Hydrochemistry and energy storage in aquifers - NHV.nu

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INTRODUCTION J.W. Lyklema This volume of the series Proceedings and Information of the TNO Committee on Hydrological Research (CHO-TNO) contains the contributions as presented on the 48th technical meeting of the CHO-TNO, "Hydrochemistry and energy storage in aquifers". During this symposium recent results have been presented on research which has been conducted within the framework of Annex VI of the International Energy Agency (IEA); Environmental and Chemical Aspects of Thermal Energy Storage in Aquifers and Research and Development of Water Treatment Methods. The Dutch contribution within the IEA framework is coordinated and sponsored by the Netherlands Agency for Energy and the Environment (NOVEM BV) in the Dutch research program: National Research Program on Geothermal Energy and Energy Storage in Aquifers (NOAA). Earlier research has shown that major problems can occur in operating plants when the effects of periodic changes in chemical equilibria due to heating and cooling are not correctly taken into account. A better understanding of the important chemical processes has been obtained by chemical modelling both empirically and theoretically in the laboratoria and by computer experiments. Also the interrelationship with microbiological processes has been studied extensively.
Of crucial importance are the water treatment methods. Clogging, scaling and corrosion processes can impair the system if no adequate techniques are used to avoid precipitation of various carbonates and oxides. Currently new, ecologically sound methods are being developed to counteract these precipitation processes. The results on these topics have been presented to a broad audience with a background in heat and chill storage and water resources management. We expect that the presentations have contributed to a better understanding of the importance of hydrochemical and microbiological processes in the subsoil. We hope that this will be reflected in future research projects in this field and in other fields such as soil acidification and waste disposal studies.
Page 1 and 2: 4 'Hydrochemistry and energy storag
Page 4 and 5: CONTENTS AUTHORS INTRODUCTION J.W.
Page 6 and 7: 4 Corrosion 5 Some conclusions Refe
Page 8 and 9: AUTHORS 0. Andersson VIAK AB P.O. B
Page 12 and 13: THE INTERNATIONAL ENERGY AGENCY AND
Page 14 and 15: 3 THE IEA The International Energy
Page 16 and 17: In addition to projects in the doma
Page 18 and 19: THE RELATION BETWEEN AQUIFER THERNl
Page 20 and 21: 3 VIABILITY ATES systems contribute
Page 22 and 23: Figure 4 Temperature fluctuations o
Page 24 and 25: 10°C between two cycles. We have t
Page 26: groundwater quality so seriously th
Page 29 and 30: developed within Annex VI (Environm
Page 31 and 32: carbonate phase, the use of a high-
Page 33 and 34: generally contain sufficient organi
Page 35 and 36: precipitation from solutions at nea
Page 37 and 38: of the water for storage. These tre
Page 39 and 40: the higher ATES temperatures. There
Page 41 and 42: One of our research objectives is t
Page 43 and 44: COUDRAIN-RIBSTEIN, A. and GOBLET, P
Page 45 and 46: SPOSITO, G, and LeVESQUE, C.S. ; 19
Page 47 and 48: saturation with respect to calcite
Page 49 and 50: system would influence the hydroche
Page 51 and 52: columns were heated from 11°C to 9
Page 53 and 54: (Table 2), clearly shows that the i
Page 55 and 56: Plate 1: CaC03 grain from first cen
Page 57 and 58: decrease in ca2+ activity, to reach
Page 59 and 60: y thermodynamic equilibrium calcula
Page 61 and 62:
HOLM, T.R., EISENREICH, S.J., ROSEN
Page 63 and 64:
INTRODUCTION The use of aquifers fo
Page 65 and 66:
As can be seen "cloggingn has been
Page 67 and 68:
specific capacity of the well and c
Page 69 and 70:
the water being injected. The reaso
Page 71 and 72:
Figure 5 Simplified stability diagr
Page 73 and 74:
3.4 Clogging by organic slime Clogg
Page 75 and 76:
4 CORROSION 4.1 Forms of corrosion
Page 77 and 78:
When halogens are known to be prese
Page 79 and 80:
available on the market. SOME CONCL
Page 82 and 83:
BIOGEOCHEMICAL ASPECTS OF AQUIFER T
Page 84 and 85:
In accordance with Figure 1 mangane
Page 86 and 87:
at a neutral pH is kinetically dete
Page 88 and 89:
of such biocides used against desul
Page 90 and 91:
HYDROGEOCHEMICAL TRANSPORT MODELLIN
Page 92 and 93:
The complexity of the models with a
Page 94 and 95:
The comparison shows that inclusion
Page 96 and 97:
the component O2 (Oxygen) has been
Page 98 and 99:
The results of a recent solubility
Page 100 and 101:
The neutral "exchangeable" complex
Page 102 and 103:
SrC12 elution of Delft sediment, sh
Page 104 and 105:
The saturation ratios can be used i
Page 106 and 107:
Recovered water in the long term te
Page 108 and 109:
Cumulat~ve Flow (103m3) Cumulative
Page 110 and 111:
Dissolution of silicates is in much
Page 112 and 113:
KIRKNER, D.J., and REEVES, H.; 1988
Page 114 and 115:
WATER TREATMENT AND ENVIRONMENTAL E
Page 116 and 117:
Table 1 Ove~iew of chemical treatme
Page 118 and 119:
calculated with a computer model th
Page 120:
Figure 1 Schematic representation o
Page 123 and 124:
addition shows an increase in neces
Page 125 and 126:
Table 4 summarizes the primary envi
Page 127 and 128:
wsts for this overdimensioning may
Page 129 and 130:
_? Primary circuit Figure 7 Reactor
Page 131:
Problems with iron precipitation ca
Page 134 and 135:
RESEARCH ON HYDROCHEMISTRY AND WATE
Page 136 and 137:
ANNEX XI L - -1 I Figure 1 Relation
Page 138 and 139:
stores. F. To test selected water t
Page 140 and 141:
(Fe, Ca, Mg) solid solutions. The p
Page 142 and 143:
corrosion and scaling rates under d
Page 144:
the industry. For this treatment no
Page 149 and 150:
Water nuisance. Proceedings of Tech
Page 151:
No. 36 No. 37 No. 38 Urban storm wa
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