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Hydrogen embrittlement in power plant steels - Indian Academy of ...

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<strong>Hydrogen</strong> <strong>embrittlement</strong> <strong>in</strong> <strong>power</strong> <strong>plant</strong> <strong>steels</strong> 443<br />

(a)<br />

STAGE II CRACK GROWTH RATE (m/sec)<br />

10 −5<br />

10 −6<br />

TEMPERATURE o C<br />

40 20 0 −20 −40 −60<br />

18 Ni (250) MARAGING STEEL<br />

133<br />

57<br />

28<br />

12 kN/m 2<br />

(b)<br />

60 40 20 0 −20 −40 −60<br />

3 . 0 3 . 4 3 . 8 4 . 2 4 . 6 5 . 0 3 . 0 3 . 4 3 . 8 4 . 2 4 . 6 5 . 0<br />

10 3 /T (K −1 )<br />

10 3 /T (K −1 )<br />

APPARENT THRESHOLD STRESS INTENSITY FACTOR (MPa m )<br />

120<br />

110<br />

100<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

18 Ni (250)<br />

18 Ni (200)<br />

P H2 = 133 kN/m 2<br />

Figure 15. Effect <strong>of</strong> temperature on (a) stage II crack growth rate for 18Ni (250) marag<strong>in</strong>g <strong>steels</strong>,<br />

(b) K IHE for two grades <strong>of</strong> marag<strong>in</strong>g steel (Gangl<strong>of</strong>f 1977).<br />

5.3 Yield strength<br />

For a wide variety <strong>of</strong> environments, K IHE exhibits a two-stage dependence on yield strength<br />

(figure 16) (Akhurst & Baker 1981). Below a yield strength <strong>of</strong> 690 MPa, crack growth susceptibility<br />

is not affected by yield strength. But at higher strength levels, K IHE decreases<br />

and reaches a lower limit<strong>in</strong>g value at 1300 MPa (Akhurst & Baker 1981). Our <strong>in</strong>vestigations<br />

(Parvathavarth<strong>in</strong>i 1995) on 9Cr–1Mo ferritic steel also showed similar trends (figure 17).<br />

In this <strong>in</strong>vestigation, constant load experiments on s<strong>in</strong>gle-edge notch specimens <strong>of</strong> different<br />

yield strengths with <strong>in</strong> situ hydrogen charg<strong>in</strong>g were conducted with vary<strong>in</strong>g K I values. High<br />

strength material (water-quenched from anneal<strong>in</strong>g temperature) exhibited lower K IHE compared<br />

to low strength material (air-cooled from anneal<strong>in</strong>g temperature). The crack growth<br />

100<br />

80<br />

KTH (MPa m )<br />

60<br />

40<br />

20<br />

0<br />

1000<br />

1200 1400 1600 1800 2000<br />

yield strength (MPa)<br />

Figure 16. K IHE as a function <strong>of</strong> yield strength for<br />

4340 steel (Akhurst & Baker 1981).

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