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Microstructural formation in relation to<br />
the content of phosphorous and sodium Al Si7Mg<br />
Sodium Sand casting<br />
[ppm]<br />
140<br />
cooling rate 0.1 K/s<br />
120<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
Overmodifi ed<br />
Granular<br />
Modifi ed<br />
Lamellar<br />
can be omitted in the foundry. At low<br />
cooling rates, strontium modifi cation is<br />
less effective so that it is not advisable<br />
to use this in sand casting processes.<br />
To avoid the burn-off of strontium, any<br />
cleaning and degassing of Sr-modifi ed<br />
melts should be carried out with chlorine-<br />
free preparations only, preferably using<br />
argon or nitrogen. Strontium modifi cation<br />
is not greatly impaired even when<br />
remelting revert material. Larger losses<br />
22<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Phosphorous [ppm]<br />
Undermodifi ed<br />
Figure 3<br />
0 5 10 15 20 25 30 35 40 45 50 55 60<br />
can be offset by adding Sr master alloy<br />
wire in accordance with the respective<br />
manufacturer‘s instructions. At the right<br />
temperature, the addition of sodium to<br />
the melt is best done by charging standard<br />
portions. For easy handling, storage<br />
and proportioning, the manufacturer‘s<br />
recommendations and safety instructions<br />
should be followed.<br />
Since sodium burns off from the melt<br />
relatively quickly, subsequent modifi -<br />
Figure 4<br />
Microstructural formation in relation to<br />
the content of phosphorous and strontium Al Si7Mg<br />
Strontium Gravity die casting<br />
[ppm] gravity die cast test bar<br />
cooling rate 2.5 K/s<br />
450<br />
400<br />
350<br />
300<br />
250<br />
200<br />
150<br />
100<br />
50<br />
0<br />
0 10 20 30 40 50 60 70 80 90 100<br />
Phosphorous [ppm]<br />
Modifi ed Undermodifi ed Granular Lamellar<br />
cation must take place in the foundry<br />
at regular intervals. In melts modifi ed<br />
with sodium, any requested cleaning<br />
and degassing should be carried out<br />
with chlorine-free compounds only<br />
(argon or nitrogen). A certain amount<br />
of sodium burn-off is to be reckoned<br />
with, however, and needs to be taken<br />
into account in the subsequent addition<br />
of sodium. When absolutely necessary,<br />
the melt can be treated with chlorine-<br />
releasing compounds long before the