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Effect of Pd impurity on charge and spin density in metallic iron ...

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2 σ + 3 parameters at most provided the c<strong>on</strong>centrati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> impurities c is treated as variable.<br />

Otherwise the maximum number <str<strong>on</strong>g>of</str<strong>on</strong>g> variables describ<strong>in</strong>g distributi<strong>on</strong> equals 2 ( σ + 1)<br />

.<br />

Figure 2.<br />

Hyperf<strong>in</strong>e field <strong>and</strong> relative spectral shift plotted versus palladium c<strong>on</strong>centrati<strong>on</strong>. Straight<br />

l<strong>in</strong>es are the lowest order approximati<strong>on</strong>s to the trends observed, particularly for shifts.<br />

Table III<br />

Essential results obta<strong>in</strong>ed with<strong>in</strong> b<strong>in</strong>omial distributi<strong>on</strong> model with σ = 3. The last row shows<br />

the averages <str<strong>on</strong>g>of</str<strong>on</strong>g> respective columns, where appropriate.<br />

c<br />

[at. %]<br />

< B > 3<br />

[T]<br />

± 0.02<br />

(3)<br />

B 0<br />

[T]<br />

± 0.02<br />

∆B 1<br />

[T]<br />

± 0.02<br />

∆B 2<br />

[T]<br />

± 0.02<br />

∆B 3<br />

[T]<br />

± 0.02<br />

< S<br />

> 3<br />

[mm/s]<br />

± 0.002<br />

0 32.97 0<br />

(3)<br />

S 0<br />

[mm/s]<br />

± 0.002<br />

∆S 1<br />

[mm/s]<br />

± 0.002<br />

∆S 2<br />

[mm/s]<br />

± 0.002<br />

∆S 3<br />

[mm/s]<br />

± 0.002<br />

0.95 33.18 32.96 1.66 0.95 0.61 0.008 0.006 0.015 0.011 0.006<br />

2.76 33.55 33.07 1.28 1.05 0.68 0.023 0.018 0.015 0.011 0.005<br />

4.71 33.87 33.17 1.39 0.97 0.38 0.035 0.026 0.018 0.014 0.004<br />

6.63 34.20 32.86 1.41 0.97 0.92 0.045 0.042 0.004 0.003 0.001<br />

8.04 34.50 33.00 1.37 1.14 0.85 0.052 0.047 0.007 0.004 0.001<br />

10.59 34.67 32.98 1.16 1.19 0.58 0.065 0.061 0.003 0.003 0.002<br />

33.01 1.38 1.05 0.67<br />

Figure 3 shows distributi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> the hyperf<strong>in</strong>e field <strong>and</strong> total shift encountered <strong>in</strong> some <str<strong>on</strong>g>of</str<strong>on</strong>g> the<br />

<strong>in</strong>vestigated samples. C<strong>on</strong>tributi<strong>on</strong>s from sub-spectra hav<strong>in</strong>g relative <strong>in</strong>tensities lesser than<br />

6

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