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Chemwatch Australian MSDS 31-1353 - FUJIFILM Australia

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<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 1 of 10<br />

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION<br />

PRODUCT NAME<br />

<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

SYNONYMS<br />

"Product Code: 850117 / 750117" 61<strong>31</strong>6<br />

PROPER SHIPPING NAME<br />

CORROSIVE LIQUID, N.O.S.(contains PDTA ferric ammonium salt)<br />

PRODUCT USE<br />

For processing of colour negative film.<br />

SUPPLIER<br />

Company: <strong>FUJIFILM</strong> <strong>Australia</strong> Pty Ltd<br />

Address:<br />

114 Old Pittwater Road<br />

Brookvale<br />

NSW, 2100<br />

<strong>Australia</strong><br />

Telephone: +61 2 9466 2600<br />

Emergency Tel: +61 1800 039 008<br />

Emergency Tel: +61 3 9573 <strong>31</strong>12<br />

Fax: +61 2 9938 1975<br />

Section 2 - HAZARDS IDENTIFICATION<br />

STATEMENT OF HAZARDOUS NATURE<br />

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.<br />

CHEMWATCH HAZARD RATINGS<br />

Flammability<br />

Toxicity<br />

Body Contact<br />

Reactivity<br />

Chronic<br />

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4<br />

RISK<br />

Risk Codes<br />

Risk Phrases<br />

R22<br />

• Harmful if swallowed.<br />

R36/38 • Irritating to eyes and skin.<br />

R43<br />

• May cause SENSITISATION by skin contact.<br />

R52/53 • Harmful to aquatic organisms, may cause long- term adverse<br />

effects in the aquatic environment.<br />

R68(3)<br />

• Possible risk of irreversible effects.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 2 of 10<br />

Section 2 - HAZARDS IDENTIFICATION<br />

SAFETY<br />

Safety Codes<br />

S23<br />

S24<br />

S25<br />

S36<br />

S37<br />

S39<br />

S53<br />

S40<br />

S13<br />

S26<br />

S46<br />

S60<br />

Safety Phrases<br />

• Do not breathe gas/fumes/vapour/spray.<br />

• Avoid contact with skin.<br />

• Avoid contact with eyes.<br />

• Wear suitable protective clothing.<br />

• Wear suitable gloves.<br />

• Wear eye/face protection.<br />

• Avoid exposure - obtain special instructions before use.<br />

• To clean the floor and all objects contaminated by this material, use water.<br />

• Keep away from food, drink and animal feeding stuffs.<br />

• In case of contact with eyes, rinse with plenty of water and contact Doctor or<br />

Poisons Information Centre.<br />

• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show<br />

this container or label).<br />

• This material and its container must be disposed of as hazardous waste.<br />

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS<br />

NAME CAS RN %<br />

PDTA ferric ammonium salt 111687-36-6 10-20<br />

ammonium bromide 12124-97-9 5-10<br />

succinic acid 110-15-6 3-7<br />

maleic acid 110-16-7 3-7<br />

ammonium nitrate 6484-52-2 1-5<br />

imidazole 288-32-4 1-5<br />

water 7732-18-5 50-70<br />

Section 4 - FIRST AID MEASURES<br />

SWALLOWED<br />

• IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.<br />

• For advice, contact a Poisons Information Centre or a doctor.<br />

• Urgent hospital treatment is likely to be needed.<br />

• In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive<br />

measures as indicated by the patient's condition.<br />

EYE<br />

■ If this product comes in contact with the eyes:<br />

• Wash out immediately with fresh running water.<br />

• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting<br />

the upper and lower lids.<br />

• Seek medical attention without delay; if pain persists or recurs seek medical attention.<br />

• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.<br />

SKIN<br />

■ If skin contact occurs:<br />

• Immediately remove all contaminated clothing, including footwear.<br />

• Flush skin and hair with running water (and soap if available).<br />

• Seek medical attention in event of irritation.<br />

INHALED<br />

• If fumes, aerosols or combustion products are inhaled remove from contaminated area.<br />

• Other measures are usually unnecessary.<br />

• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.<br />

• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).<br />

• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semirecumbent<br />

posture) and must be kept under medical observation even if no symptoms are (yet) manifested.<br />

• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative<br />

may be considered.<br />

NOTES TO PHYSICIAN<br />

■ Treat symptomatically.<br />

For acute or short term repeated exposures to iron and its derivatives:<br />

• Always treat symptoms rather than history.<br />

• In general, however, toxic doses exceed 20 mg/kg of ingested material (as elemental iron) with lethal doses exceeding 180 mg/kg.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 3 of 10<br />

Section 4 - FIRST AID MEASURES<br />

• Control of iron stores depend on variation in absorption rather than excretion. Absorption occurs through aspiration, ingestion<br />

and burned skin.<br />

• Hepatic damage may progress to failure with hypoprothrombinaemia and hypoglycaemia. Hepatorenal syndrome may occur.<br />

For acute or short term repeated exposures to strong acids:<br />

• Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.<br />

• Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling<br />

• Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.<br />

• Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating<br />

action of the acid on proteins in specific tissues.<br />

For acute or short-term repeated exposures to highly alkaline materials:<br />

• Respiratory stress is uncommon but present occasionally because of soft tissue edema.<br />

• Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.<br />

• Oxygen is given as indicated.<br />

• The presence of shock suggests perforation and mandates an intravenous line and fluid administration.<br />

Treatment of intoxication by the bromide ion includes hydration, the maintenance of mild water diuresis, and sodium, or even<br />

better, ammonium chloride (10-15 gm. daily in divided doses) with an osmotic or high ceiling diuretic.<br />

In acute poisoning the stomach should be emptied by aspiration and lavage and sodium chloride given by intravenous infusion.<br />

Section 5 - FIRE FIGHTING MEASURES<br />

EXTINGUISHING MEDIA<br />

■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media<br />

which may be used. Choice of extinguishing media should take into account surrounding areas.<br />

Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce<br />

floating layers of combustible substances.<br />

In such an event consider:<br />

• foam.<br />

FIRE FIGHTING<br />

• Alert Fire Brigade and tell them location and nature of hazard.<br />

• Wear full body protective clothing with breathing apparatus.<br />

• Prevent, by any means available, spillage from entering drains or water course.<br />

• Use fire fighting procedures suitable for surrounding area.<br />

FIRE/EXPLOSION HAZARD<br />

• Non combustible.<br />

• Not considered a significant fire risk, however containers may burn.<br />

Decomposition may produce toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of<br />

burning organic material.<br />

FIRE INCOMPATIBILITY<br />

■ None known.<br />

HAZCHEM<br />

2X<br />

Section 6 - ACCIDENTAL RELEASE MEASURES<br />

MINOR SPILLS<br />

• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or<br />

disposal of material.<br />

• Check regularly for spills and leaks.<br />

• Clean up all spills immediately.<br />

• Avoid breathing vapours and contact with skin and eyes.<br />

• Control personal contact by using protective equipment.<br />

• Contain and absorb spill with sand, earth, inert material or vermiculite.<br />

MAJOR SPILLS<br />

• Clear area of personnel and move upwind.<br />

• Alert Fire Brigade and tell them location and nature of hazard.<br />

• Wear full body protective clothing with breathing apparatus.<br />

• Prevent, by any means available, spillage from entering drains or water course.<br />

Personal Protective Equipment advice is contained in Section 8 of the <strong>MSDS</strong>.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 4 of 10<br />

Section 7 - HANDLING AND STORAGE<br />

PROCEDURE FOR HANDLING<br />

• DO NOT allow clothing wet with material to stay in contact with skin.<br />

• Avoid all personal contact, including inhalation.<br />

• Wear protective clothing when risk of exposure occurs.<br />

• Use in a well-ventilated area.<br />

• Avoid contact with moisture.<br />

SUITABLE CONTAINER<br />

• DO NOT use aluminium or galvanised containers.<br />

• Check regularly for spills and leaks.<br />

• Lined metal can, lined metal pail/ can.<br />

• Plastic pail.<br />

• Polyliner drum.<br />

• Packing as recommended by manufacturer.<br />

For low viscosity materials<br />

• Drums and jerricans must be of the non-removable head type.<br />

• Where a can is to be used as an inner package, the can must have a screwed enclosure.


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 5 of 10<br />

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION<br />

MALEIC ACID:<br />

SUCCINIC ACID:<br />

■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat.<br />

Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various<br />

airborne concentrations.<br />

<strong>FUJIFILM</strong> CN-16S N2 SUC:<br />

PDTA FERRIC AMMONIUM SALT:<br />

■ The recommended TLV is thought to reduce the likelihood of respiratory irritation and skin irritation from exposure to<br />

aerosols and mists of soluble iron salts.<br />

WATER:<br />

■ No exposure limits set by NOHSC or ACGIH.<br />

PERSONAL PROTECTION<br />

RESPIRATOR<br />

•Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)<br />

EYE<br />

• Safety glasses with side shields.<br />

• Chemical goggles.<br />

• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,<br />

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a<br />

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and<br />

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of<br />

chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at<br />

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed<br />

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].<br />

HANDS/FEET<br />

• Wear chemical protective gloves, eg. PVC.<br />

• Wear safety footwear or safety gumboots, eg. Rubber.<br />

NOTE:<br />

• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other<br />

protective equipment, to avoid all possible skin contact.<br />

• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.<br />

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:<br />

• frequency and duration of contact,<br />

• chemical resistance of glove material,<br />

• glove thickness and<br />

• dexterity.<br />

OTHER<br />

• Overalls.<br />

• PVC Apron.<br />

• PVC protective suit may be required if exposure severe.<br />

• Eyewash unit.<br />

ENGINEERING CONTROLS<br />

■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed<br />

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to<br />

provide this high level of protection.<br />

The basic types of engineering controls are:<br />

Process controls which involve changing the way a job activity or process is done to reduce the risk.<br />

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation<br />

that strategically "adds" and "removes" air in the work environment.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 6 of 10<br />

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES<br />

APPEARANCE<br />

Clear dark green acidic liquid with no odour; mixes with water.<br />

PHYSICAL PROPERTIES<br />

Liquid.<br />

Mixes with water.<br />

Corrosive.<br />

Acid.<br />

State Liquid Molecular Weight Not Applicable<br />

Melting Range (°C) Not Available Viscosity Not Available<br />

Boiling Range (°C) >100 Solubility in water (g/L) Miscible<br />

Flash Point (°C) Not Applicable pH (1% solution) Not Availab le<br />

Decomposition Temp (°C) Not Available pH (as supplied) 3.8<br />

Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa ) ~2.0 @ 25C<br />

Upper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.17<br />

Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available<br />

(air=1)<br />

Volatile Component (%vol) Not Available Evaporation Rate Not Available<br />

imidazole<br />

log Kow (Sangster 1997): - 0.08<br />

Section 10 - STABILITY AND REACTIVITY<br />

CONDITIONS CONTRIBUTING TO INSTABILITY<br />

• Contact with alkaline material liberates heat.<br />

For incompatible materials - refer to Section 7 - Handling and Storage.<br />

Section 11 - TOXICOLOGICAL INFORMATION<br />

POTENTIAL HEALTH EFFECTS<br />

ACUTE HEALTH EFFECTS<br />

SWALLOWED<br />

■ Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be<br />

fatal or may produce serious damage to the health of the individual.<br />

EYE<br />

■ This material can cause eye irritation and damage in some persons.<br />

SKIN<br />

■ This material can cause inflammation of the skin oncontact in some persons.<br />

The material may accentuate any pre-existing dermatitis condition.<br />

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.<br />

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.<br />

INHALED<br />

■ There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to<br />

such irritation can cause further lung damage.<br />

Not normally a hazard due to non-volatile nature of product.<br />

CHRONIC HEALTH EFFECTS<br />

■ Strong evidence exists that this substance may cause irreversible mutations (though not lethal) even following a single<br />

exposure.<br />

Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general<br />

population.<br />

Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational<br />

exposure.<br />

There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby.<br />

Based on experience with similar materials, there is a possibility that exposure to the material may reduce fertility in humans<br />

at levels which do not cause other toxic effects.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 7 of 10<br />

Section 11 - TOXICOLOGICAL INFORMATION<br />

Chronic intoxication with ionic bromides, historically, has resulted from medical use of bromides but not from environmental or<br />

occupational exposure; depression, hallucinosis, and schizophreniform psychosis can be seen in the absence of other signs of<br />

intoxication. Bromides may also induce sedation, irritability, agitation, delirium, memory loss, confusion, disorientation,<br />

forgetfulness (aphasias), dysarthria, weakness, fatigue, vertigo, stupor, coma, decreased appetite, nausea and vomiting,<br />

diarrhoea, hallucinations, an acne like rash on the face, legs and trunk, known as bronchoderma (seen in 25-30% of case involving<br />

bromide ion), and a profuse discharge from the nostrils (coryza).<br />

Chelates are occasionally used in therapies for various forms of poisoning. A systemic reaction known as the "excessive chelation<br />

syndrome" consists mainly of general unwellness, fatigue, thirst, followed by chills and fever. Muscle ache, headache, loss of<br />

appetite, nausea and occasionally increased urinary urgency and frequency may occur, as may cold-like symptoms.<br />

Wide area external application of antihistamines can cause various side effects, including sensitisation and eczema.<br />

TOXICITY AND IRRITATION<br />

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis<br />

of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,<br />

e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simply<br />

determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are<br />

equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with<br />

stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are<br />

noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.<br />

No significant acute toxicological data identified in literature search.<br />

for acid mists, aerosols, vapours<br />

Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH<br />

falls to about 6.5. Cells from the respiratory tract have not been examined in this respect.<br />

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergenic<br />

condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of<br />

highly irritating compound.<br />

CARCINOGEN<br />

Nitrate or nitrite International Agency for Research on Cancer Group<br />

(ingested) under<br />

(IARC) - Agents Reviewed by the IARC<br />

conditions that<br />

Monographs<br />

result in endogenous<br />

nitrosation<br />

Non- arsenical International Agency for Research on Cancer Group 2A<br />

insecticides<br />

(IARC) - Agents Reviewed by the IARC<br />

(occupational<br />

Monographs<br />

exposures in spraying<br />

and application of)<br />

Section 12 - ECOLOGICAL INFORMATION<br />

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

This material and its container must be disposed of as hazardous waste.<br />

Ecotoxicity<br />

Ingredient Persistence: Persistence: Air Bioaccumulation Mobility<br />

Water/Soil<br />

PDTA ferric ammonium salt No Data No Data<br />

Available<br />

Available<br />

ammonium bromide No Data No Data<br />

Available<br />

Available<br />

succinic acid LOW No Data LOW HIGH<br />

Available<br />

maleic acid LOW No Data LOW HIGH<br />

Available<br />

ammonium nitrate No Data No Data LOW<br />

Available<br />

Available<br />

imidazole LOW No Data LOW HIGH<br />

Available<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 8 of 10<br />

Section 13 - DISPOSAL CONSIDERATIONS<br />

• Containers may still present a chemical hazard/ danger when empty.<br />

• Return to supplier for reuse/ recycling if possible.<br />

Otherwise:<br />

• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to<br />

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.<br />

• Where possible retain label warnings and <strong>MSDS</strong> and observe all notices pertaining to the product.<br />

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws<br />

operating in their area.<br />

A Hierarchy of Controls seems to be common - the user should investigate:<br />

• Reduction.<br />

• DO NOT allow wash water from cleaning or process equipment to enter drains.<br />

• It may be necessary to collect all wash water for treatment before disposal.<br />

• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.<br />

• Where in doubt contact the responsible authority.<br />

• Recycle wherever possible.<br />

• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable<br />

treatment or disposal facility can be identified.<br />

• Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-lime<br />

followed by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a<br />

licenced apparatus (after admixture with suitable combustible material).<br />

• Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water. Observe all label safeguards<br />

until containers are cleaned and destroyed.<br />

Section 14 - TRANSPORTATION INFORMATION<br />

Labels Required: CORROSIVE<br />

HAZCHEM:<br />

2X (ADG7)<br />

ADG7:<br />

Class or Division: 8 Subsidiary Risk: None<br />

UN No.: 1760 Packing Group: III<br />

Special Provision: 223 274 Limited Quantity: 5 L<br />

Portable Tanks & Bulk T7 Portable Tanks & Bulk TP1 TP28<br />

Containers -<br />

Containers - Special<br />

Instruction:<br />

Provision:<br />

Packagings & IBCs - None Packagings & IBCs - P001 IBC03 LP01<br />

Packing Instruction:<br />

Special Packing<br />

Provision:<br />

Name and Description: CORROSIVE LIQUID, N.O.S. (contains PDTA ferric<br />

ammonium salt)<br />

Land Transport UNDG:<br />

Class or division: 8 Subsidiary risk: None<br />

UN No.: 1760 UN packing group: III<br />

Shipping Name:CORROSIVE LIQUID, N.O.S. (contains PDTA ferric ammonium<br />

salt)<br />

Air Transport IATA:<br />

ICAO/IATA Class: 8 ICAO/IATA Subrisk: None<br />

UN/ID Number: 1760 Packing Group: III<br />

Special provisions:<br />

A3<br />

Shipping name:CORROSIVE LIQUID, N.O.S.(contains PDTA ferric ammonium salt)<br />

Maritime Transport IMDG:<br />

IMDG Class: 8 IMDG Subrisk: None<br />

UN Number: 1760 Packing Group: III<br />

EMS Number: F- A, S- B Special provisions: 223 274<br />

Limited Quantities:<br />

5 L<br />

Shipping name:CORROSIVE LIQUID, N.O.S.(contains PDTA ferric ammonium salt)<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 9 of 10<br />

Section 14 - TRANSPORTATION INFORMATION<br />

Section 15 - REGULATORY INFORMATION<br />

POISONS SCHEDULE None<br />

REGULATIONS<br />

Regulations for ingredients<br />

PDTA ferric ammonium salt (CAS: 111687-36-6) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Hazardous Substances","<strong>Australia</strong> Inventory of Chemical Substances (AICS)","<strong>Australia</strong> National Pollutant Inventory"<br />

ammonium bromide (CAS: 12124-97-9) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Inventory of Chemical Substances (AICS)","<strong>Australia</strong> National Pollutant Inventory","<strong>Australia</strong> Standard for the Uniform<br />

Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","<strong>Australia</strong> Standard for the Uniform Scheduling of Medicines<br />

and Poisons (SUSMP) - Schedule 4","<strong>Australia</strong> Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5",<br />

"<strong>Australia</strong> Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","OECD List of High Production<br />

Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway","OSPAR National List of Candidates for<br />

Substitution – United Kingdom","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been<br />

established"<br />

succinic acid (CAS: 110-15-6) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Inventory of Chemical Substances (AICS)","<strong>Australia</strong> National Pollutant Inventory","International Fragrance Association<br />

(IFRA) Survey: Transparency List","OECD List of High Production Volume (HPV) Chemicals"<br />

maleic acid (CAS: 110-16-7) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Hazardous Substances","<strong>Australia</strong> Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV)<br />

Chemicals","United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely<br />

Restricted or Not Approved by Governments"<br />

ammonium nitrate (CAS: 6484-52-2) is found on the following regulatory lists;<br />

"<strong>Australia</strong> - <strong><strong>Australia</strong>n</strong> Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water<br />

supply - inorganic chemicals)","<strong>Australia</strong> - <strong><strong>Australia</strong>n</strong> Capital Territory - Environment Protection Regulation: Ambient<br />

environmental standards (STOCK - inorganic chemicals)","<strong>Australia</strong> - <strong><strong>Australia</strong>n</strong> Capital Territory - Environment Protection<br />

Regulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)","<strong>Australia</strong> -<br />

<strong><strong>Australia</strong>n</strong> Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm<br />

(STOCK)","<strong>Australia</strong> - Western <strong>Australia</strong> Hazardous Substances Prohibited for Specified Uses or Methods of Handling","<strong>Australia</strong><br />

Council of <strong><strong>Australia</strong>n</strong> Governments (COAG) Chemicals of Security Concern","<strong>Australia</strong> Dangerous Goods Code (ADG Code) - Goods Too<br />

Dangerous To Be Transported","<strong>Australia</strong> Inventory of Chemical Substances (AICS)","<strong>Australia</strong> National Pollutant Inventory",<br />

"<strong>Australia</strong> Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","OECD List of High<br />

Production Volume (HPV) Chemicals"<br />

imidazole (CAS: 288-32-4) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Inventory of Chemical Substances (AICS)","<strong>Australia</strong> National Pollutant Inventory","OECD List of High Production Volume<br />

(HPV) Chemicals"<br />

water (CAS: 7732-18-5) is found on the following regulatory lists;<br />

"<strong>Australia</strong> Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECD<br />

List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"<br />

No data for Fujifilm CN-16S N2 SUC (CW: <strong>31</strong>-<strong>1353</strong>)<br />

Section 16 - OTHER INFORMATION<br />

Denmark Advisory list for selfclassification of dangerous substances<br />

Substance CAS Suggested codes<br />

imidazole 288- 32- 4 Xn; R22<br />

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as<br />

independent review by the <strong>Chemwatch</strong> Classification committee using available literature references.<br />

A list of reference resources used to assist the committee may be found at:<br />

www.chemwatch.net/references.<br />

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether<br />

the reported Hazards are Risks in the workplace or other settings.<br />

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or<br />

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written<br />

permission from CHEMWATCH. TEL (+61 3) 9572 4700.<br />

continued...


<strong>FUJIFILM</strong> CN-16S N2 SUC<br />

<strong>Chemwatch</strong> Independent Material Safety Data Sheet<br />

Issue Date: 16-Mar-2012 CHEMWATCH <strong>31</strong>-<strong>1353</strong><br />

9<strong>31</strong>7SP(cs)<br />

Version No:2.0<br />

CD 2012/1 Page 10 of 10<br />

Section 16 - OTHER INFORMATION<br />

Issue Date: 16-Mar-2012<br />

Print Date: 16-Mar-2012<br />

This is the end of the <strong>MSDS</strong>.

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