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5" day - Central Institute of Brackishwater Aquaculture

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2. IDENTIFICATION AND MANAGEMtKT OF ACID SULPEUTE SOILS IN<br />

SHRIMP FARMS<br />

Acid W sedimcmr known u rid sulphue soib (ASS) hve bun<br />

ikntifmd nsanly u a major sut+ <strong>of</strong> p r o m pmb*mc in Sourh<br />

AI*.SovmE.nA.4E.n~ML.mdAIumlLAoidrulphmBoibIrC<br />

cxtmrlvc on couul pbs in the bwpb buc am less oanmon in temprme Mom.<br />

Anempu to recl.bn aopiul nungrove swunpl fa 8quruh md rice poductions<br />

<strong>of</strong>ten haw mulled in the dcvelopmat <strong>of</strong> unpoductive wid sulphatc roils. It has<br />

been estimated that India hr ova 2 million ha <strong>of</strong> ASS that have the pamtial to csua<br />

long-term production pmblomr. if cxuvmtd. Oxidised AS% ware louted in shrimp<br />

h and along unrlr that umncst &imp padr to thc emury.<br />

Acld ~lph- mll ir cbc mmmon nmnc given to mil md adimant maining<br />

oxidiubb, a rlmdy oxidimd arlphida. Thc piacipl form <strong>of</strong> rulphii is iron<br />

pyrirc (cubic Feh) although ocher forms Nth u monaulphidm exin in smalkr<br />

concmmtions. If the roil m ins in a reduced condition so that no oxidation <strong>of</strong> the<br />

sulphide occun. the soil is ref4 u a poccntial uid sulphate soil PASS) or a<br />

rulphudic soil (oxidisable sulphur compounds). Where (he sulphiks arc exposed to<br />

air, lo that oxidation un ukc p b, the roil is dled an achul acid sulphatc sot1<br />

(AASS) or tul&uric mil (fleld VH <strong>of</strong> 3.8 md chloride to wldutc mio in soil<br />

solutlon < 2 m d), Oxidisin8 con&tionr frrquently overlie reducik conditions in the<br />

some pr<strong>of</strong>ile so that M SS and PASS appl) to different pans <strong>of</strong>the same pmfik.<br />

2.1 Nahrc <strong>of</strong> .dd r8lpb8tc mils<br />

When the sea level rox and inundate pond. sulphatc in he seawater m~xed u ith<br />

land sediments containing iron oxides and organic maner. The resulting chemical<br />

reactions pmduced large qwtitiu <strong>of</strong> iron sulphidcr in the waterlogged sediments.<br />

Under nrmnl condltlonr iron ~ lphih layen ur cowmi by warn and colonlzcd by<br />

nallve vrgotation.<br />

~~fl, (s) + 4 SO,'. + ~CHIO + YI + F ~ 6) I + 8HCOj + 4Hfi<br />

Sedimmt Seawater Orgmic m*tcr 4?ite<br />

fhe five conditions nauury for the formation <strong>of</strong> sulphides in codstal sediments are<br />

I. Supply <strong>of</strong> sulphte<br />

2. Supply <strong>of</strong> easily decomposed orplnic W.<br />

3. An depute <strong>of</strong> iron<br />

4. Aluerobic conditions together with chcmiully reducing microbes<br />

flushing to remow soluble d o n p.oducu.<br />

5. Tidal action<br />

T & n g u mdimwtts wnahrtag Pyma mu ru- ud ammhk they<br />

damduadmdcka(*IW.. Hanr.iftb.ymniaod.ndqxpodmtheair,<br />

oxldulon rsub ud ~lpburlc wid b M. Thr ummvy leutmns lor rulpbwk<br />

widtamuionfraninmpyrh.8n:

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