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assessment of changes in the phosphorus status of forest ...

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assess P <strong>status</strong> or any <strong>changes</strong> <strong>in</strong> P <strong>status</strong> <strong>of</strong> soils by us<strong>in</strong>g simple methods, ra<strong>the</strong>r <strong>the</strong><br />

complex nature <strong>of</strong> <strong>in</strong>teractions requires special techniques <strong>of</strong>ten <strong>in</strong>volv<strong>in</strong>g a number<br />

<strong>of</strong> different methods. It was shown that P <strong>in</strong> <strong>the</strong> soil solution phase determ<strong>in</strong>es P<br />

uptake but it is <strong>the</strong> most dynamic component <strong>of</strong> soil P. Through solubility product<br />

diagrams it has been possible to assign <strong>the</strong> dom<strong>in</strong>ant <strong>in</strong>organic forms <strong>of</strong> P which may<br />

be determ<strong>in</strong><strong>in</strong>g <strong>the</strong> concentrations <strong>of</strong> P <strong>in</strong> soil solutions. A conceptual framework is<br />

normally used to assign differences <strong>in</strong> <strong>the</strong> lability <strong>of</strong> different soil P fractions with<br />

respect to <strong>the</strong>ir availability for uptake. Sequential extraction methods are used to<br />

obta<strong>in</strong> P fractions which are differently labile. However, not <strong>the</strong> easily labile fractions<br />

undergo <strong>changes</strong> <strong>in</strong> <strong>the</strong> long term but <strong>in</strong> many cases <strong>the</strong> fractions <strong>of</strong> moderate to low<br />

turnover <strong>in</strong>dicat<strong>in</strong>g <strong>the</strong> dynamic equilibria occurr<strong>in</strong>g among different forms <strong>of</strong> P. This<br />

creates a problem for select<strong>in</strong>g <strong>the</strong> suitable chemical fractions which could be<br />

extracted by appropriate methods. Consequently <strong>the</strong>re are many different types <strong>of</strong> soil<br />

P tests which are used both <strong>in</strong> agriculture and <strong>forest</strong>ry. Agricultural methods have<br />

been developed specifically to provide fertilizer recommendations for crops, and are<br />

thus <strong>of</strong> limited use to describe <strong>the</strong> long-term P <strong>status</strong> <strong>of</strong> <strong>forest</strong> soils. The limitations<br />

and advantages <strong>of</strong> various methods have been described.<br />

We recommend a method <strong>in</strong>clud<strong>in</strong>g repeated extractions <strong>of</strong> soil P by us<strong>in</strong>g an<br />

appropriate extractant. The selection <strong>of</strong> extractant(s) would require some <strong>in</strong>itial<br />

studies. Such a repeated desorption <strong>of</strong> P from soils will provide a capacity factor<br />

giv<strong>in</strong>g <strong>the</strong> amount <strong>of</strong> labile fraction and a desorption rate function which may be<br />

related to soil characteristics. Any change <strong>in</strong> those two parameters would <strong>the</strong>n<br />

<strong>in</strong>dicate a change <strong>in</strong> P <strong>status</strong> <strong>of</strong> soil. The development <strong>of</strong> <strong>the</strong> method should be done<br />

on a small but representative set <strong>of</strong> soils <strong>of</strong> <strong>the</strong> BZE collective. In order to save<br />

resources, for <strong>the</strong> rest <strong>of</strong> <strong>the</strong> samples <strong>the</strong>se parameters may be obta<strong>in</strong>ed by develop<strong>in</strong>g<br />

suitable models us<strong>in</strong>g NIRS or MIRS techniques. The proposed method will still<br />

require a high level <strong>of</strong> resource commitment to be made available <strong>in</strong> future under <strong>the</strong><br />

BZE program. Despite <strong>the</strong> major concerns <strong>of</strong> <strong>changes</strong> <strong>in</strong> P <strong>status</strong> <strong>of</strong> <strong>forest</strong> soils, this<br />

area <strong>of</strong> research has not received sufficient attention <strong>in</strong> <strong>the</strong> past.<br />

4. ACKNOWLEDGEMENTS<br />

A number <strong>of</strong> persons provided ideas, data evaluation and support for this document.<br />

We wish to thank for <strong>the</strong>ir efforts: Dr. Carl Hoecke, Dr. Jan Evers, Dr. Henn<strong>in</strong>g<br />

Meesenburg and Dr. Michael M<strong>in</strong>drup.<br />

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