Introduction - Lehrstuhl für Thermodynamik
Introduction - Lehrstuhl für Thermodynamik
Introduction - Lehrstuhl für Thermodynamik
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ENERGY CONVERSION IN A HYDROGEN FUELED DIESEL<br />
ENGINE:<br />
OPTIMIZATION OF THE MIXTURE FORMATION AND<br />
COMBUSTION<br />
PETER PRECHTL; FRANK DORER; FRANZ MAYINGER<br />
<strong>Lehrstuhl</strong> A <strong>für</strong> <strong>Thermodynamik</strong>, Technische Universität München,<br />
D-85747 Garching, Germany<br />
C. VOGEL; V. SCHNURBEIN<br />
MAN B&W DIESEL AG, Stadtbachstr. 1, D-86153 Augsburg, Germany<br />
Abstract. A large-bore, four-stroke engine, with high pressure injection and<br />
compression ignition, running with hydrogen, is a modern concept for clean energy<br />
conversion without CO2 emission. The key processes for reliable engine operation are a<br />
good mixture formation, a reliable ignition and efficient combustion. The investigations<br />
of these processes are carried out in a rapid compression machine, with modern optical<br />
measurement techniques.<br />
1. <strong>Introduction</strong><br />
The simple reaction of hydrogen and oxygen into water as a clean method for energy<br />
conversion, the high energy density, the wide ignition ranges and the high burning<br />
velocities have been the reasons for a long time for people to investigate the usability of<br />
hydrogen as a fuel for internal combustion engines. Short overviews are given in [1,2].<br />
In recent years, extensive research has been done with different concepts on the<br />
application of hydrogen for engine use. A summary of German activities is given in [3].<br />
The method of internal mixing and compression ignition (C.I.) combines the advantages<br />
of the high efficiency of a diesel engine and the clean combustion of hydrogen and<br />
oxygen. For this combustion method, however, one main problem has to be solved<br />
which is the auto-ignition of hydrogen. A variety of studies on this topic have shown<br />
that a reliable running C.I. engine cannot be realized yet [4,5,6,7]. In a cooperation of<br />
MAN B&W Diesel AG and two departments of the Technische Universtät München, a<br />
large-bore, four-stroke engine running with hydrogen is being developed. The research<br />
project is supported by the Bayerische Forschungsstiftung (Bavarian Research<br />
Foundation). The <strong>Lehrstuhl</strong> <strong>für</strong> Verbrennungskraftmaschinen und Kraftfahrzeuge<br />
(LVK, department of internal combustion engines and motor vehicles) is investigating
the behavior of a single cylinder test engine. The <strong>Lehrstuhl</strong> A <strong>für</strong> <strong>Thermodynamik</strong><br />
(LAT, department of thermodynamics) is investigating the injection and combustion<br />
process with modern optical measurement techniques in a rapid compression machine<br />
(RCM) under realistic conditions. As mentioned above, the ignition of hydrogen under<br />
internal mixing conditions is the key process for a reliable engine operation. Due to this<br />
fact it is main subject of the current research activities at the LAT.<br />
2. Experimental Investigations<br />
In a first phase the experiments are carried out in the RCM by varying of the<br />
compression ratio, the load pressure and the flow condition (variation of the swirl and<br />
the turbulence). The compression ratio reaches a value up to 22, and the compression<br />
end pressure is between 5 and 11 MPa. The temperature reaches values over 950 K. The<br />
hydrogen is injected with a pressure between 25 and 33 MPa, and a maximum injection<br />
duration of 15 ms. In the next step the influence of the injector geometry is analyzed.<br />
For these experiments nozzles with a hole number of 6 up to 24 and a slot nozzle with<br />
nearly equivalent cross-sections were manufactured. These measurements were carried<br />
out under the same pressure conditions.<br />
2.1. EXPERIMENTAL SETUP<br />
The experimental setup used for these investigations is based on an fully optically<br />
accessible rapid compression machine (RCM). The machine simulates a single<br />
compression stroke under realistic conditions. This experimental setup allows a variety<br />
of investigations under different conditions. It is simple to replace the injection device<br />
or the nozzle geometry. The compression ratio, the load, the intake temperature as well<br />
as the injection timing can be varied. In addition to that fact a swirl or a turbulence can<br />
be engendered in the combustion chamber. On the top of the combustion chamber the<br />
electro-hydraulic-controlled injection device for pressurized hydrogen is mounted. The<br />
hydrogen is supplied from single bottles and from bundles. The hydrogen is compressed<br />
with a 30 MPa piston compressor, and it is stored in a small high pressure tank before<br />
the injection. The optical access to the combustion chamber of the RCM is realized<br />
through a large quartz window in the bottom of the piston and additional windows in<br />
the cylinder walls. The RCM allows a maximum combustion pressure over 20 MPa.<br />
This setup allows the use of optical measurement techniques, such as laser-induced<br />
fluorescence (LIF) [8] for the detection of several species like OH, and fast imaging<br />
techniques, such as the high speed digital video and Schlieren techniques to visualize<br />
the mixing and combustion process. A typical setup using the high speed video camera<br />
is shown in figure 1. The dimensions of the machine are in a 1:1 scale to the single<br />
cylinder test engine, which has a piston displacement of about 14 liters and a power<br />
output of approximately 180 kW. The velocity of the piston of the rapid compression<br />
machine corresponds to the piston speed of the engine with 800 – 900 RPM near the top<br />
dead center (TDC). The emitted light (self-fluorescence) from the ignition and the<br />
combustion process is observed using a digital high speed camera at a frame rate of<br />
13,500 Hz. In addition to the conventional data, such as the pressure, the piston
displacement, the needle lift and other required signals, the images are stored digitally.<br />
In the next step the data is analyzed, combined with the images and recorded to a digital<br />
mpeg-film. These films give a good impression of the location and the spatial<br />
distribution of the ignition and combustion process. This method contributes to a better<br />
understanding and an efficient improvement of the combustion concept.<br />
Figure 1: Experimental setup using the rapid compression machine (RCM) and a high<br />
speed video camera to observe the ignition and combustion process<br />
2.2. RESULTS AND DISCUSSION<br />
In the first series of experiments it has been shown that the compression ratio has a<br />
significant influence on the ignition delay. Higher temperatures lead to shorter ignition<br />
delays. However, large variations of the ignition delays have been observed in all the<br />
experiments. The ignition occurs statistically distributed in the combustion chamber.<br />
The analysis of the films proves the assumption that an ignition of a single jet does not<br />
lead to the ignition of other hydrogen jets, as is shown in figure 2. It has also been<br />
observed that several jets have not ignited. It can be inferred that different areas of<br />
combustible hydrogen mixtures of the injected jets in a single compression cycle can<br />
have different ignition delays. As a result, cycle-to-cycle variations in the pressure<br />
recordings are expected, and the possibility of miss-fire can not be excluded. Possible<br />
reasons can be statistical effects on the ignition due to the compression end<br />
temperatures being near the auto-ignition temperature of hydrogen and the varying<br />
mixing conditions. It is likely that there is an influence of the purity of the pressurized<br />
hydrogen, the intake-air or of the leakage in the injection system on the ignition. All
three possibilities were analyzed. The results show that there is no contamination of the<br />
hydrogen compression and of the high pressure storage system. Furthermore, the air<br />
supply system also has no contamination. The injection device has an oil sealing system<br />
which was suspected to leak impurities of oil into the injected hydrogen.<br />
pressure [bar]<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
260<br />
-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />
time [s]<br />
piston displacement<br />
pressure<br />
needle lift = injection duration<br />
Figure 2: Typical ignition process of a 6 hole nozzle<br />
The installation of another injector with dry sealings has no significant impact on the<br />
statistical ignition behavior. But it has to be taken into account that the hydrogen is used<br />
as it is delivered from a commercial gas supplier. That means it is delivered as a<br />
compressed gas, and it is not as chemically clean as liquid hydrogen (the boiling<br />
temperature of liquid hydrogen is 20 K). The phenomenon of auto-ignition, which is<br />
difficult to realize, and the variations of the ignition delays were also observed and<br />
380<br />
360<br />
340<br />
320<br />
300<br />
280<br />
piston displacement [mm]
discussed by other researchers working on the topic [6, 7, 4, 2]. The ignition delays<br />
estimated from calculations of hydrogen air mixtures with zero dimensional calculations<br />
[9-11] are in a range of 2 ms at compression end temperatures of 1050 K. Siebers [12]<br />
reports ignition delays in his experiments of 0.5 ms at temperatures of 1200 K.<br />
pressure [bar]<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
pressure<br />
piston stroke<br />
-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />
time [s]<br />
needle lift<br />
Figure 3:Typical ignition process of a slot nozzle with a slot height of 100 um; flame<br />
propagation around the nozzle within 0.4 ms<br />
An enhanced flow field in the combustion chamber, which can be realized<br />
through a swirl or a turbulence, improves the reliability of the ignition and reduces the<br />
variations of the ignition delays. Due to the critical-flow injection of the hydrogen [13]<br />
into the combustion chamber and its high speed in the nozzle outlets of about 1400 m/s<br />
380<br />
360<br />
340<br />
320<br />
300<br />
280<br />
260<br />
piston stroke [mm]
(which is the speed of sound), the injected jets are not deflected in the vicinity of the<br />
outlets. Owing to the strong slow-down of the injected hydrogen, a significant influence<br />
on the penetration direction can be observed at a distance of 50 mm from the nozzle.<br />
pressure [bar]<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
pressure<br />
needle lift<br />
piston displacement<br />
-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />
time [s]<br />
Figure 4: Typical ignition process of a combined nozzle with 6 x 0.6 and 12 x 0.4 mm;<br />
fast flame propagation, fast combustion and good spatial use of the entire combustion<br />
chamber<br />
In order to run the engine under similar conditions like a diesel engine with a<br />
high compression ratio and late gaseous injection, a nozzle geometry with 6 or more<br />
holes is set up. All the experiments with hole numbers up to 10 show that a burning jet<br />
hardly ignites the neighbor jet. As discussed above, this behavior leads to large<br />
380<br />
360<br />
340<br />
320<br />
300<br />
280<br />
260<br />
piston displacement [mm]
variations in the pressure recordings. As a result of these observations a nozzle system<br />
with a spatially connected combustible mixture distribution was set up. Experiments<br />
with nozzles with 18 holes or a slot show a much better combustion behavior than those<br />
with 6 to 10 holes. Once auto-ignition occurs, the flame propagates very fast over all<br />
injected jets. Due to the equivalent cross-section of the nozzles the diameter of the holes<br />
decreases with the increase of the number of holes. A smaller bore diameter reduces the<br />
momentum of the injected hydrogen significantly (~d 2 ). Owing to a smaller momentum<br />
the jet is slowed down faster and a reduced penetration speed of the jets can be<br />
observed. Due to the smaller speed the auto-ignition begins in the vicinity of the nozzle.<br />
The best ignition behavior is observed with a slot nozzle. Figure 3 illustrates the<br />
ignition process of a nozzle with a slot height of 100 um. Under these conditions an<br />
earlier and a better reproducible ignition can be achieved. On the other hand a longer<br />
combustion duration is observed. The flow conditions have significant influence on the<br />
combustion process. Nozzle geometries with low jet velocities and large ignitable areas<br />
have good auto-ignition properties, but induce insufficient conditions for a fast and<br />
effective overall combustion. The flow energy for the mixing process is lost in highly<br />
throttling nozzles. The nozzles with 6 holes show, in contrast to nozzles with more bore<br />
holes, better combustion properties as soon as the hydrogen is ignited. The combination<br />
of both advantages leads to the application of nozzles with a series of large and small<br />
bores. The existence of the small bores ensure an early and reliable ignition in the<br />
vicinity of the nozzle and a fast flame propagation, which ignites the surrounding jets.<br />
The large bores, however, cause a high momentum of the injected hydrogen, which<br />
leads to good mixing. Figure 4 illustrates the ignition and the combustion process of a<br />
combined 18-hole nozzle with 6 x 0.6 mm and 12 x 0.4 mm bores. A fast flame<br />
propagation around the nozzle is achieved within 0.6 milliseconds. In addition to that<br />
fact a faster penetration of the jets from the large bore holes to the wall of the cylinder is<br />
observed, which results in a more efficient use of the whole combustion chamber.<br />
Nozzles of these types are, at present, the best combination of a reliable ignition and of<br />
an efficient combustion. However, the variations of the ignition processes and the<br />
pressure rise rates are higher than those observed in real diesel engines. In addition to<br />
that fact an improvement of the ignition of the hydrogen near the nozzle can be<br />
expected using slow-opening valves. These types of valves are used in modern<br />
combustion concepts of diesel engines with Common-Rail injection systems, with<br />
which the pressure rise rates can be controlled and the emissions can be reduced.<br />
Although an operation of a C.I. engine using hydrogen seems to be possible<br />
under the above discussed conditions, alternative ignition devices should still be<br />
considered. The low ignition energy of hydrogen suggests the use of a spark plug<br />
ignition under late internal mixing conditions. The varying auto-ignition behavior of the<br />
hydrogen, because of possible impurities, can lead to pre-ignitions under early-injection<br />
conditions. Due to this fact S.I. (spark ignition) hydrogen engines have a reduced<br />
compression ratio of about 8-10 [14 15, 16]. The possibility of setting up a<br />
configuration with late internal mixing and spark ignition, as that used in a new<br />
generation of GDI (gasoline direct injection) engines, is also of great interest. For this<br />
reason experiments have been set up with a small modification to the cylinder head of<br />
the RCM, the insertion of a spark plug. With the same nozzle geometry and a reduced<br />
compression ratio, the auto-ignition can be avoided, which enables a reliable and a fast
ignition of the hydrogen. Due to the optimized arrangement of the holes in the nozzle, a<br />
fast flame propagation around the nozzle is achieved within 1 ms. Figure 5 shows a<br />
spark ignited combustion. The spark-plug timing is set 1 ms after the beginning of the<br />
hydrogen injection. With a late injection near TDC and an immediate ignition with a<br />
spark plug, high compression ratios can be realized, as opposed to external or early<br />
internal mixing.<br />
pressure [bar]<br />
100<br />
80<br />
60<br />
40<br />
20<br />
pressure<br />
0<br />
260<br />
-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />
time [s]<br />
needle lift<br />
piston displacement<br />
Figure 5: Spark ignition of a late injected hydrogen jet<br />
360<br />
340<br />
320<br />
300<br />
280<br />
piston displacement [mm]
3. Conclusions<br />
The developed setup for the investigations of a hydrogen-fueled large-bore C.I. engine<br />
with a high pressure injection system allows a detailed analysis of all relevant<br />
processes. The modern optical techniques enable the analysis of the mixing, the ignition<br />
and the combustion processes. The results obtained with this setup contribute to a better<br />
understanding of the very fast processes. Furthermore this setup allows an efficient<br />
testing and development of engine components. The auto-ignition of hydrogen has been<br />
observed. High pressures and temperatures have a positive influence on a short ignition<br />
delay. Turbulence and swirl support the propagation of the flame over the whole<br />
combustion chamber and regulate the combustion for smoother pressure rates. At<br />
present, combined nozzles containing 18 bores with different diameters seem to be the<br />
best injection geometry to assure small variations of the ignition delay and of the<br />
pressure. However, the current ignition behavior of hydrogen in a C.I. engines without<br />
ignition sources is not applicable yet. Therefore further improvement for a smooth and<br />
safe engine operation is still required. Modern injection concepts with their possibilities<br />
of pilot injection and slow-opening rates offer additional options for improvement.<br />
However, further ignition sources for hydrogen under late internal mixing conditions<br />
have to be considered, and should be investigated.<br />
References<br />
1. Das L. M., Hydrogen Engines: A view of the Past and a look into the future, Int. J.<br />
Hydrogen Energy, Vol. 15, 425-443, 1990<br />
2. Wong J. K. S. Compression ignition of hydrogen in a direct injection diesel<br />
engine modified as a low heat-rejection-engine Int. J. Hydrogen Energy, Vol. 15,<br />
No. 7, 507-514, 1990<br />
3. TÜV Bayern, Energieträger Wasserstoff 1996, TÜV Bayern Sachsen<br />
Forschungsprojekte und Anwendungen, Westendstr. 199, 80686 München,<br />
Germany<br />
4. Furuhama S. and Kabayashi Y. Development of a hot surface ignition hydrogen<br />
injection two stroke engine Proc. 4 th World Hydrogen Energy Conference Vol. 3,<br />
California. 1982<br />
5. Karim G. A., Klat S. R., Experimental and analytical studies of hydrogen as fuel in<br />
Compression Ignition Engines. ASME Paper No. 75-DGP-19, 1975<br />
6. Homan H. S., Reynolds R. K., De Boer P. C. T. and Mclean W. J. Int. J. Hydrogen<br />
Energy, Vol. 4, 315-325, 1979<br />
7. Ikegami M., Miwa K. Shioji M. A study of hydrogen fueled compression ignition<br />
engines Int. J. Hydrogen Energy, Vol. 4, 341-353, 1982<br />
8. Eckbreth A.C. Laser Diagnostics for Combustion Temperature and Species,<br />
Abacus Press, 1988<br />
9. Warnatz J., Maas U. Technische Verbrennung, Springer-Lehrbuch, 1993<br />
10. Maas U., Warnatz J. Ignition Processes in Hydrogen-Oxygen Mixtures,<br />
Combustion and Flame 74, 53-69, 1988
11. Dorer F., Prechtl P., Mayinger F. Investigation of Mixture Formation and<br />
Combustion Processes in a Hydrogen Fueled Diesel Engine, Hypothesis II, August<br />
1997<br />
12. Siebers D., Naber J. Hydrogen Combustion under Diesel Engine Conditions, XI<br />
World Hydrogen Conference, 1503-1512, 1996<br />
13. Stephan K., Mayinger F. <strong>Thermodynamik</strong>, 1/2. edition, Springer, Berlin, 1986<br />
14. Digeser, Jorach, Enderle, Daimler Benz AG The intercooled hydrogen truck<br />
engine with early internal fuel injection – a means of achieving low emissions and<br />
high specific output Hydrogen Combustion under Diesel Engine Conditions, XI<br />
World Hydrogen Conference, 1537-1546, 1996<br />
15. Knorr, Held, Prümm, MAN Nürnberg, The MAN hydrogen system for city buses,<br />
XI World Hydrogen Conference, 1611-1620, 1996<br />
16. Peschka W, Hydrogen the future cryofuel in internal combustion engines, (DLR,<br />
BMW) XI World Hydrogen Conference, 1611-1620, 1996