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Aluminium Casting Alloys - Aleris

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Microstructural formation in relation to<br />

the content of phosphorous and sodium Al Si7Mg<br />

Sodium Sand casting<br />

[ppm]<br />

140<br />

cooling rate 0.1 K/s<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Overmodifi ed<br />

Granular<br />

Modifi ed<br />

Lamellar<br />

can be omitted in the foundry. At low<br />

cooling rates, strontium modifi cation is<br />

less effective so that it is not advisable<br />

to use this in sand casting processes.<br />

To avoid the burn-off of strontium, any<br />

cleaning and degassing of Sr-modifi ed<br />

melts should be carried out with chlorine-<br />

free preparations only, preferably using<br />

argon or nitrogen. Strontium modifi cation<br />

is not greatly impaired even when<br />

remelting revert material. Larger losses<br />

22<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Phosphorous [ppm]<br />

Undermodifi ed<br />

Figure 3<br />

0 5 10 15 20 25 30 35 40 45 50 55 60<br />

can be offset by adding Sr master alloy<br />

wire in accordance with the respective<br />

manufacturer‘s instructions. At the right<br />

temperature, the addition of sodium to<br />

the melt is best done by charging standard<br />

portions. For easy handling, storage<br />

and proportioning, the manufacturer‘s<br />

recommendations and safety instructions<br />

should be followed.<br />

Since sodium burns off from the melt<br />

relatively quickly, subsequent modifi -<br />

Figure 4<br />

Microstructural formation in relation to<br />

the content of phosphorous and strontium Al Si7Mg<br />

Strontium Gravity die casting<br />

[ppm] gravity die cast test bar<br />

cooling rate 2.5 K/s<br />

450<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Phosphorous [ppm]<br />

Modifi ed Undermodifi ed Granular Lamellar<br />

cation must take place in the foundry<br />

at regular intervals. In melts modifi ed<br />

with sodium, any requested cleaning<br />

and degassing should be carried out<br />

with chlorine-free compounds only<br />

(argon or nitrogen). A certain amount<br />

of sodium burn-off is to be reckoned<br />

with, however, and needs to be taken<br />

into account in the subsequent addition<br />

of sodium. When absolutely necessary,<br />

the melt can be treated with chlorine-<br />

releasing compounds long before the

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