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Chapter 9

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HEINS09-095-117v4.qxd 12/30/06 1:58 PM Page 116<br />

- <strong>Chapter</strong> 9 -<br />

a 6.00 g NaHCO 3<br />

b11002 = 60.0% NaHCO<br />

10.00 g<br />

3<br />

a 4.00 g Na 2CO 3<br />

b11002 = 40.0% Na<br />

10.00 g<br />

2 CO 3<br />

54. The balanced equation is 2 KClO 3 ¡ 2 KCl + 3 O 2<br />

12.82 g mixture - 9.45 g residue = 3.37 g O 2 lost by heating<br />

Because the O 2 lost came only from KClO 3 , we can use it to calculate the amount of<br />

KClO 3 in the mixture.<br />

The conversion is: g O 2 ¡ mol O 2 ¡ mol KClO 3 ¡ g KClO 3<br />

13.37 g O 2 2a 1 mol<br />

32.00 g ba2 mol KClO 3<br />

ba 122.6 g b = 8.61 g KClO<br />

3 mol O 2 mol<br />

3 in the mixture<br />

a 8.61 g KClO 3<br />

12.82 g sample b11002 = 67.2% KClO 3<br />

55. The balanced equation is<br />

Al(OH) 3 (s) + 3 HCl(aq) ¡ AlCl 3 (aq) + 3 H 2 O(l)<br />

The conversion is: L HCl ¡ g HCl ¡ mol HCl ¡ mol Al(OH) 3 : g Al(OH) 3<br />

a 2.5 L<br />

day<br />

g HCl<br />

ba3.0 ba 1 mol<br />

L<br />

36.46 g b ¢ 1 mol Al1OH2 3<br />

3 mol HCl<br />

≤ a 78.00 g b = 5.3 g Al1OH2<br />

mol<br />

3 >day<br />

Now calculate the number of 400. mg tablets that can be made from 5.3 g Al(OH) 3<br />

¢ 5.3 g Al(OH) 3 1000 mg<br />

≤ a ba 1 tablet<br />

day<br />

g 400. mg b = 13 tablets>day<br />

56.<br />

4 P + 5 O 2 ¡ P 4 O 10<br />

P 4 O 10 + 6 H 2 O ¡ 4 H 3 PO 4<br />

In the first reaction:<br />

120.0 g P2a 1 mol b = 0.646 mol P<br />

30.97 g<br />

130.0 g O 2 2a 1 mol<br />

32.00 g b = 0.938 mol O 2<br />

0.646 mol P 3.44 mol P<br />

This is a ratio of<br />

=<br />

0.938 mol O 2 5.00 mol O 2<br />

Therefore, P is the limiting reactant and the P 4 O 10 produced is:<br />

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