Chemwatch MSDS Print - FUJIFILM Australia

Fujifilm CP-49HV II PC P1-R 

Chemwatch Material Safety Data Sheet 

Issue Date: 27-Feb-2012 CHEMWATCH 26-6393 

9317SP 

Version No:2.0 

Page 1 of 9 

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME 


PROPER SHIPPING NAME 

POTASSIUM HYDROXIDE SOLUTION 

PRODUCT NUMBERS 

61125 

PRODUCT USE 

For processing of photographic colour paper. 

SUPPLIER 

Company: FUJIFILM Australia Pty Ltd 

Address: 

114 Old Pittwater Road 

Brookvale 

NSW, 2100 

Australia 

Telephone: +61 2 9466 2600 

Emergency Tel:+61 1800 039 008 

Emergency Tel:+61 3 9573 3112 

Fax: +61 2 9938 1975 

Section 2 - HAZARDS IDENTIFICATION 

STATEMENT OF HAZARDOUS NATURE 

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. 

CHEMWATCH HAZARD RATINGS 

Flammability 

Toxicity 

Body Contact 

Reactivity 

Chronic 

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 

RISK 

■ Irritating to eyes and skin. 

■ May cause SENSITISATION by 

skin contact. 

■ Toxic to soil organisms. 

SAFETY 

• Do not breathe gas/fumes/vapour/spray. 

• Avoid contact with skin. 

• Avoid contact with eyes. 

• Wear suitable gloves. 

• Wear eye/face protection. 

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• To clean the floor and all objects contaminated by this 

material, use water. 

• In case of contact with eyes, rinse with plenty of water and 

contact Doctor or Poisons Information Centre. 

• If swallowed, IMMEDIATELY contact Doctor or Poisons Information 

Centre. (show this container or label). 

• This material and its container must be disposed of as hazardous 

waste. 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS 

NAME CAS RN % 

potassium carbonate 584-08-7 5-10 

EDTA tetrapotassium salt 5964-35-2 1-5 

N- [2- (4- amino- N- ethyl- m- 92-09-1 1-5 

toluidino)ethyl]methanesulfonamide 

potassium hydroxide 1310-58-3 0.5-1.5 

other non hazardous ingredients >60 

Section 4 - FIRST AID MEASURES 

SWALLOWED 

• Immediately give a glass of water. 

• First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 

EYE 

■ If this product comes in contact with the eyes: 

• Wash out immediately with fresh running water. 

• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting 

the upper and lower lids. 

• Seek medical attention without delay; if pain persists or recurs seek medical attention. 

• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. 

SKIN 

■ If skin contact occurs: 

• Immediately remove all contaminated clothing, including footwear. 

• Flush skin and hair with running water (and soap if available). 

• Seek medical attention in event of irritation. 

INHALED 

• If fumes, aerosols or combustion products are inhaled remove from contaminated area. 

• Other measures are usually unnecessary. 

• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. 

• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). 

• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semirecumbent 

posture) and must be kept under medical observation even if no symptoms are (yet) manifested. 

• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative 

may be considered. 

NOTES TO PHYSICIAN 

■ Treat symptomatically. 

For acute or short-term repeated exposures to highly alkaline materials: 

• Respiratory stress is uncommon but present occasionally because of soft tissue edema. 

• Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary. 

• Oxygen is given as indicated. 

• The presence of shock suggests perforation and mandates an intravenous line and fluid administration. 

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Section 5 - FIRE FIGHTING MEASURES 

EXTINGUISHING MEDIA 

■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media 

which may be used. Choice of extinguishing media should take into account surrounding areas. 

Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce 

floating layers of combustible substances. 

In such an event consider: 

• foam. 

FIRE FIGHTING 

• Alert Fire Brigade and tell them location and nature of hazard. 

• Wear full body protective clothing with breathing apparatus. 

• Prevent, by any means available, spillage from entering drains or water course. 

• Use fire fighting procedures suitable for surrounding area. 

FIRE/EXPLOSION HAZARD 

• The material is not readily combustible under normal conditions. 

• However, it will break down under fire conditions and the organic component may burn. 

• Not considered to be a significant fire risk. 

• Heat may cause expansion or decomposition with violent rupture of containers. 

Decomposes on heating and produces toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), other 

pyrolysis products typical of burning organic material. 

May emit corrosive fumes. 

FIRE INCOMPATIBILITY 

■ None known. 

HAZCHEM 

2R 

Section 6 - ACCIDENTAL RELEASE MEASURES 

MINOR SPILLS 

■ Environmental hazard - contain spillage. 

• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or 

disposal of material. 

• Check regularly for spills and leaks. 

• Clean up all spills immediately. 

• Avoid breathing vapours and contact with skin and eyes. 

• Control personal contact with the substance, by using protective equipment. 

• Contain and absorb spill with sand, earth, inert material or vermiculite. 

MAJOR SPILLS 

■ Environmental hazard - contain spillage. 

• Clear area of personnel and move upwind. 


• Wear full body protective clothing with breathing apparatus. 


Personal Protective Equipment advice is contained in Section 8 of the MSDS. 

Section 7 - HANDLING AND STORAGE 

PROCEDURE FOR HANDLING 

• DO NOT allow clothing wet with material to stay in contact with skin. 

• Avoid all personal contact, including inhalation. 

• Wear protective clothing when risk of exposure occurs. 

• Use in a well-ventilated area. 

• Avoid contact with moisture. 

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SUITABLE CONTAINER 

• Lined metal can, lined metal pail/ can. 

• Plastic pail. 

• Polyliner drum. 

• Packing as recommended by manufacturer. 

For low viscosity materials 

• Drums and jerricans must be of the non-removable head type. 

• Where a can is to be used as an inner package, the can must have a screwed enclosure.




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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION 

PERSONAL PROTECTION 

RESPIRATOR 

•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) 

EYE 

• Safety glasses with side shields. 

• Chemical goggles. 

• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, 

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a 

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and 

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of 

chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at 

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed 

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]. 

HANDS/FEET 

• Wear chemical protective gloves, eg. PVC. 

• Wear safety footwear or safety gumboots, eg. Rubber. 

NOTE: 

• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other 

protective equipment, to avoid all possible skin contact. 

• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. 

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: 

• frequency and duration of contact, 

• chemical resistance of glove material, 

• glove thickness and 

• dexterity. 

OTHER 

• Overalls. 

• PVC Apron. 

• PVC protective suit may be required if exposure severe. 

• Eyewash unit. 

ENGINEERING CONTROLS 

■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed 

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to 

provide this high level of protection. 

The basic types of engineering controls are: 

Process controls which involve changing the way a job activity or process is done to reduce the risk. 

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation 

that strategically "adds" and "removes" air in the work environment. 

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES 

APPEARANCE 

Amber yellow alkaline liquid; mixes with water. 

PHYSICAL PROPERTIES 

Liquid. 

Mixes with water. 

Corrosive. 

Alkaline. 

State Liquid Molecular Weight Not Applicable 

Melting Range (°C) Not Available Viscosity Not Available 

Boiling Range (°C) >100 Solubility in water (g/L) Miscible 

Flash Point (°C) Not Applicable pH (1% solution) Not Available 

Decomposition Temp (°C) Not Available pH (as supplied) 13.4 

Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) ~2.0 @ 20C 

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Upper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.18 

Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Applicable 

(air=1) 

Volatile Component (%vol) Not Available Evaporation Rate Not Available 

Section 10 - STABILITY AND REACTIVITY 

CONDITIONS CONTRIBUTING TO INSTABILITY 

• Presence of incompatible materials. 

• Product is considered stable. 

• Hazardous polymerisation will not occur. 

For incompatible materials - refer to Section 7 - Handling and Storage. 

Section 11 - TOXICOLOGICAL INFORMATION 

POTENTIAL HEALTH EFFECTS 

ACUTE HEALTH EFFECTS 

SWALLOWED 

■ The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is 

because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual, 

following ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident. Present definitions of harmful or 

toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health). 

Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant 

quantities is not thought to be cause for concern. 

EYE 

■ This material can cause eye irritation and damage in some persons. 

SKIN 

■ This material can cause inflammation of the skin oncontact in some persons. 

The material may accentuate any pre-existing dermatitis condition. 

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. 

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. 

INHALED 

■ Not normally a hazard due to non-volatile nature of product. 

Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain and damage to the mucous 

membrane. In severe cases, lung swelling may develop, sometimes after a delay of hours to days. There may be low blood pressure, 

a weak and rapid pulse, and crackling sounds. 

CHRONIC HEALTH EFFECTS 

■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general 

population. 

Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational 

exposure. 

There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to 

the general population. 

Prolonged oral treatment with sulfonamides has caused nausea, vomiting, diarrhoea, abdominal pain, loss of appetite, inflammation 

of the mouth cavity, impaired folic acid absorption, exacerbation of porphyria, acidosis, liver damage with impaired blood 

clotting, jaundice and inflammation of the pancreas. Effects on the kidney include blood and crystals in the urine, painful and 

frequent urination or lack of urine with nitrogen retention. Nervous system symptoms include headache, drowsiness, trouble 

sleeping, dizziness, ringing in the ears, hearing loss, depression, hallucinations, inco-ordination, paralysis of muscles, 

numbness in the extremities, spinal cord damage and inflammation, convulsions and unconsciousness. Effects on the blood include a 

change in blood cell distribution with loss of white blood cells and platelets, and anaemia, which Africans seem to be more prone 

to developing than Europeans. Cyanosis can occur owing to complexes being formed by haemoglobin. Eye effects include inflamed 

cornea and conjunctiva with eyelid swelling and in severe cases, fear of the light. Allergies and cross-sensitivity is common, 

and can cause itches, wheals and sometimes a severe red rash with blisters that is often fatal. This class of drugs can scar the 

cornea and conjunctiva, cause swelling around the eyes, painful and inflamed joints, reduced sperm counts, pneumonia, fever, 

chills, hair loss, inflammation of vessels, lupus, reduced lung function, infertility, hypothyroidism and goitre, and increased 

urinary output. More seriously, the lungs may become permanently scarred and there may be irreversible damage to the nervous 

system and muscles. Inflammation of the skin has occurred after the drug is ingested and has travelled through the bloodstream. 

Skin effects often occur when there has been exposure in conjunction with UV light. Clothed areas are initially less likely to be 

affected but may be in later stages. Rarely there may be persistence of inflammation on light contact even after the drug has 

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been removed. 

Repeated exposure to hydroxylamine and derivatives may result in respiratory sensitisation with asthma-like symptoms. 

TOXICITY AND IRRITATION 

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis 

of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, 

e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simply 

determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are 

equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with 

stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are 

noteworthy if they produce an allergic test reaction in more than 1% of the persons tested. 

No significant acute toxicological data identified in literature search. 

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergenic 

condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of 

highly irritating compound. 

Section 12 - ECOLOGICAL INFORMATION 

Toxic to soil organisms. 

This material and its container must be disposed of as hazardous waste. 

Ecotoxicity 

Ingredient Persistence: Persistence: Air Bioaccumulation Mobility 

Water/Soil 

potassium carbonate No Data No Data 

Available 

Available 

EDTA tetrapotassium salt No Data No Data 

Available 

Available 

N- [2- (4- amino- N- ethyl- m- HIGH No Data LOW MED 

toluidino)ethyl]methanesulfonami 

Available 

de 

potassium hydroxide No Data No Data LOW 

Available 

Available 

Section 13 - DISPOSAL CONSIDERATIONS 

• Containers may still present a chemical hazard/ danger when empty. 

• Return to supplier for reuse/ recycling if possible. 

Otherwise: 

• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to 

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. 

• Where possible retain label warnings and MSDS and observe all notices pertaining to the product. 

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws 

operating in their area. 

A Hierarchy of Controls seems to be common - the user should investigate: 

• Reduction. 

• DO NOT allow wash water from cleaning or process equipment to enter drains. 

• It may be necessary to collect all wash water for treatment before disposal. 

• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. 

• Where in doubt contact the responsible authority. 

• Recycle wherever possible. 

• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable 

treatment or disposal facility can be identified. 

• Treat and neutralise at an approved treatment plant. 

• Treatment should involve: Neutralisation with suitable dilute acid followed by: burial in a land-fill specifically licenced to 

accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable 

combustible material). 

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Section 14 - TRANSPORTATION INFORMATION 

Labels Required: CORROSIVE 

HAZCHEM: 

2R (ADG7) 

Land Transport UNDG: 

Class or division: 8 Subsidiary risk: None 

UN No.: 1814 UN packing group: III 

Shipping Name:POTASSIUM HYDROXIDE SOLUTION 

Air Transport IATA: 

ICAO/IATA Class: 8 ICAO/IATA Subrisk: None 

UN/ID Number: 1814 Packing Group: III 

Special provisions: 

A3 

Cargo Only 

Packing Instructions: 856 Maximum Qty/Pack: 60 L 

Passenger and Cargo 

Passenger and Cargo 

Packing Instructions: 852 Maximum Qty/Pack: 5 L 

Passenger and Cargo Limited Quantity 

Passenger and Cargo Limited Quantity 

Packing Instructions: Y841 Maximum Qty/Pack: 1 L 

Shipping name:POTASSIUM HYDROXIDE SOLUTION 

Maritime Transport IMDG: 

IMDG Class: 8 IMDG Subrisk: None 

UN Number: 1814 Packing Group: III 

EMS Number: F-A,S-B Special provisions: 223 

Limited Quantities: 5 L 

Shipping name:POTASSIUM HYDROXIDE SOLUTION 

Section 15 - REGULATORY INFORMATION 

POISONS SCHEDULE 

S5 

REGULATIONS 

Regulations for ingredients 

potassium carbonate (CAS: 584-08-7, 6381-79-9) is found on the following regulatory lists; 

"Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their 

Threshold Quantity) Table 2", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical 

Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and 

Poisons (SUSMP) - Appendix C", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 

2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard 

for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of 

Medicines and Poisons (SUSMP) - Schedule 6", "CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in 

Food in General, Unless Otherwise Specified, in Accordance with GMP", "International Council of Chemical Associations (ICCA) - 

High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals" 

EDTA tetrapotassium salt (CAS: 5964-35-2) is found on the following regulatory lists; 

"Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons 

(SUSMP) - Schedule 4", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution 

– United Kingdom" 

N-[2-(4-amino-N-ethyl-m-toluidino)ethyl]methanesulfonamide (CAS: 92-09-1) is found on the 

following regulatory lists; 


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(SUSMP) - Schedule 4" 

potassium hydroxide (CAS: 1310-58-3) is found on the following regulatory lists; 

"Australia Exposure Standards", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", 


(SUSMP) - Appendix C", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", 

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for 

the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of 

Medicines and Poisons (SUSMP) - Schedule 6", "CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in 

Food in General, Unless Otherwise Specified, in Accordance with GMP", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", 

"IMO IBC Code Chapter 17: Summary of minimum requirements", "International Council of Chemical Associations (ICCA) - High 

Production Volume List", "OECD List of High Production Volume (HPV) Chemicals" 

No data for Fujifilm CP-49HV II PC P1-R (CW: 26-6393) 

Section 16 - OTHER INFORMATION 

Denmark Advisory list for selfclassification of dangerous substances 

Substance CAS Suggested codes 

N- [2- (4- amino- N- ethyl- m- 92- 09- 1 Xn; R22 R43 N; 

toluidino)ethyl]methanesulfonamide R50/53 

INGREDIENTS WITH MULTIPLE CAS NUMBERS 

Ingredient Name CAS 

potassium carbonate 584-08-7, 6381-79-9 

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as 

independent review by the Chemwatch Classification committee using available literature references. 

A list of reference resources used to assist the committee may be found at: 

www.chemwatch.net/references. 

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether 

the reported Hazards are Risks in the workplace or other settings. 

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or 

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written 

permission from CHEMWATCH. TEL (+61 3) 9572 4700. 

Issue Date: 27-Feb-2012 

Print Date: 7-May-2012 

This is the end of the MSDS.

Fujifilm CP-49HV II PC P2-R - Part A 


Issue Date: 15-Apr-2011 CHEMWATCH 26-6394 

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PRODUCT NAME 



61125 

PRODUCT USE 


SUPPLIER 


Address: 


Brookvale 

NSW, 2100 


Telephone: +61 2 9466 2600 

Emergency Tel:+61 1800 039 008 


Fax: +61 2 9938 1975 



HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. 


Flammability 

Toxicity 

Body Contact 

Reactivity 

Chronic 


RISK 

■ Irritating to eyes. 

■ May cause SENSITISATION by 

skin contact. 

SAFETY 









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• If swallowed, IMMEDIATELY contact Doctor or Poisons Information 

Centre. (show this container or label). 


NAME CAS RN % 

EDTA ferric ammonium salt 21265-50-9 15-30 

succinic acid 110-15-6 3-7 

ammonium nitrate 6484-52-2 1-5 

water 7732-18-5 60-80 


SWALLOWED 

• If swallowed do NOT induce vomiting. 

• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and 

prevent aspiration. 

• Observe the patient carefully. 

• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. 

EYE 


• Wash out immediately with fresh running water. 



• Seek medical attention without delay; if pain persists or recurs seek medical attention. 

• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. 

SKIN 

■ If skin contact occurs: 

• Immediately remove all contaminated clothing, including footwear. 



INHALED 

• If fumes, aerosols or combustion products are inhaled remove from contaminated area. 

• Other measures are usually unnecessary. 



For acute or short term repeated exposures to iron and its derivatives: 

• Always treat symptoms rather than history. 

• In general, however, toxic doses exceed 20 mg/kg of ingested material (as elemental iron) with lethal doses exceeding 180 mg/kg. 

• Control of iron stores depend on variation in absorption rather than excretion. Absorption occurs through aspiration, ingestion 

and burned skin. 

• Hepatic damage may progress to failure with hypoprothrombinaemia and hypoglycaemia. Hepatorenal syndrome may occur. 








• foam. 

FIRE FIGHTING 


• Wear breathing apparatus plus protective gloves in the event of a fire. 

• Prevent, by any means available, spillage from entering drains or water courses. 


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Decomposition may produce toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of 

burning organic material. 

May emit poisonous fumes. 




HAZCHEM 

None 


MINOR SPILLS 





MAJOR SPILLS 

■ Moderate hazard. 



• Wear breathing apparatus plus protective gloves. 









• Prevent concentration in hollows and sumps. 






STORAGE INCOMPATIBILITY 

■ Salts of ethylenediaminetetraacetic acid (EDTA): 

• should not come into contact with strong oxidisers 

• are incompatible with metals such as zinc, aluminum, carbon steel, copper, copper alloys, galvanized metals and nickel. 

• in contact with metals, such as aluminum, may generate flammable hydrogen gas 

• in contact with bases, may evolve hydrogen and oxygen. 

STORAGE REQUIREMENTS 

• Store in original containers. 

• Keep containers securely sealed. 

• Store in a cool, dry, well-ventilated area. 

• Store away from incompatible materials and foodstuff containers. 

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EXPOSURE CONTROLS 

Source Material TWA TWA STEL STEL Peak Peak TWA Notes 

ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC 

__________ __________ ______ ______ ______ ______ ______ ______ ______ ______ 

Australia (Iron salts, 1 

Exposure 

soluble (as Fe)) 

Standards 

The following materials had no OELs on our records 

• succinic acid: CAS:110- 15- 6 

• ammonium nitrate: CAS:6484- 52- 2 

• water: CAS:7732- 18- 5 

MATERIAL DATA 

AMMONIUM NITRATE: 

SUCCINIC ACID: 

■ It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there 

is evidence of health effects at airborne concentrations encountered in the workplace. 

At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal 

experiments or clinical experience). 

NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply. 

EDTA FERRIC AMMONIUM SALT: 

FUJIFILM CP-49HV II PC P2-R - PART A: 

■ The recommended TLV is thought to reduce the likelihood of respiratory irritation and skin irritation from exposure to 

aerosols and mists of soluble iron salts. 

AMMONIUM NITRATE: 

SUCCINIC ACID: 

■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. 

Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various 

airborne concentrations. 

WATER: 

■ No exposure limits set by NOHSC or ACGIH. 


RESPIRATOR 

•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) 

EYE 










HANDS/FEET 



NOTE: 

• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other 

protective equipment, to avoid all possible skin contact. 

• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. 

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OTHER 

• Overalls. 

• P.V.C. apron. 

• Barrier cream. 

• Skin cleansing cream. 










APPEARANCE 

Red brown liquid with a slight ammonia odour; mixes with water. 


Liquid. 



Melting Range (°C) Not Applicable Viscosity Not Available 




Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) Not Available 


Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available 

(air=1) 

Volatile Component (%vol) Not Available Evaporation Rate Not Applicable 










SWALLOWED 

■ Accidental ingestion of the material may be damaging to the health of the individual. 

Large doses of ammonia or injected ammonium salts may produce diarrhoea and may be sufficiently absorbed to produce increased 

production of urine and systemic poisoning. Symptoms include weakening of facial muscle, tremor, anxiety, reduced muscle and limb 

control. 

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EYE 

■ This material can cause eye irritation and damage in some persons. 

SKIN 

■ The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC 

Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that 

suitable gloves be used in an occupational setting. 

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. 

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. 

INHALED 

■ The material is not thought to produce either adverse health effects or irritation of the respiratory tract following 

inhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced 

following exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum 

and that suitable control measures be used in an occupational setting. 

Not normally a hazard due to non-volatile nature of product. 


■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general 

population. 

Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational 

exposure. 

Chelates are occasionally used in therapies for various forms of poisoning. A systemic reaction known as the "excessive chelation 

syndrome" consists mainly of general unwellness, fatigue, thirst, followed by chills and fever. Muscle ache, headache, loss of 

appetite, nausea and occasionally increased urinary urgency and frequency may occur, as may cold-like symptoms. 

Injection of EDTA and it salts can cause severe kidney damage with tissue death and internal bleeding, bone marrow depression and 

critically low levels of calcium. 


■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis 

of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, 

e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simply 

determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are 

equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with 

stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are 

noteworthy if they produce an allergic test reaction in more than 1% of the persons tested. 

No significant acute toxicological data identified in literature search. 

For ethylenediaminetetraacetic acid (EDTA) and its salts: 

EDTA is a strong organic acid (approximately 1000 times stronger than acetic acid). It has a high affinity for alkaline-earth 

ions (for example, calcium and magnesium) and heavy-metal ions (for example, lead and mercury). 

CARCINOGEN 

Nitrate or nitrite International Agency for Group 

(ingested) under Research on Cancer (IARC) - 

conditions that 

Agents Reviewed by the IARC 

result in endogenous 

Monographs 

nitrosation 


No data 

Ecotoxicity 


Water/Soil 

EDTA ferric ammonium salt No Data No Data 

Available 

Available 

succinic acid LOW No Data LOW HIGH 

Available 

ammonium nitrate No Data No Data LOW 

Available 

Available 

continued...




9317SP 


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• Containers may still present a chemical hazard/ danger when empty. 

• Return to supplier for reuse/ recycling if possible. 

Otherwise: 

• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to 

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. 

• Where possible retain label warnings and MSDS and observe all notices pertaining to the product. 

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws 

operating in their area. 










• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in 

a licenced apparatus (after admixture with suitable combustible material). 

• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. 


HAZCHEM: 

None (ADG7) 

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG 



None 

REGULATIONS 


EDTA ferric ammonium salt (CAS: 21265-50-9) is found on the following regulatory lists; 

"Australia Exposure Standards", "Australia Hazardous Substances", "Australia Inventory of Chemical Substances (AICS)", "Australia 

National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4", 

"International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) 

Chemicals" 

succinic acid (CAS: 110-15-6) is found on the following regulatory lists; 

"Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "IMO IBC Code Chapter 17: Summary 

of minimum requirements", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International 

Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals" 

ammonium nitrate (CAS: 6484-52-2) is found on the following regulatory lists; 

"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water 

supply - inorganic chemicals)", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient 

environmental standards (STOCK - inorganic chemicals)", "Australia - Australian Capital Territory - Environment Protection 

Regulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)", "Australia - 

Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm 

(STOCK)", "Australia - Queensland Hazardous Materials and Prescribed Quantities for Major Hazard Facilities", "Australia - 

Western Australia Hazardous Substances Prohibited for Specified Uses or Methods of Handling", "Australia Council of Australian 

Governments (COAG) Chemicals of Security Concern", "Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be 

Transported", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", 

"Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - 

Appendix F (Part 3)", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum 

continued...




9317SP 


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requirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "International Agency for 

Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Council of Chemical Associations (ICCA) - 

High Production Volume List", "International Maritime Dangerous Goods Requirements (IMDG Code) - Goods Forbidden for Transport", 

"OECD List of High Production Volume (HPV) Chemicals" 

water (CAS: 7732-18-5) is found on the following regulatory lists; 

"Australia Inventory of Chemical Substances (AICS)", "IMO IBC Code Chapter 18: List of products to which the Code does not apply", 

"International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", 

"OSPAR National List of Candidates for Substitution – Norway" 

No data for Fujifilm CP-49HV II PC P2-R - Part A (CW: 26-6394) 











Issue Date: 15-Apr-2011 



Fujifilm CP-49HV II PC P2-R - Part B 



9317SP 


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PRODUCT NAME 



61125 

PRODUCT USE 


SUPPLIER 


Address: 


Brookvale 

NSW, 2100 


Telephone: +61 2 9466 2600 

Emergency Tel:+61 1800 039 008 


Fax: +61 2 9938 1975 



HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. 


Flammability 

Toxicity 

Body Contact 

Reactivity 

Chronic 


RISK 

■ Harmful by inhalation. 

■ Danger of cumulative effects. 

■ Irritating to eyes, respiratory 

system and skin. 

SAFETY 




• Wear suitable protective clothing. 

• Wear suitable gloves. 


• Use only in well ventilated areas. 

• Keep container in a well ventilated place. 

continued...




9317SP 


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• Keep container tightly closed. 

• Keep away from food, drink and animal feeding stuffs. 



• If swallowed, IMMEDIATELY contact Doctor or Poisons 

Information Centre. (show this container or label). 


NAME CAS RN % 

diammonium thiosulfate 7783-18-8 20-40 

ammonium bisulfite 10192-30-0 10-20 

water 7732-18-5 40-60 


SWALLOWED 

• If swallowed do NOT induce vomiting. 

• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and 

prevent aspiration. 

• Observe the patient carefully. 

• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. 

EYE 


• Immediately hold eyelids apart and flush the eye continuously with running water. 



• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. 

• Transport to hospital or doctor without delay. 

SKIN 

■ If skin or hair contact occurs: 



INHALED 

• If fumes or combustion products are inhaled remove from contaminated area. 

• Lay patient down. Keep warm and rested. 

• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid 

procedures. 

• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket 

mask as trained. Perform CPR if necessary. 

• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. 

• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). 

• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semirecumbent 

posture) and must be kept under medical observation even if no symptoms are (yet) manifested. 

• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative 

may be considered. 



Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung oedema often do not manifest 

until a few hours have passed and they are aggravated by physical effort. 

continued...




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• foam. 

FIRE FIGHTING 


• Wear breathing apparatus plus protective gloves in the event of a fire. 

• Prevent, by any means available, spillage from entering drains or water courses. 







Decomposition may produce toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), other pyrolysis 

products typical of burning organic material. 

May emit poisonous fumes. 




HAZCHEM 

None 


MINOR SPILLS 





MAJOR SPILLS 

■ Moderate hazard. 



• Wear breathing apparatus plus protective gloves. 









• Prevent concentration in hollows and sumps. 





continued...




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STORAGE INCOMPATIBILITY 

■ For inorganic thiosulfates 

• Avoid storage with acids, metal nitrites, sodium nitrite, halogens and oxidizing agents. 

• Forms explosive product with potassium nitrate, sodium nitrate 

• Reacts with acids, forming sulfur dioxide 

• Incompatible with halogens, lead, silver and mercury salts. iodine. 

• Contact with acids produces toxic fumes. 

• Incidents involving interaction of active oxidants and reducing agents, either by design or accident, are usually very 

energetic and examples of so-called redox reactions. 

• Reacts with metals producing flammable / explosive hydrogen gas. 

• Avoid strong bases. 

Sulfites and hydrosulfites (dithionites) : 

• may react explosively with strong oxidising agents. 

• react with water or steam to produce corrosive acid solutions and sulfur oxide fumes - aqueous solutions are incompatible with 

oxidisers, strong acids, alkalis, ammonia, aliphatic amines, alkanolamines, alkylene oxides, amides, epichlorohydrin, organic 

anhydrides, isocyanates, nitromethane, vinyl acetate 

• aqueous solutions attack metals in presence of moisture 

• generate gaseous sulfur dioxide in contact with oxidising and nonoxidising acids. 

Sulfur dioxide: 

• reacts with water or steam forming sulfurous acid; reaction may be violent 

• reacts with acrolein, alcohols, aluminium powder, alkali metals, amines, bromine, pentafluoride, caustics, caesium, acetylene 

carbide, chlorates, chlorine trifluoride, chromium powder, copper or its alloy powders, diethylzinc, fluorine, lead dioxide, 

lithium acetylene carbide, metal powders, monolithium acetylide-ammonia, nitryl chloride, potassium acetylene carbide, 

potassium acetylide, potassium chlorate, rubidium carbide, silver azide, sodium, sodium acetylide, stannous oxide; reaction may 

be violent 

• decomposes above 60 deg. C releasing oxides of sulfur 

• Incompatible with alkalis, alkylene oxides, ammonia, aliphatic amines, alkanolamines, amides, organic anhydrides, caesium 

monoxide, epichlorohydrin, ferrous oxide, halogens, interhalogens, isocyanates, lithium nitrate, manganese, metal acetylides, 

metal oxides, perbromyl fluoride, red phosphorus, potassium azide, rubidium acetylide, sodium hydride, sulfuric acid. 

STORAGE REQUIREMENTS 

• Store in original containers. 

• Keep containers securely sealed. 

• Store in a cool, dry, well-ventilated area. 

• Store away from incompatible materials and foodstuff containers. 


EXPOSURE CONTROLS 

The following materials had no OELs on our records 

• diammonium thiosulfate: CAS:7783- 18- 8 

• ammonium bisulfite: CAS:10192- 30- 0 

• water: CAS:7732- 18- 5 

MATERIAL DATA 

AMMONIUM BISULFITE: 

FUJIFILM CP-49HV II PC P2-R - PART B: 

■ Inorganic sulfites, bisulfites and metabisulfites (sodium, potassium and ammonium salts) liberate sulfur dioxide under 

certain conditions. Therefore the officially tabled exposure limits for these chemicals normally correspond to the yield of 

liberated sulfur dioxide.




9317SP 


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WATER: 

■ No exposure limits set by NOHSC or ACGIH. 


RESPIRATOR 

•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) 

EYE 










HANDS/FEET 








OTHER 

• Overalls. 

• P.V.C. apron. 

• Barrier cream. 

• Skin cleansing cream. 










APPEARANCE 

Pale yellow liquid with a slight ammonia odour; mixes with water. 


Liquid. 



Melting Range (°C) Not Available Viscosity Not Available 




Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) Not Available 


continued...




9317SP 


Page 6 of 8 


Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available 

(air=1) 

Volatile Component (%vol) Not Available Evaporation Rate Not Available 










SWALLOWED 

■ Accidental ingestion of the material may be damaging to the health of the individual. 

Thiosulfate salts are poorly absorbed and stimulate the emptying of thebowel. 

Large doses of ammonia or injected ammonium salts may produce diarrhoea and may be sufficiently absorbed to produce increased 

production of urine and systemic poisoning. Symptoms include weakening of facial muscle, tremor, anxiety, reduced muscle and limb 

control. 

EYE 

■ If applied to the eyes, this material causes severe eye damage. 

SKIN 

■ Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful 

effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. 

This material can cause inflammation of the skin oncontact in some persons. 

INHALED 

■ Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. 

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung 

damage. 


■ Substance accumulation, in the human body, is likely and may cause some concern following repeated or long-term occupational 

exposure. 

There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to 

the general population. 

Sulfites and bisulfites can cause narrowing of the airways, stomach upset, flushing, low blood pressure, tingling sensation, 

itchy wheal, swelling and shock, and asthmatics are especially prone. They induce allergic-like reactions which can occur on 

first contact with the material. 

Chronic explosure to sulfur dioxide (SO2) particle complexes in polluted air can aggravate chronic disease, such as asthma, 

chronic pulmonary disease, and coronary artery disease. It is not clear what is the concentration level required to cause these 

effects. Although sulfur dioxide does not cause cancer by itself, it might act as a promotor in tumour growth when there was 

simultaneous exposure to arsenic. Animal testing showed that simultaneous exposure to benz(a)pyrene and sulfur dioxide increases 

the rate of cancer development compared to exposure to only one of the above substances. 


■ No significant acute toxicological data identified in literature search. 

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergenic 

condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of 

highly irritating compound. 

CARCINOGEN 

Sulfites International Agency for Group 3 

Research on Cancer (IARC) - 

Agents Reviewed by the IARC 

Monographs 

continued...




9317SP 


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No data 

Ecotoxicity 


Water/Soil 

diammonium thiosulfate No Data No Data LOW 

Available 

Available 

ammonium bisulfite No Data No Data 

Available 

Available 


■ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to 

laws operating in their area. 










• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in 

a licenced apparatus (after admixture with suitable combustible material). 

• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. 


HAZCHEM: 

None (ADG7) 

■ Air transport may be forbidden if this material is flammable, corrosive or toxic gases may be released under normal conditions 

of transport. 

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG 



None 

REGULATIONS 

Fujifilm CP-49HV II PC P2-R - Part B (CAS: ) is found on the following regulatory lists; 

"International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs" 


diammonium thiosulfate (CAS: 7783-18-8) is found on the following regulatory lists; 

"Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical 

Substances (AICS)", "Australia National Pollutant Inventory", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code 

Chapter 17: Summary of minimum requirements", "International Council of Chemical Associations (ICCA) - High Production Volume 

List", "OECD List of High Production Volume (HPV) Chemicals" 

continued...




9317SP 


Page 8 of 8 


ammonium bisulfite (CAS: 10192-30-0) is found on the following regulatory lists; 

"Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "GESAMP/EHS Composite List - 

GESAMP Hazard Profiles", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "OECD 

List of High Production Volume (HPV) Chemicals" 

water (CAS: 7732-18-5) is found on the following regulatory lists; 

"Australia Inventory of Chemical Substances (AICS)", "IMO IBC Code Chapter 18: List of products to which the Code does not apply", 

"International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", 

"OSPAR National List of Candidates for Substitution – Norway" 











Issue Date: 15-Apr-2011

Chemwatch MSDS Print - FUJIFILM Australia

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