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BAYPREG Brosch GB neu_A4.fh11 - BaySystems - customized ...

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– NO LIMIT – A TOUGH LIGHTWEIGHT FOR COMPOSITE PRODUCTION


THE PU COMPOSITE SYSTEM FOR<br />

THE SPORTS AND LEISURE INDUSTRY<br />

Customers of up-market sports and leisure equipment<br />

tend to be very well informed. They know exactly<br />

what performance they expect from their equipment<br />

and they want a design that suits their lifestyle.<br />

TOUGH AND LIGHTWEIGHT FOR COMPOSITE PRODUCTION<br />

When they buy something, they send a clear<br />

message to the manufacturers about the quality<br />

and durability they want from the products<br />

and about the desired level of innovation.<br />

The key factors for the equipment manufacturers<br />

are the versatility of the polyurethane components<br />

used to make the products and an optimum<br />

production process. Criteria such as environmental<br />

protection and customization are also becoming<br />

increasingly important.<br />

The <strong>BAYPREG</strong> ® 2-component polyurethane system<br />

satisfies all these requirements. Its outstanding<br />

versatility sets completely new standards both<br />

in industrial-scale production and in small-scale<br />

<strong>customized</strong> manufacture.


CONTENTS<br />

4 Baypreg ®<br />

, the future-proof alternative<br />

6 An extremely versatile material<br />

8 Manufacturers hold the trump cards<br />

10 Unbeatable processing advantages<br />

12 Facts and figures<br />

14 Everything is possible...<br />

16 An alliance with nature – A successful partnership<br />

18 Your contacts: All you need to know


4<br />

Rear section of camper van<br />

with a core of expanded polystyrene<br />

THE FUTURE-PROOF<br />

ALTERNATIVE<br />

...to conventional epoxy resins.<br />

Baypreg ® has been successfully used for the production of<br />

composite polyurethane parts since 1990. Over the years, the<br />

product range has been extended from the original core<br />

business of water sports and now covers the entire leisure<br />

segment. Key applications are in the camping, skiing and<br />

snowboarding segments. Many leading manufacturers of<br />

high-strength moldings see Baypreg ® as a convincing alternative<br />

to conventional epoxy resins. The arguments for using<br />

Baypreg ® are indeed persuasive, because Baypreg ®<br />

- is solvent-free<br />

- is suitable for all compression molding processes<br />

- is compatible with almost any core materials such as<br />

polystyrene, wood, plastics, PU, aluminum and paper<br />

honeycomb<br />

- can be processed with many reinforcing fiber materials<br />

(e.g. glass, carbon and natural fibers)


Baypreg ® , in this case Baypreg ® F, a grade developed espe-<br />

cially for automotive applications – has been used in the automotive<br />

industry for many years in fully automated processes.<br />

Paper honeycomb structures are generally used as the core<br />

material in combination with natural fibers or glass fibers for<br />

surface reinforcement.<br />

Sailing boat with<br />

glass fiber reinforcement<br />

Wakeboard with<br />

glass fiber reinforcement<br />

Baypreg ® is also the product of choice when parts cannot be<br />

produced on automated production lines due to their complicated<br />

shape or complex design. By modifying the system<br />

to make it react more slowly, Baypreg ® provides an easy-touse,<br />

economical solution for prototypes, small production<br />

runs or special <strong>customized</strong> products. This is especially useful<br />

for medium-sized companies.<br />

Natural fiber composites<br />

5


6<br />

<strong>BAYPREG</strong> ®<br />

GLASS-FIBER<br />

COMPOSITES<br />

•<br />

AN EXTREMELY<br />

VERSATILE MATERIAL<br />

Baypreg ® parts made of glass fiber-reinforced boast a range<br />

of truly outstanding properties including very high impact<br />

strength and torsional rigidity even at low temperatures.<br />

Typical applications include sandwich elements for the sports<br />

and leisure sector, such as snowboards, wakeboards and<br />

skis, where maximum demands are made on the material's<br />

properties.<br />

• Rescue board – Manufacturer:<br />

Karl Niedersüss, Rohrbach, Austria


Baypreg ® parts reinforced with natural fibers have<br />

extra stability and are especially light in weight.<br />

Baypreg ® has an extremely wide range of applications.<br />

It is used, for example, to manufacture steps and rear<br />

sections for recreational vehicles (RVs), trunk floors,<br />

tables and wall panels, floors and walls for stage<br />

building, and ultra-light rescue boards for use in<br />

accidents and emergencies.<br />

Glass fiber mat<br />

•<br />

<strong>BAYPREG</strong> ®<br />

NATURAL FIBER COMPOSITES<br />

•• Table made of Baypreg ® – Manufacturer:<br />

Triple-E Meubilair B. V., Winsum (F.R.), NL<br />

••<br />

Natural fiber mat<br />

7


Glass fiber – impregnated with <strong>BAYPREG</strong> ®<br />

Natural fiber – impregnated with <strong>BAYPREG</strong> ®<br />

Aramid fiber – impregnated with <strong>BAYPREG</strong> ®<br />

MANUFACTURERS<br />

HOLD THE TRUMP CARDS<br />

Baypreg ® is available in two versions:<br />

– As a resin for sandwich structures where an optimum<br />

bond between the individual elements is essential.<br />

The material is also suitable for bonding decorative<br />

surfaces.<br />

– As a resin incorporating a release agent for molded<br />

articles without decorative facings, for example structural<br />

components in interior applications.


A MATERIAL WITH<br />

MANY FACES<br />

Baypreg ® can be readily processed with all kinds of<br />

conventional fiber materials such as glass carbon<br />

and natural fibers. Because of the relatively low<br />

viscosity of <strong>BAYPREG</strong> ® , outstanding wetting and<br />

saturation of the fiber materials is ensured.<br />

Baypreg ® provides an excellent bond to many core<br />

materials such as polyurethane, polystyrene, wood<br />

and various honeycomb structures. It can be processed<br />

at a wide range of mold temperatures,<br />

extending from 120 °C down to just 65 °C. This means<br />

that <strong>BAYPREG</strong> ® can also be used in combination<br />

with heat-sensitive inserts and decorative films.<br />

• Step for a camper van – Manufacturer:<br />

Formtec, PUR-Verarbeitungs GmbH, Dornstetten, D<br />

•<br />

Carbon fiber mat<br />

9<br />

Core materials


10<br />

UNBEATABLE<br />

PROCESSING ADVANTAGES<br />

Long potlife<br />

Once the two components have been mixed together in a<br />

cup, it takes 3 – 10 minutes for the initial thermal reaction<br />

to start. The actual chemical reaction begins after 10 – 20<br />

minutes and ends with solidification after a further 3 – 5<br />

minutes (all figures are approximate). This means the<br />

mixture can be processed by hand for up to 25 minutes at<br />

ambient temperatures of between 20 and 23 °C.<br />

Compression mold<br />

Spray head<br />

Long open time for the impregnated fiber<br />

After application of the reactive mix using a 2-component<br />

spray machine, the impregnated fiber has an open time of<br />

up to 45 minutes at room temperature (20 – 23 °C). This<br />

means that the fiber can be further processed in this period<br />

without any loss of quality.<br />

Short mold residence time<br />

Introducing the impregnated fiber material into the heated<br />

mold triggers the controlled reaction of the 2-component<br />

system. The reaction is soon completed and the part cures<br />

very quickly.<br />

Low mold temperatures<br />

Under normal circumstances, a mold temperature of 80 °C<br />

is enough to ensure rapid, economical curing. However,<br />

because temperatures of up to 120 °C are also possible,<br />

the mold residence times can be shortened considerably<br />

if desired. In special cases – if, for example, heat-sensitive<br />

inserts or decorative films are being used – the mold<br />

temperature can be reduced to 65 °C, although the parts<br />

will then naturally have to spend longer in the mold in<br />

order to achieve top-quality results.<br />

No post-curing necessary<br />

Following removal from the mold and subsequent cooling,<br />

the composite part attains its final strength without any<br />

need for annealing. As a result, energy costs can be lowered.<br />

These energy savings, in combination with the shorter<br />

production cycles made possible by the reduced mold<br />

residence times, make an important contribution to costeffective<br />

production.


Free of solvents<br />

Because Baypreg ® is solvent-free, it presents few problems<br />

in terms of safety and toxicology when processed<br />

by compression molding. Nevertheless, the safety precautions<br />

listed in the EU directives must be observed during<br />

processing.<br />

A TOUGH LIGHTWEIGHT FOR COMPOSITE PRODUCTION<br />

Outstanding mechanical properties<br />

The composite materials have high tensile and flexural<br />

strength despite their low weight per unit area. The glass<br />

transition temperature (approx. 100 °C) is also superior<br />

to that of many comparable materials.<br />

High impact strength<br />

Glass fiber composites are noted for their extremely high<br />

impact strength even at very low temperatures.<br />

Unlimited design freedom<br />

Baypreg ® can also be used to make parts with complex<br />

geometries. Fasteners, fixing devices or stabilizers can be<br />

directly integrated, and subsequent machining is also<br />

possible.<br />

... but that's not all<br />

If short cycle times and high productivity are imperative,<br />

ultra-fast Baypreg ® F systems developed specifically for<br />

the automotive industry by Bayer MaterialScience are the<br />

answer.<br />

11


•<br />

12<br />

Baypreg ® sheets<br />

without fiber mats<br />

••<br />

Baypreg ® laminate<br />

with 65% glass fiber<br />

• Camper van steps, load test<br />

•• Fracture under load<br />

force > 4,000 N<br />

Flexural tests<br />

Flex modulus (N/mm 2 )<br />

Flexural stress (N/mm 2 )<br />

Outer fiber strain (%)<br />

Tensile tests<br />

Tensile E-modulus (MPa)<br />

Tensile stress (MPa)<br />

Impact test<br />

Impact strength (kJ/m2 )<br />

Torsion pendulum test<br />

Glass transition temp. (Tg °C)<br />

Viscosity D48/s 25°C<br />

Flexural tests<br />

Flex modulus (N/mm2)<br />

Flexural stress (N/mm2)<br />

Outer fiber strain (%)<br />

Tensile tests<br />

Tensile E-modulus (MPa)<br />

Tensile stress (MPa)<br />

Torsion pendulum test<br />

Glass transition temp. (Tg °C)<br />

FACTS AND FIGURES<br />

Baypreg ®<br />

2872<br />

98<br />

4,63<br />

3106<br />

64<br />

18,27<br />

90<br />

Baypreg ®<br />

with internal<br />

release agent<br />

1400<br />

24500<br />

690<br />

3,35<br />

22200<br />

450<br />

90<br />

Baypreg ®<br />

with internal<br />

release agent<br />

2625<br />

94<br />

5,36<br />

2684<br />

59<br />

22,83<br />

90<br />

Baypreg ®<br />

low viscosity<br />

2100<br />

21200<br />

650<br />

3,35<br />

26800<br />

450<br />

90<br />

Baypreg ®<br />

high viscosity<br />

5400<br />

27700<br />

756<br />

3,42<br />

27500<br />

480<br />

105


10 4<br />

8<br />

6<br />

4<br />

2<br />

10 3<br />

8<br />

6<br />

4<br />

2<br />

10 2<br />

8<br />

6<br />

4<br />

2<br />

10 1<br />

8<br />

6<br />

4<br />

2<br />

0<br />

SPECIALIST INFORMATION:<br />

GLASS TRANSITION TEMPERATURE<br />

Torsion pendulum process DIN EN ISO 6721-2 B<br />

Material: Baypreg ® VP PU 60BV 11<br />

w: 7,96 mm / h: 1,22mm / L: 50 mm<br />

10 0<br />

10 -1<br />

10<br />

Torsion storage modulus G’ to<br />

Damping tan �<br />

Elongation �<br />

°C -100 -80 -60 -40 -20 0 20 40 60 80 100 120 140 160 180 200 220 240 °C<br />

13


14<br />

2-comp. metering/spraying unit<br />

- Baypreg ® systems are normally processed with fiber<br />

materials by compression molding. This requires a heatable<br />

mold made of aluminum or steel, capable of resisting a<br />

clamping pressure of 5 bar.<br />

Spraying Compression molding<br />

EVERYTHING IS<br />

POSSIBLE...<br />

- The <strong>BAYPREG</strong> ® components can be metered and mixed<br />

manually or processed on an industrial scale on 2-component<br />

polyurethane machines. The ready-to-use polyurethane<br />

system is then applied to one or both sides of the fiber<br />

material by pouring or spraying.


Opening<br />

- The fiber material is cut to size and placed in the mold,<br />

which may be treated with release agent.<br />

- If the fiber mat is treated outside the heated mold, open<br />

times of up to 45 minutes at room temperature (20 – 23 °C)<br />

are possible. Closing the heated mold triggers the forming<br />

and curing process.<br />

THE VARIABLE POLYURETHANE<br />

COMPOSITE SYSTEM<br />

Compression molding time as<br />

a function of temperature<br />

Formtemperatur (°C)<br />

120<br />

100<br />

80<br />

65<br />

Molding time (min)<br />

2 - 3<br />

4 - 5<br />

6 - 8<br />

12 - 13<br />

Further processing<br />

15


16<br />

• Trunk floor<br />

•• Composite component<br />

••• Trunk lid<br />

TOUGH AND LIGHTWEIGHT FOR COMPOSITE PRODUCTION<br />

• ••<br />

AN ALLIANCE WITH NATURE –<br />

A SUCCESSFUL PARTNERSHIP<br />

In modern-day industrial production, natural fibers like hemp,<br />

flax and sisal are making an unexpected comeback. In combination<br />

with natural fibers, Bayer MaterialScience's Baypreg ®<br />

polyurethane system produces high-quality, hard-wearing,<br />

break-resistant and lightweight composite parts that can resist<br />

even severe mechanical stresses and long-term vibrations.<br />

•••


•<br />

AN ALLIANCE WITH NATURE –<br />

FOR THE SAKE OF THE ENVIRONMENT<br />

Combining Baypreg ® with an ecologically friendly core material<br />

such as a honeycomb made of recycled paper results in a<br />

modern, innovative system for the manufacture of high-tech<br />

products using renewable raw materials. It is also entirely<br />

free of solvents. The use of annual plants like hemp, sisal and<br />

flax as renewable resources encourages their cultivation.<br />

•• •••<br />

By virtue of their rapid growth, the plants reduce the content<br />

of carbon dioxide (CO2 ) in the environment. On incineration<br />

of the solvent-free parts at the end of their useful life, the<br />

CO2 originally bound by the plant is released back into the<br />

natural cycle.<br />

• Klapptisch<br />

•• Flachssamen<br />

••• Hanfgewebematte<br />

17


18<br />

YOUR CONTACTS:<br />

ALL YOU NEED TO KNOW<br />

Would you like to find out more about Baypreg ® ?<br />

We have all the information you need.<br />

Just give us a call.<br />

TOUGH AND LIGHTWEIGHT FOR COMPOSITE PRODUCTION<br />

Elke Springer<br />

Bayer MaterialScience AG<br />

<strong>BaySystems</strong> Elastomers<br />

Spraying & Reinforcement<br />

51368 Leverkusen<br />

Tel. ++49 – 214 30 2 67 17<br />

Fax ++49 – 214 30 2 62 93<br />

elke.springer@ bayerbms.com<br />

Dr. Dirk Wegener<br />

Bayer MaterialScience AG<br />

<strong>BaySystems</strong> Elastomers<br />

Spraying & Reinforcement<br />

51368 Leverkusen<br />

Tel. ++49 – 214 30 3 12 03<br />

Fax ++49 – 214 30 2 62 93<br />

dirk.wegener@ bayerbms.com


This information and our technical advice – whether verbal, in writing or by way of trials – are given in good faith but without warranty,<br />

and this also applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify<br />

the information currently provided – especially that contained in our safety data and technical information sheets – and to test our<br />

products as to their suitability for the intended processes and uses. The application, use and processing of our products and the products<br />

manufactured by you on the basis of our technical advice are beyond our control and, therefore, entirely your own responsibility. Our<br />

products are sold in accordance with the current version of our General Conditions of Sale and Delivery.<br />

Edition: 2007-02 · Order no.: MS005090 · Printed in Germany · E<br />

Bayer MaterialScience AG<br />

51368 Leverkusen, Deutschland<br />

www.bayermaterialscience.de

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