Bayer CropScience AG Page 1 of 82 BCS-RD-D ... - IR-4 Project
Bayer CropScience AG Page 1 of 82 BCS-RD-D ... - IR-4 Project
Bayer CropScience AG Page 1 of 82 BCS-RD-D ... - IR-4 Project
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<strong>Bayer</strong> <strong>CropScience</strong> <strong>AG</strong> <strong>Page</strong> 21 <strong>of</strong> <strong>82</strong><br />
<strong>BCS</strong>-<strong>RD</strong>-D-ROCS Method-No. 00857<br />
D-40789 Monheim Report No. MR-099/04<br />
4.1.7 Standard Mixture Solutions<br />
Standard mixture solutions were prepared by dilution with acetonitrile/water mixture<br />
(2/8, v/v + 0.22 mL/L formic acid).<br />
Table 5: Preparation Scheme.<br />
No. Target Concentrations (mg/L)<br />
C1<br />
C2<br />
C3<br />
C4<br />
C5<br />
C6<br />
C7<br />
C8<br />
C9<br />
C10<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.05 each)<br />
[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.01 each)<br />
[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.005 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.002 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.001 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.0005 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.0001 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.00005 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.00001 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
[BYI], [Enol], [Ketohydroxy], [Mono-hydroxy],<br />
[Gluco] (0.000005 each)<br />
[[BYI- 13 C], [Enol- 13 C], [Ketohydroxy- 13 C],<br />
[Mono-hydroxy- 13 C], [Gluco- 13 C] (0.001 each)<br />
Prepared<br />
by Removal<br />
<strong>of</strong> (mL)<br />
*: acetonitrile/water (2/8, v/v + 0.22 mL/L formic acid).<br />
No. <strong>of</strong><br />
Solution<br />
Dilution to<br />
(mL)<br />
Solvent<br />
5 + 1 A2 + B2 100 *<br />
1 + 1 A2 + B2 100 *<br />
0.5 + 1 A2 + B2 100 *<br />
0.2 + 1 A2 + B2 100 *<br />
1 + 1 A3 + B2 100 *<br />
1 + 1 A4 + B2 100 *<br />
1 + 1 A5 + B2 100 *<br />
1 + 1 A6 + B2 100 *<br />
1 + 1 A8 + B2 100 *<br />
0.1 + 1 A6 + B2 100 *
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