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[Luyben] Process Mod.. - Student subdomain for University of Bath

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84 MATHEMATICAL MODELS OF CHEMICAL ENGINEERING SYSTEMS<br />

level controllers. Reflux flows are fixed. Steam flows to the reboilers are set by<br />

temperature controllers. Assume equimolal overflow, negligible vapor holdup, and<br />

negligible condenser and reboiler dynamics. Use a linear liquid hydraulic relationship<br />

where L and fi, are the initial steadystate liquid rate and holdup and fl is a constant<br />

with units <strong>of</strong> seconds.<br />

3.18. The rate <strong>of</strong> pulp lay-down F on a paper machine is controlled by controlling both<br />

the pressure P and the height <strong>of</strong> slurry h in a feeder drum with cross-sectional area<br />

A. F is proportional to the square root <strong>of</strong> the pressure at the exit slit. The air vent<br />

rate G is proportional to the square root <strong>of</strong> the air pressure in the box P. Feedback<br />

controllers set the inflow rates <strong>of</strong> air G, and slurry F, to hold P and h. The system is<br />

isothermal.<br />

Derive a dynamic mathematical model describing the system.<br />

Restriction<br />

FIGURE P3.18<br />

3.19. A wax filtration plant has six filters that operate in parallel, feeding from one<br />

common feed tank. Each filter can handle 1000 gpm when running, but the filters<br />

must be taken <strong>of</strong>f-line every six hours <strong>for</strong> a cleaning procedure that takes ten<br />

minutes. The operating schedule calls <strong>for</strong> one filter to be cleaned every hour.<br />

How many gallons a day can the plant handle? If the flow rate into the feed<br />

tank is held constant at this average flow rate, sketch how the liquid level in the feed<br />

tank varies over a typical three-hour period.<br />

3.20. Alkylation is used in many petroleum refineries to react unsaturated butylenes with<br />

isobutane to <strong>for</strong>m high octane iso-octani: (alkylate). The reaction is carried out in a<br />

two liquid-phase system: sulfuric acid/hydrocarbon.<br />

The butylene feed stream is split and fed into each <strong>of</strong> a series <strong>of</strong> perfectly<br />

mixed tanks (usually in one large vessel). This stepwise addition <strong>of</strong> butylene and the<br />

large excess <strong>of</strong> isobutane that is used both help to prevent undesirable reaction <strong>of</strong><br />

butylene molecules with each other to <strong>for</strong>m high-boiling, low octane polymers. Low<br />

temperature (40°F) also favors the desired iC,/Ch reaction.<br />

The reaction is exothermic. One method <strong>of</strong> heat removal that is <strong>of</strong>ten used is<br />

autorefrigeration: the heat <strong>of</strong> vaporization <strong>of</strong> the boiling hydrocarbon liquid soaks<br />

up the heat <strong>of</strong> reaction.

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