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Renewable Energy in Industrial Applications – an ... - Unido

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ANNEXES<br />

process<strong>in</strong>g <strong>in</strong>dustry for the production of foil,<br />

moulds, t<strong>in</strong>s, cups, bottles <strong>an</strong>d other packag<strong>in</strong>g.<br />

Poly-3-hydroxybutyrate<br />

The biopolymer poly-3-hydroxybutyrate (PHB) is a<br />

polyester produced by certa<strong>in</strong> bacteria as they<br />

process glucose or starch. Its characteristics are<br />

similar to those of petroplastic polypropylene.<br />

The South Americ<strong>an</strong> sugar <strong>in</strong>dustry has decided<br />

to exp<strong>an</strong>d PHB production to <strong>an</strong> <strong>in</strong>dustrial scale.<br />

PHB c<strong>an</strong> be used for production of tr<strong>an</strong>sparent<br />

film that is biodegradable without residue.<br />

Polyamide 11<br />

Polyamide 11 (PA 11) is a biopolymer derived<br />

from natural oil. It is also known by the trade<br />

name Rils<strong>an</strong> B, commercialised by Arkema. PA 11<br />

belongs to the technical polymers family <strong>an</strong>d is<br />

not biodegradable. PA 11 is used <strong>in</strong> high<br />

perform<strong>an</strong>ce applications such as automotive fuel<br />

l<strong>in</strong>es, pneumatic airbrake tub<strong>in</strong>g, electrical <strong>an</strong>titermite<br />

cable sheath<strong>in</strong>g, oil <strong>an</strong>d gas flexible<br />

pipes, sports shoes, electronic device<br />

components <strong>an</strong>d catheters.<br />

Genetically modified bioplastics<br />

Look<strong>in</strong>g further ahead, some of the second<br />

generation bioplastics m<strong>an</strong>ufactur<strong>in</strong>g<br />

technologies under development adopt a "pl<strong>an</strong>t<br />

factory" model <strong>in</strong> which they use genetically<br />

modified (GM) crops or genetically modified<br />

bacteria to optimise efficiency. A ch<strong>an</strong>ge <strong>in</strong> the<br />

consumer perception of GM technology <strong>in</strong> Europe<br />

will be required for these to be widely accepted.<br />

iii. Bio Build<strong>in</strong>g Blocks<br />

Hydrolysis pl<strong>an</strong>ts, based on a r<strong>an</strong>ge of processes,<br />

are already operat<strong>in</strong>g commercially.The Biof<strong>in</strong>e<br />

process, is a commercialised technology that<br />

uses two-step dilute m<strong>in</strong>eral acid hydrolysis to<br />

break down biomass conta<strong>in</strong><strong>in</strong>g lignocellulose<br />

<strong>in</strong>to <strong>in</strong>termediate chemicals that c<strong>an</strong> be further<br />

tr<strong>an</strong>sformed <strong>in</strong>to 2-Methyltetrahydrofur<strong>an</strong> (MeTHF)<br />

<strong>an</strong>d other chemical products. The Biof<strong>in</strong>e process<br />

was developed by BioMetics Inc with fund<strong>in</strong>g<br />

from the United States Department of <strong>Energy</strong>.<br />

A pilot pl<strong>an</strong>t produc<strong>in</strong>g 1 t/day of <strong>in</strong>termediate<br />

chemicals has been operat<strong>in</strong>g <strong>in</strong> South Glens<br />

Falls, New York s<strong>in</strong>ce 1998. The first commercialscale<br />

biomass-based pl<strong>an</strong>t, which produces 10<br />

t/day of levul<strong>in</strong>ic acid from local tobacco bagasse<br />

<strong>an</strong>d paper mill sludge, has been built <strong>in</strong> Caserta,<br />

Italy, by Le Calorie. This started operation <strong>in</strong><br />

2006.<br />

Levul<strong>in</strong>ic acid c<strong>an</strong> be produced <strong>in</strong> yields of up to<br />

70%, or about 0.5 kg per kg of cellulose, along<br />

with formic acid <strong>an</strong>d furfural as valuable by<br />

products. Used for years <strong>in</strong> food, fragr<strong>an</strong>ce, <strong>an</strong>d<br />

specialty chemical applications, levul<strong>in</strong>ic acid is a<br />

precursor for methyltetrahydrofur<strong>an</strong>,<br />

v-valerolactone, <strong>an</strong>d ethyl levul<strong>in</strong>ate, which c<strong>an</strong><br />

all be blended with diesel or gasol<strong>in</strong>e to create<br />

cle<strong>an</strong>er-burn<strong>in</strong>g fuels. Another derivative,<br />

diphenolic acid, is a potential replacement for<br />

bisphenol which is suspected to be <strong>an</strong> endocr<strong>in</strong>e<br />

disrupter.<br />

iv. Wood Board <strong>an</strong>d Eng<strong>in</strong>eered Wood Materials<br />

Wood board materials are made from th<strong>in</strong><br />

sheets (plywood), particles (particle board) <strong>an</strong>d<br />

oriented str<strong>an</strong>d board or fibers (fibreboard).<br />

Eng<strong>in</strong>eered wood <strong>in</strong>cludes a r<strong>an</strong>ge of derivative<br />

wood products which are m<strong>an</strong>ufactured by us<strong>in</strong>g<br />

adhesives to b<strong>in</strong>d together the str<strong>an</strong>ds,<br />

particles, fibers, or veneers of wood to form<br />

composite materials. These products are<br />

eng<strong>in</strong>eered to precise design specifications<br />

which are tested to meet national or<br />

<strong>in</strong>ternational st<strong>an</strong>dards.<br />

Typically, eng<strong>in</strong>eered wood products are made<br />

from the same hardwoods <strong>an</strong>d softwoods that<br />

are used to m<strong>an</strong>ufacture lumber. Sawmill scraps<br />

<strong>an</strong>d other wood waste c<strong>an</strong> be used for<br />

eng<strong>in</strong>eered wood composed of wood particles or<br />

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