NATO/CCMS Pilot Study Evaluation of Demonstrated and ... - CLU-IN

NATO/CCMS Pilot Project on Contaminated Land and Groundwater (Phase III) January 2002
A unified passive technological process for the in situ sorption of heavy metals, radionuclides, and textile
wastes using iron oxide-, alumina- and silica-based metallurgical solid wastes functioning as barrier
material in conjunction with granular metallic iron is on the way of development. The presumed process
is planned to be finished with in situ stabilization/solidification.
10. REFERENCES
1. S. Arayici, R. Apak and V. Apak, “Equilibrium modeling of pH in environmental treatment
processes,” J. Environ. Sci. and Health, Pt. A-Environ. Sci. and Eng., 31 (1996) 1127-1134.
2. R. Apak, G. Atun, K. Güçlü, E. Tütem and G. Keskin, “Sorptive removal of cesium-137 and
strontium-90 from water by unconventional sorbents. I. Usage of bauxite wastes (red muds),” J. Nucl.
Sci. Technol., 32 (1995) 1008-1017.
3. R. Apak, G. Atun, K. Güçlü and E. Tütem, “Sorptive removal of cesium-137 and strontium-90 from
water by unconventional sorbents. II. Usage of coal fly ash,” J. Nucl. Sci. Technol., 33 (1996) 396-
402.
4. F. Kilinçkale, S. Ayhan and R. Apak, “Solidification-stabilization of heavy metal-loaded red muds
and fly ashes,” J. Chem. Technol. Biotechnol., 69 (1997) 240-246.
5. R. Apak, E. Tütem, M. Hügül and J. Hizal, “Heavy metal cation adsorption onto unconventional
sorbents (red muds and fly ashes),” Water Research, 32 (1998) 430-440.
6. R. Apak, “Heavy metal and pesticide removal from contaminated groundwater by the use of
metallurgical waste sorbents,” NATO/CCMS International Meeting, 18-22 November 1991,
Washington, DC, USA.
7. R. Apak, “Uranium(VI) adsorption by soil in relation to speciation,” Mediterranean Conference on
Environmental Geotechnology, 24-27 May 1992, Çesme, Turkey.
8. E. Tütem and R. Apak, “The role of metal-ligand complexation equilibria in the retention and
mobilization of heavy metals in soil,” Contaminated Soil’95 Proceeding of the Fifth International
FZK/TNO Conference on Contaminated Soil, 30 Oct.-3 Nov. 1995, Maastricht, Netherlands, W. J.
van den Brink, R. Bosman and F. Arendt (eds.), Kluwer Academic Publishers, Vol. I, 425-426.
9. R. Apak, “Sorption/solidification of selected heavy metals and radionuclides from water,”
NATO/CCMS Pilot Study International Meeting on ‘Evaluation of Emerging and Demonstrated
Technologies for the Treatment of Contaminated Land and Groundwater’, 17-21 March 1997, Golden
Colorado, USA.
10. K. Güçlü, unpublished Ph.D. thesis (Supervisor: R. Apak), “Investigation and modeling of heavy
metal adsorption dependent upon pH and complexing agents,” Department of Chemistry, Faculty of
Engineering, Istanbul University, 1999, Istanbul.
11. M. Hapka, J. S. Thompson and J. M. Whang, “Method for precipitating a solid phase of metal,” 1995,
provisional patent application.
12. R. R. Rumer and J. K. Mitchell, “Assessment of barrier containment technologies,” International
Containment Technology Workshop, 29-31 Aug. 1995, Baltimore, Maryland: Proceedings, pp. 221-
223.
13. K. Güçlü and R. Apak, “Investigation of adsorption of free- and bound- EDTA onto red muds for
modeling the uptake of metal-organic complexes by hydrated oxides,” 19th International Meeting on
Organic Geochemistry, 6-10 Sept. 1999, Istanbul (accepted as presentation).
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