Wisconsin's Role in Great Lakes Restoration - American Water ...
Wisconsin's Role in Great Lakes Restoration - American Water ...
Wisconsin's Role in Great Lakes Restoration - American Water ...
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The Importance of Quantify<strong>in</strong>g Gas Generation and Migration <strong>in</strong> Contam<strong>in</strong>ated<br />
Sediments<br />
Nathaniel R. Keller, RMT Inc., Madison, WI, nate.keller@rmt<strong>in</strong>c.com<br />
Ted M. O‘Connell, RMT Inc., Madison, WI, ted.oconnell@rmt<strong>in</strong>c.com<br />
Eugene L. McL<strong>in</strong>n, RMT Inc., Madison, WI, gene.mcl<strong>in</strong>n@rmt<strong>in</strong>c.com<br />
Thomas R. Stolzenburg, RMT Inc., Madison, WI, tom.stolzenburg@rmt<strong>in</strong>c.com<br />
Recent work by RMT at a number of contam<strong>in</strong>ated sediment sites has shown that ebullition<br />
(biogenic gas generation) with<strong>in</strong> sediment can cause migration of chemical contam<strong>in</strong>ation<br />
(specifically <strong>in</strong> NAPL form) <strong>in</strong>to the overly<strong>in</strong>g water column. This mechanism, which has<br />
previously not been recognized, is a critical parameter <strong>in</strong> remedy selection and design.<br />
Biogenic gas from sediments can cause functional failure of sediment caps. Examples of<br />
ebullition driven NAPL transport, cap failure, and gas quantification will be discussed. This talk<br />
will specifically focus on the means and methods currently be<strong>in</strong>g researched and used to<br />
measure gas generation from sediments. Gas generation measurement is much more<br />
challeng<strong>in</strong>g than other typically-measured sediment parameters, such as contam<strong>in</strong>ant<br />
concentration, bulk sediment properties, or even dissolved transport. Gas generation poses<br />
unique scal<strong>in</strong>g issues, spatial and temporal variations, and sampl<strong>in</strong>g device design<br />
challenges. This presentation will showcase a number of approaches that are be<strong>in</strong>g tested.<br />
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