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doi:10.1595/147106711X554008<br />

•<strong>Platinum</strong> <strong>Metals</strong> Rev., 2011, 55, (2)•<br />

Iridium content, wt%<br />

Pt 20 40 60 80 Ir<br />

2454<br />

Gold content, at%<br />

Pt 20 40 60 80 Au<br />

1800<br />

2200<br />

Liquid<br />

1600<br />

Liquid<br />

Temperature, ºC<br />

1800<br />

1400<br />

1000<br />

1769<br />

α<br />

Temperature, ºC<br />

1400<br />

1200<br />

α<br />

α 1 α 2<br />

α 1 + α 2<br />

600<br />

Pt 20 40 60 80 Ir<br />

Iridium content, at%<br />

Fig. 26. Pt-Ir phase diagram showing a miscibility<br />

gap at low temperatures (20)<br />

1000<br />

800<br />

Pt 20 40 60 80 Au<br />

Gold content, wt%<br />

Fig. 27. Pt-Au phase diagram showing a miscibility<br />

gap at low temperature (25)<br />

2 mm<br />

200 µm<br />

2 mm<br />

Fig. 28. Pt-5Cu alloy: from a transverse<br />

section of a 19 mm × 19 mm<br />

ingot, which was rod milled,<br />

annealed in a furnace and finished<br />

at 10 mm × 10 mm by drawing. The<br />

sample shows residual coarse grain<br />

microstructure from the as-cast<br />

condition and fractures along the bar<br />

axis (microhardness 208 ± 13 HV 200 ).<br />

The small square shows the position<br />

of the detail seen in Figure 29<br />

Fig. 29. Pt-5Cu alloy: detail of<br />

Figure 28, with coarse grains and<br />

small opened cracks evident<br />

Fig. 30. Pt-5Cu alloy: from a transverse<br />

section of a 19 mm × 19 mm<br />

bar, which was hot hammered,<br />

torch annealed and finished by<br />

drawing. The sample has<br />

homogeneous microstructure with<br />

small grain size (microhardness<br />

200 ± 9 HV 200 ). The small square<br />

shows the position of the detail<br />

seen in Figure 31<br />

81 © 2011 Johnson Matthey

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