1st International Symposium on Nanoscience and Nanomaterials Keywords: Biosynthesis, Water hyacinth, Metal nanoparticles, Transmission Electron Microscopy Green-chemistry methods are becoming more important nowadays; particularly the use of bioreduction to produce metal nanoparticles is well established as a significant contribution to <strong>de</strong>velop clusters and one-dimensional nanostructures. The utilization of this method is part of a self-sustained technology where the biomass source is water hyacinth (Eichhornia crassipes), a plant that is consi<strong>de</strong>red a pest. This research presents the results of biosynthesis by dried biomass of water hyacinth in aqueous solutions of MnSO4, K2Cr2O7, FeCl3, CoCl2 and Ag standard solution, precursors of Mn2+, Cr3+, 2+, Fe3+, 2+ Co3+, 2+ and Ag+ ions on scale size of quantum confinement (
1st International Symposium on Nanoscience and Nanomaterials 2 Departamento <strong>de</strong> Nanocatálisis, Centro <strong>de</strong> Nanociencias y Nanotecnología (<strong>CNyN</strong>) – <strong>Universidad</strong> <strong>Nacional</strong> Autónoma <strong>de</strong> México. Ensenada, B.C. –México 3 Departamento <strong>de</strong> Física, ESFM-IPN, C. P. 07738, D.F., México 4 Departamento <strong>de</strong> Ingeniería Química, Instituto Tecnológico <strong>de</strong> Los-Mochis, Blvd. Juan <strong>de</strong> Dios Bátiz, 81250 Los-Mochis, Sinaloa, México a inocente@imre.oc.uh.cu, b vitalii@cnyn.unam.mx, c ffcb@cnyn.unam.mx, d fchavez@esfm.ipn, e e<strong>de</strong>rlugomedina@yahoo.com.mx Keywords: Mor<strong>de</strong>nite; Nanoparticles; Copper; Silver; Zinc. The zeolites modified with ions, clusters and nanoparticles of copper, zinc and silver are of great interest due to both catalytic and microbicidal properties of these metals, which allows <strong>de</strong>veloping of materials for very different applications. In this work thermal reduction of supported on mor<strong>de</strong>nite threemetallic mixture Cu 2+ -Ag + -Zn 2+ in hydrogen flow was studied, applying DRX, UV-Vis, and TPR-H 2 methods. It was found that the sample properties <strong>de</strong>pend on the sequence used to exchange these cations in mor<strong>de</strong>nite. Reduction of Cu 2+ and Ag + and formation of resultant clusters and nanoparticles were influenced by the presence of Zn 2+ . The three-metallic systems allow obtaining materials with diverse metallic species, and such method can constitute an alternative to influence the size and aggregation of metal species. Thanks are given to E. Aparicio, I. Gradilla, J. Peralta and E. Flores for the technical support. This research was supported by CONACYT, Mexico through grant 102907, and UNAM-PAPIIT through grants IN110608 and IN207511. O-013 TEMPERATURE DEPENDECE OF VIBRATIONAL MODES ON A CARBON NANOTUBE Joel Antúnez García 1,a , Donald Homero Galván 1,b 1 Centro <strong>de</strong> Nanociencias y Nanotecnología (<strong>CNyN</strong>) – <strong>Universidad</strong> <strong>Nacional</strong> Autónoma <strong>de</strong> México. Ensenada, B. C., México a jantunez@cnyn.unam.mx, b donald@cnyn.unam.mx Keywords: modified embed<strong>de</strong>d atom method, molecular dynamics, carbon nanotube, vibrational mo<strong>de</strong>s. Trough molecular dynamics (MD) simulations we have studied the vibrational mo<strong>de</strong>s, as temperature function, of unsupported zigzag (7,0) carbon nanotube. The MD simulations were carried within the framework of the modified embed<strong>de</strong>d atom method (MEAM). The temperatures un<strong>de</strong>r study were 50, 100, 200, 300, 400 and 500 oK and the simulation length of each running was of 300 ps. Our results shown that in<strong>de</strong>pen<strong>de</strong>nt of the temperature, the vibrational mo<strong>de</strong>s are restricted to a very narrow high frequencies band. On the other hand, although the high frequencies are excited as the temperature increases and the coupling of certain mo<strong>de</strong>s along three cylindrical coordinates are always present, their relation is not direct. O-014 SYNTHESIS OF HIERARCHICALLY STRUCTURED γ-ALUMINA AS A SUPPORT FOR HDS CATALYSTS J. N. Díaz <strong>de</strong> León 1,a , G. Torres 2,b , T. A. Zepeda 1,c , S. Fuentes 1,d and V. Petranosvkii 1,e 1 Centro <strong>de</strong> Nanociencias y Nanotecnología - UNAM, Km. 107 Carretera Tijuana-Ensenada, CP. 22800, Ensenada, B.C. México 2 Posgrado en Ciencias e Ingeniería <strong>de</strong> Materiales <strong>CNyN</strong>, UNAM 17