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Grivory GV-5H

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Metallerstatning<br />

Metallersättning<br />

Metaalvervanging<br />

Metalreplacement


Why replacing die casting metals with <strong>Grivory</strong><br />

Part cost reduction<br />

Weight reduction<br />

No post and surface treatment<br />

necessary<br />

Integration of functions


Design and Colour


Cost reduction


4<br />

Typical cost comparison<br />

Al - die casting versus <strong>Grivory</strong> <strong>GV</strong><br />

Manufacturing cost per part [EUR]<br />

3<br />

2<br />

Cost reduction = - 40 %<br />

1<br />

0<br />

Part in Al-Die Casting<br />

Part in <strong>Grivory</strong> <strong>GV</strong><br />

Material Tool Staff & Machine Post Treatment


Massive increase of metal prices in the last 5<br />

years.<br />

Copper [$/to]<br />

+ 500%<br />

Aluminium [$/to]<br />

Zinc [$/to] + 300%<br />

+ 260%


Comparison of costs per volume<br />

60<br />

price [€/dm^3]<br />

50<br />

40<br />

30<br />

20<br />

2002<br />

2007<br />

10<br />

0<br />

Aluminum Zinc Cooper Magnesium <strong>Grivory</strong><br />

<strong>GV</strong>/HT


<strong>Grivory</strong> <strong>GV</strong> och HT<br />

<br />

<br />

<br />

Metal replacement with<br />

<strong>Grivory</strong> <strong>GV</strong> & HT<br />

New product<br />

developments<br />

- <strong>Grivory</strong> <strong>GV</strong>X<br />

Typical applications


<strong>Grivory</strong><br />

semi-crystalline, partial-aromatic Polyamides<br />

<strong>Grivory</strong> <strong>GV</strong><br />

Matrix polymer: PA66 + PA6I/6T<br />

high stiffness & strength,<br />

good toughness<br />

very good creep behaviour<br />

less influence of moisture<br />

absorption (dimensions,<br />

properties)<br />

good surface quality<br />

<strong>Grivory</strong> HT1 / HT2<br />

Matrix polymer: PA6T/6I (HT1)<br />

PA6T/66 (HT2)<br />

high stiffness and strength also<br />

at elevated temperatures<br />

excellent creep behaviour<br />

good dimensional stability,<br />

constant mechanical properties<br />

after moisture absorption<br />

improved chemical resistance<br />

to chemicals and hot water


<strong>Grivory</strong> Properties<br />

<strong>Grivory</strong> <strong>GV</strong>-<strong>5H</strong> <strong>Grivory</strong> HT2V-<strong>5H</strong> <strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

Melting Point °C °C 260 310 325<br />

HDT (1,8 Mpa) °C 235 285 285<br />

Long Term Usage temp. °C 120 140 150<br />

Short Term usage temp °C 180 240 250<br />

Pulse temperature °C n.a 300 300<br />

E. Modulus dry<br />

Cond.<br />

Impact strength dry<br />

Cond.<br />

Mpa 18'000<br />

17’000<br />

KJ/m2 85<br />

85<br />

17'000<br />

17’000<br />

80<br />

80<br />

18'000<br />

17’500<br />

80<br />

80


20<br />

<strong>Grivory</strong> show high stiffness even after<br />

moisture absorption<br />

Tensile E-Modulus [MPa, 23°C]<br />

18<br />

dry as moulded<br />

conditioned<br />

5% < 5%<br />

16<br />

14<br />

12<br />

35%<br />

30%<br />

10<br />

8<br />

PA 6 GF50 PA 66 GF50 <strong>Grivory</strong> <strong>GV</strong>-<strong>5H</strong> <strong>Grivory</strong> HTV-<strong>5H</strong>1


<strong>Grivory</strong> creeps significantly less than PA 66<br />

Elongation [%]<br />

0.7<br />

ISO 899 / 23°C / conditioned<br />

0.6<br />

Load = 40 MPa<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

HTV-<strong>5H</strong>1 <strong>GV</strong>-<strong>5H</strong> PA 66 GF50<br />

0.0<br />

0.1 1 10 100 1000 10000<br />

Time [ h ]


<strong>Grivory</strong> in direct comparison to metal die<br />

castings<br />

<strong>Grivory</strong> <strong>GV</strong>-<strong>5H</strong><br />

<strong>Grivory</strong> HTV-<br />

<strong>5H</strong>1<br />

Zn-DC: ZnAl4Cu1<br />

Al-DC: EN AC-<br />

AlSi9Cu3<br />

Brass:<br />

CuZn39Pb1Al-C


400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

The strength of <strong>Grivory</strong> is similar<br />

as the one of metal die castings<br />

Tensile Strength [MPa] ISO 527<br />

-20°C 23°C 80°C 120°C<br />

0<br />

Zn-DC Al-DC Brass-DC <strong>GV</strong>-<strong>5H</strong> HTV-<strong>5H</strong>1<br />

x<br />

Data Sheet Values<br />

x


100<br />

Metal die castings are considerable stiffer<br />

than <strong>Grivory</strong><br />

Tensile E-Modulus [GPa]<br />

ISO 527<br />

-20°C 23°C 80°C 120°C<br />

80<br />

60<br />

40<br />

20<br />

0<br />

x<br />

Zn-DC Al-DC Brass-DC <strong>GV</strong>-<strong>5H</strong> HTV-<strong>5H</strong>1<br />

Data Sheet Values<br />

x


Under long term load<br />

zinc die-cast creeps more than <strong>Grivory</strong><br />

1.5<br />

1.2<br />

0.9<br />

Elongation [%] 100 MPa/23°C/cond., ISO 899<br />

<strong>Grivory</strong> <strong>GV</strong>-<strong>5H</strong><br />

<strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

0.6<br />

0.3<br />

Zinc<br />

Alu<br />

0<br />

0.1 1 10 100 1000 10000<br />

Time [h]


Screw joints with metric screws<br />

Bearing in <strong>Grivory</strong> <strong>GV</strong>-<strong>5H</strong><br />

M8 thread by injection<br />

moulding process<br />

Condition: 23°C/50% r.L .


Strength of <strong>Grivory</strong> <strong>GV</strong> on "die casting level"<br />

1.7 tonnes<br />

(car and frame)<br />

Bearing breaks at<br />

3200 kg, the M8<br />

screw at 3300 kg


New product developments<br />

<strong>Grivory</strong> <strong>GV</strong>X


<strong>Grivory</strong> <strong>GV</strong>X<br />

<strong>Grivory</strong> <strong>GV</strong>X: Outstanding<br />

mechanical properties in<br />

combination with easy<br />

processing behavior<br />

<strong>Grivory</strong> <strong>GV</strong>X:<br />

Remarkable low warpage<br />

for high precision


Significantly Increased Stiffness<br />

30000<br />

ISO 527 (1 mm / min, 23 °C)<br />

Tensile modulus [MPa]<br />

25000<br />

20000<br />

15000<br />

10000<br />

5000<br />

+ 56 %<br />

dry<br />

cond.<br />

dry<br />

cond.<br />

0<br />

<strong>GV</strong>-<strong>5H</strong><br />

<strong>GV</strong>X-7H


Significantly Increased Strength<br />

ISO 527 (5 mm / min, 23 °C)<br />

Tensile strength [MPa]<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

+ 16 %<br />

dry<br />

cond.<br />

dry<br />

cond.<br />

0<br />

<strong>GV</strong>-<strong>5H</strong><br />

<strong>GV</strong>X-7H


Significant Increased Transverse Stiffness<br />

20000<br />

ISO 527 (1 mm / min, 23 °C)<br />

Tensile modulus [MPa]<br />

15000<br />

10000<br />

5000<br />

0<br />

+<br />

26%<br />

transverse parallel<br />

transverse parallel<br />

<strong>GV</strong>-<strong>5H</strong><br />

<strong>GV</strong>X-<strong>5H</strong>


Comparable Flow Length With High Fiber Content<br />

spiral flow test :<br />

1.5 X 10 mm<br />

<strong>GV</strong>X-<strong>5H</strong><br />

<strong>GV</strong>X-7H<br />

<strong>GV</strong>-<strong>5H</strong><br />

pressure: 1000<br />

bar<br />

tool temperature: 100°C<br />

melt temperature: 300°C<br />

0 100 200 300<br />

Flow length [mm]


Low Warpage<br />

flatness [mm]<br />

0,7<br />

0,6<br />

0,5<br />

0,4<br />

0,3<br />

0,2<br />

0,1<br />

0<br />

average value of 10 parts<br />

<strong>GV</strong>-<strong>5H</strong><br />

<strong>GV</strong>X-<strong>5H</strong>


Improved Surface Quality<br />

<strong>Grivory</strong> <strong>GV</strong>X shows an excellent surface quality even with<br />

high fiber contents<br />

<strong>Grivory</strong> <strong>GV</strong>X-6H<br />

60 % glass fiber content !


Comparison of Properties<br />

<strong>GV</strong>-<strong>5H</strong><br />

<strong>GV</strong>X-<strong>5H</strong><br />

Stiffness<br />

Surface Quality<br />

Strength<br />

Warpage<br />

Performance<br />

Isotropy<br />

Flowability<br />

Impact<br />

Notched Impact


Housing and filter bowl of water filter<br />

<strong>Grivory</strong> <strong>GV</strong>-4H WA<br />

Pressure Pn = 16 bar<br />

Pressure swell test =<br />

200'000 cycles<br />

Chemical resistance<br />

Drinking water approvals<br />

Easy coloring


Application in <strong>Grivory</strong> HT<br />

Throttle Body (Dev.)<br />

Requirements<br />

• stiffness<br />

• chemical resistance<br />

• dimensional stability<br />

metal substitution


Application in <strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

Oil Pump Housing (Dev.)<br />

Requirements<br />

• high mechanical performance<br />

• temperature resistance<br />

up to 150°C<br />

• oil resistance<br />

• weight saving<br />

• cost saving<br />

metal substitution


Requirements<br />

• high mechanical performance<br />

• temperature resistance<br />

up to 150°C<br />

• oil resistance<br />

• weight saving<br />

• cost saving<br />

Application in <strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

Oil Pump Housing (Dev.)<br />

metal substitution


Application in <strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

Clutch Central Slave Cylinder<br />

Requirements<br />

• strength and stiffness<br />

• resistance to heat and chemicals<br />

• dimensional stability<br />

also after water absorption<br />

metal substitution


Application in <strong>Grivory</strong> HTV-<strong>5H</strong>1<br />

Spring Housing (ABS Air Vent)<br />

Requirements<br />

• high level of stiffness<br />

• low creep<br />

• low warp<br />

No. 313


<strong>Grivory</strong> <strong>GV</strong>-4H<br />

Housing Cold-Water-Meter<br />

Salesman: Barlog Plastics


<strong>Grivory</strong> HT1V- 4FWA<br />

Cartridge / Housing for Thermostatic Shower


<strong>Grivory</strong> HT1V- 5FWA<br />

Regulator Knob for Shower Panel<br />

Salesman: EMS France


<strong>Grivory</strong> HT1V- 5FWA<br />

Cartidge for water tap<br />

Requirements:<br />

<br />

<br />

<br />

<br />

Mechanical:<br />

i Pressure 16 bar<br />

i Pressure swell test 60 bar<br />

i Permanent easy turn<br />

i no leakage during lifetime<br />

Thermal:<br />

i Temperature 20°C - 60°C<br />

Chemical:<br />

i hot water resistance<br />

i Resistance to chlorine<br />

i Resistance to detergents<br />

General:<br />

i drinking water regulations<br />

Salesman: Th. Müller


<strong>Grivory</strong> HT1V- 5FWA<br />

Head Work


<strong>Grivory</strong> HT1V- 4FWA<br />

Housing Heat Exchanger for Swimming Pools<br />

<br />

<br />

<br />

<br />

<br />

hydrolysis resistance<br />

resistance to chlorine<br />

high mechanical<br />

strength (working<br />

pressure up to 6 bar)<br />

heating capacity<br />

47,5KW@90°C<br />

water temp. up to 40°C<br />

contact with drinking<br />

water


<strong>Grivory</strong> HT1V- 4FWA<br />

Different Parts for Coffee Machines<br />

Requirements:<br />

<br />

<br />

<br />

<br />

Stiffness/Strength at high<br />

Temperatures<br />

Chemical Resistance<br />

Hydrolysis Resistance<br />

Food Approval<br />

Salesman: Th. Mueller

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