page 523 and 524:
TABLE 5.25 Liquid Thermal Conductiv
Page 525 and 526:
Page 527 and 528:
TABLE 5.26 Thermal Conductivity of
Page 529 and 530:
TABLE 5.29 Van der Waals’ Constan
Page 531 and 532:
Page 533 and 534:
Page 535 and 536:
Page 537 and 538:
Page 539 and 540:
Page 541 and 542:
TABLE 5.30 Triple Points of Various
Page 543 and 544:
PHYSICAL PROPERTIES 5.171 This equa
Page 545 and 546:
SECTION 6 THERMODYNAMIC PROPERTIES
Page 547 and 548:
THERMODYNAMICPROPERTIES 6.3 6.1.1.2
Page 549 and 550:
THERMODYNAMICPROPERTIES 6.5 A gener
Page 551 and 552:
THERMODYNAMICPROPERTIES 6.7 TABLE 6
Page 553 and 554:
THERMODYNAMICPROPERTIES 6.9 TABLE 6
Page 555 and 556:
THERMODYNAMICPROPERTIES 6.11 TABLE
Page 557 and 558:
Page 559 and 560:
Page 561 and 562:
Page 563 and 564:
Page 565 and 566:
THERMODYNAMIC PROPERTIES 6.21 TABLE
Page 567 and 568:
Page 569 and 570:
Page 571 and 572:
Page 573 and 574:
Page 575 and 576:
Page 577 and 578:
Page 579 and 580:
Page 581 and 582:
Page 583 and 584:
Page 585 and 586:
Page 587 and 588:
Page 589 and 590:
Page 591 and 592:
Page 593 and 594:
Page 595 and 596:
Page 597 and 598:
Page 599 and 600:
Page 601 and 602:
Page 603 and 604:
Page 605 and 606:
Page 607 and 608:
Page 609 and 610:
Page 611 and 612:
Page 613 and 614:
Page 615 and 616:
Page 617 and 618:
Page 619 and 620:
Page 621 and 622:
Page 623 and 624:
Page 625 and 626:
Page 627 and 628:
Page 629 and 630:
Page 631 and 632:
Page 633 and 634:
Page 635 and 636:
Page 637 and 638:
Page 639 and 640:
Page 641 and 642:
Page 643 and 644:
Page 645 and 646:
THERMODYNAMIC PROPERTIES 6.101 TABL
Page 647 and 648:
Page 649 and 650:
Page 651 and 652:
Page 653 and 654:
Page 655 and 656:
Page 657 and 658:
Page 659 and 660:
Page 661 and 662:
Page 663 and 664:
Page 665 and 666:
Page 667 and 668:
Page 669 and 670:
Page 671 and 672:
Page 673 and 674:
Page 675 and 676:
Page 677 and 678:
Page 679 and 680:
PClF 3 THERMODYNAMIC PROPERTIES 6.1
Page 681 and 682:
Page 683 and 684:
Page 685 and 686:
Page 687 and 688:
THERMODYNAMIC PROPERTIES 6.143 The
Page 689 and 690:
TABLE 6.5 Critical Properties (Cont
Page 691 and 692:
Page 693 and 694:
Page 695 and 696:
Page 697 and 698:
Page 699 and 700:
Page 701 and 702:
Page 703 and 704:
SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
Page 705 and 706:
TABLE 7.1 Wavelengths of X-Ray Emis
Page 707 and 708:
SPECTROSCOPY 7.5 TABLE 7.1 Waveleng
Page 709 and 710:
TABLE 7.2 Wavelengths of Absorption
Page 711 and 712:
TABLE 7.3 Critical X-Ray Absorption
Page 713 and 714:
TABLE 7.4 X-Ray Emission Energies i
Page 715 and 716:
SPECTROSCOPY 7.13 Emission line K 1
Page 717 and 718:
TABLE 7.7 Analyzing Crystals for X-
Page 719 and 720:
SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
Page 721 and 722:
TABLE 7.9 Electronic Absorption Ban
Page 723 and 724:
TABLE 7.11 Absorption Wavelength of
Page 725 and 726:
SPECTROSCOPY 7.23 TABLE 7.13 Solven
Page 727 and 728:
7.3 FLUORESCENCE TABLE 7.16 Fluores
Page 729 and 730:
SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 731 and 732:
TABLE 7.18 Detection Limits in ng/m
Page 733 and 734:
Page 735 and 736:
Page 737 and 738:
TABLE 7.19 Sensitive Lines of the E
Page 739 and 740:
TABLE 7.19 Sensitive Lines of the E
Page 741 and 742:
In terms of m, the wavenumber of m
Page 743 and 744:
The ionization constant can be calc
Page 745 and 746:
SPECTROSCOPY 7.43 TABLE 7.20 Absorp
Page 747 and 748:
Page 749 and 750:
Page 751 and 752:
TABLE 7.22 Absorption Frequencies o
Page 753 and 754:
Page 755 and 756:
Page 757 and 758:
Page 759 and 760:
Page 761 and 762:
Page 763 and 764:
Page 765 and 766:
Page 767 and 768:
TABLE 7.27 Absorption Frequencies i
Page 769 and 770:
TABLE 7.28 Infrared Transmitting Ma
Page 771 and 772:
7.69
Page 773 and 774:
7.6 RAMAN SPECTROSCOPY SPECTROSCOPY
Page 775 and 776:
SPECTROSCOPY 7.73 TABLE 7.30 Raman
Page 777 and 778:
SPECTROSCOPY 7.75 TABLE 7.30 Raman
Page 779 and 780:
TABLE 7.32 Raman Frequencies of Cum
Page 781 and 782:
TABLE 7.33 Raman Frequencies of Car
Page 783 and 784:
TABLE 7.34 Raman Frequencies of Oth
Page 785 and 786:
TABLE 7.35 Raman Frequencies of Aro
Page 787 and 788:
TABLE 7.36 Raman Frequencies of Sul
Page 789 and 790:
TABLE 7.39 Raman Frequencies of Mis
Page 791 and 792:
7.7 NUCLEAR MAGNETIC RESONANCE TABL
Page 793 and 794:
TABLE 7.41 Nuclear Properties of th
Page 795 and 796:
TABLE 7.42 Proton Chemical Shifts (
Page 797 and 798:
SPECTROSCOPY 7.95 TABLE 7.44 Estima
Page 799 and 800:
TABLE 7.46 Proton Spin Coupling Con
Page 801 and 802:
SPECTROSCOPY 7.99 TABLE 7.48 Solven
Page 803 and 804:
TABLE 7.49 Carbon-13 Chemical Shift
Page 805 and 806:
SPECTROSCOPY 7.103 TABLE 7.51 Effec
Page 807 and 808:
TABLE 7.54 Carbon-13 Chemical Shift
Page 809 and 810:
TABLE 7.56 One-Bond Carbon-Hydrogen
Page 811 and 812:
TABLE 7.58 Carbon-Carbon Spin Coupl
Page 813 and 814:
7 Li CH3Li 15 SPECTROSCOPY 7.111 TA
Page 815 and 816:
TABLE 7.63 Nitrogen-15 (or Nitrogen
Page 817 and 818:
TABLE 7.64 Nitrogen-15 Chemical Shi
Page 819 and 820:
TABLE 7.69 Fluorine-19 Chemical Shi
Page 821 and 822:
TABLE 7.72 Silicon-29 Chemical Shif
Page 823 and 824:
TABLE 7.73 Phosphorus-31 Chemical S
Page 825 and 826:
TABLE 7.74 Phosphorus-31 Spin Coupl
Page 827 and 828:
when z 3 and y 1. The empirical f
Page 829 and 830:
Masses 19 and 31 Alcohol Mass 66
Page 831 and 832:
TABLE 7.76 Condensed Table of Mass
Page 833 and 834:
Page 835 and 836:
Page 837 and 838:
Page 839 and 840:
Page 841 and 842:
SECTION 8 ELECTROLYTES, ELECTROMOTI
Page 843 and 844:
ELECTROLYTES, EMF, AND CHEMICAL EQU
Page 845 and 846:
Page 847 and 848:
Page 849 and 850:
Page 851 and 852:
Page 853 and 854:
Page 855 and 856:
Page 857 and 858:
Page 859 and 860:
TABLE 8.7 Proton Transfer Reactions
Page 861 and 862:
TABLE 8.7 Proton Transfer Reactions
Page 863 and 864:
Page 865 and 866:
Page 867 and 868:
Page 869 and 870:
Page 871 and 872:
Page 873 and 874:
Page 875 and 876:
Page 877 and 878:
Page 879 and 880:
Page 881 and 882:
Page 883 and 884:
Page 885 and 886:
Page 887 and 888:
Page 889 and 890:
Page 891 and 892:
Page 893 and 894:
Page 895 and 896:
Page 897 and 898:
Page 899 and 900:
Page 901 and 902:
Page 903 and 904:
Page 905 and 906:
Page 907 and 908:
Page 909 and 910:
Page 911 and 912:
Page 913 and 914:
TABLE 8.9 Selected Equilibrium Cons
Page 915 and 916:
8.75 3-tert-Butylbenzoic acid (0) 4
Page 917 and 918:
4-Hydroxyproline (1) 1.900 1C 1.850
Page 919 and 920:
N-Propionylglycine (1) 3.728 3.723
Page 921 and 922:
Page 923 and 924:
Page 925 and 926:
Page 927 and 928:
Page 929 and 930:
Page 931 and 932:
Page 933 and 934:
Page 935 and 936:
Page 937 and 938:
Page 939 and 940:
Page 941 and 942:
Page 943 and 944:
Page 945 and 946:
TABLE 8.14 National Bureau of Stand
Page 947 and 948:
Page 949 and 950:
Page 951 and 952:
Page 953 and 954:
Page 955 and 956:
Page 957 and 958:
Page 959 and 960:
1 part 0.1% neutral red in alc. * V
Page 961 and 962:
TABLE 8.25 Fluorescent Indicators (
Page 963 and 964:
3,3-Dimethoxybenzidine dihydrochlor
Page 965 and 966:
Page 967 and 968:
Page 969 and 970:
Page 971 and 972:
Page 973 and 974:
Page 975 and 976:
Page 977 and 978:
Page 979 and 980:
Page 981 and 982:
Page 983 and 984:
Page 985 and 986:
Page 987 and 988:
Page 989 and 990:
Page 991 and 992:
Page 993 and 994:
Page 995 and 996:
Page 997 and 998:
8.7 CONDUCTANCE ELECTROLYTES, EMF,
Page 999 and 1000:
Page 1001 and 1002:
Page 1003 and 1004:
TABLE 8.35 Equivalent Conductivitie
Page 1005 and 1006:
KCl 127.3 124.4 122.4 115.8 112.0 1
Page 1007 and 1008:
NaIO 3 75.2 72.6 70.9 64.4 60.5 1
Page 1009 and 1010:
Conductance of an Electrolyte Solut
Page 1011 and 1012:
9.2 SECTION 9 9.1 LINEAR FREE ENERG
Page 1013 and 1014:
9.4 SECTION 9 TABLE 9.1 Hammett and
Page 1015 and 1016:
9.6 SECTION 9 TABLE 9.1 Hammett and
Page 1017 and 1018:
9.8 SECTION 9 TABLE 9.3 pKa and Rho
Page 1019 and 1020:
10.2 SECTION 10 10.4.6 Polyacrylate
Page 1021 and 1022:
10.4 SECTION 10 10.2 ADDITIVES TO P
Page 1023 and 1024:
10.6 SECTION 10 injection molding.
Page 1025 and 1026:
10.8 SECTION 10 10.3 FORMULAS AND K
Page 1027 and 1028:
10.10 SECTION 10 Key properties of
Page 1029 and 1030:
10.12 SECTION 10 10.3.8 Fluorocarbo
Page 1031 and 1032:
10.14 SECTION 10 10.3.11 Phenolics
Page 1033 and 1034:
10.16 SECTION 10 The resin has the
Page 1035 and 1036:
10.18 SECTION 10 10.3.19 Polyuretha
Page 1037 and 1038:
10.20 SECTION 10 10.3.22 Sulfones B
Page 1039 and 1040:
TABLE 10.2 Properties of Commercial
Page 1041 and 1042:
Page 1043 and 1044:
Page 1045 and 1046:
Page 1047 and 1048:
Page 1049 and 1050:
Page 1051 and 1052:
Page 1053 and 1054:
Page 1055 and 1056:
Page 1057 and 1058:
Page 1059 and 1060:
Page 1061 and 1062:
Page 1063 and 1064:
Page 1065 and 1066:
Page 1067 and 1068:
Page 1069 and 1070:
Page 1071 and 1072:
Page 1073 and 1074:
Page 1075 and 1076:
10.58 SECTION 10 10.4 FORMULAS AND
Page 1077 and 1078:
10.60 SECTION 10 10.4.8 Polychlorop
Page 1079 and 1080:
10.62 SECTION 10 Styrene-butadiene
Page 1081 and 1082:
10.5 CHEMICAL RESISTANCE TABLE 10.4
Page 1083 and 1084:
10.6 GAS PERMEABILITY TABLE 10.5 Ga
Page 1085 and 1086:
TABLE 10.5 Gas Permeability Constan
Page 1087 and 1088:
TABLE 10.7 Constants ofFats and Oil
Page 1089 and 1090:
TABLE 10.8 Constants ofWaxes Wax Me
Page 1091 and 1092:
SECTION 11 PRACTICAL LABORATORY INF
Page 1093 and 1094:
11.1 COOLING TABLE 11.1 Cooling Mix
Page 1095 and 1096:
11.2 DRYING AND HUMIDIFICATION TABL
Page 1097 and 1098:
PRACTICAL LABORATORY INFORMATION 11
Page 1099 and 1100:
TABLE 11.7 Relative Humidity from D
Page 1101 and 1102:
3-Methyl-1-butanol 132.0 Cyclohexyl
Page 1103 and 1104:
TABLE 11.9 Molecular Elevation of t
Page 1105 and 1106:
Page 1107 and 1108:
TABLE 11.11 Solvents of Chromatogra
Page 1109 and 1110:
Page 1111 and 1112:
TABLE 11.13 McReynolds’ Constants
Page 1113 and 1114:
Page 1115 and 1116:
Page 1117 and 1118:
Page 1119 and 1120:
FIGURE 11.1 Profile of a solute ban
Page 1121 and 1122:
Page 1123 and 1124:
TABLE 11.16 Guide to Ion-Exchange R
Page 1125 and 1126:
TABLE 11.16 Guide to Ion-Exchange R
Page 1127 and 1128:
Page 1129 and 1130:
Page 1131 and 1132:
11.5 GRAVIMETRIC ANALYSIS TABLE 11.
Page 1133 and 1134:
TABLE 11.19 Gravimetric Factors (Co
Page 1135 and 1136:
Page 1137 and 1138:
Page 1139 and 1140:
Page 1141 and 1142:
Page 1143 and 1144:
Page 1145 and 1146:
Page 1147 and 1148:
Page 1149 and 1150:
Page 1151 and 1152:
Page 1153 and 1154:
Page 1155 and 1156:
Page 1157 and 1158:
Page 1159 and 1160:
Sodium tetraphenylborate, NaB(C 6H
Page 1161 and 1162:
TABLE 11.24 Porosities of Fritted G
Page 1163 and 1164:
TABLE 11.26 HeatingTemperatures, Co
Page 1165 and 1166:
Page 1167 and 1168:
TABLE 11.28 Titrimetric (Volumetric
Page 1169 and 1170:
Page 1171 and 1172:
Page 1173 and 1174:
Page 1175 and 1176:
Page 1177 and 1178:
HN 3 PRACTICAL LABORATORY INFORMATI
Page 1179 and 1180:
11.6.5 Precipitation Titrations PRA
Page 1181 and 1182:
Page 1183 and 1184:
Page 1185 and 1186:
TABLE 11.31 Indicators for Precipit
Page 1187 and 1188:
TABLE 11.33 Variation of 4 with pH
Page 1189 and 1190:
Page 1191 and 1192:
TABLE 11.38 Common Demasking Agents
Page 1193 and 1194:
TABLE 11.41 Pipet Capacity Toleranc
Page 1195 and 1196:
TABLE 11.45 Cubical Coefficients of
Page 1197 and 1198:
TABLE 11.48 Standard Stock Solution
Page 1199 and 1200:
TABLE 11.48 Standard Stock Solution
Page 1201 and 1202:
Page 1203 and 1204:
Page 1205 and 1206:
Page 1207 and 1208:
Page 1209 and 1210:
Page 1211 and 1212:
Page 1213 and 1214:
Page 1215 and 1216:
Page 1217 and 1218:
Page 1219 and 1220:
Page 1221 and 1222:
Page 1223 and 1224:
Page 1225 and 1226:
Page 1227 and 1228:
11.8 SIEVES AND SCREENS TABLE 11.53
Page 1229 and 1230:
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
Page 1233 and 1234:
TABLE 11.57 Type E Thermocouples: N
Page 1235 and 1236:
TABLE 11.59 Type K Thermocouples: N
Page 1237 and 1238:
TABLE 11.61 Type R Thermocouples: P
Page 1239 and 1240:
TABLE 11.63 Type T Thermocouples: C
Page 1241 and 1242:
Index Terms Links Abbreviations: of
Page 1243 and 1244:
Index Terms Links Aggregation, stat
Page 1245 and 1246:
Index Terms Links Anions, inorganic
Page 1247 and 1248:
Index Terms Links Benzoylacetone, f
Page 1249 and 1250:
Index Terms Links Carbon-carbon: bo
Page 1251 and 1252:
Index Terms Links Chemical shifts:
Page 1253 and 1254:
Index Terms Links Correction for so
Page 1255 and 1256:
Index Terms Links Dielectric streng
Page 1257 and 1258:
Index Terms Links Emergent stem cor
Page 1259 and 1260:
Index Terms Links Excitation wavele
Page 1261 and 1262:
Index Terms Links Gases: equations
Page 1263 and 1264:
Index Terms Links Hydrogen: binary
Page 1265 and 1266:
Index Terms Links Iodine: bond diss
Page 1267 and 1268:
Index Terms Links Lithium: bond dis
Page 1269 and 1270:
Index Terms Links Mode for set of n
Page 1271 and 1272:
Index Terms Links Nitrogen-oxygen d
Page 1273 and 1274:
Index Terms Links Peak asymmetry fa
Page 1275 and 1276:
Index Terms Links Polybutylene poly
Page 1277 and 1278:
Index Terms Links Precipitates, hea
Page 1279 and 1280:
Index Terms Links Rankine scale, co
Page 1281 and 1282:
Index Terms Links Selection rules:
Page 1283 and 1284:
Index Terms Links Specific gravity:
Page 1285 and 1286:
Index Terms Links Sulfuric acid sol
Page 1287 and 1288:
Index Terms Links Thiosulfate: form
Page 1289 and 1290:
Index Terms Links Vaporization: ent
Page 1291:
Index Terms Links Zincon, formation
show all

LANGE'S HANDBOOK OF CHEMISTRY

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?