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A Life Cycle Assessment of the PureCell Stationary Fuel Cell System ...

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<strong>Pure<strong>Cell</strong></strong> <strong>System</strong> Maintenance<br />

Several maintenance activities are needed to keep <strong>the</strong> fuel cell functioning properly over<br />

its entire lifetime. Maintenance activities included in <strong>the</strong> inventory table are <strong>the</strong><br />

replacement <strong>of</strong> activated carbon for water treatment and <strong>the</strong> hexavalent chromium<br />

emissions caused by cleaning <strong>the</strong> condenser. O<strong>the</strong>r maintenance activities include<br />

replacing <strong>the</strong> Rohm and Haas resin for water treatment, a quarterly replacement <strong>of</strong> air<br />

filters and o<strong>the</strong>r replacements which are done on a case-by-case basis (e.g., blowers and<br />

fans). These are however not included in <strong>the</strong> LCA because no data on <strong>the</strong>se activities are<br />

available.<br />

Materials Amount Unit Waste treatment<br />

Activated carbon <strong>Pure<strong>Cell</strong></strong><br />

system 1852.5 lb<br />

Total 1852.5 lb<br />

Waste to treatment<br />

inorganic general 1852.5 lb Landfill Compostables<br />

chromium compounds 570 kg LT waste to chemical landfill<br />

chromium compounds 570 kg Waste to chemical landfill<br />

Table 4-26: <strong>Pure<strong>Cell</strong></strong> system maintenance inventory data<br />

The activated carbon for water treatment is replaced three times a year. Initially, 60 lb<br />

activated carbon is used in <strong>the</strong> <strong>Pure<strong>Cell</strong></strong> system. The maintenance data are based on a<br />

<strong>Pure<strong>Cell</strong></strong> system lifetime <strong>of</strong> 85,000 hrs. In <strong>the</strong> definition <strong>of</strong> <strong>the</strong> <strong>Pure<strong>Cell</strong></strong> system<br />

lifetime 8000 hrs is regarded as one year (vs. 8760 actual hours); this means that <strong>the</strong><br />

lifetime in years is 10 5/8 year. The total amount <strong>of</strong> activated carbon needed for<br />

maintenance <strong>the</strong>n becomes: 120 lb + (9*180) lb + 5 *180lb<br />

= 1852. 5lb<br />

.<br />

8<br />

The activated carbon waste is indicated as ‘inorganic general’ and is assumed to end up<br />

in landfills.<br />

The condenser is cleaned annually resulting in waste water containing hexavalent<br />

chromium. Per annual cleaning 15 to 30 gallons <strong>of</strong> waste water are produced with a<br />

hexavalent chromium concentration below 5%. For <strong>the</strong> calculations it is assumed that 15<br />

gallons with a 5% hexavalent chromium concentration are produced annually.<br />

15 Gallons is equal to 57 liter or 57 kg. With 10 annual cleanings, this results in 570 kg<br />

waste water to treatment, containing 28.5 kg Cr (VI)<br />

. This is a conservative estimate: it<br />

is expected that most <strong>of</strong> this is Cr (III). Although <strong>the</strong> waste is described as ‘chromium<br />

compounds’, <strong>the</strong> SimaPro s<strong>of</strong>tware only recognizes <strong>the</strong> amount <strong>of</strong> waste and <strong>the</strong> waste<br />

treatment it is sent to. This means that it is not possible in SimaPro to include <strong>the</strong> exact<br />

amount <strong>of</strong> hexavalent chromium in <strong>the</strong> model. The 570 kg waste is assumed to go to<br />

landfill; it appears twice in <strong>the</strong> inventory table because both <strong>the</strong> short-term and long-term<br />

effects are taken into account.<br />

43

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