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Review of diesel particulate matter sampling - Department of ...

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Figure 14. - Illustration <strong>of</strong> factors affecting <strong>diesel</strong> aerosol dilution at the<br />

tailpipe<br />

Data shown in figure 15 came from two different field studies (Kittelson, et al.,1988). In field<br />

study 2 the <strong>sampling</strong> distance was determined by towing a mobile laboratory on a flatbed<br />

trailer behind the tractor at speeds <strong>of</strong> 50 to 55 mi/hr (22-25 m/s). Atmospheric residence<br />

times were very short, ranging from 0.01 to 0.4 s. Dilution ratios ranged from 3 to 90:1. In<br />

field study 5 the mobile laboratory followed the tractor down the roadway at the same speeds.<br />

Dilution ratios <strong>of</strong> 1,000:1 were obtained in approximately 1 s at a distance <strong>of</strong> about 25 m.<br />

The relationship between the saturation ratio and dilution ratio and impact on the extractable<br />

fraction is complex. The saturation ratio and extractable fraction peak at intermediate dilution<br />

ratios (approximately 5 to 50:1). The opportunity for homogeneous and heterogeneous<br />

nucleation is greatest when the saturation ratio is highest. However, the amount <strong>of</strong> time spent<br />

at high saturation ratio is very short for on-highway conditions, typically less than 1 sec. The<br />

importance <strong>of</strong> the extractable fraction to the nuclei mode was suggested in the discussion <strong>of</strong><br />

figures 11 and 12 where size distributions for engines with high and low extractable fractions<br />

are shown. The VN/VT ratio (volume fraction in the nuclei mode) for the engine with high<br />

extractable fraction is 53,000 part/μm 3 compared to 5,100 part/μm 3 for the engine with low<br />

extractable fraction.<br />

01/14/99 Page 38

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