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Rahul Dewan - Jacobs University

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1. INTRODUCTION<br />

thinner than the absorption length of the material. Over the last decade, several concepts<br />

have been proposed to enhance the absorption of light in thin-film silicon solar<br />

cells. Most of the concepts are based on random nanotexturing of the contact layers of<br />

the solar cells. Conversion efficiencies higher than 10% have been demonstrated for<br />

amorphous and thin-film microcrystalline silicon solar cells by introducing randomly<br />

textured interfaces in the solar cell [6, 7]. For micromorph (amorphous and microcrystalline<br />

silicon) tandem solar cells stable efficiencies of up to 11.9% have been demonstrated<br />

using textured interfaces [8]. The introduction of textured interfaces reduces<br />

reflection losses and enhances light scattering and diffraction within the device. Due<br />

to multiple reflections within the silicon layer the optical path length of the incident<br />

light is greatly enhanced. This leads to a significantly enhanced short circuit current<br />

and quantum efficiency in the red and infrared part of the optical spectrum.<br />

1.2 Outline of the Thesis<br />

In order to understand the optical propagation within such thin-film devices, it is imperative<br />

to use numerical methods and solve the Maxwell’s equations rigorously. The<br />

finite difference time domain method, finite element method, or rigorous coupled wave<br />

analysis are commonly used to simulate the near-field and far-field wave propagation<br />

in such devices [9–13]. By considering the near field optics, the nanotexturing process<br />

for efficient solar cells can be understood and optimized. Within the scope of<br />

this thesis, the optical enhancement and losses of microcrystalline thin-film silicon solar<br />

cells with periodic surface textures were investigated. Beginning with a simplified<br />

grating structure, the investigation in this work sequentially moved onto investigating<br />

the influence of 3-dimensional pyramid textures on the optical wave propagation in<br />

the thin-film devices. The different design parameters and methods are discussed in<br />

the different chapters of this thesis. This thesis has been organized in such a way that<br />

each of the chapters can be read as stand alone chapters as well. The structure of the<br />

thesis is briefly described in the following:<br />

In chapter 2, the key parameters that entail the study of thin-film silicon solar<br />

cells are described. The optical properties of the different materials in the stratified<br />

thin-film solar cell stack are discussed. Understanding these properties and how these<br />

optical properties interact together in a solar cell is essential for optimization towards<br />

efficient solar cells. Theoretical limits on the absorption enhancement and efficiency<br />

of solar cells are derived, which serve as a benchmark for comparing the results in<br />

the later chapters. The commonly used light confinement techniques in research and<br />

production are also described.<br />

In chapter 3, the algorithms for the numerical methods used in this study are described.<br />

A brief recap on the fundamentals of electromagnetics theory was presented<br />

2

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