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Introduction - Lehrstuhl für Thermodynamik

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ENERGY CONVERSION IN A HYDROGEN FUELED DIESEL<br />

ENGINE:<br />

OPTIMIZATION OF THE MIXTURE FORMATION AND<br />

COMBUSTION<br />

PETER PRECHTL; FRANK DORER; FRANZ MAYINGER<br />

<strong>Lehrstuhl</strong> A <strong>für</strong> <strong>Thermodynamik</strong>, Technische Universität München,<br />

D-85747 Garching, Germany<br />

C. VOGEL; V. SCHNURBEIN<br />

MAN B&W DIESEL AG, Stadtbachstr. 1, D-86153 Augsburg, Germany<br />

Abstract. A large-bore, four-stroke engine, with high pressure injection and<br />

compression ignition, running with hydrogen, is a modern concept for clean energy<br />

conversion without CO2 emission. The key processes for reliable engine operation are a<br />

good mixture formation, a reliable ignition and efficient combustion. The investigations<br />

of these processes are carried out in a rapid compression machine, with modern optical<br />

measurement techniques.<br />

1. <strong>Introduction</strong><br />

The simple reaction of hydrogen and oxygen into water as a clean method for energy<br />

conversion, the high energy density, the wide ignition ranges and the high burning<br />

velocities have been the reasons for a long time for people to investigate the usability of<br />

hydrogen as a fuel for internal combustion engines. Short overviews are given in [1,2].<br />

In recent years, extensive research has been done with different concepts on the<br />

application of hydrogen for engine use. A summary of German activities is given in [3].<br />

The method of internal mixing and compression ignition (C.I.) combines the advantages<br />

of the high efficiency of a diesel engine and the clean combustion of hydrogen and<br />

oxygen. For this combustion method, however, one main problem has to be solved<br />

which is the auto-ignition of hydrogen. A variety of studies on this topic have shown<br />

that a reliable running C.I. engine cannot be realized yet [4,5,6,7]. In a cooperation of<br />

MAN B&W Diesel AG and two departments of the Technische Universtät München, a<br />

large-bore, four-stroke engine running with hydrogen is being developed. The research<br />

project is supported by the Bayerische Forschungsstiftung (Bavarian Research<br />

Foundation). The <strong>Lehrstuhl</strong> <strong>für</strong> Verbrennungskraftmaschinen und Kraftfahrzeuge<br />

(LVK, department of internal combustion engines and motor vehicles) is investigating


the behavior of a single cylinder test engine. The <strong>Lehrstuhl</strong> A <strong>für</strong> <strong>Thermodynamik</strong><br />

(LAT, department of thermodynamics) is investigating the injection and combustion<br />

process with modern optical measurement techniques in a rapid compression machine<br />

(RCM) under realistic conditions. As mentioned above, the ignition of hydrogen under<br />

internal mixing conditions is the key process for a reliable engine operation. Due to this<br />

fact it is main subject of the current research activities at the LAT.<br />

2. Experimental Investigations<br />

In a first phase the experiments are carried out in the RCM by varying of the<br />

compression ratio, the load pressure and the flow condition (variation of the swirl and<br />

the turbulence). The compression ratio reaches a value up to 22, and the compression<br />

end pressure is between 5 and 11 MPa. The temperature reaches values over 950 K. The<br />

hydrogen is injected with a pressure between 25 and 33 MPa, and a maximum injection<br />

duration of 15 ms. In the next step the influence of the injector geometry is analyzed.<br />

For these experiments nozzles with a hole number of 6 up to 24 and a slot nozzle with<br />

nearly equivalent cross-sections were manufactured. These measurements were carried<br />

out under the same pressure conditions.<br />

2.1. EXPERIMENTAL SETUP<br />

The experimental setup used for these investigations is based on an fully optically<br />

accessible rapid compression machine (RCM). The machine simulates a single<br />

compression stroke under realistic conditions. This experimental setup allows a variety<br />

of investigations under different conditions. It is simple to replace the injection device<br />

or the nozzle geometry. The compression ratio, the load, the intake temperature as well<br />

as the injection timing can be varied. In addition to that fact a swirl or a turbulence can<br />

be engendered in the combustion chamber. On the top of the combustion chamber the<br />

electro-hydraulic-controlled injection device for pressurized hydrogen is mounted. The<br />

hydrogen is supplied from single bottles and from bundles. The hydrogen is compressed<br />

with a 30 MPa piston compressor, and it is stored in a small high pressure tank before<br />

the injection. The optical access to the combustion chamber of the RCM is realized<br />

through a large quartz window in the bottom of the piston and additional windows in<br />

the cylinder walls. The RCM allows a maximum combustion pressure over 20 MPa.<br />

This setup allows the use of optical measurement techniques, such as laser-induced<br />

fluorescence (LIF) [8] for the detection of several species like OH, and fast imaging<br />

techniques, such as the high speed digital video and Schlieren techniques to visualize<br />

the mixing and combustion process. A typical setup using the high speed video camera<br />

is shown in figure 1. The dimensions of the machine are in a 1:1 scale to the single<br />

cylinder test engine, which has a piston displacement of about 14 liters and a power<br />

output of approximately 180 kW. The velocity of the piston of the rapid compression<br />

machine corresponds to the piston speed of the engine with 800 – 900 RPM near the top<br />

dead center (TDC). The emitted light (self-fluorescence) from the ignition and the<br />

combustion process is observed using a digital high speed camera at a frame rate of<br />

13,500 Hz. In addition to the conventional data, such as the pressure, the piston


displacement, the needle lift and other required signals, the images are stored digitally.<br />

In the next step the data is analyzed, combined with the images and recorded to a digital<br />

mpeg-film. These films give a good impression of the location and the spatial<br />

distribution of the ignition and combustion process. This method contributes to a better<br />

understanding and an efficient improvement of the combustion concept.<br />

Figure 1: Experimental setup using the rapid compression machine (RCM) and a high<br />

speed video camera to observe the ignition and combustion process<br />

2.2. RESULTS AND DISCUSSION<br />

In the first series of experiments it has been shown that the compression ratio has a<br />

significant influence on the ignition delay. Higher temperatures lead to shorter ignition<br />

delays. However, large variations of the ignition delays have been observed in all the<br />

experiments. The ignition occurs statistically distributed in the combustion chamber.<br />

The analysis of the films proves the assumption that an ignition of a single jet does not<br />

lead to the ignition of other hydrogen jets, as is shown in figure 2. It has also been<br />

observed that several jets have not ignited. It can be inferred that different areas of<br />

combustible hydrogen mixtures of the injected jets in a single compression cycle can<br />

have different ignition delays. As a result, cycle-to-cycle variations in the pressure<br />

recordings are expected, and the possibility of miss-fire can not be excluded. Possible<br />

reasons can be statistical effects on the ignition due to the compression end<br />

temperatures being near the auto-ignition temperature of hydrogen and the varying<br />

mixing conditions. It is likely that there is an influence of the purity of the pressurized<br />

hydrogen, the intake-air or of the leakage in the injection system on the ignition. All


three possibilities were analyzed. The results show that there is no contamination of the<br />

hydrogen compression and of the high pressure storage system. Furthermore, the air<br />

supply system also has no contamination. The injection device has an oil sealing system<br />

which was suspected to leak impurities of oil into the injected hydrogen.<br />

pressure [bar]<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

260<br />

-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />

time [s]<br />

piston displacement<br />

pressure<br />

needle lift = injection duration<br />

Figure 2: Typical ignition process of a 6 hole nozzle<br />

The installation of another injector with dry sealings has no significant impact on the<br />

statistical ignition behavior. But it has to be taken into account that the hydrogen is used<br />

as it is delivered from a commercial gas supplier. That means it is delivered as a<br />

compressed gas, and it is not as chemically clean as liquid hydrogen (the boiling<br />

temperature of liquid hydrogen is 20 K). The phenomenon of auto-ignition, which is<br />

difficult to realize, and the variations of the ignition delays were also observed and<br />

380<br />

360<br />

340<br />

320<br />

300<br />

280<br />

piston displacement [mm]


discussed by other researchers working on the topic [6, 7, 4, 2]. The ignition delays<br />

estimated from calculations of hydrogen air mixtures with zero dimensional calculations<br />

[9-11] are in a range of 2 ms at compression end temperatures of 1050 K. Siebers [12]<br />

reports ignition delays in his experiments of 0.5 ms at temperatures of 1200 K.<br />

pressure [bar]<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

pressure<br />

piston stroke<br />

-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />

time [s]<br />

needle lift<br />

Figure 3:Typical ignition process of a slot nozzle with a slot height of 100 um; flame<br />

propagation around the nozzle within 0.4 ms<br />

An enhanced flow field in the combustion chamber, which can be realized<br />

through a swirl or a turbulence, improves the reliability of the ignition and reduces the<br />

variations of the ignition delays. Due to the critical-flow injection of the hydrogen [13]<br />

into the combustion chamber and its high speed in the nozzle outlets of about 1400 m/s<br />

380<br />

360<br />

340<br />

320<br />

300<br />

280<br />

260<br />

piston stroke [mm]


(which is the speed of sound), the injected jets are not deflected in the vicinity of the<br />

outlets. Owing to the strong slow-down of the injected hydrogen, a significant influence<br />

on the penetration direction can be observed at a distance of 50 mm from the nozzle.<br />

pressure [bar]<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

pressure<br />

needle lift<br />

piston displacement<br />

-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />

time [s]<br />

Figure 4: Typical ignition process of a combined nozzle with 6 x 0.6 and 12 x 0.4 mm;<br />

fast flame propagation, fast combustion and good spatial use of the entire combustion<br />

chamber<br />

In order to run the engine under similar conditions like a diesel engine with a<br />

high compression ratio and late gaseous injection, a nozzle geometry with 6 or more<br />

holes is set up. All the experiments with hole numbers up to 10 show that a burning jet<br />

hardly ignites the neighbor jet. As discussed above, this behavior leads to large<br />

380<br />

360<br />

340<br />

320<br />

300<br />

280<br />

260<br />

piston displacement [mm]


variations in the pressure recordings. As a result of these observations a nozzle system<br />

with a spatially connected combustible mixture distribution was set up. Experiments<br />

with nozzles with 18 holes or a slot show a much better combustion behavior than those<br />

with 6 to 10 holes. Once auto-ignition occurs, the flame propagates very fast over all<br />

injected jets. Due to the equivalent cross-section of the nozzles the diameter of the holes<br />

decreases with the increase of the number of holes. A smaller bore diameter reduces the<br />

momentum of the injected hydrogen significantly (~d 2 ). Owing to a smaller momentum<br />

the jet is slowed down faster and a reduced penetration speed of the jets can be<br />

observed. Due to the smaller speed the auto-ignition begins in the vicinity of the nozzle.<br />

The best ignition behavior is observed with a slot nozzle. Figure 3 illustrates the<br />

ignition process of a nozzle with a slot height of 100 um. Under these conditions an<br />

earlier and a better reproducible ignition can be achieved. On the other hand a longer<br />

combustion duration is observed. The flow conditions have significant influence on the<br />

combustion process. Nozzle geometries with low jet velocities and large ignitable areas<br />

have good auto-ignition properties, but induce insufficient conditions for a fast and<br />

effective overall combustion. The flow energy for the mixing process is lost in highly<br />

throttling nozzles. The nozzles with 6 holes show, in contrast to nozzles with more bore<br />

holes, better combustion properties as soon as the hydrogen is ignited. The combination<br />

of both advantages leads to the application of nozzles with a series of large and small<br />

bores. The existence of the small bores ensure an early and reliable ignition in the<br />

vicinity of the nozzle and a fast flame propagation, which ignites the surrounding jets.<br />

The large bores, however, cause a high momentum of the injected hydrogen, which<br />

leads to good mixing. Figure 4 illustrates the ignition and the combustion process of a<br />

combined 18-hole nozzle with 6 x 0.6 mm and 12 x 0.4 mm bores. A fast flame<br />

propagation around the nozzle is achieved within 0.6 milliseconds. In addition to that<br />

fact a faster penetration of the jets from the large bore holes to the wall of the cylinder is<br />

observed, which results in a more efficient use of the whole combustion chamber.<br />

Nozzles of these types are, at present, the best combination of a reliable ignition and of<br />

an efficient combustion. However, the variations of the ignition processes and the<br />

pressure rise rates are higher than those observed in real diesel engines. In addition to<br />

that fact an improvement of the ignition of the hydrogen near the nozzle can be<br />

expected using slow-opening valves. These types of valves are used in modern<br />

combustion concepts of diesel engines with Common-Rail injection systems, with<br />

which the pressure rise rates can be controlled and the emissions can be reduced.<br />

Although an operation of a C.I. engine using hydrogen seems to be possible<br />

under the above discussed conditions, alternative ignition devices should still be<br />

considered. The low ignition energy of hydrogen suggests the use of a spark plug<br />

ignition under late internal mixing conditions. The varying auto-ignition behavior of the<br />

hydrogen, because of possible impurities, can lead to pre-ignitions under early-injection<br />

conditions. Due to this fact S.I. (spark ignition) hydrogen engines have a reduced<br />

compression ratio of about 8-10 [14 15, 16]. The possibility of setting up a<br />

configuration with late internal mixing and spark ignition, as that used in a new<br />

generation of GDI (gasoline direct injection) engines, is also of great interest. For this<br />

reason experiments have been set up with a small modification to the cylinder head of<br />

the RCM, the insertion of a spark plug. With the same nozzle geometry and a reduced<br />

compression ratio, the auto-ignition can be avoided, which enables a reliable and a fast


ignition of the hydrogen. Due to the optimized arrangement of the holes in the nozzle, a<br />

fast flame propagation around the nozzle is achieved within 1 ms. Figure 5 shows a<br />

spark ignited combustion. The spark-plug timing is set 1 ms after the beginning of the<br />

hydrogen injection. With a late injection near TDC and an immediate ignition with a<br />

spark plug, high compression ratios can be realized, as opposed to external or early<br />

internal mixing.<br />

pressure [bar]<br />

100<br />

80<br />

60<br />

40<br />

20<br />

pressure<br />

0<br />

260<br />

-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012<br />

time [s]<br />

needle lift<br />

piston displacement<br />

Figure 5: Spark ignition of a late injected hydrogen jet<br />

360<br />

340<br />

320<br />

300<br />

280<br />

piston displacement [mm]


3. Conclusions<br />

The developed setup for the investigations of a hydrogen-fueled large-bore C.I. engine<br />

with a high pressure injection system allows a detailed analysis of all relevant<br />

processes. The modern optical techniques enable the analysis of the mixing, the ignition<br />

and the combustion processes. The results obtained with this setup contribute to a better<br />

understanding of the very fast processes. Furthermore this setup allows an efficient<br />

testing and development of engine components. The auto-ignition of hydrogen has been<br />

observed. High pressures and temperatures have a positive influence on a short ignition<br />

delay. Turbulence and swirl support the propagation of the flame over the whole<br />

combustion chamber and regulate the combustion for smoother pressure rates. At<br />

present, combined nozzles containing 18 bores with different diameters seem to be the<br />

best injection geometry to assure small variations of the ignition delay and of the<br />

pressure. However, the current ignition behavior of hydrogen in a C.I. engines without<br />

ignition sources is not applicable yet. Therefore further improvement for a smooth and<br />

safe engine operation is still required. Modern injection concepts with their possibilities<br />

of pilot injection and slow-opening rates offer additional options for improvement.<br />

However, further ignition sources for hydrogen under late internal mixing conditions<br />

have to be considered, and should be investigated.<br />

References<br />

1. Das L. M., Hydrogen Engines: A view of the Past and a look into the future, Int. J.<br />

Hydrogen Energy, Vol. 15, 425-443, 1990<br />

2. Wong J. K. S. Compression ignition of hydrogen in a direct injection diesel<br />

engine modified as a low heat-rejection-engine Int. J. Hydrogen Energy, Vol. 15,<br />

No. 7, 507-514, 1990<br />

3. TÜV Bayern, Energieträger Wasserstoff 1996, TÜV Bayern Sachsen<br />

Forschungsprojekte und Anwendungen, Westendstr. 199, 80686 München,<br />

Germany<br />

4. Furuhama S. and Kabayashi Y. Development of a hot surface ignition hydrogen<br />

injection two stroke engine Proc. 4 th World Hydrogen Energy Conference Vol. 3,<br />

California. 1982<br />

5. Karim G. A., Klat S. R., Experimental and analytical studies of hydrogen as fuel in<br />

Compression Ignition Engines. ASME Paper No. 75-DGP-19, 1975<br />

6. Homan H. S., Reynolds R. K., De Boer P. C. T. and Mclean W. J. Int. J. Hydrogen<br />

Energy, Vol. 4, 315-325, 1979<br />

7. Ikegami M., Miwa K. Shioji M. A study of hydrogen fueled compression ignition<br />

engines Int. J. Hydrogen Energy, Vol. 4, 341-353, 1982<br />

8. Eckbreth A.C. Laser Diagnostics for Combustion Temperature and Species,<br />

Abacus Press, 1988<br />

9. Warnatz J., Maas U. Technische Verbrennung, Springer-Lehrbuch, 1993<br />

10. Maas U., Warnatz J. Ignition Processes in Hydrogen-Oxygen Mixtures,<br />

Combustion and Flame 74, 53-69, 1988


11. Dorer F., Prechtl P., Mayinger F. Investigation of Mixture Formation and<br />

Combustion Processes in a Hydrogen Fueled Diesel Engine, Hypothesis II, August<br />

1997<br />

12. Siebers D., Naber J. Hydrogen Combustion under Diesel Engine Conditions, XI<br />

World Hydrogen Conference, 1503-1512, 1996<br />

13. Stephan K., Mayinger F. <strong>Thermodynamik</strong>, 1/2. edition, Springer, Berlin, 1986<br />

14. Digeser, Jorach, Enderle, Daimler Benz AG The intercooled hydrogen truck<br />

engine with early internal fuel injection – a means of achieving low emissions and<br />

high specific output Hydrogen Combustion under Diesel Engine Conditions, XI<br />

World Hydrogen Conference, 1537-1546, 1996<br />

15. Knorr, Held, Prümm, MAN Nürnberg, The MAN hydrogen system for city buses,<br />

XI World Hydrogen Conference, 1611-1620, 1996<br />

16. Peschka W, Hydrogen the future cryofuel in internal combustion engines, (DLR,<br />

BMW) XI World Hydrogen Conference, 1611-1620, 1996

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