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Aluminium Casting Alloys - Aleris

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<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Content<br />

4<br />

Introduction 5<br />

Recycled aluminium 6<br />

Technology and service<br />

for our customers<br />

Quality Management 7<br />

Work safety and health 8<br />

protection<br />

Environmental protection<br />

<strong>Aluminium</strong> and aluminium 9<br />

casting alloys<br />

<strong>Aluminium</strong> – Material properties<br />

Recycling of aluminium<br />

Shaping by casting 10<br />

Product range and 11<br />

form of delivery<br />

Technical consultancy 12<br />

service<br />

Selecting aluminium 13<br />

casting alloys<br />

Criteria for the selection of 14<br />

aluminium casting alloys<br />

Infl uence of the 18<br />

most important alloying<br />

elements on aluminium<br />

casting alloys<br />

Infl uencing the 19<br />

microstructural formation of<br />

aluminium castings<br />

Grain refi nement 20<br />

Modifi cation of AlSi eutectic 21<br />

Refi nement of 23<br />

primary silicon<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Melt quality and melt cleaning 24<br />

Avoiding impurities 25<br />

Melt testing and 28<br />

inspection procedure<br />

Thermal analysis 30<br />

Selecting the casting process 31<br />

Pressure die casting 32<br />

process<br />

Gravity die casting process<br />

Sand casting process 34<br />

<strong>Casting</strong>-compliant design 35<br />

Solidifi cation simulation 37<br />

and thermography<br />

Avoiding casting defects 38<br />

Heat treatment of 40<br />

aluminium castings<br />

Metallurgy –<br />

fundamental principles<br />

Solution annealing 41<br />

Quenching<br />

Ageing 42<br />

Mechanical machining of 44<br />

aluminium castings<br />

Welding and joining 45<br />

aluminium castings<br />

Suitability and behaviour<br />

Applications in the<br />

aluminium sector<br />

Welding processes<br />

Weld preparation 47<br />

Weld fi ller materials<br />

Surface treatment: corrosion 48<br />

and corrosion protection<br />

Information on physical data, 50<br />

strength properties and<br />

strength calculations<br />

Notes on the casting 51<br />

alloy tables<br />

Overview: <strong>Aluminium</strong> casting 52<br />

alloys by alloy group<br />

Eutectic aluminium-silicon 59<br />

casting alloys<br />

Near-eutectic wheel 63<br />

casting alloys<br />

The 10 per cent aluminium- 66<br />

silicon casting alloys<br />

The 7 and 5 per cent 71<br />

aluminium-silicon<br />

casting alloys<br />

Al SiCu casting alloys 76<br />

AlMg casting alloys 81<br />

<strong>Casting</strong> alloys for special 87<br />

applications


Introduction<br />

Many of you have most certainly worked<br />

with the “old“ <strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Catalogue – over the years in thousands<br />

of workplaces in the aluminium industry,<br />

it has become a standard reference<br />

book, a reliable source of advice about<br />

all matters relating to the selection and<br />

processing of aluminium casting alloys.<br />

Even if you are holding this <strong>Aluminium</strong><br />

<strong>Casting</strong> <strong>Alloys</strong> Catalogue in your hands<br />

for the fi rst time, you will quickly fi nd your<br />

way around with the help of the following<br />

notes and the catalogue‘s detailed index.<br />

How is this <strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Catalogue structured? The catalogue<br />

consists of three separate parts. In the<br />

fi rst part, we provide details on our com-<br />

pany – a proven supplier of aluminium<br />

casting alloys.<br />

In the second part, all technical aspects<br />

which have to be taken into account in<br />

the selection of an aluminium casting alloy<br />

are explained in detail. All details are<br />

based on the DIN EN 1676: 2010 standard.<br />

The third part begins with notes on the<br />

physical data, tensile strength characteristics<br />

and strength calculations of<br />

aluminium casting alloys. Subsequently,<br />

all standardised aluminium casting alloys<br />

in accordance with DIN EN 1676 as well<br />

as common, non-standardised casting<br />

alloys are depicted in a summary table<br />

together with their casting/technical and<br />

other typical similarities in “alloy families”.<br />

The aim of this new, revised and redesigned<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> Catalogue<br />

is to give the user of aluminium<br />

casting alloys a clear, well laid-out companion<br />

for practical application. Should<br />

you have any questions concerning the<br />

selection and use of aluminium casting<br />

alloys, please contact our foundry consultants<br />

or our sales staff.<br />

You can also refer to www.aleris.com.<br />

We would be pleased to advise<br />

you and wish you every success<br />

in your dealings with aluminium<br />

casting alloys!<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

5


Recycled aluminium<br />

Technology and service for our customers<br />

Employing approx. 600 people, <strong>Aleris</strong><br />

Recycling produces high-quality casting<br />

and wrought alloys from recycled<br />

aluminium. The company‘s headquarters<br />

are represented by the “Erftwerk”<br />

in Grevenbroich near Düsseldorf which<br />

is also the largest production facility in<br />

the group. Other production facilities<br />

in Germany (Deizisau, Töging), Norway<br />

(Eidsväg, Raudsand) and Great Britain<br />

(Swansea) are managed from here. With<br />

up to 550,000 mt, <strong>Aleris</strong> Recycling avails<br />

of the largest production capacities in<br />

Europe and is also one of the world‘s<br />

leading suppliers of technology and<br />

services relating to aluminium casting<br />

alloys. <strong>Aleris</strong> Recycling also offers a wide<br />

range of high-quality magnesium alloys.<br />

<strong>Aluminium</strong> recycled from scrap and<br />

dross has developed to become a<br />

highly-complex technical market of the<br />

future. This is attributable to the steady<br />

increase in demand for raw materials,<br />

the sustainability issue, increased environmental<br />

awareness among producers<br />

and consumers alike and, not least, the<br />

necessity to keep production costs as<br />

low as possible.<br />

This is where aluminium offers some essential<br />

advantages. Recycled aluminium<br />

can be generated at only a fraction of the<br />

energy costs (approx. 5%) compared to<br />

primary aluminium manufactured from<br />

bauxite with the result that it makes a<br />

signifi cant contribution towards reduc-<br />

ing CO 2 emissions. This light-alloy metal<br />

can be recycled any number of times<br />

and good segregation even guarantees<br />

no quality losses.<br />

6<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Its properties are not impaired when<br />

used in products. The metallic value is<br />

retained which represents a huge economic<br />

incentive to collect, treat and melt<br />

the metal in order to reuse it at the end<br />

of its useful life.<br />

For this reason, casting alloys from <strong>Aleris</strong><br />

Recycling can be used for manufacturing<br />

new high-quality cast products such as<br />

crankcases, cylinder heads or aluminium<br />

wheels while wrought materials can be<br />

used for manufacturing rolled and pressed<br />

products, for example. Key industries<br />

supplied include:<br />

Rolling mills and extrusion plants<br />

Automotive industry<br />

Transport sector<br />

Packaging industry<br />

Engineering<br />

Building and construction<br />

Electronics industry<br />

as well as other companies in the<br />

<strong>Aleris</strong> Group.<br />

State-of-the-art production facilities and<br />

an extensive range of products made of<br />

aluminium in the form of scrap, chips or<br />

dross are collected and treated by <strong>Aleris</strong><br />

Recycling before melting in tilting rotary<br />

furnaces with melting salt, for example,<br />

whereby the salt prevents the aluminium<br />

from oxidising while binding contaminants<br />

(salt slag). Modern processing and<br />

melting plants at <strong>Aleris</strong> Recycling enable<br />

effi cient yet environmentally-friendly re-<br />

cycling of aluminium scrap and dross.<br />

The technology used is largely based on<br />

our own developments and – in terms of<br />

yield and melt quality – works signifi cantly<br />

more effi ciently than fi xed axis rotary<br />

furnaces and hearth furnaces. The melt<br />

gleaned from these furnaces has a very<br />

low gas content thanks to the special gas<br />

purging technique we use as well as<br />

being homogeneous and largely free of<br />

oxide inclusions and/or contaminants.<br />

The resulting high quality of <strong>Aleris</strong> alloys<br />

enables our customers to open up an increasing<br />

number of possible applications.<br />

All management processes and the entire<br />

process chain from procurement<br />

through production to sale are subject to<br />

systematic Quality Management. Combined<br />

with Quality Management certifi ed<br />

to ISO/TS 16949 and DIN EN ISO 9001,<br />

this guarantees that our clients‘ maximum<br />

requirements and increasing demands<br />

can be fulfi lled.<br />

The product range offered by <strong>Aleris</strong> Re-<br />

cycling comprises more than 250 differ-<br />

ent casting and wrought alloys. They can<br />

be supplied as ingots with unit weights<br />

of approx. 6 kg (in stacks of up to 1,300<br />

kg) as well as pigs of up to 1,400 kg or<br />

as liquid metal. Based on our sophisticated<br />

crucible technology and optimised<br />

transport logistics, <strong>Aleris</strong> Recycling supplies<br />

customers with liquid aluminium in<br />

a just-in-time process and at the appropriate<br />

temperature.


Due to its future-oriented corporate<br />

structure, <strong>Aleris</strong> Recycling supplies the<br />

market with an increasing number of<br />

applications involving high-quality secondary<br />

aluminium. This service is not restricted<br />

to the area of casting alloys but<br />

also applies for 3000- and 5000-grade<br />

wrought alloys, for example. <strong>Aleris</strong> Recycling<br />

is also capable of offering some<br />

6000-grade secondary aluminium alloys<br />

largely required by the automotive sector.<br />

For this so-called upgrade, <strong>Aleris</strong> applies<br />

special production technologies when<br />

it comes to manufacturing high-quality<br />

alloys from scrap.<br />

Recycled aluminium is increasingly be-<br />

coming a complex range at the interface<br />

between high-tech production, trade and<br />

service. In addition, customers demand<br />

intensive consulting as well as individual<br />

service. <strong>Aleris</strong> Recycling enjoys an excellent<br />

position in this regard.<br />

At its various locations, the company<br />

units offer a high degree of recycling expertise,<br />

manufacturing competence and<br />

delivery reliability for its customers. With<br />

the result that <strong>Aleris</strong> Recycling guarantees<br />

its customers a high level of effi ciency<br />

and added value while supporting their<br />

success on the market.<br />

Quality Management<br />

We believe that our most important cor-<br />

porate goal is to meet in full our custom-<br />

ers‘ requirements and expectations in<br />

terms of providing them with products<br />

and services of consistent quality. In order<br />

to meet this goal, our guidelines and<br />

integrated management system specifi -<br />

cations outline rules and regulations that<br />

are binding for all staff.<br />

As a manufacturer of aluminium casting<br />

alloys, we are certifi ed according to ISO/<br />

TS 16949. In addition, we operate according<br />

to DIN EN ISO 9001 standards.<br />

The principle of avoiding errors is para-<br />

mount in all our individual procedures and<br />

regulations. In other words, our priority<br />

is to strive to achieve a zero-error target.<br />

By effectively combating the sources of<br />

errors, we create the right conditions for<br />

reliability and high quality standards.<br />

We have also established a comprehen-<br />

sive process of continuous improvement<br />

(PMO, Best Practice, Six Sigma etc.) in<br />

our plants in response to the demands<br />

being placed on our company by the<br />

increasing trend towards business globalisation.<br />

This creates the right climate<br />

for creative thinking and action.<br />

All members of staff, within their own<br />

area of responsibility, endeavour to ensure<br />

that operational procedures are<br />

constantly improved, even if in small,<br />

gradual stages, with a clear focus on<br />

our customers‘ needs.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

7


Work safety and health protection<br />

Our staff are our most valuable asset. Work<br />

safety and health protection, therefore,<br />

have top priority for us, and also make<br />

a valuable contribution to the success<br />

of our company. Our “Work safety and<br />

health protection” programme is geared<br />

towards achieving a zero accident rate,<br />

and towards avoiding occupational illnesses.<br />

Depending on the respective<br />

location, we are certifi ed to OHSAS<br />

18001 or OHRIS.<br />

All management members and staff are<br />

obliged to comply with legal regulations<br />

and company rules at all times, to protect<br />

their own health and the health of<br />

other members of staff and, when engaged<br />

in any company operations, to<br />

do their utmost to ensure that accidents<br />

and work-related illnesses are avoided,<br />

as well as anything that might have a<br />

negative impact on the general company<br />

environment. Management provides the<br />

appropriate level of resources required<br />

to achieve these goals.<br />

There are regular internal and external<br />

training seminars on the topic of work<br />

safety, and detailed programmes to improve<br />

health protection. These help to<br />

maintain our comparatively low accident<br />

and illness rates.<br />

8<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Environmental protection<br />

Following the validation of our environ-<br />

mental management system in conformity<br />

with EMAS II and certifi cation to DIN EN<br />

ISO 14001, we have undertaken not only<br />

to meet all the required environmental<br />

standards, but also to work towards a<br />

fundamental, systematic and continual<br />

improvement in the level of environmental<br />

protection within the company.<br />

Our management system and environ-<br />

mental policy are documented in the<br />

company manual which describes all<br />

the elements of the system in easily<br />

understood terms, while serving as a<br />

reference for all regulations concerning<br />

the environment.<br />

The environmental impacts of our com-<br />

pany operations in terms of air purity,<br />

protection of water bodies, noise and<br />

waste are checked at regular intervals.<br />

By modifying procedures, reusing mate-<br />

rials and recycling residues, we optimise<br />

the use of raw materials and energy in<br />

order to conserve resources as effi ciently<br />

as possible.<br />

We pursue a policy of open information<br />

and provide interested members of the<br />

public with comprehensive details of<br />

the company‘s activities in a particular<br />

location, and an explanation of the<br />

environmental issues involved. For us,<br />

open dialogue with the general public,<br />

our suppliers, customers and other<br />

contractual partners is as much a part<br />

of routine operations as reliable co-operation<br />

with the relevant authorities and<br />

trade associations.<br />

Likewise, ecological standards are incorporated<br />

in development and planning<br />

processes for new products and production<br />

processes, as are other standards<br />

required by the market or society at large.<br />

Our staff is fully conscious of all environmental<br />

protection issues and is keen to<br />

ensure that the environmental policy is<br />

reliably implemented in day-to-day operations<br />

within the company.


<strong>Aluminium</strong> and aluminium casting alloys<br />

<strong>Aluminium</strong> – Material properties<br />

<strong>Aluminium</strong> has become the most widely<br />

used non-ferrous metal. It is used in the<br />

transport sector, construction, the pack-<br />

aging industry, mechanical engineering,<br />

electrical engineering and design. New<br />

fi elds of application are constantly open-<br />

ing up as the advantages of this material<br />

speak for themselves:<br />

<strong>Aluminium</strong> is light; its specifi c weight<br />

is substantially lower than other<br />

common metals and, at the same<br />

time, it is so strong that it can with<br />

stand high stress.<br />

<strong>Aluminium</strong> is very corrosionresistant<br />

and durable. A thin,<br />

natural oxide layer protects<br />

aluminium against decomposition<br />

from oxygen, water or chemicals.<br />

<strong>Aluminium</strong> is an excellent<br />

conductor of electricity,<br />

heat and cold.<br />

<strong>Aluminium</strong> is non-toxic, hygienic<br />

and physiologically harmless.<br />

<strong>Aluminium</strong> is non-magnetic.<br />

<strong>Aluminium</strong> is decorative and<br />

displays high refl ectivity.<br />

<strong>Aluminium</strong> has outstanding<br />

formability and can be<br />

processed in a variety of ways.<br />

<strong>Aluminium</strong> alloys are easy to cast<br />

as well as being suitable for all known<br />

casting processes.<br />

<strong>Aluminium</strong> alloys are<br />

distinguished by an excellent<br />

degree of homogeneity.<br />

<strong>Aluminium</strong> and aluminium<br />

alloys are easy to machine.<br />

<strong>Casting</strong>s made from aluminium<br />

alloys can be given an artifi cial,<br />

wear-resistant oxide layer<br />

using the ELOXAL process.<br />

<strong>Aluminium</strong> is an outstanding<br />

recycling material.<br />

Recycling of aluminium<br />

Long before the term “recycling” became<br />

popular, recycling circuits already exist-<br />

ed in the aluminium sector. Used parts<br />

made from aluminium or aluminium alloys<br />

as well as aluminium residue materials<br />

arising from production and fabrication<br />

are far too valuable to end up as landfi<br />

ll. One of the great advantages of this<br />

metal, and an added plus for its use as a<br />

construction material, is that aluminium<br />

parts, no matter the type, are extremely<br />

well suited to remelting.<br />

The energy savings made in<br />

recycling aluminium are<br />

considerable. Remelting requires<br />

only about 5 % of the energy<br />

initially required to produce<br />

primary aluminium.<br />

As a rule, aluminium recycling<br />

retains the value added to the<br />

metal. <strong>Aluminium</strong> can be recycled<br />

to the same quality level as the<br />

original metal.<br />

<strong>Aluminium</strong> recycling safeguards<br />

and supplements the supply of<br />

raw materials while saving<br />

resources, protecting the<br />

environment and conserving<br />

energy. Recycling is therefore also<br />

a dictate of economic reason.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

9


The experience accumulated over many<br />

decades, the use of state-of-the-art<br />

technology in scrap preparation, remelting<br />

and exhaust gas cleaning as well<br />

as our constant efforts to develop new,<br />

environmentally-sound manufacturing<br />

technology puts us in a position to<br />

achieve the best possible and effi cient<br />

recycling rates. At the same time, they<br />

also help us to make the most effi cient<br />

use of energy and auxiliary materials.<br />

10<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Shaping by casting<br />

<strong>Casting</strong> represents the shortest route<br />

from raw materials to fi nished parts – a<br />

fact which has been known for fi ve thou-<br />

sand years. Through continuous further<br />

development and, in part, by a selective<br />

return to classic methods such as the<br />

lost-form process, casting has remained<br />

at the forefront of technical progress.<br />

The most important advantage of the<br />

casting process is that the possibilities<br />

of shaping the part are practically limitless.<br />

<strong>Casting</strong>s are, therefore, easier and<br />

cheaper to produce than machined and/<br />

or joined components. The general waiving<br />

of subsequent machining not only<br />

results in a good density and path of<br />

force lines but also in high form strength.<br />

Furthermore, waste is also avoided. As a<br />

rule, the casting surface displays a tight,<br />

fi ne-grained structure and, consequently,<br />

is also resistant to wear and corrosion.<br />

The variety of modern casting processes<br />

makes it possible to face up to the<br />

economic realities, i.e. the optimisation<br />

of investment expenditure and costs<br />

in relation to the number of units. With<br />

casting, the variable weighting of production<br />

costs and quality requirements<br />

are also possible.<br />

When designing the shape of the cast-<br />

ing, further possibilities arise from the<br />

use of inserts and/or from joining the<br />

part to other castings or workpieces.<br />

In the last decade, aluminium has at-<br />

tained a leading position among cast<br />

metals because, in addition to its other<br />

positive material properties, this light<br />

metal offers the greatest possible variety<br />

of casting and joining processes.


Product range and form of delivery<br />

As ecological and economic trends sensibly<br />

move towards the development of<br />

closed material circuits, the clear dividing<br />

lines between the three classic quality<br />

grades of aluminium casting alloys are<br />

ever-decreasing. In future, people will<br />

simply talk about “casting alloys”. In<br />

practice, this is already the case. Metal<br />

from used parts is converted back into<br />

the same fi eld of application. The DIN<br />

EN 1676 and 1706 standards with their<br />

rather fl uid quality transitions take this<br />

trend into account.<br />

<strong>Aleris</strong> is one of only a few companies<br />

to produce a wide range of aluminium<br />

alloys; our product spectrum extends<br />

from classic secondary alloys to highpurity<br />

alloys for special applications.<br />

Production is in full compliance with<br />

the European DIN EN 1676 standard<br />

or international standards and in many<br />

cases, manufactured to specifi c cus-<br />

tomer requirements. We have also been<br />

offering several aluminium casting al-<br />

loys as protected brand-name alloys<br />

for many years, e.g. Silumin ®® , Pantal ®®<br />

and Autodur ® .<br />

Our casting alloys are delivered in the<br />

form of ingots with a unit weight of approx.<br />

6 kg or as liquid metal.<br />

We distinguish between ingots cast in<br />

open moulds and horizontal continu-<br />

ously cast ingots (so-called HGM). Ingots<br />

are dispatched in bundles of up to<br />

approx. 1,300 kg.<br />

The delivery of liquid or molten metal is<br />

useful and economic when large quanti-<br />

ties of one homogeneous casting alloy are<br />

required and the equipment for tapping<br />

and holding the molten metal containers<br />

is available. Supplying molten metal can<br />

lead to a substantial reduction in costs<br />

as a result of saving melting costs and<br />

a reduction in melting losses. The supply<br />

of liquid metal also provides a viable<br />

alternative in cases where new melting<br />

capacities need to be built to comply<br />

with emission standards or where space<br />

is a problem.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 11


Technical consultancy service<br />

The technical consultancy service is<br />

the address for questions relating to<br />

foundry technology. We provide assis-<br />

tance in clarifying aluminium casting alloy<br />

designations as stated in German and<br />

international standards or the temper<br />

conditions for castings. We also offer<br />

advice on the selection of alloys and can<br />

provide aluminium foundries or users of<br />

castings with information on:<br />

<strong>Aluminium</strong> casting alloys<br />

Chemical and physical properties<br />

<strong>Casting</strong> and solidifi cation<br />

behaviour<br />

<strong>Casting</strong> processes and details<br />

regarding foundry technology<br />

Melt treatment possibilities, such as<br />

cleaning, degassing, modifi cation<br />

or grain refi nement<br />

Possibilities of infl uencing the<br />

strength of castings by means<br />

of alloying elements or heat<br />

treatment<br />

Questions relating to surface<br />

fi nish and surface protection.<br />

12<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Technical consultants also provide as-<br />

sistance in evaluating casting defects or<br />

surface fl aws and offer suggestions with<br />

regard to eliminating defects. They sup-<br />

ply advice on the design of castings, the<br />

construction of dies, the casting system<br />

and the confi guration of feeders.<br />

Technical consultants also provide tech-<br />

nical support to aluminium foundries in<br />

the preparation of chemical analyses,<br />

microsections and structural analyses.<br />

Customer feedback coupled with exten-<br />

sive experience in the foundry sector fa-<br />

cilitates the continuous optimisation and<br />

quality improvement of our aluminium<br />

casting alloys.<br />

In co-operation with our customers, we<br />

are working on gaining wider acceptance<br />

of our aluminium casting alloys in new<br />

fi elds of application.<br />

Where required and especially where<br />

fundamental problems arise, we arrange<br />

contracts with leading research institutes<br />

in Europe and North America.


Selecting aluminium casting alloys<br />

To supplement and provide greater depth<br />

to our technical explanations, we refer<br />

you to standard works on aluminium<br />

and aluminium casting alloys. Further<br />

details on other specialist literature are<br />

available and can be requested at any<br />

time. We would be delighted to advise<br />

you in such matters.<br />

Should you have any queries or com-<br />

ments, which are always welcome,<br />

please contact our technical service.<br />

Standard works on aluminium and aluminium<br />

casting alloys:<br />

“<strong>Aluminium</strong>-Taschenbuch”, Verlag<br />

Beuth, Düsseldorf<br />

“<strong>Aluminium</strong> viewed from within -<br />

Profi le of a modern metal”, Prof.<br />

Dr. D. G. Altenpohl, Verlag Beuth,<br />

Düsseldorf.<br />

Once the requirements of a casting<br />

have been determined, the selection of<br />

the correct casting alloy from the multitude<br />

of possibilities often represents<br />

a problem for the designer and also for<br />

the foundryman. In this case, the “<strong>Aluminium</strong>-Taschenbuch”<br />

can be of great<br />

assistance.<br />

In the European DIN EN 1676 and DIN<br />

EN 1706 standards, the most important<br />

aluminium casting alloys have been collated<br />

in a version which is valid Europewide.<br />

Consequently, there are already<br />

more than 41 standard aluminium casting<br />

alloys available.<br />

<strong>Aluminium</strong> foundries should – according<br />

to their respective structure – limit themselves<br />

to as small a number of casting<br />

alloys as possible in order to use their<br />

melting equipment economically, to keep<br />

inventories as low as possible and to reduce<br />

the risk of mixing alloys.<br />

With regard to the quality of a casting,<br />

it is more sensible to process a casting<br />

alloy which is operational in use than one<br />

which displays slightly better properties<br />

on paper but is actually more diffi cult to<br />

process. The quality potential of a casting<br />

alloy is only exploited in a casting if<br />

the cast piece is as free as possible of<br />

casting defects and is suitable for subsequent<br />

process steps (e.g. heat treatment).<br />

Our sales team and technicians are on<br />

hand to provide foundries and users<br />

of castings with assistance in selecting<br />

the correct aluminium casting alloy.<br />

As far as possible, the use of common<br />

aluminium casting alloys is recommended.<br />

These involve well-known and proven<br />

casting alloys and we stand fully behind<br />

the quality properties of these casting<br />

alloys which are often manufactured in<br />

large quantities, are more cost-effective<br />

than special alloys and, in most cases,<br />

can be delivered at short notice.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 13


Criteria for the selection of<br />

aluminium casting alloys<br />

In the following section, we provide an<br />

insight into the chemical and physical<br />

potentials of aluminium casting alloys by<br />

describing their various properties. The<br />

standardisation provided here helps to<br />

establish whether a casting alloy is suitable<br />

for the specifi c demands placed<br />

on a casting.<br />

Degree of purity<br />

One important selection criteria is the de-<br />

gree of purity of a casting alloy. With the<br />

increasing purity of a casting alloy family,<br />

the corrosion resistance and ductility of<br />

the as-cast structure also increase; the<br />

selection of pure feedstock for making<br />

casting alloys, however, will necessarily<br />

cause costs to rise.<br />

The increasing importance of the closedcircuit<br />

economy means that, for the producer<br />

of aluminium casting alloys, the<br />

transition between the previous quality<br />

grades for aluminium casting alloys is<br />

becoming ever more fl uid.<br />

Due to their high purity, casting alloys<br />

made from primary aluminium display the<br />

best corrosion resistance as well as high<br />

ductility. By way of example, Silumin-Beta<br />

with max. 0.15 % Fe, max. 0.03 % Cu<br />

and max. 0.07 % Zn can be mentioned.<br />

In many countries, the Silumin trademark<br />

has already become a synonym for aluminium-silicon<br />

casting alloys.<br />

14<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Classifi cation of casting alloys acc. to strength properties 1)<br />

Table 1<br />

<strong>Casting</strong> alloy Temper Tensile Elongation Brinell<br />

strength hardness<br />

Rm [MPa]<br />

A5 [%] HB<br />

Strong Al Cu4Ti T6 330 7 95<br />

and ductile Silumin-Beta T6 290 4 90<br />

Al Si10Mg(a) T6 260 1 90<br />

Hard Al Si8Cu3 F 170 1 75<br />

Al Si18CuNiMg F 180 1 90<br />

Ductile Silumin F 170 7 45<br />

Other Al Mg3 F 150 5 50<br />

1) Typical values for permanent mould casting,<br />

established on separately-cast test bars.<br />

<strong>Casting</strong> alloys made from scrap are,<br />

with regard to ductility and corrosion<br />

resistance, inferior to other casting alloy<br />

groups due to their lower purity. They are,<br />

however, widely applicable and meet the<br />

set performance requirements.<br />

Strength properties<br />

Strength properties should be discussed<br />

as a further selection criterion (Table 1).<br />

A rough subdivision into four groups is<br />

practical:<br />

“strong and ductile”<br />

The most important age-hardenable<br />

casting alloys belong to this group. By<br />

means of different kinds of heat treatment,<br />

their properties can be adjusted<br />

either in favour of high tensile strength<br />

or high elongation. In Table 1, the typical<br />

combinations of R and A values for<br />

m<br />

different casting alloys are compared.<br />

These casting alloys are used for highgrade<br />

construction components, especially<br />

for critical parts.<br />

“hard”<br />

The casting alloys of this group must<br />

display a certain tensile strength and<br />

hardness without particular requirements<br />

being placed on the metal‘s elongation.<br />

First of all, Al SiCu alloys belong to this<br />

group. Due to their Cu, Mg and Zn content,<br />

these casting alloys experience a<br />

certain amount of self-hardening after<br />

casting (approx. 1 week). These alloys<br />

are particularly important for pressure<br />

die casting since it is in pressure die<br />

casting – except for special processes<br />

such as vacuum die casting – that process-induced<br />

structural defects occur,<br />

preventing high elongation values. Due<br />

to its particularly strong self-hardening<br />

characteristics, the Autodur casting al-


Table 2<br />

Classifi cation of casting alloys acc. to casting properties<br />

Fluidity Thermal<br />

crack<br />

susceptibility<br />

<strong>Casting</strong> alloy Type of solidifi cation<br />

High Low Silumin<br />

Al Si12<br />

Exogenous-shell forming<br />

Al S12(Cu) Exogenous-rough wall<br />

Al Si10Mg<br />

Silumin-Beta<br />

Al Si8Cu3<br />

Pantal 7<br />

Al Si5Mg<br />

Al Cu4Ti<br />

Endogenous-dendritic<br />

Al Mg3 Endogenous-globular<br />

Low High Al Mg5 Mushy<br />

loy represents a special case allowing<br />

hardness values of approx. 100 HB and<br />

a corresponding strength – albeit at very<br />

low ductility – in all casting processes.<br />

Hypereutectic AlSi casting alloys such<br />

as Al Si18CuNiMg and Al Si17Cu4Mg,<br />

for example, which display particularly<br />

high wear resistance due to their high<br />

silicon content, can also be classifi ed<br />

in this group.<br />

“ductile”<br />

<strong>Casting</strong> alloys which display particu-<br />

larly high ductility, e.g. Silumin-Kappa<br />

(Al Si11Mg), come under this general<br />

heading. This casting alloy is frequently<br />

used for the manufacture of automobile<br />

wheels.<br />

In this particular application, a high elongation<br />

value is required for safety reasons.<br />

“other”<br />

<strong>Casting</strong> alloys for more decorative purposes<br />

with lower strength properties, e.g.<br />

Al Mg3, belong to this category.<br />

<strong>Casting</strong> properties<br />

Further selection criteria comprise cast-<br />

ing properties such as the fl uidity or<br />

solidifi cation behaviour which sets the<br />

foundryman certain limits. Not every<br />

ideally-shaped casting can be cast in<br />

every casting alloy.<br />

A simplifi ed summary of the casting prop-<br />

erties associated with the most important<br />

casting alloys is shown in Table 2.<br />

Co-operation between the technical designer<br />

and an experienced foundryman<br />

works to great advantage when looking<br />

for the optimum casting alloy for a particular<br />

application.<br />

Given constant conditions, the fl uidity<br />

of a metallic melt is established by de-<br />

termining the fl ow length of a test piece.<br />

Theoretically, low fl uidity can be offset<br />

by a higher casting temperature; this is,<br />

however, linked with disadvantages such<br />

as oxidation and hydrogen absorption as<br />

well as increased mould wear. Eutectic<br />

AlSi casting alloys such as Silumin or<br />

Al Si12 display high fl uidity. Hypoeutectic<br />

AlSi casting alloys such as Pantal 7 have<br />

medium values. AlCu and AlMg casting<br />

alloys display low fl uidity.<br />

Hypereutectic AlSi casting alloys such<br />

as Al Si17Cu4Mg occupy a special posi-<br />

tion. In their case, very long fl ow paths<br />

are observed. This does not however<br />

necessarily lead to a drop in the melt<br />

temperature since primary silicon crystals<br />

already form in the melt. The melt<br />

still fl ows well because the latent heat<br />

of solidifi cation of the primary silicon<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 15


Selection criteria for aluminium casting alloys<br />

<strong>Casting</strong> properties Strength characteristics Corrosion<br />

resistance*<br />

Shrinkage Fluidity Thermal crack High strength Strong Ductile Hard<br />

formation susceptibility and ductile (T6) and ductile<br />

Coarse High Low Silumin<br />

Silumin-Kappa<br />

Silumin-Delta<br />

Al Si12<br />

Silumin-Beta<br />

Pantal 7<br />

Al Cu4Ti<br />

Al Si12(Cu)<br />

Al Si10Mg<br />

Al Si10Mg(Cu)<br />

Al Mg3Si<br />

Al Si12CuNiMg<br />

Al Si17Cu4Mg<br />

Al Si18CuNiMg<br />

Autodur<br />

Al Si8Cu3<br />

Al Mg3<br />

Al Mg5<br />

Fine Low High Al Mg9<br />

* Analogue to DIN EN 1706<br />

heats up the remainder of the melt. The<br />

already solidifi ed silicon, however, causes<br />

increased mould wear and very uneven<br />

distribution in the castings. In these<br />

casting alloys, high melting and holding<br />

temperatures are necessary so that a<br />

casting temperature of at least 720 °C<br />

for pressure die casting and 740 °C<br />

for sand and gravity die casting has to<br />

be attained.<br />

The susceptibility to hot tearing is almost<br />

the opposite of fl uidity (Tables 2 and 3).<br />

By hot tearing, we mean a separation of<br />

the already crystallised phases during<br />

16<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

solidifi cation, e.g. under the infl uence of<br />

shrinkage or other tensions which can<br />

be transmitted via the casting moulds.<br />

The cracks or tears arising can be healed<br />

by, among other things, the feeding of<br />

residual melt. Eutectic and near-eutectic<br />

AlSi casting alloys also behave particularly<br />

well in this case, while AlCu and AlMg<br />

casting alloys behave particularly badly.<br />

In practice, there are mixed forms and<br />

transitional forms of these solidifi cation<br />

modes. The solidifi cation behaviour is<br />

responsible for the formation of shrink-<br />

Table 3<br />

age cavities and porosity, for example,<br />

or other defects in the cast structure<br />

as it determines the distribution of the<br />

volume defi cit in the casting. To curb<br />

the aforementioned casting defects,<br />

casting/technical measures need to be<br />

taken: e.g. by making adjustments to<br />

the sprue system, the thermal balance<br />

of the mould or by controlling the gas<br />

content of the melt. A volume defi cit<br />

occurs during transition from liquid to<br />

solid state. This is quite small in high<br />

silicon casting alloys since the silicon<br />

increases in volume during solidifi cation.<br />

In any case, the volume defi cit incurred


needs to be offset as far as possible by<br />

casting/technical means (see also the<br />

section on “Avoiding casting defects”).<br />

Figure 1 indicates the main types of so-<br />

lidifi cation; each type is shown at two<br />

successive points in time. With regard<br />

to aluminium, only high-purity aluminium<br />

belongs to Solidifi cation Type A (“exogenous-shell<br />

forming”). The only casting<br />

alloy which corresponds to this type is<br />

the eutectic silicon alloy or Al Si12 with<br />

approx. 13 % silicon.<br />

The hypoeutectic AlSi casting alloys<br />

solidify according to Type C (“spongy”),<br />

AlMg casting alloys according to a mix-<br />

ture of Types D and E (“mushy” or “shellforming”).<br />

The remaining casting alloys<br />

also represent intermediate types. At high<br />

solidifi cation speeds, the solidifi cation<br />

types move upwards, i.e. in the direction<br />

of “exogenous-rough wall”.<br />

Shell-forming casting alloys with “smooth-<br />

wall” or “rough-wall” solidifi cation are sus-<br />

ceptible to the formation of macroshrink-<br />

age which can only be prevented to a<br />

limited extent by feeding. <strong>Casting</strong> alloys<br />

of a spongy-mushy type are susceptible<br />

to shrinkage porosity which can only be<br />

avoided to a limited extent by feeding.<br />

In castings which demand feeding by<br />

material accumulation in particular and<br />

Exogenous solidifi cation types<br />

A Smooth wall B Rough wall C Spongy<br />

Endogenous solidifi cation types<br />

D Mushy E Shell forming<br />

Mould<br />

Fluid<br />

Strong<br />

Picture 1<br />

which should be extensively pore-free –<br />

as well as pressure-tight – the preferred<br />

casting alloys are to be found at the top<br />

of Table 3.<br />

For complex castings whose geometry<br />

does not allow each material accumulation<br />

to be achieved with a feeder, the<br />

casting alloys listed in Table 3 offer advantages<br />

provided that a certain amount<br />

of microporosity is taken into account.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 17


i Fe<br />

Infl uence of the most important<br />

alloying elements on aluminium<br />

casting alloys<br />

Silicon<br />

improves the casting properties<br />

produces age-hardenability in<br />

combination with magnesium but<br />

causes a grey colour during anodisation<br />

in pure AlCu casting alloys (e.g.<br />

Al Cu4Ti), silicon is a harmful impurity<br />

and leads to hot tearing<br />

susceptibility.<br />

Iron<br />

at a content of approx. 0.2 % and<br />

above, has a decidedly negative<br />

infl uence on the ductility (elongation<br />

at fracture); this results in a<br />

very brittle AlFe(Si) compound in<br />

the form of plates which appear in<br />

micrographs as “needles”; these<br />

plates act like large-scale microstructural<br />

separations and lead to<br />

fracture when the slightest strain<br />

is applied<br />

at a content of approx. 0.4 % and<br />

above, reduces the tendency to<br />

stickiness in pressure die casting.<br />

18<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Copper<br />

increases the strength, also at<br />

high temperatures (hightemperature<br />

strength)<br />

produces age-hardenability<br />

impairs corrosion resistance<br />

in binary AlCu casting alloys, the<br />

large solidifi cation range needs to<br />

be taken into account from a<br />

casting/technical point of view.<br />

Manganese<br />

partially offsets iron‘s negative<br />

effect on ductility when iron<br />

content is > 0.15 %<br />

segregates in combination with<br />

iron and chromium<br />

reduces the tendency to stickiness<br />

in pressure die casting.<br />

Magnesium<br />

produces age-hardenability in<br />

combination with silicon,<br />

copper or zinc; with zinc also<br />

self-hardening<br />

improves corrosion resistance<br />

increases the tendency towards<br />

oxidation and hydrogen<br />

absorption<br />

binary AlMg casting alloys are<br />

diffi cult to cast owing to their large<br />

solidifi cation range.<br />

Zinc<br />

increases strength<br />

produces (self) age-hardenability<br />

in conjunction with magnesium.<br />

Nickel<br />

increases high-temperature<br />

strength.<br />

Titanium<br />

increases strength (solid-solution<br />

hardening)<br />

produces grain refi nement on its<br />

own and together with boron.


Infl uencing the microstructural<br />

formation of aluminium castings<br />

Measures infl uencing microstructural<br />

formation are aimed at improving the<br />

mechanical and casting properties. In<br />

practice, apart from varying the cooling<br />

speed by means of different mould<br />

materials, additions to the melt are usually<br />

used.<br />

Common treatment measures include:<br />

grain refi nement of the solid<br />

solution with Ti and/or B<br />

transformation of the eutectic Si<br />

from lamellar into granular form<br />

modifi cation of the eutectic Si<br />

with Na or Sr<br />

refi nement of the eutectic<br />

Si with Sb<br />

refi nement of the Si primary<br />

phase with P or Sb.<br />

The marked areas in Figure 1 denote<br />

where it makes sense to carry out the<br />

respective types of treatment on AlSi<br />

casting alloys.<br />

Some of these measures are explained<br />

in more detail in the following section.<br />

Types of treatment to infl uence grain structure Figure 1<br />

Temperature<br />

[°C]<br />

700<br />

600<br />

500<br />

400<br />

0 2 4 6 8 10 12 14 16 18 20 22 24<br />

Silicon [wt. – %]<br />

Primary Si refi nement<br />

Grain refi nement<br />

Modifi cation<br />

Melt<br />

+ Al 660 °C<br />

Al Al + Si<br />

Melt<br />

Melt + Si<br />

Eutectic temperature 577 C°<br />

Al Si5 Al Si7 Al Si9 Al Si12 Al Si18<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 19


Grain refi nement<br />

The solidifi cation of many aluminium<br />

casting alloys begins with the formation<br />

of aluminium-rich dendritic or equiaxed<br />

crystals. In the beginning, these solidifi ed<br />

crystallites are surrounded by the remain-<br />

ing melt and, starting from nucleation<br />

sites, grow on all sides until they touch<br />

the neighbouring grain or the mould wall.<br />

The characterisation of a grain is the<br />

equiaxed spatial arrangement on the<br />

lattice level. For casting/technical or<br />

optical/decorative reasons as well as<br />

for reasons of chemical resistance, it is<br />

often desirable to set the size of these<br />

grains as uniformly as possible or as fi nely<br />

as technically possible. To achieve this,<br />

so-called grain refi nement is frequently<br />

carried out. The idea is to offer the solidifying<br />

aluminium as many nucleating<br />

agents as possible.<br />

Since grain refi nement only affects the<br />

α-solid solution, it is more effective when<br />

the casting alloy contains little silicon,<br />

i.e. a lower fraction of eutectic (Figure 2).<br />

Grain refi nement is particularly important<br />

in AlMg and AlCu casting alloys in order<br />

to reduce their tendency to hot tearing.<br />

From a technical and smelting perspective,<br />

grain refi nement mostly takes place<br />

by adding special Al TiB master alloys.<br />

20<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

We pre-treat the appropriate casting alloys<br />

when producing the alloys so that<br />

grain refi nement in the foundry is either<br />

unnecessary or only needs a freshen-<br />

up. The latter can be done in the form of<br />

salts, pellets or preferably with titanium<br />

master alloy wire, following the manufacturer’s<br />

instructions.<br />

Effect of silicon content on grain<br />

refi nement with Al Ti5B1 master alloy<br />

Mean grain diameter <strong>Casting</strong> temperature 720 °C<br />

[µm]<br />

1400<br />

holding time 5 min<br />

1200<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

0<br />

Columnar and<br />

equiaxed crystals<br />

Silicon [%]<br />

Without grain<br />

refi nement<br />

With grain refi nement<br />

Al Ti5B1: 2,0 kg/mt<br />

Since every alloying operation means<br />

more contaminants in the melt, grain<br />

refi nement should only be carried out<br />

for the reasons referred to above.<br />

Figure 2<br />

0 2 4 6 8 10 12<br />

To make a qualitative assessment of a<br />

particular grain refi nement treatment,<br />

thermal analysis can be carried out (see<br />

section on “Melt testing and inspection<br />

procedure”).


Modifi cation of AlSi eutectic<br />

(refi nement)<br />

By “modifi cation”, we mean the use<br />

of a specifi c melt treatment to set a<br />

fi ne-grained eutectic silicon in the cast<br />

structure which improves the mechanical<br />

properties (and elongation in particular)<br />

as well as the casting properties in many<br />

cases. As a general rule, modifi cation<br />

is carried out by adding small amounts<br />

of sodium or strontium. To facilitate an<br />

understanding of the possible forms of<br />

eutectic silicon, these are depicted in<br />

Figure 2 (a-e) for Al Si11 with a varying<br />

Na content:<br />

a) The lamellar condition only<br />

appears in casting alloys which<br />

are virtually free of phosphorous<br />

or modifi cation agents, e.g.<br />

Na or Sr.<br />

b) In granular condition which<br />

appears in the presence of<br />

phosphorous without Na or Sr, the<br />

silicon crystals exist in the form of<br />

coarse grains or plates.<br />

c) In undermodifi ed and<br />

d) to a great extent in fully-modifi ed<br />

microstructural condition, e.g.<br />

by adding Na or Sr, they are<br />

signifi cantly reduced in size,<br />

rounded and evenly distributed<br />

which has a particularly positive<br />

effect on elongation.<br />

e) In the case of overmodifi cation<br />

with sodium, vein-like bands with<br />

coarse Si crystals appear.<br />

Overmodifi cation can therefore<br />

mean deterioration as regards<br />

mechanical properties.<br />

Figures 3 and 4 depict the formation of<br />

microstructural conditions or the degree<br />

of modifi cation as a result of interaction<br />

between sodium and strontium and the<br />

phosphorous element. It can be ascer-<br />

tained that the disruption of modifi cation<br />

due to small amounts of phosphorous<br />

is relatively slight. In Sr modifi cation, a<br />

high phosphorous content can be offset<br />

by an increased amount of modifying<br />

agent. In aluminium casting alloys with a<br />

silicon content exceeding 7 %, eutectic,<br />

silicon takes up a larger part of the area<br />

of a metallographic specimen. From a<br />

silicon content of approx. 7 to 13 %,<br />

the type of eutectic formation, e.g.<br />

grained or modifi ed, thus plays a key<br />

role in determining the performance<br />

characteristics, especially the ductility<br />

Types of grain structure<br />

a) Lamellar b) Granular<br />

d) Modifi ed<br />

e) Overmodifi ed<br />

or elongation. When higher elongation is<br />

required in a workpiece, aluminium cast-<br />

ing alloys containing approx. 7 to 13 %<br />

silicon will thus be modifi ed by adding<br />

approx. 0.0040 to 0.0100 % sodium (40<br />

to 100 ppm).<br />

In casting alloys with approx. 11 % silicon,<br />

particularly for use in low-pressure die<br />

casting, strontium can also be used as a<br />

long-term modifi er since the melting loss<br />

behaviour of this element is substantially<br />

better than that of sodium. In this case,<br />

the recommended addition is approx.<br />

0.014 to 0.04 % Sr (140 to 400 ppm).<br />

With suitable casting alloys, the required<br />

amount of strontium can be added<br />

during alloy manufacture so that, as<br />

a rule, the modifi cation process step<br />

c) Undermodifi ed<br />

Picture 2<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 21


Microstructural formation in relation to<br />

the content of phosphorous and sodium Al Si7Mg<br />

Sodium Sand casting<br />

[ppm]<br />

140<br />

cooling rate 0.1 K/s<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Overmodifi ed<br />

Granular<br />

Modifi ed<br />

Lamellar<br />

can be omitted in the foundry. At low<br />

cooling rates, strontium modifi cation is<br />

less effective so that it is not advisable<br />

to use this in sand casting processes.<br />

To avoid the burn-off of strontium, any<br />

cleaning and degassing of Sr-modifi ed<br />

melts should be carried out with chlorine-<br />

free preparations only, preferably using<br />

argon or nitrogen. Strontium modifi cation<br />

is not greatly impaired even when<br />

remelting revert material. Larger losses<br />

22<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Phosphorous [ppm]<br />

Undermodifi ed<br />

Figure 3<br />

0 5 10 15 20 25 30 35 40 45 50 55 60<br />

can be offset by adding Sr master alloy<br />

wire in accordance with the respective<br />

manufacturer‘s instructions. At the right<br />

temperature, the addition of sodium to<br />

the melt is best done by charging standard<br />

portions. For easy handling, storage<br />

and proportioning, the manufacturer‘s<br />

recommendations and safety instructions<br />

should be followed.<br />

Since sodium burns off from the melt<br />

relatively quickly, subsequent modifi -<br />

Figure 4<br />

Microstructural formation in relation to<br />

the content of phosphorous and strontium Al Si7Mg<br />

Strontium Gravity die casting<br />

[ppm] gravity die cast test bar<br />

cooling rate 2.5 K/s<br />

450<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Phosphorous [ppm]<br />

Modifi ed Undermodifi ed Granular Lamellar<br />

cation must take place in the foundry<br />

at regular intervals. In melts modifi ed<br />

with sodium, any requested cleaning<br />

and degassing should be carried out<br />

with chlorine-free compounds only<br />

(argon or nitrogen). A certain amount<br />

of sodium burn-off is to be reckoned<br />

with, however, and needs to be taken<br />

into account in the subsequent addition<br />

of sodium. When absolutely necessary,<br />

the melt can be treated with chlorine-<br />

releasing compounds long before the


fi rst addition of sodium. If such treat-<br />

ment is carried out after adding sodium<br />

or strontium, chlorine may react with<br />

these elements and remove them from<br />

the melt, thereby preventing any further<br />

modifi cation.<br />

Modifi cation with sodium or strontium<br />

increases the tendency to gas absorption<br />

in the melt. As a result of the reaction<br />

of the precipitating hydrogen with<br />

the rapidly-forming oxides, defects can<br />

occur in the casting, especially cumulant<br />

microporosity. In many practical cases,<br />

this potential for micropore formation<br />

is even desirable. Then, the purpose<br />

of modification is also to offset the<br />

expected macroshrinkage by forming<br />

many micropores.<br />

An accurate assessment of the effects<br />

of modifi cation can only be made by<br />

means of metallographic examination.<br />

As a quick test, thermal analysis can be<br />

carried out if it is possible to establish by<br />

means of a preliminary metallographic<br />

examination which depression value is<br />

necessary to attain a suffi ciently-modi-<br />

fi ed grain structure (for more information<br />

on thermal analysis, please refer to the<br />

section on “Methods for monitoring the<br />

melt”). Under the same conditions, rapid<br />

determination of the modifi ed condition<br />

is also possible by measuring the electrical<br />

conductance of a sample.<br />

In aluminium casting alloys of the type<br />

Al Si7Mg, a refi nement of the eutectic<br />

silicon with antimony (Sb) is possible.<br />

A Sb content of at least 0.1 % is required.<br />

This treatment, however, only produces<br />

a fi ner formation of the lamellar eutectic<br />

silicon and is not really modifi cation<br />

in the traditional sense. The danger of<br />

contamination of other melts by closedcircuit<br />

material containing Sb exists as<br />

even a Sb content of approx. 100 ppm<br />

can disturb normal sodium or strontium<br />

modifi cation. What‘s more, refi nement<br />

with antimony can be easily disturbed<br />

by only a low level of phosphorous (a<br />

few ppm) (Figure 5). In contrast to modifi<br />

cation, refi nement with antimony can<br />

not be checked by means of thermal<br />

analysis of a melt sample.<br />

Figure 5<br />

Infl uence of antimony and phosphorous<br />

content on the form of the eutectic silicon of Al Si7Mg<br />

Antimony<br />

[%]<br />

0.30<br />

0.20<br />

0.10<br />

0.00<br />

Coarse-lamellar<br />

Acceptable Coarse-lamellar<br />

to granular<br />

Phosphorous [ppm]<br />

Refi nement of primary silicon<br />

In hypereutectic AlSi casting alloys<br />

(e.g. Al Si18CuNiMg), the silicon-rich,<br />

polygonal primary crystals solidify fi rst.<br />

To produce as many fi ne crystals as pos-<br />

sible in the as-cast structure, nucleating<br />

agents need to be provided.<br />

High-purity base<br />

0 2 4 6 8 10<br />

This is done with the aid of prepara-<br />

tions or master alloys which contain<br />

phosphorous-aluminium compounds.<br />

This treatment can also be carried out<br />

when the alloy is being manufactured<br />

and, in most cases, the foundryman<br />

does not need to repeat the process.<br />

If required, the quality of such primary<br />

refi nement can be checked by means<br />

of thermal analysis.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 23


Melt quality and melt cleaning<br />

All factors which come under the general<br />

term of “melt quality” have a direct<br />

effect on the quality of the casting to be<br />

produced. Inversely, according to DIN EN<br />

1706, the cast samples play a valuable<br />

role in checking the quality of the melt.<br />

Most problems in casting are caused by<br />

two natural properties of liquid melts, i.e.<br />

their marked tendency to form oxides<br />

and their tendency towards hydrogen<br />

absorption. Furthermore, other insoluble<br />

impurities, such as Al-carbides or<br />

refractory particles as well as impurities<br />

with iron, play an important role.<br />

As mentioned in other sections, the<br />

larger oxide fi lm can lead to a material<br />

separation in the microstructure and,<br />

consequently, to a reduction in the load-<br />

bearing cross-section of the casting.<br />

The solubility of hydrogen in aluminium<br />

decreases discontinuously during the<br />

transition from liquid to solid so that as<br />

solidifi cation takes place, precipitating<br />

gaseous hydrogen reacting with existing<br />

oxides can cause voids which can<br />

in turn take various forms ranging from<br />

large pipe-like blisters to fi nely-distributed<br />

micro-porosity.<br />

24<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Critical melting temperatures<br />

in relation to the segregation factor<br />

Temperature<br />

[°C]<br />

650<br />

640<br />

630<br />

620<br />

610<br />

600<br />

590<br />

0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2<br />

Segregation factor [(Fe)+2(Mn)+3(Cr)]<br />

Al Si8Cu3 Al Si6Cu4 Al Si12(Cu)<br />

To achieve good melt quality, the for-<br />

mation of oxides and the absorption<br />

of hydrogen have to be suppressed as<br />

much as possible on the one hand, while<br />

other hydrogen and oxides have to be<br />

removed from the melt as far as possible<br />

on the other, although this is only<br />

possible to a certain extent.<br />

Figure 6


Avoiding impurities<br />

Ingot quality<br />

An essential prerequisite for a good<br />

casting is good ingot quality. The metal<br />

should be cleaned effectively and the in-<br />

gots should display neither metallic nor<br />

non-metallic inclusions. The ingots must<br />

be dry (there is a risk of explosion when<br />

damp) and no oil or paint residue should<br />

be present on their surface. When using<br />

revert material, this should be in lumps,<br />

if possible, and well cleaned.<br />

Melting<br />

When melting ingots or revert material,<br />

it must be ensured that the metal is not<br />

exposed unnecessarily to the fl ame or<br />

furnace atmosphere. The pieces of metal<br />

should be melted down swiftly, i.e. follow-<br />

ing short preheating, immersed directly<br />

in the liquid melt.<br />

Large-volume hearth or crucible furnaces<br />

are best suited to melting. Furnaces with<br />

melting bridges are oxide producers and<br />

they lead to expensive, unnecessary and<br />

irretrievable metal losses.<br />

The type and state of the melt in contact<br />

with refractory materials are of particular<br />

importance in the melting and holding<br />

of aluminium.<br />

<strong>Aluminium</strong> and aluminium casting alloys<br />

in a molten state are very aggressive, especially<br />

when AlSi melts contain sodium<br />

or strontium as modifying agents. With<br />

an eye to quality, reactions, adherences,<br />

infi ltrations, abrasive wear and decompo-<br />

sition have to be kept within limits when<br />

using melting crucibles and refractory<br />

materials as well as during subsequent<br />

processing. The care and maintenance<br />

as well as cleanliness of equipment are<br />

equally important. Adhering materials<br />

can very easily lead to the undesired<br />

redissolving of oxides in the melt and<br />

cause casting defects.<br />

Melting temperature<br />

The temperature of the melt must be set<br />

individually for each alloy.<br />

Too low melting temperatures lead to<br />

longer residence times and, as a result,<br />

to greater oxidation of the pieces jut-<br />

ting out of the melt. The melt becomes<br />

homogeneous too slowly, i.e. local undercooling<br />

allows segregation to take<br />

place, even as far as tenacious gravity<br />

segregation of the FeMnCrSi type phases.<br />

The mathematical interrelationship for<br />

the segregation of heavy intermetallic<br />

phases is depicted in Figure 6.<br />

Furthermore, at too low temperatures,<br />

autopurifi cation of the melt (oxides rising)<br />

can not take place.<br />

When the temperature of the melt is too<br />

high, increased oxide formation and<br />

gassing can occur. Lighter alloying elements,<br />

e.g. magnesium, are subject to<br />

burn-off in any case; this must be offset<br />

by appropriate additions. Too high<br />

melting temperatures aggravate this loss<br />

by burning.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 25


Conducting the melting operation<br />

As long as the melt is in a liquid condi-<br />

tion, it has a tendency to oxidise and<br />

absorb hydrogen. Critical points during<br />

subsequent processing include decanta-<br />

tion, the condition or maintenance of the<br />

transfer vessel, possible reactions with<br />

refractory materials as well as transport<br />

or metal tapping. The addition of grain<br />

refi ners and modifying agents above the<br />

required amount can lead to an increase<br />

in non-metallic impurities and greater<br />

hydrogen absorption.<br />

To minimise an enrichment of iron in the<br />

melt, direct contact between ferrous<br />

materials and the melt is to be avoided.<br />

For this reason, steel tools and containers<br />

(casting ladles) must be carefully<br />

dressed. Similarly, but also on economic<br />

grounds, the feed tubes for low-pressure<br />

die casting – made from cast iron up to<br />

now – should be replaced by ceramic<br />

feed tubes.<br />

Even during the casting process itself<br />

and especially due to turbulence in the<br />

fl ow channel, oxide skins can once again<br />

form which in turn can lead to casting<br />

defects. <strong>Casting</strong> technology is thus required<br />

to fi nd ways of preventing the<br />

excessive oxidation of the melt, e.g. by<br />

means of intelligent runners and gating<br />

systems (please refer to the section on<br />

“Selecting the casting process”).<br />

26<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Figure 7<br />

Hydrogen content of various<br />

casting alloy melts after different types of treatment<br />

Hydrogen<br />

[ml/100g]<br />

0.50<br />

0.40<br />

0.30<br />

0.20<br />

0.10<br />

0.00<br />

After melting<br />

10 20 30 0.5 2 4 24 10 20<br />

Rotary<br />

degassing<br />

[min]<br />

Holding<br />

in [h]<br />

Type of melt treatment<br />

Al Si8Cu3 Pantal 7 Al Mg5<br />

Gassing<br />

Rotary<br />

degassing<br />

[min]<br />

24h


Cleaning and degassing the melt<br />

Our casting alloys consist of effectively<br />

cleaned metal. Since reoxidation always<br />

takes place during smelting, and in<br />

practice revert material is always used,<br />

a thorough cleaning of the melt is necessary<br />

prior to casting.<br />

Holding the aluminium melt at the cor-<br />

rect temperature for a long time is an ef-<br />

fective cleaning method. It is, however,<br />

very time-intensive and not carried out<br />

that often as a result. Foundrymen are<br />

thus left with only intensive methods, i.e.<br />

using technical equipment or the usual<br />

commercially available mixture of salts.<br />

In principle, melt cleaning is a physical<br />

process: the gas bubbles rising through<br />

the liquid metal attach oxide fi lms to their<br />

outer surfaces and allow hydrogen to dif-<br />

fuse into the bubbles from the melt. Both<br />

are transported to the bath surface by the<br />

bubbles. It is therefore clear that in order<br />

for cleaning of the melt to be effective, it<br />

is desirable to have as many small gas<br />

bubbles as possible distributed across<br />

the entire cross-section of the bath.<br />

Dross can be removed from the surface<br />

of the bath, possibly with the aid of oxide-binding<br />

salts.<br />

Inert-gas fl ushing by means of an im-<br />

peller is a widely-used, economical and<br />

environmentally-sound cleaning process.<br />

The gas stream is dispersed in the form<br />

of very small bubbles by the rapid turning<br />

of a rotor and, in conjunction with the<br />

good intermixing of the melt, this leads<br />

to very effi cient degassing. To achieve<br />

an optimum degassing effect, the various<br />

parameters such as rotor diameter<br />

and revolutions per minute, gas fl ow<br />

rate, treatment time, geometry and size<br />

of the crucible used as well as the alloy,<br />

have to be co-ordinated. The course of<br />

degassing and reabsorption of hydrogen<br />

is depicted for various casting alloys<br />

in Figure 7.<br />

When using commercially available salt<br />

preparations, the manufacturer‘s instruc-<br />

tions concerning use, proportioning,<br />

storage and safety should be followed.<br />

Apart from this, attention should also be<br />

paid to the quality and care of tools and<br />

auxiliary materials used for cleaning so<br />

that the cleaning effect is not impaired.<br />

If practically feasible, it is also possible<br />

to fi lter the melt using a ceramic foam<br />

fi lter. In the precision casting of high-<br />

grade castings, especially in the sand<br />

casting process, the use of ceramic<br />

fi lters in the runner to the sand mould<br />

has proved to be a success. Above all,<br />

such a fi lter leads to an even fl ow and<br />

can retain coarse impurities and oxides.<br />

In the gravity die casting of sensitive<br />

hydraulic parts, or when casting sub-<br />

sequently anodised decorative fi ttings<br />

in Al Mg3, ladling out of a device which<br />

is fi tted with in-line fi lter elements and<br />

separated from the remaining melt bath<br />

is very common.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 27


Melt testing and inspection procedure<br />

To assess the effectiveness of the clean-<br />

ing process or the quality of the melt, the<br />

following test and inspection methods<br />

can be used to monitor the melt:<br />

Reduced pressure test<br />

This method serves to determine the<br />

tendency to pore formation in the melt<br />

during solidifi cation. A sample, which<br />

can contain a varying number of gas<br />

bubbles depending on the gas content,<br />

is allowed to solidify at an underpressure<br />

of 80 mbar. The apparent density is then<br />

compared with that of a sample which<br />

is solidifi ed at atmospheric pressure.<br />

The so-called “Density Index” is then<br />

calculated using the following equation:<br />

DI = (dA - d80)/dA x 100 %<br />

DI = Density Index<br />

dA = density of the sample solidifi ed<br />

at atmospheric pressure<br />

d80 = density of the sample solidifi ed<br />

at under 80 mbar<br />

28<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

The Density Index allows a certain inference<br />

to be drawn about the hydrogen<br />

content of the melt. It is, however, strongly<br />

infl uenced by the alloying elements and,<br />

above all, by varying content of impurities<br />

so that the hydrogen content must not<br />

on any account be stated as a Density<br />

Index value (Figure 8).<br />

The assessment of melt quality by means<br />

of an underpressure density sample therefore<br />

demands the specifi c determination<br />

of a critical Density Index value for each<br />

casting alloy and for each application.<br />

The underpressure density method is,<br />

however, a swift and inexpensive method<br />

with the result that it is already used<br />

in many foundries for quality control.<br />

To keep results comparable, sampling<br />

should always be carried out according<br />

to set parameters.<br />

Determination of the hydrogen<br />

content in the melt<br />

Reliable instruments have been in operation<br />

for years for measuring the hydrogen<br />

content in aluminium melts. They work<br />

according to the principle of establishing<br />

equilibration between the melt and a<br />

measuring probe so that the actual gas<br />

content in the melt is determined and not<br />

in the solid sample. In this way, the effectiveness<br />

of the degassing treatment can<br />

be assessed quickly. The procurement of<br />

such an instrument for continuous quality<br />

monitoring is only worthwhile when it is<br />

used frequently; in small foundries, the<br />

hiring of an instrument to solve problems<br />

is suffi cient.


Determination of insoluble<br />

non-metallic impurities<br />

For determining the number and type<br />

of insoluble non-metallic impurities in<br />

aluminium melts, the Porous Disc Filtration<br />

Apparatus (PoDFA) method, among<br />

others, can be used. In this particular<br />

method, a precise amount of the melt<br />

is squeezed through a fi ne fi lter and<br />

the trapped impurities are investigated<br />

metallographically with respect to their<br />

type and number. The PoDFA method<br />

is one of the determination procedures<br />

which facilitates the acquisition, both<br />

qualitatively and quantitatively, of the<br />

impurity content. It is used primarily for<br />

evaluating the fi ltration and other clean-<br />

ing treatments employed and, in casting<br />

alloys production, is utilised at regular<br />

intervals for the purpose of quality control.<br />

This method is not suitable for making<br />

constant routine checks since it is very<br />

time-consuming and entails high costs.<br />

Correlation between the hydrogen content<br />

and density index in unmodifi ed Al Si9Mg alloy<br />

Density index Measurement acc. to Chapel<br />

[%]<br />

35<br />

at vacum 30 mbar<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

0 0.1 0.2 0.3 0.4 0.5 0.6<br />

Hydrogen content [ml/100g]<br />

Figure 8<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 29


Thermal analysis<br />

To evaluate the effectiveness of melt<br />

treatment measures, e.g. modifi cation,<br />

grain refi nement and primary silicon re-<br />

fi ning, thermal analysis has proved itself<br />

to be a fast and relatively inexpensive<br />

method in many foundries. The test<br />

method is based on the comparison of<br />

two cooling curves of the investigated<br />

melts (Figures 9 and 10).<br />

The undercooling effect (recalescence)<br />

occurring during primary solidifi cation<br />

allows conclusions to be made about<br />

the effectiveness of a grain refi nement<br />

treatment, whereby the recalescence<br />

values do not however allow conclusions<br />

to be drawn as regards the later grain<br />

size in the microstructure. Modifi cation is<br />

shown in thermal analysis by a decrease<br />

in the eutectic temperature (depression)<br />

in comparison to the unmodifi ed state.<br />

Here too, the level of the depression<br />

values depend strongly on the content<br />

of accompanying and alloying elements<br />

(e.g. Mg) and, consequently, the de-<br />

pression values required for suffi cient<br />

modifi cation must be established case<br />

by case, by means of parallel microstruc-<br />

tural investigations.<br />

30<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Thermal analysis for monitoring<br />

the grain refi nement of Al casting alloys<br />

Temperature<br />

[T]<br />

T L<br />

T L<br />

Time [t]<br />

With grain refi nement Without grain refi nement<br />

Liquidus temperature [T L ]<br />

Thermal analysis for monitoring<br />

the modifi cation of Al casting alloys<br />

Temperature<br />

[°C]<br />

585<br />

580<br />

577<br />

575<br />

570<br />

565<br />

560<br />

Figure 9<br />

0 10 20<br />

Time [sec]<br />

30 40 50<br />

Modifi ed Undermodifi ed Eutectic temperature<br />

Figure 10


Selecting the casting process<br />

As mentioned in the introduction, the<br />

entire “casting” process is the shortest<br />

route from molten metal to a part which<br />

is almost ready for use. All sections of<br />

this catalogue contain advice on how the<br />

entire experience should be carried out.<br />

The casting process is selected according<br />

to various criteria such as batch<br />

size, degree of complexity or requisite<br />

mechanical properties of the casting.<br />

Some examples:<br />

The sand casting process is used<br />

predominantly in two fi elds of appli-<br />

cation: for prototypes and small-scale<br />

production on the one hand and for the<br />

volume production of castings with a<br />

very complex geometry on the other.<br />

For the casting of prototypes, the main<br />

arguments in favour of the sand casting<br />

process are its high degree of fl exibility<br />

in the case of design changes and the<br />

comparably low cost of the model. In volume<br />

production, the level of complexity<br />

and precision achieved in the castings<br />

are its main advantages.<br />

When higher mechanical properties are<br />

required in the cast piece, such as higher<br />

elongation or strength, gravity die cast-<br />

ing, and to a limited extent pressure die<br />

casting, are used. In gravity die casting,<br />

there is the possibility of using sand<br />

cores. Large differences in wall thick-<br />

nesses can be favourably infl uenced<br />

with the help of risers. Cylinder heads<br />

for water-cooled engines represent a<br />

typical application.<br />

In the low-pressure gravity die process<br />

with its upward and controllable cavity<br />

fi lling, the formation of air pockets is re-<br />

duced to a minimum and, consequently,<br />

high casting quality can be achieved. In<br />

addition to uphill fi lling, the overpressure<br />

of approx. 0.5 bar has a positive effect<br />

on balancing out defects caused by<br />

shrinkage. The low-pressure die casting<br />

process is particularly advantageous in<br />

the casting of rotationally symmetrical<br />

parts, e.g. in the manufacture of passenger<br />

vehicle wheels.<br />

Pressure die casting is the most widely<br />

used casting process for aluminium<br />

casting alloys. Pressure die casting is<br />

of particular advantage in the volume<br />

production of parts where the requirement<br />

is on high surface quality and the<br />

least possible machining. Special applications<br />

(e.g. vacuum) during casting<br />

enable castings to be welded followed<br />

by heat treatment which fully exploits<br />

the property potential displayed by the<br />

casting alloy.<br />

In addition to conventional pressure die<br />

casting, thixocasting is worthy of mention<br />

since heat-treatable parts can also<br />

be manufactured using this process.<br />

The special properties are achieved<br />

by shaping the metal during the solidliquid<br />

phase.<br />

Squeeze-casting is another casting pro-<br />

cess to be mentioned; here, solidifi cation<br />

takes place at high pressure. In this way,<br />

an almost defect-free microstructure<br />

can be produced even where there are<br />

large transitions in the cross-section<br />

and insuffi cient feeding.<br />

Other special casting processes include:<br />

Precision casting<br />

Evaporative pattern casting<br />

Plaster mould casting<br />

Vacuum sand casting<br />

Centrifugal casting.<br />

The considerations above concern casting<br />

as an overall process.<br />

In the following notes on casting prac-<br />

tice, the actual pouring of the molten<br />

metal into prepared moulds and the<br />

subsequent solidifi cation control are<br />

looked at in more detail.<br />

From the numerous casting processes,<br />

which differ from one another in the type<br />

of mould material (sand casting, per-<br />

manent dies etc.) or by pressurisation<br />

(pressure die casting, low-pressure die<br />

casting etc.), a few notes are provided<br />

here on the most important processes.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 31


Pressure die casting process<br />

This process takes up the largest share.<br />

The hydraulically-controlled pressure<br />

die casting machine and the in-built<br />

die make up the central element of the<br />

process. The performance, the precise<br />

control of the hydraulic machine, the<br />

quality of the relatively expensive tools<br />

made from hot work steel are the decisive<br />

factors in this process. In contrast,<br />

the fl ow properties and solidifi cation<br />

of the aluminium casting alloys play a<br />

rather subordinate role in this “forced”<br />

casting process.<br />

The pouring operation in horizontal pressure<br />

die casting begins with the casting<br />

chamber being fi lled with metal. The<br />

fi rst movement, i.e. the slow advance of<br />

the plunger and the consequent pile-up<br />

of metal until the sleeve is completely<br />

fi lled, is the most important operation.<br />

In doing this, no fl ashover of the metal<br />

or other turbulence may occur until all of<br />

the air in the sleeve has been squeezed<br />

out. Immediately afterwards, the actual<br />

casting operation begins with the rapid<br />

casting phase. High injection pressure is<br />

essential to achieve high fl ow velocities<br />

in the metal. In this way, the die can be<br />

fi lled in a few hundredths of a second.<br />

Throughout the casting operation, the<br />

liquid metal streams are subject to the<br />

laws of hydrodynamics. Sharp turns<br />

and collisions with the die walls lead<br />

to a clear division of the metal stream.<br />

32<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Parts generated using the horizontal<br />

pressure die casting process are lightweight<br />

as low wall thicknesses can be<br />

achieved. They have a good surface<br />

fi nish, high dimensional accuracy and<br />

only require a low machining allowance<br />

in their design. Many bore holes can be<br />

pre-cast.<br />

The melting and casting temperatures<br />

should not be too low and should be<br />

checked constantly. Pre-melting alu-<br />

minium casting alloys is useful. The melt<br />

can thus be given a good clean in order<br />

to keep the melt homogeneous and to<br />

avoid undesirable gravity segregation<br />

(see Figure 6). From a statistical point<br />

of view, more casting defects arise from<br />

cold metal than from hot. It is particu-<br />

larly important to keep a suffi ciently high<br />

melting temperature, even with hypere-<br />

utectic alloys. These comments are also<br />

valid for other casting processes.<br />

Gravity die casting process<br />

The gravity die casting which includes<br />

the well-known low-pressure die casting<br />

process is applied. The main fi elds of<br />

application are medium- or high-volume<br />

production using high-grade alloys, and<br />

also low to medium component weight<br />

using heat-treatable alloys. Compared<br />

with sand casting, the aluminium castings<br />

display very good microstructural<br />

properties as well as good to very good<br />

mechanical properties which result from<br />

the rapid cooling times and the other<br />

easily-controlled operating parameters.<br />

The castings have high dimensional accuracy<br />

and stability as well as a good<br />

surface fi nish, are heat-treatable and<br />

can also be anodised.<br />

The basis for good quality castings is,<br />

not least, the right melt treatment and<br />

the appropriate casting temperature (see<br />

section on “Melt quality and melt cleaning”).<br />

For castings with high surface or<br />

microstructural quality requirements,<br />

such as in decorative or subsequently<br />

anodised components or in pressuretight<br />

hydraulic parts, it is useful to fi lter<br />

the melt before casting.


Demands on the casting system<br />

To keep disadvantages and defects –<br />

which constantly arise from an oxide<br />

skin forming on the melt – within limits,<br />

the gating system must guarantee low<br />

turbulence in the metal stream and also<br />

a smooth, controlled fi lling of the die<br />

cavity. With the transition from a liquid<br />

to a solid condition, volume contraction<br />

occurs; this can amount to up to 7 %<br />

of the volume. This shrinkage is controllable<br />

when the solid-liquid interface<br />

runs – controlled or directed – through<br />

the casting, mostly from the bottom to<br />

the top. This task, namely to effect a<br />

directed solidifi cation, can be achieved<br />

with a good pouring system.<br />

The castings are usually arranged “upright”<br />

in the die. The greatest mass can<br />

thus be placed in the bottom of the die.<br />

Quality requirements can be, for example,<br />

high strength, high-pressure tightness or<br />

decorative anodising quality.<br />

One example of an “ideal” gating system<br />

which meets the highest casting requirements<br />

is the so-called “slit gate system”.<br />

Here, the metal is conducted upwards<br />

continuously or discontinuously to the<br />

casting via a main runner. During mould<br />

fi lling, the melt is thus superimposed layer<br />

upon layer with the hotter metal always<br />

fl owing over the already solidifying metal.<br />

The standpipe ends in the top riser and<br />

supplies it with hot metal. This way, the<br />

solidifi cation can be directed from below,<br />

possibly supported by cooling, towards<br />

the top running through the casting and<br />

safeguarding the continuous supply of<br />

hot metal. When there is a wide fl are in<br />

the casting, the gating system has to be<br />

laid out on both sides. This symmetry en-<br />

sures a division of the metal and also an<br />

even distribution of the heat in the die.<br />

In low-pressure die casting, directing<br />

the solidifi cation by means of the gating<br />

system is not possible. Nor is there<br />

any great possibility of classic feeding.<br />

Directional solidifi cation is only possible<br />

by controlling the thermal balance of the<br />

die during casting. This mostly requires<br />

the installation of an expensive cooling-<br />

heating system.<br />

Simulation calculations for die fi lling and<br />

solidifi cation can be useful when laying<br />

out and designing the die and possibly<br />

the cooling. In actual production, the<br />

cooling and cycle time can be optimised<br />

by means of thermography (see section<br />

on “Solidifi cation simulation and ther-<br />

mography”).<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 33


Sand casting process<br />

This process is used especially for in-<br />

dividual castings, prototypes and small<br />

batch production. It is, however, also<br />

used for the volume production of cast-<br />

ings with a very complex geometry (e.g.<br />

inlet manifolds, cylinder heads or crank-<br />

cases for passenger vehicle engines).<br />

During shaping and casting, most large<br />

sand castings display in-plane expan-<br />

sion. With this fl at casting method, gating<br />

systems like those which are normal in<br />

gravity die casting for directing solidifi ca-<br />

tion are often not applicable. If possible,<br />

a superimposed fi lling of the die cavity<br />

should be attempted here.<br />

34<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Another generally valid casting rule for<br />

correct solidifi cation is to arrange risers<br />

above the thick-walled parts, cooling (e.g.<br />

by means of chills) at opposite ends. This<br />

way, the risers can perform their main<br />

task longer, namely to conduct the supply<br />

of molten metal into the contracted<br />

end. Insulated dies are often helpful.<br />

The cross-section ratio in the sprue system<br />

should be something like the following:<br />

Sprue :<br />

Sum of the runner cross-section :<br />

Sum of the gates:<br />

like 1 : 4 : 4.<br />

This facilitates keeping the run-in laun-<br />

der full and leads to a smoother fl ow<br />

of the metal. This way, the formation of<br />

oxides due to turbulence can be kept<br />

within limits. The main runner must lie<br />

in the drag, the gates in the cope. In the<br />

production of high-grade castings, it is<br />

normal to install ceramic fi lters or sieves<br />

made from glass fi bre. The selection of<br />

the casting process and the layout of<br />

the casting system should be carried<br />

out in close co-operation between the<br />

customer, designer and foundryman (see<br />

section on “<strong>Casting</strong>-compliant design”).


<strong>Casting</strong>-compliant design<br />

The following notes on the design of<br />

aluminium castings are provided to help<br />

exploit in full the advantages and design<br />

possibilities of near net shape casting.<br />

They also align practical requirements<br />

with material suitability.<br />

<strong>Aluminium</strong> casting alloys can be processed<br />

in practically all conventional<br />

casting processes, whereby pressure die<br />

casting accounts for the largest volume,<br />

followed by gravity die casting and sand<br />

casting. The most useful casting process<br />

is not only dependent on the number and<br />

weight of pieces but also on other technical<br />

and economic conditions (see section<br />

on “Selecting the casting process”).<br />

To fi nd the optimum solution and produce<br />

a light part as cheaply and rationally as<br />

possible, co-operation between the designer,<br />

caster and materials engineer is<br />

always necessary. Knowledge concerning<br />

the loads applied, the distribution of<br />

stress, the range of chemical loading and<br />

operation temperatures is important.<br />

In the valid European standard, DIN EN<br />

1706 for aluminium castings, there are<br />

strength values only for separately-cast<br />

bars using sand and gravity die casting.<br />

For samples cut from the cast piece,<br />

a reduction in the 0.2 % proof stress<br />

and ultimate tensile strength values of<br />

up to 70 % and a decrease in elongation<br />

of up to 50 % from the test bar can<br />

be anticipated. When the alloy and the<br />

casting process are specifi ed, so too is<br />

the next point within the framework of<br />

the design, i.e. determination of the die<br />

parting line. Die parting on one level is<br />

not only the cheapest for patterns and<br />

dies but also for subsequent working and<br />

machining. Likewise, every effort should<br />

be made to produce a casting without<br />

undercuts. This is followed by designing<br />

and determining the actual dimensions<br />

of the part. The constant guideline must<br />

be to achieve a defect-free cast structure<br />

wherever possible.<br />

Only through good cast quality can the<br />

technical requirements be met and the<br />

full potential of the casting alloy be exploited.<br />

Every effort and consideration<br />

must be made therefore to design a light,<br />

functionally effi cient part whose manu-<br />

facture and machining can be carried out<br />

as effi ciently as possible. For this and<br />

subsequent considerations, the use of<br />

solidifi cation simulation is available (see<br />

section on “Solidifi cation simulation and<br />

thermography”).<br />

<strong>Casting</strong> alloys shrink during solidifi ca-<br />

tion, i.e. their volume is reduced. This<br />

increases the risk of defects in the cast<br />

structure, such as cavities, pores or<br />

shrinkage holes, tears or similar. The<br />

most important requirement is thus to<br />

avoid material accumulations by hav-<br />

ing as even a wall thickness as possible.<br />

In specialist literature, the following lower<br />

limits for wall thickness are given:<br />

Sand castings: 3-4 mm<br />

Gravity die castings: 2-3 mm<br />

Pressure die castings: 1-1.5 mm.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 35


The minimum values are also dependent<br />

on the casting alloy and the elongation of<br />

the casting. In pressure die casting, the<br />

minimum wall thickness also depends<br />

on the position of and distance to the<br />

gate system.<br />

Generally speaking, the wall thickness<br />

should be as thin as possible and only<br />

as thick as necessary. With increasing<br />

wall thickness, the specifi c strength of<br />

the cast structure deteriorates.<br />

Determining casting-compliant wall<br />

thicknesses also means, especially with<br />

sand and gravity die casting, that the die<br />

must fi rst of all be fi lled perfectly. During<br />

subsequent solidifi cation, a dense cast<br />

structure can only occur if the shrinkage<br />

is offset by feeding from liquid melt. Here,<br />

a wall thickness extending upwards as a<br />

connection to the riser may be necessary.<br />

36<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Another possible way of avoiding material<br />

accumulations is to loosen the nodes.<br />

At points where fi ns cross, a mass accumulation<br />

can be prevented by staggering<br />

the wall layout.<br />

The corners where walls or fi ns meet<br />

should be provided with as large transi-<br />

tions as possible. Where walls of different<br />

thickness meet, the transitions should<br />

be casting-compliant.<br />

Where the casting size and process<br />

permit, bores should be pre-cast. This<br />

improves the cross-section ratio and<br />

structural quality.<br />

Apart from the points referred to above,<br />

a good design also takes account of<br />

practical points and decorative appear-<br />

ance as well as the work procedures<br />

and machining which follow the actual<br />

casting operation.<br />

Fettling the casting, i.e. removing the<br />

riser and feeders, must be carried out as<br />

effi ciently as possible. Grinding should<br />

be avoided where possible. Reworking<br />

and machining should also be easy to<br />

carry out. Machining allowances are to<br />

be kept as small as possible.<br />

Essential inspections or quality tests<br />

should be facilitated by constructive<br />

measures.


Solidifi cation simulation and thermography<br />

Solidifi cation simulation<br />

A basic aim in the manufacture of cast-<br />

ings is to avoid casting defects while<br />

minimising the amount of material in the<br />

recycling circuit.<br />

Optimisation of the manufacture of cast-<br />

ings with regard to casting geometry,<br />

gating and feeding system and cast-<br />

ing parameters can be achieved via<br />

numerical simulation of die fi lling and<br />

the mechanisms of solidifi cation on the<br />

computer. <strong>Casting</strong> defects can thus be<br />

detected in good time and the casting<br />

design and casting system optimised<br />

before the fi rst casting operation takes<br />

place. In principle, fl ow and thermal con-<br />

duction phenomena which occur during<br />

casting can be calculated numerically<br />

using simulation programmes.<br />

In calculation models, the casting and<br />

die geometry – which fi rst of all must be<br />

available in a CAD volume model – is thus<br />

divided into small volume elements (Finite<br />

Difference Method). The fl ow velocities<br />

and temperatures in the individual volume<br />

elements are then calculated using<br />

a numerical method.<br />

Possible positive effects of simulation<br />

calculations include:<br />

Optimisation of the casting before<br />

casting actually takes place<br />

Avoiding casting defects<br />

Optimisation of the feeding system<br />

(reducing material in the recycling<br />

circuit)<br />

Optimisation of the casting<br />

process (reducing cycle times)<br />

Increasing process stability<br />

Visualisation of the die-fi lling and<br />

solidifi cation process.<br />

A simulation programme does not opti-<br />

mise on its own and can not, and should<br />

not, replace the experienced foundry-<br />

man. To exploit the potential of die-fi lling<br />

and solidifi cation simulation to the full,<br />

it should be applied as early as possible,<br />

i.e. already at the design stage of<br />

the casting.<br />

Thermography<br />

Even after a casting goes into volume<br />

production, it is often desirable and nec-<br />

essary to optimise the casting process<br />

and increase process stability. Besides<br />

the aforementioned solidifi cation simula-<br />

tion, periodic thermal monitoring of the<br />

dies by means of thermography is used<br />

in particular.<br />

In this process, a thermogramme of the<br />

die or casting to be investigated is made<br />

with the aid of an infrared camera. This<br />

way, the effectiveness of cooling, e.g. in<br />

pressure or gravity die casting, can be<br />

checked or optimised and the optimum<br />

time for lifting determined.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 37


Avoiding casting defects<br />

As shown in Table 4, there are two<br />

phenomena which – individually or in<br />

combination – can lead to defects in<br />

emergent castings:<br />

1. The continuous (new) formation of<br />

oxides in the liquid state and<br />

2. volume contraction during the transition<br />

from liquid to solid state.<br />

During transition from liquid to solid<br />

state, the dissolved hydrogen in the melt<br />

precipitates and, on interacting with oxides,<br />

causes the well-known problem of<br />

microporosity or gas porosity.<br />

The task of melt management and<br />

treatment is to keep oxide formation<br />

and, consequently, the dangers to cast<br />

quality within limits. Information about<br />

this is provided in the sections on “Melt<br />

38<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

quality and melt cleaning” as well as<br />

“Methods for melt monitoring” and “Se-<br />

lecting the casting process”. Here are a<br />

few key points:<br />

Use good quality ingots<br />

Quality-oriented melting technology<br />

and equipment<br />

Correct charging of the ingots<br />

(dry, rapid melting)<br />

Temperature control during<br />

melting and casting<br />

Melt cleaning and melt control<br />

Safety measures during treatment,<br />

transport and casting<br />

Volume contraction during the transition<br />

from liquid to solid state can - depending<br />

on the casting alloy - be up to 7 %<br />

volume. Under unfavourable conditions,<br />

part of this volume difference can be the<br />

cause of defects in castings, e.g. shrink<br />

marks, shrink holes, pores or tears. To<br />

produce a good casting, the possibility<br />

of feeding additional molten metal into<br />

the contracting microstructure during<br />

solidifi cation must exist. In pressure<br />

casting processes, this occurs by means<br />

of pressurisation; in gravity die casting,<br />

this is done primarily by feeding.<br />

The type of solidifi cation is also impor-<br />

tant when considering suitable casting/<br />

technical measures. In AlSi casting al-<br />

loys with approx. 13 % Si, a frozen shell<br />

forms during solidifi cation while, in hy-<br />

poeutectic AlSi casting alloys as well<br />

as in AlMg and AlCu casting alloys, a<br />

predominantly dendritic or globular so-<br />

lidifi cation occurs.<br />

In gravity die casting processes, the<br />

feeders are laid out in particularly critical<br />

or thick areas of the casting. The feed-<br />

ers require hot metal in appropriately<br />

large volumes to execute their task. The<br />

combination of feeding and cooling is<br />

useful. Heat removal to accelerate and<br />

control solidifi cation at the lower end<br />

of the casting or in solid areas can be<br />

effected by means of metal plates or<br />

surface chills (cooling elements).


As already shown in the section on cast-<br />

ing processes, an uncontrolled or tur-<br />

bulent fi lling of the die cavity can have a<br />

negative infl uence on the quality of the<br />

casting. A gating system which allows<br />

the solidifi cation front to be controlled<br />

upwards through the casting from the<br />

bottom up to the feeder is helpful. A<br />

good casting system, e.g. side stand<br />

pipe-slit gate, begins the fi lling in the<br />

lower part of the die and always layers<br />

the new hot metal on the lower, already<br />

solidifi ed part and also supplies the<br />

feeder with hot metal.<br />

A casting system of this type can par-<br />

tially cushion the negative effect caused<br />

by volume contraction while conducting<br />

the molten metal in such a way that fresh<br />

oxidation of the melt due to turbulence<br />

is avoided.<br />

Classifi cation of casting defects<br />

Source of defect Consequences Optimisation<br />

for the casting possibilities<br />

Oxidation and Pores Melt treatment<br />

hydrogen- Aeration and degassing<br />

absoption Inclusions Melting and<br />

Leakiness casting temperature<br />

Surface defects Filter<br />

Machining<br />

Loss of strength<br />

and elongation<br />

Volume contraction Cavity Gating system<br />

Shrinkage Solidifi cation control<br />

Aeration Feeding<br />

Leakiness Grain refi nement<br />

Loss of strength Modifi cation<br />

and elongation<br />

Two methods can be used to reduce<br />

the number of defective parts due to<br />

porosity: In hot isostatic pressing (HIP),<br />

porous castings are subjected to high<br />

pressure at elevated temperatures so<br />

that shrinkage and pores inside the castings<br />

are reduced; they do not, however,<br />

completely disappear. A second and<br />

less costly possibility is the sealing of<br />

castings by immersing them in plastic<br />

solutions. The shrinkage and pores,<br />

which extend to the surface, are fi lled<br />

with plastic and therefore sealed.<br />

Table 4<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 39


Heat treatment of aluminium castings<br />

Heat treatment gives users of castings<br />

the possibility of specifi cally improv-<br />

ing the mechanical properties or even<br />

chemical resistance. Depending on the<br />

casting type, the following common and<br />

applied methods for aluminium castings<br />

can be used:<br />

Stress relieving<br />

Stabilising<br />

Homogenising<br />

Soft annealing<br />

Age-hardening.<br />

The most important form of heat treatment<br />

for aluminium castings is artifi cial<br />

ageing. Further information is provided<br />

below.<br />

40<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Ageing time [h]<br />

Metallurgy – fundamental principles<br />

For age-hardening to take place, there<br />

must be a decreasing solubility of a par-<br />

ticular alloy constituent in the α-solid so-<br />

lution with falling temperature. As a rule,<br />

age-hardening comprises three steps:<br />

In solution annealing, suffi cient amounts<br />

of the important constituents for age-<br />

hardening are dissolved in the α-solid<br />

solution.<br />

With rapid quenching, these constituents<br />

remain in solution. Afterwards, the parts<br />

are relatively soft.<br />

Figure 11.1<br />

Yield strength of<br />

gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />

Yield strength R p0,2<br />

[MPa]<br />

280<br />

240<br />

200<br />

160<br />

120<br />

0<br />

0 2 4 6 8 10 12 14 16<br />

160 °C 180 °C 200 °C<br />

As-cast state<br />

In ageing, mostly artifi cial ageing, precipitation<br />

of the forcibly dissolved components<br />

takes place in the form of small<br />

sub-microscopically phases which cause<br />

an increase in hardness and strength.<br />

These tiny phases, which are technically<br />

referred to as “coherent or semicoherent<br />

phases”, represent obstacles<br />

to the movement of dislocations in the<br />

metal, thereby strengthening the previously<br />

easily-formable metal.<br />

The following casting alloy types are<br />

age-hardenable:<br />

Al Cu<br />

Al CuMg<br />

Al SiMg<br />

Al MgSi<br />

Al ZnMg.<br />

Figure 11.2<br />

Elongation of<br />

gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />

Elongation A5 [%]<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

0 2 4 6 8 10 12 14 16<br />

Ageing time [h]<br />

160 °C 180 °C 200 °C<br />

As-cast state


Solution annealing<br />

To bring the hardened constituents into<br />

solution as quickly as possible and in a<br />

suffi cient amount, the solution anneal-<br />

ing temperature should be as high as<br />

possible with, however, a safety margin<br />

of approx. 15 K to the softening point<br />

of the casting alloy in order to avoid incipient<br />

fusion. For this reason, it is often<br />

suggested that casting alloys containing<br />

Cu should undergo step-by-step solution<br />

annealing (at fi rst 480 °C, then 520 °C).<br />

The annealing time depends on the wall<br />

thickness and the casting process. Com-<br />

pared with sand castings, gravity die cast-<br />

ings require a shorter annealing time to<br />

dissolve the constituents suffi ciently due<br />

to their fi ner microstructure. In principle,<br />

an annealing time of around one hour<br />

Figure 11.3<br />

Tensile strength of<br />

gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />

Tensile strength Rm [MPa]<br />

360<br />

320<br />

280<br />

240<br />

200<br />

160<br />

0 2 4 6 8 10 12 14 16<br />

Ageing time [h]<br />

160 °C 180 °C 200 °C<br />

As-cast state<br />

suffi ces. The normally longer solution<br />

annealing times of up to 12 hours, as<br />

for example in Al SiMg alloys, produce<br />

a good spheroidising or rounding of the<br />

eutectic silicon and, therefore, a marked<br />

improvement in elongation.<br />

The respective values for age-hardening<br />

temperatures and times for the individual<br />

casting alloys can be indicated on the<br />

respective data sheets.<br />

During the annealing phase, the strength<br />

of the castings is still very low. They must<br />

also be protected against bending and<br />

distortion. With large and sensitive castings,<br />

it may be necessary to place them<br />

in special jigs.<br />

Quenching<br />

Hot castings must be cooled in water as<br />

rapidly as possible (5-20 seconds de-<br />

pending on wall thickness) to suppress<br />

any unwanted, premature precipitation of<br />

the dissolved constituents. After quench-<br />

ing, the castings display high ductility.<br />

This abrupt quenching and the ensuing<br />

increase in internal stresses can lead<br />

to distortion of the casting. Parts are<br />

often distorted by vapour bubble pressure<br />

shocks incurred during the rapid<br />

immersion of hollow castings. If this is<br />

a problem, techniques such as spraying<br />

under a water shower or quenching in<br />

hot water or oil have proved their value<br />

as a fi rst cooling phase.<br />

Nevertheless, any straightening work<br />

necessary at this stage should be carried<br />

out after quenching and before ageing.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 41


Ageing<br />

The procedure of ageing brings about<br />

the decisive increase in hardness and<br />

strength of the cast structure through<br />

the precipitation of the very small hardening<br />

phases. Only after this does the<br />

part have its defi nitive service properties<br />

and its external shape and dimensions.<br />

Common alloys mostly undergo artifi cial<br />

ageing. The ageing temperatures and<br />

times can be varied as required. In this<br />

Figure 11.4<br />

Brinell hardness of<br />

gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />

Brinell hardness<br />

[HB]<br />

160<br />

140<br />

120<br />

100<br />

80<br />

60<br />

0 2 4 6 8 10 12 14 16<br />

42<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Ageing time [h]<br />

160 °C 180 °C 200 °C<br />

As-cast state<br />

way, for example, the mechanical prop-<br />

erties can be adjusted specifi cally to at-<br />

tain high hardness or strength although,<br />

in doing this, relatively lower elongation<br />

must be reckoned with. Conversely, high<br />

elongation can be also achieved while<br />

lower strength and hardness values will<br />

be the result. When selecting the ageing<br />

temperatures and times, it is best to<br />

refer to the ageing curves which have<br />

been worked out for many casting alloys<br />

(Figures 11.1-11.4).<br />

Infl uence of Magnesium<br />

on the tensile strength (Diez bars)<br />

In Al SiMg casting alloys, a further possibility<br />

of specifi cally adjusting strength<br />

and elongation arises from varying the<br />

Mg content in combination with different<br />

heat treatment parameters (Figure 12).<br />

Tensile strength Rm Alloy Al Si7 auf 99.9 base<br />

[MPa]<br />

300<br />

+ 200 ppm Sr + 1 kg/mt Al Ti3B1<br />

n=5<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

0 0.1 0.2 0.3 0.4 0.5 0.6<br />

8 h to 525 °C, H 2 O +6 h to 160 °C<br />

Magnesium [%]<br />

8 h to 525 °C, H 2 O As-cast state<br />

Figure 12


If the heat treatment does not work fi rst<br />

time, it can be repeated beginning with<br />

solution annealing. By doubling the solution<br />

time, a coarsening of the eutectic<br />

silicon can arise in the grain structure.<br />

Since the solution treatment is performed<br />

close to the alloy‘s melting temperature<br />

and the precipitation rate is highly sensitive<br />

to variations in ageing temperature,<br />

it is essential that a high degree<br />

of consistency and control is assured.<br />

Procedures used in artifi cial ageing 1)<br />

Regular maintenance, especially of the<br />

measuring and control equipment, is<br />

therefore absolutely essential.<br />

For slightly higher hardness or strength<br />

requirements, there is the non-standard<br />

possibility of “simplifi ed age-hardening”.<br />

This can be used in gravity die casting<br />

and pressure die casting when age-<br />

hardenable alloys are being poured.<br />

Decisive here is a further rapid cooling<br />

after ejection from the die, e.g. by immediately<br />

immersing the part in a bath<br />

Table 5<br />

<strong>Casting</strong> type Example Solution heat treatment Age-hardening<br />

Temperature Time Temperature Time<br />

[°C] [h] [°C] [h]<br />

Al SiMg Al Si10Mg 530 4 - 10 160 - 170 6 - 8<br />

Al SiCu Al Si9Cu3 480 6 - 10 155 - 165 6 - 2<br />

Al MgSi Al Mg3Si 550 4 - 10 155 - 175 8 - 0<br />

Al CuMg 530* 8 - 18 140 - 170 6 - 8<br />

1) Typical temperature and time values<br />

* Poss. gradual annealing at approx. 480 °C / approx. 6 h<br />

of water. Artifi cial ageing in a furnace at<br />

approx. 170 °C brings about the desired<br />

increase in hardness and strength.<br />

The procedure used in artifi cial ageing as<br />

well as typical temperatures and times<br />

are shown in Table 5.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 43


Mechanical machining of aluminium castings<br />

In general, parts made from aluminium<br />

casting alloys are easy-machinable.<br />

This also applies for all metal-cutting<br />

processes. Low cutting force allows a<br />

high volume of metal to be removed. The<br />

surface fi nish of the cast piece depends<br />

on the machining conditions, such as<br />

cutting speed, cutting geometry, lubrication<br />

and cooling.<br />

The high cutting speeds required in aluminium<br />

to achieve minimum roughness<br />

necessitate, with regard to processing<br />

machines and tools, stable, vibrationfree<br />

construction and good cutting tools.<br />

Besides the microstructure – including<br />

defects, pores or inclusions – the silicon<br />

content of the casting has a strong effect<br />

on tool wear. Modifi ed, hypoeutectic<br />

AlSi casting alloys have, e.g. the highest<br />

tool time, while hypereutectic aluminium-<br />

silicon piston casting alloys can cause<br />

very considerable tool wear.<br />

44<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

With softer materials and also with most<br />

hypoeutectic AlSi casting alloys, narrow<br />

tools, i.e. with a large rake angle, cause<br />

the least possible surface roughness.<br />

These casting alloys produce narrow-<br />

spiral or short-breaking turnings. When<br />

machining aluminium, suitable emul-<br />

sions with water are used as cooling<br />

agents and lubricants. Friable and chips<br />

and fi ne to powdery Si dust arise when<br />

machining hypereutectic casting alloys.<br />

In combination with the lubricant, this<br />

powder produces an abradant which is<br />

often processed when dry. In some respects,<br />

the machining of these casting<br />

alloy types is similar to grey cast iron.<br />

With workpieces made from Al Si12<br />

casting alloys with their very soft matrix,<br />

a large volume of long curly spirals are<br />

produced. In addition, the plastic material<br />

tends to build up edges on the tool.<br />

This leads to lubrication and, as a result,<br />

a poor surface appearance. When this<br />

occurs, it often gives the machinist the<br />

subjective impression of bad machinability<br />

although tool wear is not the cause<br />

in this case.<br />

High-speed steel and hard metal or<br />

ceramic plates are used as cutting tool<br />

materials; for microfi nishing, diamonds<br />

are often utilised.<br />

The following machining allowances are<br />

given for the main casting processes:<br />

sand castings: 1.5-3 mm<br />

gravity die castings: 0.7-1.5 mm<br />

pressure die castings: 0.3-0.5 mm.<br />

In order to minimise value losses, turnings<br />

and chips should be sorted out according<br />

to casting alloy type and stored possibly<br />

in briquettes. In addition, dampness,<br />

grease and free iron reduce the value of<br />

chips and turnings. <strong>Aluminium</strong> chips and<br />

turnings are not hazardous materials and<br />

there is no risk of fi re during storage.<br />

When grinding aluminium parts, explosion-<br />

proof separation of the dust is stipulated.


Welding and joining aluminium castings<br />

Suitability and behaviour<br />

Similar to most wrought aluminium alloys,<br />

castings made from aluminium casting<br />

alloys can, in principle, also be joined by<br />

means of fusion welding. Near-eutectic<br />

and hypoeutectic aluminium-silicon cast-<br />

ing alloys are the best to weld. Poor to<br />

unweldable are parts made from Al Cu4Ti<br />

alloys types since the Cu-content can<br />

cause the casting alloy to crack during<br />

welding. In AlMg casting alloys, the ten-<br />

dency to tearing must be counteracted<br />

by selecting a suitable weld fi ller.<br />

Applications in the aluminium sector<br />

Although near net shape casting gives<br />

the designer the greatest possible freedom<br />

in the design of castings, welding is<br />

becoming increasingly important for the<br />

joining of aluminium cast components,<br />

either for welding two or more easy-tocast<br />

parts (e.g. half shells) – whereas<br />

they would be diffi cult to cast as one –<br />

to form hollow bodies on the one hand<br />

or for joining extruded sections or sheet<br />

to castings to give a subassembly on<br />

the other, such as the case in vehicle<br />

construction, lamp posts, lamp fi ttings<br />

and heat exchangers.<br />

The production welding sector should<br />

not be underestimated, e.g. for repairing<br />

defects in castings. Besides casting<br />

defects, there is also the possibility of<br />

correcting dimensional discrepancies,<br />

removing wear by build-up welding and<br />

repairing broken components.<br />

Welding processes<br />

The most frequently used fusion weld-<br />

ing processes for joining castings are<br />

metallic-insert-gas welding (MIG weld-<br />

ing) and Tungsten-inert-gas welding<br />

(TIG welding).<br />

Metal inert-gas welding (MIG welding)<br />

In MIG welding, an inert-gas arc weld-<br />

ing process, a continuous arc burns<br />

between a melting wire electrode and<br />

the workpiece. The process works with<br />

direct current, the wire electrode acting<br />

as the positive pole. The process is carried<br />

out under an inert gas in order to<br />

protect the melt area from the hazardous<br />

infl uences of the oxygen contained<br />

in air and moisture. Argon and/or helium,<br />

both inert gases, are used as shielding<br />

gases. Normally, it is cheaper to weld<br />

using argon. The process is suitable<br />

for both manual welding and for fully-<br />

mechanised and automatic welding. In<br />

fully-mechanised and automatic welding,<br />

both the power source and burner are<br />

water-cooled. With the wire electrode<br />

acting as the positive pole, the energy<br />

density is so high that it is able to break<br />

open the tenacious and high-melting<br />

oxide layer by means of local, explosive<br />

metal vaporisation underneath the oxide.<br />

With appropriate heat conduction,<br />

it is possible to achieve a relatively narrow<br />

heat-affected zone with satisfactory<br />

strength and elongation values.<br />

A further development of MIG welding is<br />

represented by MIG pulse welding. Here,<br />

the welding current alternates between a<br />

so-called pulsed current and background<br />

current. Using this process, it is possible<br />

to carry out diffi cult tasks, i.e. thin wall<br />

thicknesses (1 mm) and out-of-position<br />

work (overhead).<br />

Today, MIG welding is the most frequently<br />

used aluminium welding process because,<br />

in addition to its easy manipulation,<br />

the investment and running costs<br />

are favourable.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 45


Tungsten-insert-gas welding<br />

(TIG welding)<br />

In TIG welding, an inert-gas shielded<br />

arc welding process, an arc burns continuously<br />

between a non-consumable<br />

electrode made of a tungsten alloy and<br />

the casting. Alternating current is normally<br />

used when welding aluminium. The<br />

welding fi ller is fed in separately from<br />

outside either by hand or mechanically.<br />

The process is carried out under an inert<br />

gas in order to protect the melt area<br />

from the hazardous infl uences of the<br />

oxygen contained in air and moisture.<br />

Argon and/or helium, both inert gases,<br />

are used as shielding gases. Welding is<br />

usually carried out with alternating current<br />

and argon which is cheaper. This is<br />

primarily a manual welding process but<br />

there is a possibility to work with a full<br />

degree of mechanisation. In TIG welding,<br />

the power source and the burner are<br />

both water-cooled. By using alternating<br />

current, the tenacious and high-melting<br />

oxide layer is broken open during welding,<br />

similar to the MIG process. Welding<br />

normal diameter material with direct<br />

current and a reverse-polarity tungsten<br />

electrode would lead to destruction due<br />

to electric overload. The electrode diameter,<br />

however, can not be increased since<br />

the current density required for welding<br />

is no longer suffi cient.<br />

46<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

In one process variant, which has an<br />

electrode with negative polarity as in the<br />

welding of steel, welding is carried out<br />

using direct current under a helium shield.<br />

Compared with argon, helium displays<br />

better thermal conductivity so that less<br />

current is required to break open the oxide<br />

layer. Consequently, the electrode is<br />

not overloaded. In TIG welding, there are<br />

also process variants which work with<br />

the pulsed-current technique.<br />

With regard to freedom from porosity,<br />

the cleanest seams can be achieved<br />

using TIG welding. One disadvantage<br />

of the TIG welding process, however, is<br />

the high local energy input. This leads<br />

to considerable softening of the zone<br />

adjacent to the weld which is also the<br />

case with MIG welding. TIG welding, for<br />

example, is an excellent process for the<br />

repair of small casting defects. Compared<br />

with the MIG process, however,<br />

TIG welding operates at lower speeds.<br />

Other thermal joining processes<br />

The group of so-called “pressure welding<br />

processes” also includes friction stear<br />

welding (FSW) which is frequently used<br />

for welding aluminium castings. Since this<br />

welding process works without any fi ller<br />

material, it is possible to join materials<br />

together which are not fusion-weldable<br />

since they would form brittle inter-metallic<br />

phases. By means of friction welding,<br />

aluminium and steel, for example, can<br />

be joined together.<br />

The principle behind the process is to heat<br />

the workpieces up to a pasty condition<br />

followed by subjecting them to strong<br />

compression. A weld upset is thus developed<br />

and, if necessary, subsequently<br />

machined. The heating is done by rotating<br />

one or both parts and fi nally pressing<br />

them against each other until they<br />

stop moving. It even allows workpieces<br />

of circular and square cross-sections to<br />

be joined together.<br />

As a result of the rotary movement and<br />

in order to keep the compression load<br />

from increasing too much, a certain crosssectional<br />

area may not be exceeded.<br />

Another welding process is represented<br />

by electron beam welding. Particular interest<br />

is being shown in this process at<br />

the moment for the welding of aluminium<br />

pressure die castings.


The process operates mostly under high<br />

vacuum. There are also process variants<br />

which work under partial vacuum and<br />

atmosphere although in these the advan-<br />

tages of this welding process, namely the<br />

production of narrower seams even with<br />

thick workpieces, are extensively lost.<br />

The welding of workpieces takes place<br />

without fi ller material. The welding energy<br />

is imparted by means of a bundled<br />

electron beam which is directed at the<br />

welding point. The electron beams are<br />

generated like those of a cathode ray<br />

tube (television) in a high vacuum. Using<br />

electron-optical focussing, different distances<br />

to the workpiece can be had with<br />

this equipment, even when the workpiece<br />

has undulating contours. Welding inside<br />

closed containers is possible.<br />

In addition to diffi cult-to-weld pressure<br />

die castings, e.g. inlet manifolds, this<br />

process has been successfully used with<br />

cast semi-fi nished products in heat exchangers<br />

and in the welding of pistons<br />

for internal combustion engines.<br />

Weld preparation<br />

To produce a sound weld, it is necessary<br />

to observe certain “rules”. Weld preparation<br />

must match the welding process<br />

being used and the wall thicknesses to<br />

be joined. Excessive oxide formation is<br />

worked off by metal-cutting. When grinding,<br />

resin-bonded grinding discs may<br />

not be used (danger of pore formation).<br />

Another possible way of removing oxides<br />

is to etch the component. Grease<br />

and dirt in the welding area have to be<br />

removed using suitable means (danger<br />

of pore formation). Components with<br />

greater wall thicknesses to be joined<br />

should be pre-heated before welding.<br />

Weld fi ller materials<br />

Weld fi ller materials are standardised.<br />

The selection of weld fi ller materials is<br />

guided by the materials of the parts to<br />

be joined. For the most commonly used<br />

aluminium materials, such as near- and<br />

hypoeutectic AlSi casting alloys as<br />

well as age-hardenable Al Si10Mg and<br />

Al Si5Mg variants, S-Al Si12 and S-Al Si5<br />

weld fi ller materials are recommended.<br />

A great danger in welding is the tendency<br />

of many materials to form cracks during<br />

the transition from liquid to solid state.<br />

The cause of these cracks is weld shrink-<br />

age stresses which occur during cooling.<br />

Often the low melting point phases of<br />

the weld fi ller materials are insuffi cient<br />

to “heal” the cracks arising. Through the<br />

selection of a softer weld fi ller material<br />

with a larger share of low melting point<br />

phases, this danger is reduced. In doing<br />

this, however, the optimum strength<br />

properties in the weld seam must be<br />

frequently foregone.<br />

The decorative anodisation of a welded<br />

joint with the aforementioned fi ller materials<br />

is not possible because the weld<br />

seam would appear dark. Technical anodic<br />

oxidation for protective and adhesive<br />

purposes is, however, always possible.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 47


Surface treatment: corrosion<br />

and corrosion protection<br />

<strong>Aluminium</strong> casting alloys – like wrought<br />

aluminium alloys – owe their corrosion<br />

resistance to a thin, tenacious coating<br />

layer of oxides and hydroxides. In the pH<br />

range from 4.5 to 8.5, this oxide layer is<br />

practically insoluble in aqueous media<br />

and aluminium casting materials suffer<br />

only negligible mass disappearance.<br />

This passivity can, however, be annulled<br />

locally at weak points in the oxide layer<br />

due to the action of water containing<br />

chloride. Since the aqueous medium,<br />

e.g. weather, only acts periodically, a<br />

protective oxide layer forms again at<br />

small, local corrosion sites, e.g. repassivation<br />

occurs. Deep pitting corrosion<br />

can only arise when there is a long-term<br />

effect from aggressive water containing<br />

chloride (e.g. sea water). Beside the<br />

chloride content, the amount of oxygen<br />

in the water also plays a role; corrosion<br />

reaction can only occur in neutral media<br />

(pH = 4.5-8.5) in the presence of<br />

oxygen. The remedy for this can come<br />

in the form of passive protection by<br />

coating or by means of active cathodic<br />

corrosion protection using a sacrifi cial<br />

anode, for example.<br />

Magnesium as an alloying element<br />

causes the formation of a thicker oxide<br />

layer containing MgO and, consequently,<br />

provides greater corrosion protection<br />

against water containing chlorides and<br />

48<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

slightly alkaline media (e.g. ammonia<br />

solutions) since magnesium oxide in<br />

contrast to aluminium oxide is insoluble<br />

in alkaline solutions.<br />

Copper as an alloying element causes<br />

a deterioration in corrosion properties.<br />

This increases slightly with a rising Cu-<br />

content in the range below 0.2 % copper,<br />

above 0.2 to 0.4 % more strongly.<br />

Already with a Cu-content of 0.2 %,<br />

permanent action from aqueous solutions<br />

containing chlorine can have a very<br />

negative effect on corrosion behaviour.<br />

The negative infl uence of iron on cor-<br />

rosion behaviour is not as distinctive<br />

as that of copper. With an Fe-content<br />

of up to 0.6 %, there is no signifi cant<br />

deterioration in the corrosion behaviour<br />

of casting alloys.<br />

The surface treatment of aluminium cast<br />

products is carried out to improve their<br />

corrosion resistance, for decorative<br />

purposes or to increase the strength<br />

of the components.<br />

A homogeneous, non-porous cast struc-<br />

ture free from shrink holes and cracks<br />

makes coating easier. The quality of the<br />

coating is infl uenced decisively by the<br />

pre-treatment.<br />

Wiping, immersion and steam degreasing<br />

(in that order) produce increasingly<br />

grease-free surfaces without removing<br />

the surface oxide fi lm. Grinding, brush-<br />

ing, abrasive blasting or polishing do not<br />

remove the oxide fi lm completely and,<br />

as a rule, act as a preparation to further<br />

surface treatment. Possible sources of<br />

defects leading to subsequent faults<br />

comprise the use of brushes made of<br />

brass or non-stainless steel as well as<br />

sand or steel shot.<br />

When grinding, the use of ceramic<br />

grinding elements without further pretreatment<br />

frequently leads to good paint<br />

adhesion. One precondition is that no<br />

fi nes from the grinding elements are<br />

pressed into the surface of the casting.<br />

Chemical degreasing agents with<br />

a pickling or etching effect remove the<br />

oxide layer and, as a consequence, all<br />

impurities. It is also worth mentioning<br />

that there is also matt or bright pickling<br />

before anodic oxidation to produce a<br />

special surface fi nish.<br />

Following the alkaline pickling of AlMg<br />

or AlSi casting alloys, the pickling fi lm<br />

must be removed by means of an acid<br />

after-treatment with nitric acid, nitric/<br />

hydrofl uoric acid or sulphuric/hydrofl<br />

uoric acid. Instead of alkaline pickling<br />

with fi nal dipping, it is more benefi cial<br />

to use an acidic fl uoride-containing<br />

pickling solution immediately.


Despite careful acid cleaning, a lacquered<br />

aluminium surface can still display<br />

adhesive failure after a certain time<br />

due to environmental effects. Firstly,<br />

a conversion layer, which forms as a<br />

result of the reaction between chemicals<br />

containing chrome and the metal,<br />

passivates the aluminium surface and<br />

protects it from the water diffused by<br />

each layer of lacquer. With respect to<br />

the promotion of adhesion and corrosion<br />

inhibition, the almost equivalent<br />

green and yellow chromate coatings<br />

have proved their worth over many<br />

years. A clear chromate coating, preferably<br />

used under clear lacquer, offers<br />

slightly less corrosion protection due<br />

to the layer being thinner. Cr-VI-free<br />

chromate-phosphate coatings meet the<br />

requirements of food processing and<br />

distribution laws and are permitted for<br />

the pre-treatment of aluminium which<br />

is used in food production, processing<br />

and packaging.<br />

A chrome-free epoxy primer should<br />

be mentioned as a possible but also<br />

qualitatively less favourable alternative.<br />

A precondition for the effectiveness of<br />

this alternate process, however, is also<br />

the removal of the aluminium oxide layer<br />

by chemical or mechanical means.<br />

Of the unlimited number of application<br />

techniques used for volume lacquering,<br />

electrostatic powder coating, whirl sin-<br />

tering and electrophoretic dip coating<br />

are to be stressed in particular because<br />

of their environmental soundness, in<br />

addition to the dip coating and spray-<br />

ing (air, airless and electrostatic) of wet<br />

paint containing solvents.<br />

With the aid of anodic oxidation, the<br />

fi nish achieved using mechanical or<br />

chemical surface treatment can be con-<br />

served permanently. These anodically<br />

produced oxide layers are connected<br />

solidly to the aluminium and, in contrast<br />

to lacquering, the surface structure of<br />

the original metal is unchanged. This<br />

can prove disadvantageous, especially<br />

in pressure die casting. In today‘s<br />

widely-used sulphuric acid anodising<br />

process, the anodically-formed oxide<br />

layers become resistant to touch (e.g.<br />

fi nger marking) and abrasion resistant<br />

after sealing in hot water and possess<br />

good electric strength. The appearance<br />

of anodically-oxidised aluminium castings<br />

is considerably infl uenced by the<br />

alloy composition and the microstructural<br />

condition. For decorative purposes,<br />

Al Mg3H, Al Mg3, Al Mg3Si, Al Mg5,<br />

Al Mg5Si and Al 99.5 and/or Al 99.7<br />

casting alloys have proved their worth.<br />

A decorative anodic oxidation of alloys<br />

with an Si-content > 1 % is not possible<br />

(with the exception of Al Si2MgTi).<br />

The possibility of producing coloured<br />

oxide layers also exists by means of dip<br />

painting, electrolytic colouring and integral<br />

colouring in special electrolytes<br />

(integral process).<br />

For surfaces which have to meet particular<br />

requirements with regard to hardness,<br />

resistance to abrasion and wear, sliding<br />

capacity and electric strength, the<br />

special possibility of using hard anodising<br />

should be taken into consideration.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 49


Information on physical data, strength properties<br />

and strength calculations<br />

The SI unit for force is the Newton (N).<br />

Strength, or proof stress, is expressed in<br />

“MPa” (Mega Pascal). The Brinell hard-<br />

ness of aluminium parts is excluded from<br />

this regulation.<br />

For the tensile strength, 0.2 proof stress,<br />

elongation and Brinell hardness of cast-<br />

ings, DIN EN 1706 contains only binding<br />

minimum values at room temperature<br />

for separately-cast test bars using sand<br />

casting, gravity die casting and invest-<br />

ment casting. The mechanical values<br />

for pressure die cast samples are not<br />

binding and are included only for information.<br />

The values for fatigue strength<br />

or endurance are valid for the best available<br />

casting process and again are only<br />

for information. For samples taken from<br />

the casting, DIN EN 1706 sets out the<br />

following: with respect to the 0.2 proof<br />

stress and tensile strength, the values<br />

reached in castings can be above the<br />

set values in the tables (for separatelycast<br />

test pieces) but not below 70 % of<br />

these set values. With regard to elongation,<br />

the values determined for the<br />

castings can be above the set values<br />

in the tables (for separately-cast test<br />

pieces) or at certain critical points up<br />

to 50 % below these values. Individual<br />

details about the mechanical, physical<br />

and other properties as well as the approximate<br />

working fi gures can be taken<br />

from the casting alloy sheets.<br />

50<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

The actual values reached in the casting<br />

depend on the casting/technical measures<br />

taken, the solidifi cation speed and<br />

also, where applicable, the heat treat-<br />

ment. When the end product has to meet<br />

special requirements, an appropriate<br />

casting alloy is required which, corre-<br />

spondingly, also incurs higher casting/<br />

technical expenses. A few details for<br />

calculating the strength of constructions<br />

which are subjected to static stress are<br />

given below. With dynamic stress, lower<br />

values are estimated.<br />

Surface pressure:<br />

p = approx. 0.8 R [MPa]<br />

p0,2<br />

Shear strength:<br />

B = approx. 0.5 R [MPa]<br />

p0,2<br />

Modulus of elasticity in shear:<br />

G = approx. 0.4 modulus of<br />

elasticity [GPa]<br />

Modulus of elasticity:<br />

E = approx. 70 GPa<br />

Yield strength of gravity die cast samples<br />

Strength at varying temperatures<br />

At low temperatures, the strength and<br />

elongation values of aluminium parts<br />

scarcely change. Due to the crystal<br />

structure of aluminium alloys, no sharp<br />

decrease in impact ductility can occur<br />

at low temperatures – as can happen<br />

with some ferrous metals.<br />

At higher temperatures, the strength and<br />

hardness values decrease while elongation<br />

increases. Up to approx. +150 °C,<br />

these changes are relatively small. With<br />

further increases in temperature, strength<br />

and hardness decrease even more and<br />

elongation rises. Table 6 depicts the 0.2<br />

proof stress values for gravity die cast<br />

samples at various test temperatures.<br />

Table 6<br />

Alloy / Temper Yield strength Rp0,2 [MPa]<br />

-100 °C +20 °C +100 °C +200 °C +250 °C<br />

Al Mg3Si T6 160 150 140 60 30<br />

Silumin F 120 80 60 40 30<br />

Al Si12Cu F 110 90 80 35 30<br />

Al Si8Cu3 F 120 100 90 50 25<br />

Silumin-Kappa F 90 80 70 50 30<br />

Al Mg5Si T6 130 120 110 100 70<br />

Al Si18CuNiMg F 180 170 150 100 80<br />

Al Si12CuNiMg F 200 190 170 100 70<br />

Al Si10MgCu T6 220 200 170 80 35<br />

Pantal 7 T6 215 210 180 80 30<br />

Silumin-Beta T6 220 210 200 80 30<br />

Pantal 5 T6 220 210 200 80 30


Notes on the casting alloy tables<br />

The following tables contain all standard-<br />

ised casting alloys in accordance with<br />

DIN EN 1676 as well as other common<br />

non-standardised alloys with details of<br />

their chemical composition. Provided that<br />

deviations are envisaged for castings,<br />

the corresponding details (in conformity<br />

with DIN EN 1706) are shown in brackets.<br />

Where available, the well-known and very<br />

commonly used VDS numbers (e.g. 231,<br />

226 etc.) are given in these lists.<br />

The aluminium casting alloys are arranged<br />

into seven families according to their typical<br />

casting and alloying similarities. The<br />

data, properties, rankings and standard<br />

values of the casting alloys, or the castings<br />

subsequently made from them, have been<br />

taken from DIN EN 1676 and 1706 or are<br />

based on these standards in the case of<br />

non-standardised alloys. The details are<br />

included for information only and do not<br />

represent any guarantees.<br />

Thermal and electrical conductivity are<br />

dependent on the chemical composition<br />

within the given specifi cation, solidifi ca-<br />

tion conditions and temper. In order to<br />

produce a casting with high conductivity,<br />

it is necessary to keep the content of alloying<br />

and accompanying elements low<br />

within the specifi cation.<br />

The following designation<br />

abbreviations are used in DIN EN 1676:<br />

A <strong>Aluminium</strong><br />

B Ingots (solid or liquid metal)<br />

In DIN EN 1706, the following<br />

abbreviations refer to product<br />

designations:<br />

A <strong>Aluminium</strong> casting alloy<br />

C <strong>Casting</strong><br />

The following abbreviations are used<br />

for the various casting processes:<br />

S Sand casting<br />

K Gravity die casting<br />

D Pressure die casting<br />

L Precision casting<br />

In DIN EN 1706, the following symbols<br />

apply for material conditions:<br />

F as cast<br />

O annealed<br />

T1 controlled cooling from casting<br />

and naturally aged<br />

T4 solution heat-treated and naturally<br />

aged where applicable<br />

T5 controlled cooling from casting<br />

and artifi cially aged or over-aged<br />

T6 solution heat-treated and fully<br />

artifi cially aged<br />

T64 solution heat-treated and artifi cially<br />

under-aged<br />

T7 solution heat-treated and artifi cially<br />

over-aged (stabilised)<br />

Chemical composition<br />

(all data in wt.-%)<br />

<strong>Casting</strong> characteristics and<br />

other properties<br />

Physical properties<br />

Mechanical properties at room<br />

temperature +20 °C<br />

Heat treatment of aluminium<br />

castings<br />

Mechanical properties of gravity<br />

die cast samples<br />

Processing guidelines<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 51


Overview: <strong>Aluminium</strong> casting alloys<br />

by alloy group<br />

Eutectic aluminium-silicon casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin min 12.5<br />

max 13.5 0.15 0.02 0.05 0.05 0.07 0.15 0.03 0.10 Na<br />

Al Si12(a) min 10.5<br />

max 13.5 0.40 0.03 0.35 0.10 0.15 0.05 0.15 Na<br />

(0.55) (0.05)<br />

44200 / 230<br />

Al Si12(b) min 10.5<br />

max 13.5 0.55 0.10 0.55 0.10 0.10 0.15 0.10 0.15 0.05 0.15<br />

(0.65) (0.15) (0.20)<br />

44100<br />

Al Si12(Fe)(a) min 10.5 0.45<br />

max 13.5 0.9 0.08 0.55 0.15 0.15 0.05 0.25<br />

(1.0) (0.10)<br />

44300 / 230D<br />

Al Si12(Fe)(b) min 10.0 0.45<br />

max 13.5 0.9 0.18 0.55 0.40 0.30 0.15 0.05 0.25<br />

(1.0) (0.20)<br />

44500<br />

Al Si12(Cu) min 10.5 0.05<br />

max 13.5 0.7 0.9 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />

(0.8) (1.0) (0.20)<br />

47000 / 231<br />

Al Si12Cu1(Fe) min 10.5 0.6 0.7<br />

max 13.5 1.1 1.2 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />

(1.3) (0.20)<br />

47100 / 231D<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

Near-eutectic wheel casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin-Kappa Sr min 10.5 0.05<br />

max 11.0 0.15 0.02 0.10 0.25 0.07 0.15 0.03 0.10 Sr<br />

Silumin-Beta Sr min 9.0 0.20<br />

max 10.5 0.15 0.02 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />

Al Si11 min 10.0<br />

max 11.8 0.15 0.03 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />

(0.19) (0.05)<br />

44000<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

52<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


The 10 per cent aluminium-silicon casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin-Beta / Al Si9Mg min 9.0 0.30<br />

(0.25)<br />

max 10.0 0.15 0.03 0.10 0.45<br />

(0.19) (0.05) (0.45) 0.07 0.15 0.03 0.10 Na<br />

43300<br />

Al Si10Mg(a) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.40 0.03 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15 Na<br />

(0.55) (0.05) (0.45)<br />

43000 / 239<br />

Al Si10Mg(b) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.45 0.08 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />

(0.55) (0.10) (0.45)<br />

43100<br />

Al Si10Mg(Fe) min 9.0 0.45 0.25<br />

(0.20)<br />

max 11.0 0.9 0.08 0.55 0.50 0.15 0.15 0.15 0.05 0.15 0.05 0.15<br />

(1.0) (0.10) (0.50) (0.20)<br />

43400 / 239D<br />

Al Si10Mg(Cu) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.55 0.30 0.55 0.45 0.15 0.35 0.10 0.15 0.05 0.15<br />

(0.65) (0.35) (0.45) (0.20)<br />

43200 / 233<br />

Al Si9 min 8.0<br />

max 11.0 0.55 0.08 0.50 0.10 0.05 0.15 0.05 0.05 0.15 0.05 0.15<br />

(0.65) (0.10)<br />

44400<br />

Silumin-Delta min 9.0 0.3 0.3<br />

max 10.5 0.4 0.02 0.4 0.03 0.07 0.15 0.03 0.10<br />

Silumin-Gamma min 9.0 0.4 0.15<br />

max 11.3 0.15 0.02 0.9 0.6 0.10 0.15 0.03 0.10 Sr<br />

Al Si10MnMg min 9.0 0.40 0.15<br />

(0.10)<br />

max 11.5 0.20 0.03 0.80 0.60 0.07 0.15 0.05 0.15 Sr<br />

(0.25) (0.05) (0.60) (0.20)<br />

43500<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 53


Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />

The 7 und 5 per cent aluminium-silicon casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Pantal 7 / Al Si7Mg0.3 min 6.5 0.30<br />

(0.25)<br />

max 7.5 0.15 0.03 0.10 0.45 0.07 0.18 0.03 0.10 Na / Sr<br />

(0.19) (0.05) (0.45) (0.25)<br />

42100<br />

Al Si7Mg0.6 min 6.5 0.50<br />

(0.45)<br />

max 7.5 0.15 0.03 0.10 0.70 0.07 0.18 0.03 0.10<br />

(0.19) (0.05) (0.70) (0.25)<br />

42200<br />

Al Si7Mg min 6.5 0.25<br />

(0.20)<br />

max 7.5 0.45 0.15 0.35 0.65 0.15 0.15 0.15 0.05 0.20 0.05 0.15<br />

(0.55) (0.20) (0.65) (0.25)<br />

42000<br />

Pantal 5 min 5.0 0.40 0.05<br />

max 6.0 0.15 0.02 0.10 0.80 0.07 0.20 0.03 0.10<br />

Al Si5Mg min 5.0 0.40 0.05<br />

max 6.0 0.3 0.03 0.4 0.80 0.10 0.20 0.05 0.15<br />

- / 235<br />

Al Si5Cu1Mg min 4.5 1.0 0.40<br />

(0.35)<br />

max 5.5 0.55 1.5 0.55 0.65 0.25 0.15 0.15 0.05 0.20 0.05 0.15<br />

(0.65) (0.65) (0.25)<br />

45300<br />

Al Si7Cu0.5Mg min 6.5 0.2 0.25<br />

(0.20)<br />

max 7.5 0.25 0.7 0.15 0.45<br />

(0.45)<br />

0.07 0.20 0.03 0.10<br />

45500<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

54<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Al SiCu casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total<br />

Al Si8Cu3 min 7.5 2.0 0.15 0.15<br />

(0.05)<br />

max 9.5 0.7 3.5 0.65 0.55 0.35 1.2 0.25 0.15 0.20 0.05 0.25<br />

(0.8) (0.55) (0.25)<br />

46200 / 226<br />

Al Si9Cu3(Fe) min 8.0 0.6 2.0 0.15<br />

(0.05)<br />

max 11.0 1.1 4.0 0.55 0.55 0.15 0.55 1.2 0.35 0.15 0.20 0.05 0.25<br />

(1.3) (0.55) (0.25)<br />

46000 / 226D<br />

Al Si11Cu2(Fe) min 10.0 0.45 1.5<br />

max 12.0 1.0 2.5 0.55 0.30 0.15 0.45 1.7 0.25 0.15 0.20 0.05 0.25<br />

(1.1) (0.25)<br />

46100<br />

Al Si7Cu3Mg min 6.5 3.0 0.20 0.35<br />

(0.30)<br />

max 8.0 0.7 4.0 0.65 0.60 0.30 0.65 0.15 0.10 0.20 0.05 0.25<br />

(0.8) (0.60) (0.25)<br />

46300<br />

Al Si9Cu1Mg min 8.3 0.8 0.15 0.30<br />

(0.25)<br />

max 9.7 0.7 1.3 0.55 0.65 0.20 0.8 0.10 0.10 0.18 0.05 0.25<br />

(0.8) (0.65) (0.20)<br />

46400<br />

Al Si9Cu3(Fe)(Zn) min 8.0 0.6 2.0 0.15<br />

(0.05)<br />

max 11.0 1.2 4.0 0.55 0.55 0.15 0.55 3.0 0.35 0.15 0.20 0.05 0.25<br />

(1.3) (0.55) (0.25)<br />

46500 / 226/3<br />

Al Si7Cu2 min 6.0 1.5 0.15<br />

max 8.0 0.7 2.5 0.65 0.35 0.35 1.0 0.25 0.15 0.20 0.05 0.15<br />

(0.8) (0.25)<br />

46600<br />

Al Si6Cu4 min 5.0 3.0 0.20<br />

max 7.0 0.9 5.0 0.65 0.55 0.15 0.45 2.0 0.30 0.15 0.20 0.05 0.35<br />

(1.0) (0.25)<br />

45000 / 225<br />

Al Si5Cu3Mg min 4.5 2.6 0.20<br />

(0.15)<br />

max 6.0 0.50 3.6 0.55 0.45 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />

(0.60) (0.45) (0.25)<br />

45100<br />

Al Si5Cu3 min 4.5 2.6<br />

max 6.0 0.50 3.6 0.55 0.05 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />

(0.60) (0.25)<br />

45400<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

Others<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 55


Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />

AlMg casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Al Mg3(H) min 2.7<br />

max 0.45 0.15 0.02 0.40 3.2 0.07 0.02 0.03 0.10 B/Be<br />

Al Mg3 min 2.7<br />

(2.5)<br />

max 0.45 0.40 0.03 0.45 3.5 0.10 0.15 0.05 0.15 B/Be<br />

(0.55) (0.55) (0.05) (3.5) (0.20)<br />

51100 / 242<br />

Al Mg3(Cu) min 2.5<br />

max 0.60 0.55 0.15 0.45 3.2 0.30 0.20 0.05 0.15 B/Be<br />

- / 241<br />

Al Mg3Si(H) min 0.9 2.7<br />

max 1.3 0.15 0.02 0.40 3.2 0.07 0.15 0.03 0.10 B/Be<br />

Al Mg5 min 4.8<br />

(4.5)<br />

max 0.35 0.45 0.05 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />

(0.55) (0.55) (0.10) (6.5) (0.20)<br />

51300 / 244<br />

Al Mg5(Si) min 4.8<br />

(4.5)<br />

max 1.3 0.45 0.03 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />

(1.5) (0.55) (0.05) (6.5) (0.20)<br />

51400 / 245<br />

Al Mg9(H) min 1.7 0.2 8.5<br />

max 2.5 0.50 0.02 0.5 10.5 0.07 0.15 0.03 0.10 B/Be<br />

Al Mg9 min 0.45 8.5<br />

(8.0)<br />

max 2.5 0.9 0.08 0.55 10.5 0.10 0.25 0.10 0.10 0.15 0.05 0.15 B/Be<br />

(1.0) (0.10) (10.5) (0.20)<br />

51200 / 349<br />

Al Mg5Si2Mn min 1.8 0.4 5.0<br />

(4.7)<br />

max 2.6 0.20 0.03 0.8 6.0 0.07 0.20 0.05 0.15<br />

(0.25) (0.05) (6.0) (0.25)<br />

51500<br />

Al Si2MgTi min 1.6 0.30 0.50 0.07<br />

(0.45) (0.05)<br />

max 2.4 0.50 0.08 0.50 0.65 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />

(0.60) (0.10) (0.65) (0.20)<br />

41000<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

56<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Casting</strong> alloys for special applications<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

High-strength casting alloys<br />

Al Cu4Ti min 4.2 0.15<br />

(0.15)<br />

max 0.15 0.15 5.2 0.55 0.07 0.25 0.03 0.10<br />

(0.18) (0.19) (0.30)<br />

21100<br />

Al Cu4MgTI min 4.2 0.20 0.15<br />

(0.15) (0.15)<br />

max 0.15 0.30 5.0 0.10 0.35 0.05 0.10 0.05 0.05 0.25 0.03 0.10<br />

(0.20) (0.35) (0.35) (0.30)<br />

21000<br />

Al Cu4MnMg min 4.0 0.20 0.20<br />

(0.15)<br />

max 0.10 0.15 5.0 0.50 0.50 0.03 0.05 0.03 0.03 0.05 0.03 0.10<br />

(0.20) (0.50) (0.05) (0.10) (0.10)<br />

21200<br />

Al Cu4MgTiAg min 4.0 0.01 0.15 0.5 Ag<br />

0.4<br />

max 0.05 0.10 5.2 0.50 0.35 0.05 0.35 0.03 0.10 1.0<br />

Al Cu5NiCoSbZr min 4.5 0.1 1.3 0.15 ****<br />

max 0.20 0.30 5.2 0.3 0.10 1.7 0.10 0.30 0.05 0.15<br />

Piston casting alloys<br />

Al Si12CuNiMg min 10.5 0.8 0.9<br />

(0.8)<br />

0.7<br />

max 13.5 0.6 1.5 0.35 1.5 1.3 0.35 0.20 0.05 0.15 P<br />

(0.7) (1.5) (0.25)<br />

48000 / 260<br />

Al Si18CuNiMg min 17.0 0.8 0.8 0.8<br />

max 19.0 0.3 1.3 0.10 1.3 1.3 0.10 0.15 0.05 0.15 P<br />

****) Co 0.10-0.40 Sb 0.10-0.30 Zr 0.10-0.30<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

Continuation of the table on the next page.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 57


Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />

<strong>Casting</strong> alloys for special applications<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg* min 16.0 4.0 0.5<br />

max 18.0 0.3 5.0 0.15 0.65 0.10 0.10 0.20 0.05 0.15 P<br />

Al Si17Cu4Mg** min 16.0 4.0 0.45<br />

(0.25)<br />

max 18.0 1.0 5.0 0.50 0.65 0.3 1.5 0.15 0.20 0.05 0.25<br />

(1.3) (0.65) (0.25)<br />

48100<br />

Self-hardening casting alloys<br />

Autodur min 8.5 0.3 9.5<br />

max 9.5 0.15 0.02 0.05 0.5 10.5 0.15 0.03 0.10<br />

Autodur (Fe)* min 8.5 0.3 9.5<br />

max 9.5 0.40 0.02 0.30 0.5 10.5 0.15 0.03 0.10<br />

Autodur (Fe)** min 7.5 0.25<br />

(0.20)<br />

9.0<br />

max 9.5 0.27 0.08 0.15 0.5 10.5 0.15 0.05 0.15<br />

(0.30) (0.10) (0.5)<br />

71100<br />

Rotor-<strong>Aluminium</strong><br />

Al 99.7E*** min<br />

max 0.07 0.20 0.01 0.005 0.02 0.004 0.04 Mn+Cr+ 0.03<br />

V+ Ti=<br />

0.02<br />

B 0.04<br />

Al 99.6E*** min<br />

max 0.10 0.30 0.01 0.007 0.02 0.005 0.04 Mn+Cr+ 0.03<br />

V+Ti=<br />

0.030<br />

B 0.04<br />

*) Non-standardised version<br />

**) According to DIN EN 1706: 2010<br />

***) According to DIN EN 576<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

58<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Eutectic<br />

aluminium-silicon casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin min 12.5<br />

max 13.5 0.15 0.02 0.05 0.05 0.07 0.15 0.03 0.10 Na<br />

Al Si12(a) min 10.5<br />

max 13.5 0.40 0.03 0.35 0.10 0.15 0.05 0.15 Na<br />

(0.55) (0.05)<br />

44200 / 230<br />

Al Si12(b) min 10.5<br />

max 13.5 0.55 0.10 0.55 0.10 0.10 0.15 0.10 0.15 0.05 0.15<br />

(0.65) (0.15) (0.20)<br />

44100<br />

Al Si12(Fe)(a) min 10.5 0.45<br />

max 13.5 0.9 0.08 0.55 0.15 0.15 0.05 0.25<br />

(1.0) (0.10)<br />

44300 / 230D<br />

Al Si12(Fe)(b) min 10.0 0.45<br />

max 13.5 0.9 0.18 0.55 0.40 0.30 0.15 0.05 0.25<br />

(1.0) (0.20)<br />

44500<br />

Al Si12(Cu) min 10.5 0.05<br />

max 13.5 0.7 0.9 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />

(0.8) (1.0) (0.20)<br />

47000 / 231<br />

Al Si12Cu1(Fe) min 10.5 0.6 0.7<br />

max 13.5 1.1 1.2 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />

(1.3) (0.20)<br />

47100 / 231D<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 59


Eutectic aluminium-silicon casting alloys<br />

<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

Silumin<br />

Al Si12(a)<br />

Al Si12(b)<br />

Al Si12(Fe)(a)<br />

Al Si12(Fe)(b)<br />

Al Si12(Cu)<br />

crack<br />

stability<br />

tightness state resistance anodisation<br />

Al Si12Cu1(Fe)<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Silumin 2.68 75,000 0.91 ~ 577 21 18 - 24 140 - 170<br />

Al Si12(a) 2.68 75,000 0.90 ~ 577 20 17 - 24 140 - 170<br />

Al Si12(b) 20 16 - 23 130 - 160<br />

Al Si12(Fe)(a) 2.68 75,000 0.90 ~ 577 20 16 - 22 130 - 160<br />

Al Si12(Fe)(b) 20 16 - 22 130 - 160<br />

Al Si12(Cu) 2.70 75,000 0.89 ~ 577 20 16 - 22 130 - 150<br />

Al Si12Cu1(Fe) 2.70 75,000 0.89 ~ 577 20 15 - 20 120 - 150<br />

60<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Silumin F Sand casting 150 70 6 45 60 - 90<br />

Al Si12(a) F Sand casting 150 70 5 50 60 - 90<br />

Al S12(b) F Sand casting 150 70 4 50<br />

Al Si12(Cu) F Sand casting 150 80 1 50 60 - 90<br />

Silium F Gravity die casting 170 80 7 45 60 - 90<br />

Al Si12(a) F Gravity die casting 170 80 6 55 60 - 90<br />

Al Si12(Cu) F Gravity die casting 170 90 2 55 60 - 90<br />

Al Si12(Fe)(a) F Pressure die casting 240 130 1 60 60 - 90<br />

Al Si 12(Fe)(b) F Pressure die casting 240 140 1 60<br />

Al Si12Cu1(Fe) F Pressure die casting 240 140 1 70 60 - 90<br />

The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />

as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Silumin 220 180 150 110 120 80 60 40 6 8 10 12 50 50 45 35<br />

Al Si12(a) 220 180 150 110 120 80 60 40 2,5 3 4 10 50 50 45 35<br />

Al Si12(b) 220 180 150 110 120 80 60 40 2.5 3.4 10 10 50 50 45 35<br />

Al Si12(Cu) 190 170 110 100 80 35 1 3 8 55 45 25<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Silumin 670 - 740 670 - 740 620 - 660 1.0 - 1.2 0.5 - 0.8<br />

Al Si12(a) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si12(Fe)(a) 620 - 660 0.4 - 0.6<br />

Al Si12(Cu) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si12Cu1(Fe) 620 - 660 0.4 - 0.6<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 61


Eutectic aluminium-silicon casting alloys<br />

Application notes<br />

Universal aluminium casting alloy with<br />

medium strength; in part, very good elon-<br />

gation and very good fl ow properties.<br />

Suitable for thin-walled, complicated,<br />

pressure-tight, vibration- and impact-<br />

resistant constructions.<br />

Properties and processing<br />

From the range of AlSi casting alloys,<br />

this type of alloy containing 13 % silicon<br />

has the best fl uidity. In some respects,<br />

the behaviour of the casting alloys in this<br />

range represents a special case. Some<br />

advice is provided below.<br />

In the case of free solidifi cation, e.g. a<br />

dense, bevel-shaped surface, the so-<br />

called “hammer blow”, forms on the top<br />

of the ingot. This type of solidifi cation is<br />

“shell-forming”, i.e. the crystallisation of<br />

the subsequent casting begins with the<br />

formation of a solid shell which then grows<br />

towards the middle of the cast wall. In<br />

this type of casting alloy, there are only<br />

two states, i.e. “solid” and “liquid”. Full<br />

solidifi cation of a casting takes place<br />

at the eutectic temperature of approx.<br />

577 °C). During the solidifi cation process,<br />

the volume can contract by up to 7 %.<br />

62<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

The shell thickness does not decrease.<br />

If the fl ow of liquid metal is interrupted<br />

in the middle wall region during feeding,<br />

a coarse cavity can evolve. (Additional<br />

notes also provided in the sections entitled<br />

“Infl uencing the microstructural<br />

formation of aluminium castings” and<br />

“Avoiding casting defects”.)<br />

This type of aluminium casting alloy can<br />

only be modifi ed with sodium. Sodium<br />

modifi cation is indicated for sand cast-<br />

ings and gravity die castings if particular<br />

requirements are placed on elongation<br />

of the microstructure (see Figure 2). As<br />

a general rule, casting alloys for use in<br />

sand and gravity die casting are offered<br />

in a slightly modifi ed version. Chemical<br />

resistance as well as resistance to weath-<br />

ering and a marine climate increase with<br />

the purity of the casting alloy used. A pri-<br />

mary silicon casting alloy thus meets the<br />

highest requirements in a variety of fi elds<br />

of application, e.g. in the food industry<br />

or in shipbuilding. The elongation of the<br />

cast structure is signifi cantly determined<br />

by the iron content and other impurities.<br />

The demand for high proof stress values<br />

in the casting often requires the use of<br />

primary casting alloys with the lowest<br />

possible content of iron and impurities.<br />

Heat treatment<br />

In the case of sand and gravity die cast-<br />

ings made from casting alloys low in<br />

Cu and Mg, a selective improvement<br />

in ductility can be achieved. This is ef-<br />

fected by means of solution annealing at<br />

520-530 °C with subsequent quenching<br />

in cold water.<br />

Comments<br />

The DIN EN 1676 and DIN EN 1706<br />

standards allow a very wide range of<br />

major alloying elements – silicon from<br />

10.5 to 13.5 %. The practical range for<br />

the silicon content is from 12.5 to 13.5<br />

and, in a slightly hypoeutectic range of<br />

10.5 to 11.2 %. However, these two alloys<br />

display entirely different solidifi cation<br />

behaviour. The intermediate range, with<br />

approx. 11.5 to 12.5 % silicon, runs the<br />

risk of shrinkage cavities. <strong>Casting</strong> alloys<br />

in this critical range are not offered. Even<br />

a blend of these different yet similarsounding<br />

alloys is not recommended.


Near-eutectic<br />

wheel casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin-Kappa Sr min 10.5 0.05<br />

max 11.0 0.15 0.02 0.10 0.25 0.07 0.15 0.03 0.10 Sr<br />

Silumin-Beta Sr min 9.0 0.20<br />

max 10.5 0.15 0.02 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />

Al Si11 min 10.0<br />

max 11.8 0.15 0.03 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />

(0.19) (0.05)<br />

44000<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

crack<br />

stability<br />

tightness state resistance anodisation<br />

Silumin-Kappa Sr<br />

Silumin-Beta Sr<br />

Al Si11<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Silumin-Kappa Sr 2.68 74,000 0.91 600 - 555 21 20 - 26 150 - 180<br />

Silumin-Beta Sr 2.68 74,000 0.91 600 - 550 21 20 - 26 150 - 180<br />

Al Si11 2.68 74,000 0.91 600 - 550 21 18 - 24 140 - 170<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 63


Near-eutectic wheel casting alloys<br />

Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Silumin-Kappa Sr F Gravity die casting 170 80 6 45 60 - 90<br />

Silumin-Beta Sr F Gravity die casting 170 90 5 50 60 - 90<br />

T6 Gravity die casting 290 210 4 90 60 - 90<br />

T64 Gravity die casting 250 180 6 80 60 - 90<br />

Al Si11 F Gravity die casting 170 80 7 45 60 - 90<br />

The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />

as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />

Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

Silumin-Kappa Sr T4 520 - 535 4 - 10 20 160 - 170 6 - 8<br />

Silumin-Beta Sr T4 520 - 535 4 - 10 20 150 - 160 2 - 3<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

64<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Silumin-Kappa Sr F 180 170 160 120 90 80 70 50 5 6 6 10 65 45 45 40<br />

Silumin-Beta Sr T64 260 250 210 120 200 180 170 80 4,5 6 7 10 85 80 75 60<br />

Al Si11 F 230 170 160 130 130 80 70 50 3 7 7 10 65 45 40 35<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Silumin-Kappa Sr 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Silumin-Beta Sr 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si11 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8


Application notes<br />

These casting alloy types have been<br />

developed primarily for the casting of<br />

car wheels by means of low-pressure<br />

die casting processes.<br />

Properties and processing<br />

These casting alloys have good fl uidity;<br />

the grain structure displays very high<br />

ductility and good corrosion resistance.<br />

The casting alloy Silumin-Kappa has an<br />

optimum silicon content of 10.5 to 11.0 %.<br />

In Silumin-Beta, the silicon content ranges<br />

from 9.0 and 10.5 % silicon. As a rule,<br />

these casting alloys already undergo a<br />

long-lasting strontium modifi cation (HV)<br />

during production of the ingots. The<br />

strontium addition is approx. 0.020 to<br />

0.030 %. Normally, this smelter modifi -<br />

cation does not need to be repeated at<br />

the foundry. The modifi cation of eutectic<br />

silicon, i.e. the formation of a modifi ed<br />

microstructure, is a necessity since the<br />

ductility of the cast structure of the wheels<br />

produced from these casting alloys meas-<br />

ured by means of the elongation value,<br />

for example, plays a vital role. The level<br />

of the iron content and the level of the<br />

other additions are particularly important<br />

quantities for the ductility or elongation<br />

of the cast structure. On request, these<br />

casting alloys can have a magnesium<br />

content of between 0.05 and 0.45 %.<br />

With an increasing Mg content, the alloys‘<br />

strength can be improved slightly,<br />

their elongation decreases a little with the<br />

level of the Mg content, their machinability<br />

– with respect to chip formation, chip<br />

removal and surface appearance – is<br />

improved, the resistance of the casting<br />

to chemical attack increases, lacquer<br />

adherence, however, can be impaired<br />

by the magnesium content. Only some<br />

of the Silumin-Beta casting alloys are<br />

age-hardenable. The age hardening of<br />

wheels made from alloys of the Silumin-<br />

Kappa type is not recommended. It could<br />

cause partial embrittlement which would<br />

reduce the fatigue strength of the material.<br />

For wheels which have to be heat-treated,<br />

casting alloys of the Al Si7Mg (Pantal 7)<br />

type are recommended. The solidifi cation<br />

characteristics of these casting alloys<br />

are hypoeutectic. During solidifi cation,<br />

the transition is from pasty to mushy.<br />

In the course of subsequent solidifi cation,<br />

aluminium dendrites grow into the<br />

liquid melt. They form an interconnecting<br />

network whose intervening spaces<br />

are then fi lled with the highly-fl uid AlSi<br />

eutectic which then solidifi es. If feeding<br />

is incomplete or the highly-fl uid eutectic<br />

is drawn to another place, defects such<br />

as sinks or microporosity occur. The so-<br />

lidifi cation range is approx. 30 to 45 K.<br />

With this type of casting alloy, cleaning<br />

the melt can only be effected by means<br />

of inert gas or using a vacuum. Cleaning<br />

agents containing chlorine would remove<br />

strontium from the melt. In practice, the<br />

use of purging lances or impeller equipment<br />

have proven their worth.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 65


The 10 per cent aluminium-silicon<br />

casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Silumin-Beta / Al Si9Mg min 9.0 0.30<br />

(0.25)<br />

max 10.0 0.15 0.03 0.10 0.45<br />

(0.19) (0.05) (0.45) 0.07 0.15 0.03 0.10 Na<br />

43300<br />

Al Si10Mg(a) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.40 0.03 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15 Na<br />

(0.55) (0.05) (0.45)<br />

43000 / 239<br />

Al Si10Mg(b) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.45 0.08 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />

(0.55) (0.10) (0.45)<br />

43100<br />

Al Si10Mg(Fe) min 9.0 0.45 0.25<br />

(0.20)<br />

max 11.0 0.9 0.08 0.55 0.50 0.15 0.15 0.15 0.05 0.15 0.05 0.15<br />

(1.0) (0.10) (0.50) (0.20)<br />

43400 / 239D<br />

Al Si10Mg(Cu) min 9.0 0.25<br />

(0.20)<br />

max 11.0 0.55 0.30 0.55 0.45 0.15 0.35 0.10 0.15 0.05 0.15<br />

(0.65) (0.35) (0.45) (0.20)<br />

43200 / 233<br />

Al Si9 min 8.0<br />

max 11.0 0.55 0.08 0.50 0.10 0.05 0.15 0.05 0.05 0.15 0.05 0.15<br />

(0.65) (0.10)<br />

44400<br />

Silumin-Delta min 9.0 0.3 0.3<br />

max 10.5 0.4 0.02 0.4 0.03 0.07 0.15 0.03 0.10<br />

Silumin-Gamma min 9.0 0.4 0.15<br />

max 11.3 0.15 0.02 0.9 0.6 0.10 0.15 0.03 0.10 Sr<br />

Al Si10MnMg min 9.0 0.40 0.15<br />

(0.10)<br />

max 11.5 0.20 0.03 0.80 0.60 0.07 0.15 0.05 0.15 Sr<br />

(0.25) (0.05) (0.60) (0.20)<br />

43500<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

66<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

crack tightness state resistance anodisation<br />

stability<br />

Silumin-Beta / Al Si9Mg<br />

Al Si10Mg(a)<br />

Al Si10Mg(b)<br />

Al Si10Mg(Fe)<br />

Al Si10Mg(Cu)<br />

Al Si9<br />

Silumin-Delta<br />

Silumin-Gamma<br />

Al Si10MnMg<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Silumin-Beta / Al Si9Mg 2.68 74,000 0.91 600 - 555 21 20 - 26 150 - 180<br />

Al Si10Mg(a) 2.68 74,000 0.91 600 - 550 21 19 - 25 150 - 170<br />

Al Si10Mg(b) 2.68 74,000 0.91 600 - 550 21 18 - 25 140 - 170<br />

Al Si10Mg(Fe) 2.68 74,000 0.91 600 - 550 21 16 - 21 130 - 150<br />

Al Si10Mg(Cu) 2.68 74,000 0.91 600 - 550 21 16 - 24 130 - 170<br />

Al Si9 2.69 74,000 0.91 605 - 570 21 16 - 22 130 - 150<br />

Silumin-Delta 2.69 74,000 0.91 605 - 570 21 18 - 26 130 - 170<br />

Silumin-Gamma 2.68 74,000 0.91 610 - 560 21 20 - 26 140 - 180<br />

Al Si10MnMg 21 19 - 25 140 - 170<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 67


The 10 per cent aluminium-silicon casting alloys<br />

Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Silumin-Beta / Al Si9Mg F Sand casting 150 80 2 50<br />

T6 Sand casting 230 190 2 75<br />

Al Si10Mg(a) F Sand casting 150 80 2 50<br />

T6 Sand casting 220 180 1 75<br />

Al Si10Mg(b) F Sand casting 150 80 2 50<br />

T6 Sand casting 220 180 1 75<br />

Al Si10Mg(Cu) F Sand casting 160 80 1 50<br />

T6 Sand casting 220 180 1 75<br />

Silumin-Beta / Al Si9Mg T6 Gravity die casting 290 210 4 90 80 - 110<br />

T64 Gravity die casting 250 180 6 80 80 - 110<br />

Al Si10Mg(a) F Gravity die casting 180 90 2.5 55 80 - 110<br />

T6 Gravity die casting 260 220 1 90 80 - 110<br />

T64 Gravity die casting 240 200 2 80<br />

Al Si10Mg(b) F Gravity die casting 180 90 2.5 55 80 - 110<br />

T6 Gravity die casting 260 220 1 90 80 - 110<br />

T64 Gravity die casting 240 200 2 80<br />

Al Si10Mg(Cu) F Gravity die casting 180 90 1 55 80 - 110<br />

T6 Gravity die casting 240 200 1 80 80 - 110<br />

Al Si10Mg(Fe) F Pressure die casting 240 140 1 70 60 - 90<br />

Al Si9 F Pressure die casting 220 120 2 55 60 - 90<br />

Silumin-Delta F Pressure die casting 220 120 4 55 60 - 90<br />

Silumin-Gamma F Pressure die casting 240 120 5 70 80 - 90<br />

T6 Pressure die casting 290 210 7 100<br />

The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />

as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />

68<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

Silumin-Beta / Al Si9Mg T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />

T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />

Al Si10Mg(a) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />

T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />

Al Si10Mg(b) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />

T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />

Al Si10Mg(Cu) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />

Silumin-Gamma T6 500 - 530 4 - 8 20 150 - 170 2 - 6<br />

T64 500 - 530 4 - 8 20 180 - 340 2 - 6<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

Typical process parameters<br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Silumin-Beta / Al Si9Mg T6 290 290 260 120 220 210 200 80 3.5 4 4 10 90 90 80 60<br />

Al Si10Mg(a) T6 280 260 230 120 220 220 170 80 1 1 2 8 85 90 80 60<br />

Al Si10Mg(Cu) T6 280 240 210 120 220 200 180 90 1 1 2 7 85 80 75 45<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Silumin-Beta / Al Si9Mg 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si10Mg(a) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si10Mg(b) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si10Mg(Fe) 620 - 660 0.4 - 0.6<br />

Al Si10Mg(Cu) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />

Al Si9 660 - 740 660 - 740 620 - 700 0.5 - 0.8 0.4 - 0.6<br />

Silumin-Delta 620 - 700 0.4 - 0.6<br />

Silumin-Gamma 620 - 730 0.4 - 0.6<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 69


The 10 per cent aluminium-silicon casting alloys<br />

Application notes<br />

This important group of casting alloys<br />

is used for castings with medium wall<br />

thicknesses which require higher, to the<br />

highest strength properties. The fi elds of<br />

application comprise mechanical and<br />

electrical engineering, the food industry<br />

as well as in engine and motor vehicle<br />

construction. Silumin-Beta casting alloys<br />

are also used for car wheels. Silumin-<br />

Gamma is a heat-treatable high-pressure<br />

die casting alloy. However, successful<br />

treatment requires the use of an adequate<br />

casting process (e.g. vacuum-assisted<br />

high-pressure die casting).<br />

70<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Properties and processing<br />

The fl uidities of these casting alloys are<br />

still good. Heat-treatable castings made<br />

from alloys containing magnesium dis-<br />

play particularly good machinability. With<br />

increasing purity, the ductility of the cast<br />

structure also increases. Where the requirements<br />

on corrosion resistance are<br />

high, high-purity grades are selected.<br />

Sand and gravity die castings can be<br />

artifi cially aged. In doing so, however,<br />

ductility decreases. The solidifi cation<br />

characteristics of this group of casting<br />

alloys are hypoeutectic. During the solidifi<br />

cation process, aluminium dendrites<br />

grow into the melt fi rst. The highly-fl uid<br />

AlSi eutectic then penetrates the intervening<br />

spaces of the network and clamps<br />

the microstructural framework together.<br />

If the feeding of the remaining eutectic<br />

melt is hindered in any way, defects such<br />

as sinks or micro/macrocavities occur.<br />

This causes porous areas and also leads<br />

to a weakening of the structural crosssection.<br />

During casting, therefore, attention<br />

must be paid to ensure good feeding<br />

and, as far as possible, controlled<br />

solidifi cation. The solidifi cation range<br />

amounts to approx. 45 K.<br />

Where requirements on elongation or<br />

ductility are higher, modifi cation of the<br />

melt is recommended. The casting alloys<br />

for use in gravity die casting are modifi<br />

ed with sodium or strontium. For sand<br />

casting, modifi cation with sodium only<br />

is recommended. As a general rule, the<br />

casting alloys for sand and gravity die<br />

casting are offered in versions which can<br />

be easily modifi ed.


The 7 and 5 per cent aluminium-silicon<br />

casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Pantal 7 / Al Si7Mg0.3 min 6.5 0.30<br />

(0.25)<br />

max 7.5 0.15 0.03 0.10 0.45 0.07 0.18 0.03 0.10 Na / Sr<br />

(0.19) (0.05) (0.45) (0.25)<br />

42100<br />

Al Si7Mg0.6 min 6.5 0.50<br />

(0.45)<br />

max 7.5 0.15 0.03 0.10 0.70 0.07 0.18 0.03 0.10<br />

(0.19) (0.05) (0.70) (0.25)<br />

42200<br />

Al Si7Mg min 6.5 0.25<br />

(0.20)<br />

max 7.5 0.45 0.15 0.35 0.65 0.15 0.15 0.15 0.05 0.20 0.05 0.15<br />

(0.55) (0.20) (0.65) (0.25)<br />

42000<br />

Pantal 5 min 5.0 0.40 0.05<br />

max 6.0 0.15 0.02 0.10 0.80 0.07 0.20 0.03 0.10<br />

Al Si5Mg min 5.0 0.40 0.05<br />

max 6.0 0.3 0.03 0.4 0.80 0.10 0.20 0.05 0.15<br />

- / 235<br />

Al Si5Cu1Mg min 4.5 1.0 0.40<br />

(0.35)<br />

max 5.5 0.55 1.5 0.55 0.65 0.25 0.15 0.15 0.05 0.20 0.05 0.15<br />

(0.65) (0.65) (0.25)<br />

45300<br />

Al Si7Cu0.5Mg min 6.5 0.2 0.25<br />

(0.20)<br />

max 7.5 0.25 0.7 0.15 0.45<br />

(0.45)<br />

0.07 0.20 0.03 0.10<br />

45500<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 71


The 7 and 5 per cent aluminium-silicon casting alloys<br />

<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

crack tightness state resistance anodisation<br />

stability<br />

Pantal 7 / Al Si7Mg0.3<br />

Al Si7Mg0.6<br />

Al Si7Mg<br />

Pantal 5<br />

Al Si5Mg<br />

Al Si5Cu1Mg<br />

Al Si7Cu0.5Mg<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Pantal 7 / Al Si7Mg0.3 2.66 73,000 0.92 625 - 550 22 21 - 27 160 - 180<br />

Al Si7Mg0.6 2.66 73,000 0.92 625 - 550 22 20 - 26 150 - 180<br />

Al Si7Mg 2.66 73,000 0.92 625 - 550 22 19 - 25 150 - 170<br />

Pantal 5 2.67 72,000 0.92 625 - 550 23 21 - 29 150 - 180<br />

Al Si5Mg 2.67 72,000 0.92 625 - 550 23 21 - 26 150 - 180<br />

Al Si5Cu1Mg 2.67 72,000 0.92 625 - 550 22 19 - 23 140 - 150<br />

Al Si7Cu0.5Mg 22 16 - 22 150 - 165<br />

72<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Pantal 7 / Al Si7Mg0.3 T6 Sand casting 230 190 2 75<br />

Al Si7Mg0.6 T6 Sand casting 250 210 1 85<br />

Al Si7Mg F Sand casting 140 80 2 50<br />

T6 Sand casting 220 180 1 75<br />

Pantal 5 T6 Sand casting 240 220 2 80<br />

T4 Sand casting 200 150 4 75<br />

Al Si5Mg T6 Sand casting 240 220 1 80<br />

T4 Sand casting 200 150 3 75<br />

Al Si5Cu1Mg T6 Sand casting 230 200


The 7 and 5 per cent aluminium-silicon casting alloys<br />

Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

Pantal 5 T4 520 - 535 4 - 10 20 20 - 30 120<br />

T6 520 - 535 4 - 10 155 - 165 6 - 10<br />

Al Si5Mg T4 520 - 535 4 - 10 20 20 - 30 120<br />

T6 520 - 535 4 - 10 155 - 165 6 - 10<br />

Al Si5Cu1Mg T4 520 - 535 4 - 10 20 20 - 30 120<br />

T6 520 - 535 4 - 10 155 - 165 6 - 10<br />

Pantal 7 / Al Si7Mg0.3 T6 520 - 545 4 - 10 155 - 165 6 - 10<br />

T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />

Al Si7Mg0,6 T6 520 - 545 4 - 10 155 - 165 6 - 10<br />

T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />

Al Si7Mg T6 520 - 545 4 - 10 155 - 165 6 - 10<br />

T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

74<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Pantal 7 / Al Si7Mg0.3 T6 290 290 240 120 210 210 180 80 3 4 6 10 90 90 75 45<br />

Pantal 5 T6 280 260 200 120 250 240 170 80 1 2 3 7 90 90 80 45<br />

Al Si5Mg T6 280 260 200 120 250 240 170 80 0.5 1 2 7 90 90 80 45<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Pantal 7 / Al Si7Mg0.3 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />

Al Si7Mg0.6 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />

Al Si7Mg 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />

Pantal 5 690 - 760 690 - 760 1.1 - 1.2 0.8 - 1.1<br />

Al Si5Mg 690 - 760 690 - 760 1.1 - 1.2 0.8 - 1.1<br />

Al Si5Cu1Mg 690 - 760 690 - 760 1.0 - 1.2 0.8 - 1.1


Application notes<br />

These casting alloys are used in the<br />

motor vehicle industry (chassis components,<br />

motor car and lorry wheels), for<br />

components in the aerospace industry,<br />

for parts in mechanical engineering, for<br />

hydraulic elements, in the food industry,<br />

in shipbuilding, for fi ttings and apparatus<br />

as well as for fi re extinguisher compo-<br />

nents. Their use makes particular sense<br />

when the castings undergo age harden-<br />

ing. As a result of age hardening, these<br />

casting alloys are used in structures<br />

requiring high strength. In addition, the<br />

cast structure – particularly of primary<br />

casting alloys – still displays remarkable<br />

toughness and ductility. Resistance to<br />

chemical attack increases with purity<br />

and is very good in the case of primary<br />

casting alloys.<br />

Properties and processing<br />

Owing to the low silicon content, fl uidity<br />

is only moderate. <strong>Casting</strong>s with very<br />

thin walls can not, therefore, be cast in<br />

these alloys. This group of casting alloys<br />

containing around 7 % silicon is in<br />

some respects an exception. Looking<br />

at a micrograph, it can be seen that the<br />

proportion by area of light matrix (i.e.<br />

the aluminium-rich solid solution) and<br />

the proportion by area or eutectic silicon<br />

(i.e. the dotted grey areas) each amount<br />

to approx. 50 %. Like in all hypoeutectic<br />

AlSi casting alloys, solidifi cation takes<br />

place in phases. First of all, the dendritic<br />

network made up of aluminium-rich solid<br />

solution grows into the still liquid melt.<br />

The remaining highly-fl uid eutectic melt<br />

infi ltrates this sponge and locks the struc-<br />

ture together like in a two-component<br />

composite. By means of age-harden-<br />

ing, the aluminium-rich solid solution<br />

in particular is strengthened while the<br />

connecting eutectic remains ductile. In<br />

this way, the ideal microstructure occurs,<br />

giving the highest possible strength with<br />

still acceptable elongation. The variable<br />

magnesium content which ranges from<br />

0.20 to 0.70 % gives the user the possibility<br />

of adjusting the elongation of the<br />

castings to the particular requirements.<br />

With a low magnesium content of around<br />

0.25 %, relatively high elongation values<br />

can be achieved. Where greater hardness<br />

is required, casting alloys with a magnesium<br />

content of 0.70 % can be used.<br />

The group of casting alloys with approx.<br />

5 % silicon displays many sequences<br />

and properties which are similar to the<br />

7 per cent group. The solidifi cation range<br />

is slightly greater, fl uidity is slightly less.<br />

Due to the lower silicon content, the effect<br />

of the aluminium-rich solid solution<br />

dominates. The casting alloy variants<br />

with low copper content display the best<br />

possible corrosion-resistance behaviour<br />

of all aluminium-silicon casting alloys.<br />

<strong>Casting</strong>s made from these alloys fi nd<br />

application in such areas as the food<br />

industry, in domestic appliances or in<br />

parts for the food processing industry.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 75


Al SiCu casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Al Si8Cu3 min 7.5 2.0 0.15 0.15<br />

(0.05)<br />

max 9.5 0.7 3.5 0.65 0.55 0.35 1.2 0.25 0.15 0.20 0.05 0.25<br />

(0.8) (0.55) (0.25)<br />

46200 / 226<br />

Al Si9Cu3(Fe) min 8.0 0.6 2.0 0.15<br />

(0.05)<br />

max 11.0 1.1 4.0 0.55 0.55 0.15 0.55 1.2 0.35 0.15 0.20 0.05 0.25<br />

(1.3) (0.55) (0.25)<br />

46000 / 226D<br />

Al Si11Cu2(Fe) min 10.0 0.45 1.5<br />

max 12.0 1.0 2.5 0.55 0.30 0.15 0.45 1.7 0.25 0.15 0.20 0.05 0.25<br />

(1.1) (0.25)<br />

46100<br />

Al Si7Cu3Mg min 6.5 3.0 0.20 0.35<br />

(0.30)<br />

max 8.0 0.7 4.0 0.65 0.60 0.30 0.65 0.15 0.10 0.20 0.05 0.25<br />

(0.8) (0.60) (0.25)<br />

46300<br />

Al Si9Cu1Mg min 8.3 0.8 0.15 0.30<br />

(0.25)<br />

max 9.7 0.7 1.3 0.55 0.65 0.20 0.8 0.10 0.10 0.18 0.05 0.25<br />

(0.8) (0.65) (0.20)<br />

46400<br />

Al Si9Cu3(Fe)(Zn) min 8.0 0.6 2.0 0.15<br />

(0.05)<br />

max 11.0 1.2 4.0 0.55 0.55 0.15 0.55 3.0 0.35 0.15 0.20 0.05 0.25<br />

(1.3) (0.55) (0.25)<br />

46500 / 226/3<br />

Al Si7Cu2 min 6.0 1.5 0.15<br />

max 8.0 0.7 2.5 0.65 0.35 0.35 1.0 0.25 0.15 0.20 0.05 0.15<br />

(0.8) (0.25)<br />

46600<br />

Al Si6Cu4 min 5.0 3.0 0.20<br />

max 7.0 0.9 5.0 0.65 0.55 0.15 0.45 2.0 0.30 0.15 0.20 0.05 0.35<br />

(1.0) (0.25)<br />

45000 / 225<br />

Al Si5Cu3Mg min 4.5 2.6 0.20<br />

(0.15)<br />

max 6.0 0.50 3.6 0.55 0.45 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />

(0.60) (0.45) (0.25)<br />

45100<br />

Al Si5Cu3 min 4.5 2.6<br />

max 6.0 0.50 3.6 0.55 0.05 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />

(0.60) (0.25)<br />

45400<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

76<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

crack tightness state resistance anodisation<br />

stability<br />

Al Si8Cu3<br />

Al Si9Cu3(Fe)<br />

Al Si11Cu2(Fe)<br />

Al Si7Cu3Mg<br />

Al Si9Cu1Mg<br />

Al Si9Cu3(Fe)(Zn)<br />

Al Si7Cu2<br />

Al Si6Cu4<br />

Al Si5Cu3Mg<br />

Al Si5Cu3<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Al Si8Cu3 2.77 75,000 0.88 600 - 500 21 14 - 18 110 - 130<br />

Al Si9Cu3(Fe) 2.76 75,000 0.88 600 - 500 21 13 - 17 110 - 120<br />

Al Si11Cu2(Fe) 2.75 75,000 0.88 600 - 500 20 14 - 18 120 - 130<br />

Al Si7Cu3Mg 2.77 75,000 0.88 600 - 500 21 14 - 17 110 - 120<br />

Al Si9Cu1Mg 2.76 75,000 0.88 600 - 500 21 16 - 22 130 - 150<br />

Al Si9Cu3(Fe)(Zn) 2.76 75,000 0.88 600 - 500 21 13 - 17 110 - 120<br />

Al Si7Cu2 2.77 75,000 0.88 600 - 500 21 15 - 19 120 - 130<br />

Al Si6Cu4 2.80 74,000 0.88 630 - 500 22 14 - 17 110 - 120<br />

Al Si5Cu3Mg 2.79 74,000 0.88 630 - 500 22 16 - 19 130<br />

Al Si5Cu3 2.79 74,000 0.88 630 - 500 22 16 - 19 120 - 130<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 77


Al SiCu casting alloys<br />

Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Al Si8Cu3 F Sand casting 150 90 1 60<br />

Al Si7Cu3Mg F Sand casting 180 100 1 80<br />

Al Si9Cu1Mg F Sand casting 135 90 1 60<br />

Al Si7Cu2 F Sand casting 150 90 1 60<br />

Al Si6Cu4 F Sand casting 150 90 1 60<br />

Al Si5Cu3Mg T4 Sand casting 140 70 1 60<br />

T6 Sand casting 230 200


Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

Al Si5Cu3Mg T4 480 6 - 10 20 - 60 20 - 30 120<br />

T6 480 6 - 10 20 160 6 - 12<br />

Al Si5Cu3 T4 480 6 - 10 20 - 60 20 - 30 120<br />

Al Si9Cu1Mg T6 480 6 - 10 20 160 6 - 12<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Al Si8Cu3 F 170 160 120 80 100 90 50 25 1 1 2 5 75 65 45 35<br />

Al Si6Cu4 F 170 160 130 100 100 90 60 30 1 1 1.5 4 75 65 50 40<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Al Si8Cu3 680 - 750 680 - 750 630 - 680 1.0 - 1.2 0.6 - 1.0 0.4 - 0.6<br />

Al Si9Cu3(Fe) 630 - 680 0.4 - 0.7<br />

Al Si11Cu2(Fe) 630 - 680 0.4 - 0.8<br />

Al Si7Cu3Mg 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />

Al Si9Cu1Mg 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />

Al Si9Cu3(Fe)(Zn) 630 - 680 0.4 - 0.7<br />

Al Si7Cu2 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />

Al Si6Cu4 690 - 750 690 - 750 640 - 690 1.0 - 1.2 0.6 - 1.0 0.4 - 0.6<br />

Al Si5Cu3Mg 690 - 750 690 - 750 1.0 - 1.2 0.6 - 1.0<br />

Al Si5Cu3 690 - 750 690 - 750 1.0 - 1.2 0.6 - 1.0<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 79


Al SiCu casting alloys<br />

Application notes<br />

The alloys in this group are among the<br />

most commonly used aluminium casting<br />

alloys around. They are regarded<br />

as universal casting alloys for the most<br />

important casting processes and are<br />

widely used in pressure die casting in<br />

particular. They are easily cast and are<br />

suitable for parts which are subjected<br />

to relatively high loads. They are heat<br />

resistant and, as such, are used for engine<br />

components and cylinder heads.<br />

80<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Properties and processing<br />

<strong>Aluminium</strong> casting alloys with approx. 6<br />

to 8 % silicon, 3 to 4 % copper as well<br />

as 0.3 to 0.5 % magnesium have the<br />

optimum high-temperature strength.<br />

The cast structure hardens on its own<br />

within a week of casting. Afterwards, the<br />

mechanical machinability of the casting<br />

is very good. Age hardening is some-<br />

times possible. Treatment of the melt:<br />

In sand castings or thick-walled grav-<br />

ity die castings, sodium modifi cation is<br />

possible. Often, grain refi nement is also<br />

carried out. The casting and solidifi ca-<br />

tion behaviour usually poses no problem.<br />

The type of solidifi cation is hypoeutectic.<br />

During the transition from liquid to<br />

solid state, there is a wide solidifi cation<br />

range of a pasty-mushy character. Attention<br />

must be paid to controlling the<br />

solidifi cation and feeding of the metal.<br />

There is no distinctive tendency to hot<br />

cracking or draws.<br />

Heat treatment<br />

With castings made from these casting<br />

alloys, age hardening is possible when<br />

the Cu and Mg content is appropriate. It<br />

is, however, seldom carried out. In these<br />

castings, due to the Cu content in connection<br />

with the Mg and Zn content, an<br />

independent structural hardening occurs.<br />

This process is complete within about a<br />

week. Only then should the castings be<br />

fi nished followed by checking the mechanical<br />

properties. To achieve thermal<br />

and dimensional stability in parts suitable<br />

for high-pressure applications, e.g.<br />

crankcases, cylinder heads or pistons,<br />

solution annealing with artifi cial ageing<br />

beyond the peak aged condition is sug-<br />

gested (T7). This process is also known<br />

as “stabilising” or “overageing”.


AlMg casting alloys<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Al Mg3(H) min 2.7<br />

max 0.45 0.15 0.02 0.40 3.2 0.07 0.02 0.03 0.10 B/Be<br />

Al Mg3 min 2.7<br />

(2.5)<br />

max 0.45 0.40 0.03 0.45 3.5 0.10 0.15 0.05 0.15 B/Be<br />

(0.55) (0.55) (0.05) (3.5) (0.20)<br />

51100 / 242<br />

Al Mg3(Cu) min 2.5<br />

max 0.60 0.55 0.15 0.45 3.2 0.30 0.20 0.05 0.15 B/Be<br />

- / 241<br />

Al Mg3Si(H) min 0.9 2.7<br />

max 1.3 0.15 0.02 0.40 3.2 0.07 0.15 0.03 0.10 B/Be<br />

Al Mg5 min 4.8<br />

(4.5)<br />

max 0.35 0.45 0.05 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />

(0.55) (0.55) (0.10) (6.5) (0.20)<br />

51300 / 244<br />

Al Mg5(Si) min 4.8<br />

(4.5)<br />

max 1.3 0.45 0.03 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />

(1.5) (0.55) (0.05) (6.5) (0.20)<br />

51400 / 245<br />

Al Mg9(H) min 1.7 0.2 8.5<br />

max 2.5 0.50 0.02 0.5 10.5 0.07 0.15 0.03 0.10 B/Be<br />

Al Mg9 min 0.45 8.5<br />

(8.0)<br />

max 2.5 0.9 0.08 0.55 10.5 0.10 0.25 0.10 0.10 0.15 0.05 0.15 B/Be<br />

(1.0) (0.10) (10.5) (0.20)<br />

51200 / 349<br />

Al Mg5Si2Mn min 1.8 0.4 5.0<br />

(4.7)<br />

max 2.6 0.20 0.03 0.8 6.0 0.07 0.20 0.05 0.15<br />

(0.25) (0.05) (6.0) (0.25)<br />

51500<br />

Al Si2MgTi min 1.6 0.30 0.50 0.07<br />

(0.45) (0.05)<br />

max 2.4 0.50 0.08 0.50 0.65 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />

(0.60) (0.10) (0.65) (0.20)<br />

41000<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 81


AlMg casting alloys<br />

<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

Al Mg3(H)<br />

Al Mg3<br />

Al Mg3(Cu)<br />

Al Mg3Si(H)<br />

Al Mg5<br />

Al Mg5(Si)<br />

Al Mg9(H)/Fe<br />

Al Mg9<br />

Al Mg3(Zr)<br />

Al Mg5Si2Mn<br />

Al Si2MgTi<br />

crack<br />

stability<br />

tightness state resistance anodisation<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

Al Mg3(H) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />

Al Mg3 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />

Al Mg3(Cu) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />

Al Mg3Si(H) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />

Al Mg5 2.66 69,000 0.94 630 - 550 24 15 - 21 110 - 130<br />

Al Mg5(Si) 2.66 69,000 0.94 630 - 550 24 15 - 21 110 - 140<br />

Al Mg9(H)/Fe 2.63 68,000 0.94 620 - 520 24 11 - 14 60 - 90<br />

Al Mg9 2.63 68,000 0.94 620 - 520 24 11 - 14 60 - 90<br />

Al Mg5Si2Mn 24 14 - 16 110 - 130<br />

Al Si2MgTi 23 19 - 25 140 - 160<br />

82<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Al Mg3(H) F Sand casting 140 70 5 50<br />

Al Mg3 F Sand casting 140 70 3 50<br />

Al Mg3(Cu) F Sand casting 140 70 2 50<br />

Al Mg3Si(H) F Sand casting 140 70 3 50<br />

Al Mg5 F Sand casting 16 90 3 55<br />

Al Si2MgTi F Sand casting 140 70 3 50<br />

T6 Sand casting 240 180 3 85<br />

Al Mg5(Si) F Sand casting 160 100 3 60<br />

Al Mg3(H) F Gravity die casting 150 70 5 50 60 - 90<br />

Al Mg3 F Gravity die casting 150 70 5 50 60 - 90<br />

Al Mg3(Cu) F Gravity die casting 150 70 3 50 60 - 90<br />

Al Mg3Si(H) F Gravity die casting 150 70 3 50 70 - 80<br />

T6 Gravity die casting 220 150 4 75 70 - 90<br />

Al Mg5 F Gravity die casting 180 100 4 60 60 - 90<br />

Al Si2MgTi F Gravity die casting 140 70 3 50<br />

T6 Gravity die casting 240 180 3 85<br />

Al Mg5(Si) F Gravity die casting 180 110 3 65 60 - 90<br />

T6 Gravity die casting 210 120 4 70 70 - 90<br />

Al Mg3 F 140 70 3 50<br />

Al Mg5 F 160 90 3 55<br />

Al Mg5(Si) F 180 110 3 65<br />

Al Mg9(H)/Fe F Pressure die casting 200 140 1 70 60 - 90<br />

Al Mg9 F Pressure die casting 200 130 1 70 60 - 90<br />

Al Si2MgTi F Gravity die casting 170 70 5 50<br />

Al Si2MgTi T6 Gravity die casting 260 180 5 85<br />

The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />

as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />

Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

Al Mg3Si(H) T6 545 - 555 4 - 10 20 160 - 170 8 - 10<br />

Al Mg5(Si) T6 540 - 550 4 - 10 20 160 - 170 8 - 10<br />

Al Si2MgTi T6 520 - 535 4 - 10 20 155 - 165 7 - 10<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 83


AlMg casting alloys<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

84<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Al Mg3Si(H) T6 220 210 120 80 150 140 60 30 4 4 5 14 75 45 40 20<br />

Al Mg5(Si) T6 210 200 170 140 120 110 100 70 4 4 5 8 70 70 60 30<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

Al Mg3(H) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg3 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg3(Cu) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg3Si(H) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg5 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg5(Si) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />

Al Mg9(H)/Fe 680 - 640 0.5 - 0.7<br />

Al Mg9 680 - 640 0.5 - 0.7


Application notes<br />

We produce Al Mg3-type casting alloys<br />

for handles, window handles or security<br />

covers in decorative anodised quality.<br />

For structures in the chemical industry, in<br />

shipbuilding or the food industry, which<br />

demand the highest possible resistance<br />

to chemical attack and the infl uences of<br />

maritime climates, Al Mg5-type cast-<br />

ing alloys are suitable. Heat-resistant<br />

Al Mg5Si-type casting alloys are suit-<br />

able for high-temperature applications<br />

such as engine construction. In France,<br />

the Al Si2MgTi alloy is used for handles.<br />

For pressure die castings with good corrosion<br />

resistance, Al Mg9-type casting<br />

alloys are used.<br />

Properties and processing<br />

The highest requirements are placed on<br />

the quality of these casting alloys – particularly<br />

for decorative parts which are<br />

anodised. The manufacture of these casting<br />

alloys represents a special challenge<br />

for smelters requiring much experience,<br />

the best raw materials and quality-oriented<br />

work.<br />

Notes about surface treatment<br />

As a pre-treatment, the surfaces of cast-<br />

ings made from Al Mg3, for example, are<br />

mechanically machined as well as often<br />

being chemically polished. In the anodis-<br />

ing process (electrolytically-oxidised alu-<br />

minium), a protective oxide layer, which<br />

grows inwards and is essentially more<br />

impervious, thicker, more wear resistant<br />

and more homogeneous than a natural<br />

oxide skin, is produced on the surface<br />

of a casting. On pure aluminium and on<br />

aluminium alloys which are low in precipitates,<br />

these layers are transparent.<br />

All defects such as precipitated intermetallic<br />

phases, inclusions, heterogeneities,<br />

oxide fi lms, wrinkles and other<br />

casting defects lead to disturbances in<br />

the growth of the layer formation and,<br />

consequently, impairment of the decorative<br />

appearance.<br />

As the electro-chemically formed oxide<br />

layer is also the possible carrier of discolouring<br />

substances, defects near the<br />

surface can lead to the parts having a<br />

blemished, non-decorative appearance.<br />

Hollow spaces such as wrinkles or pores<br />

which have been cut can be taken up<br />

by the aqueous solutions or electrolyte<br />

during treatment. Even later, due to a<br />

secondary reaction, the remainder of this<br />

medium can lead to local decomposition<br />

of the anodised or colour coating.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 85


AlMg casting alloys<br />

The following alloying constituents can<br />

have an infl uence on the quality and ap-<br />

pearance of anodised layers:<br />

Silicon<br />

With Si concentrations higher than<br />

0.6 %, the precipitated silicon or Mg2Si<br />

impairs transparency. The anodised layer<br />

loses its brilliance.<br />

Iron, chromium and manganese<br />

The sum total of these elements can<br />

have a yellowing effect on the anodised<br />

layer. Limiting concentrations can not<br />

be established. Their infl uence depends<br />

on the phase composition and chemical<br />

back-dissolution during anodising.<br />

Copper<br />

It has no negative infl uence when found<br />

in normal concentrations. In the case of<br />

higher additions, the layer becomes softer<br />

and the composition rougher.<br />

Zinc<br />

This element has no infl uence on the<br />

anodising process or pigmentation.<br />

Titanium<br />

Concentrations of Ti above 0.02 % have<br />

a negative effect on the electrolytic colouration<br />

of aluminium castings.<br />

86<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Notes on casting techniques<br />

To avoid the tendency to hot tearing<br />

during casting and particularly for deco-<br />

rative reasons, the cast structure must<br />

be fi ne-grained. This fi ne-grained struc-<br />

ture can already be achieved during the<br />

production of the ingots by means of<br />

intensive grain refi nement. As a general<br />

rule, this grain refi nement does not have<br />

to be repeated during pouring. Should<br />

grain refi nement decrease as a result<br />

of prolonged holding, we recommend<br />

that it be freshened up using TiB grain<br />

refi ning wire. Melt cleaning or keeping<br />

the melt clean is important in order to<br />

produce a cast piece of good quality.<br />

We recommend that only those refi n-<br />

ing fl uxes which are specifi cally suited<br />

to AlMg casting alloys be used.<br />

Bale-out vessels with ceramic fi lter ele-<br />

ments have also proven their worth. Dur-<br />

ing casting, only the fi ltrate is baled out;<br />

the ladle remainder and subsequently<br />

charged metal enter into the outside<br />

areas of the melting or holding crucible.<br />

The casting operation requires particular<br />

care in order to produce a sound casting<br />

despite the constant risk of forming<br />

oxides and shrinkage. In doing this, the<br />

confi guration of the dies and the casting<br />

system play an important role. The<br />

type of solidifi cation is globular-mushy.<br />

A good feeding system is an essen-<br />

tial prerequisite for producing a dense<br />

structure.


<strong>Casting</strong> alloys for special applications<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) /<br />

VDS-No.<br />

Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

High-strength casting alloys<br />

Al Cu4Ti min 4.2 0.15<br />

(0.15)<br />

max 0.15 0.15 5.2 0.55 0.07 0.25 0.03 0.10<br />

(0.18) (0.19) (0.30)<br />

21100<br />

Al Cu4MgTI min 4.2 0.20 0.15<br />

(0.15) (0.15)<br />

max 0.15 0.30 5.0 0.10 0.35 0.05 0.10 0.05 0.05 0.25 0.03 0.10<br />

(0.20) (0.35) (0.35) (0.30)<br />

21000<br />

Al Cu4MnMg min 4.0 0.20 0.20<br />

(0.15)<br />

max 0.10 0.15 5.0 0.50 0.50 0.03 0.05 0.03 0.03 0.05 0.03 0.10<br />

(0.20) (0.50) (0.05) (0.10) (0.10)<br />

21200<br />

Al Cu4MgTiAg min 4.0 0.01 0.15 0.5 Ag<br />

0.4<br />

max 0.05 0.10 5.2 0.50 0.35 0.05 0.35 0.03 0.10 1.0<br />

Al Cu5NiCoSbZr min 4.5 0.1 1.3 0.15 ****<br />

max 0.20 0.30 5.2 0.3 0.10 1.7 0.10 0.30 0.05 0.15<br />

Piston casting alloys<br />

AlSi12CuNiMg min 10.5 0.8 0.9<br />

(0.8)<br />

0.7<br />

max 13.5 0.6 1.5 0.35 1.5 1.3 0.35 0.20 0.05 0.15 P<br />

(0.7) (1.5) (0.25)<br />

48000 / 260<br />

Al Si18CuNiMg min 17.0 0.8 0.8 0.8<br />

max 19.0 0.3 1.3 0.10 1.3 1.3 0.10 0.15 0.05 0.15 P<br />

****) Co 0.10-0.40 Sb 0.10-0.30 Zr 0.10-0.30<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

Continuation of the table on the next page.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 87


<strong>Casting</strong> alloys for special applications<br />

Chemical composition (all data in wt.-%)<br />

Alloy<br />

Numerical Other<br />

denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg* min 16.0 4.0 0.5<br />

max 18.0 0.3 5.0 0.15 0.65 0.10 0.10 0.20 0.05 0.15 P<br />

Al Si17Cu4Mg** min 16.0 4.0 0.45<br />

(0.25)<br />

max 18.0 1.0 5.0 0.50 0.65 0.3 1.5 0.15 0.20 0.05 0.25<br />

(1.3) (0.65) (0.25)<br />

48100<br />

Self-hardening casting alloys<br />

Autodur min 8.5 0.3 9.5<br />

max 9.5 0.15 0.02 0.05 0.5 10.5 0.15 0.03 0.10<br />

Autodur (Fe)* min 8.5 0.3 9.5<br />

max 9.5 0.40 0.02 0.30 0.5 10.5 0.15 0.03 0.10<br />

Autodur (Fe)** min 7.5 0.25<br />

(0.20)<br />

9.0<br />

max 9.5 0.27 0.08 0.15 0.5 10.5 0.15 0.05 0.15<br />

(0.30) (0.10) (0.5)<br />

71100<br />

Rotor-<strong>Aluminium</strong><br />

Al 99.7E*** min<br />

max 0.07 0.20 0.01 0.005 0.02 0.004 0.04 Mn+Cr+ 0.03<br />

V+ Ti=<br />

0.02<br />

B 0.04<br />

Al 99.6E*** min<br />

max<br />

*) Non-standardised version<br />

0.10 0.30 0.01 0.007 0.02 0.005 0.04 Mn+Cr+ 0.03<br />

V+Ti=<br />

0.030<br />

B 0.04<br />

**) According to DIN EN 1706: 2010<br />

***) According to DIN EN 576<br />

Values in brackets are valid for castings according to DIN EN 1706: 2010<br />

1) According to DIN EN 1676: 2010<br />

88<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


<strong>Casting</strong> characteristics and other properties of castings<br />

Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />

crack tightness state resistance anodisation<br />

stability<br />

High-strength casting alloys<br />

Al Cu4Ti<br />

Al Cu4TiMgTi<br />

Al Cu4TiMgAg<br />

Al Cu5NiCoSbZr<br />

Piston casting alloys<br />

Al Si12CuNiMg<br />

Al Si18CuNiMg<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg 1)<br />

Al Si17Cu4Mg 2)<br />

Self-hardening casting alloys<br />

Autodur<br />

Autodur(Fe)<br />

Al Zn10Si8Mg 1)<br />

Rotor-<strong>Aluminium</strong><br />

Al 99.7E<br />

Al 99.6E<br />

1) Non-standardised version<br />

2) According to DIN EN 1706: 2010<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 89


<strong>Casting</strong> alloys for special applications<br />

Physical properties<br />

Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />

capacity temperature of thermal conductivity conductivity<br />

at 100 °C expansion<br />

g/cm3 MPa J/gK °C 10-6 /K<br />

293 K - 373 K<br />

MS/m W/(m . k)<br />

High-strength casting alloys<br />

Al Cu4Ti 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />

Al Cu4MgTi 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />

Al Cu4TiMgAg 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />

Al Cu5NiCoSbZr 2.84 76,000 0.91 650 - 550 23 18 - 24 120 - 155<br />

Piston casting alloys<br />

Al Si12CuNiMg 2.68 77,000 0.90 600 - 540 20 15 - 23 130 - 160<br />

Al Si18CuNiMg 2.68 81,000 0.90 680 - 520 19 14 - 18 115 - 140<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg 1) 2.73 81,000 0.89 650 - 510 19 14 - 18 115 - 130<br />

Al Si17Cu4Mg 2) 18 14 - 17 120 - 130<br />

Self-hardening casting alloys<br />

Autodur 2.85 75,000 0.86 640 - 550 21 15 - 20 115 - 150<br />

Autodur(Fe) 2.85 75,000 0.86 640 - 550 21 15 - 20 115 - 150<br />

Al Zn10Si8Mg 2) Rotor-<strong>Aluminium</strong><br />

21 17 - 20 120 - 130<br />

Al 99.7E 2.70 70,000 0.94 660 24 34 - 36 180 - 210<br />

Al 99.6E 2.70 70,000 0.94 660 24 32 - 34 180 - 210<br />

1) Non-standardised version<br />

2) According to DIN EN 1706: 2010<br />

90<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

High-strength casting alloys<br />

Al Cu4Ti T6 Sand casting 300 200 3 95<br />

T64 Sand casting 280 180 5 85<br />

Al Cu4TiMg T4 Sand casting 300 200 5 90<br />

Al Cu4TiMgAg T6 Sand casting 460 - 510 410 - 450 7 130 - 150<br />

T64 Sand casting 370 - 430 200 - 270 14 - 18 105 - 120<br />

Al Cu5NiCoSbZr T7 Sand casting 180 - 220 145 - 165 1 - 1.5 85 - 95 90 - 100<br />

T5 Sand casting 180 - 220 160 - 180 1 - 1.5 80 - 90 90 - 100<br />

Al Cu4Ti(H) T6 Gravity die casting 330 220 7 95 80 - 110<br />

T64 Gravity die casting 320 180 8 90<br />

Al Cu4MgTi T4 Gravity die casting 320 200 8 95 80 - 110<br />

Al Cu4TiMgAg T6 Gravity die casting 460 - 510 410 - 460 8 130 - 150 100 - 110<br />

Piston casting alloys<br />

Al Si12CuNiMg F Sand casting 140 130 ≤1 80<br />

T6 Sand casting 220 190 ≤1 90<br />

T5 Sand casting 160 140 ≤1 80<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg F Sand casting 140 130 ≤1 80<br />

T6 Sand casting 240 23 ≤1 110<br />

T5 Sand casting 230 220 ≤1 100<br />

Al Si18CuNiMg F Sand casting 140 130 ≤1 85<br />

T6 Sand casting 230 210 ≤1 100<br />

Piston casting alloys<br />

Al Si12CuNiMg F Gravity die casting 200 190 ≤1 90 80 - 110<br />

T6 Gravity die casting 280 240 ≤1 100<br />

T5 Gravity die casting 200 185 ≤1 90<br />

Al Si17Cu4Mg F Gravity die casting 180 170 ≤1 100 80 - 110<br />

T6 Gravity die casting 280 270 ≤1 130<br />

T5 Gravity die casting 165 160 ≤1 105<br />

Al Si18CuNiMg F Gravity die casting 180 170 ≤1 90 80 - 110<br />

T6 Gravity die casting 280 270 ≤1 120<br />

T5 Gravity die casting 180 170 ≤1 90<br />

Continuation of the table on the next page.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 91


<strong>Casting</strong> alloys for special applications<br />

Mechanical properties at room temperature +20 °C<br />

Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />

hardness HB<br />

Fatigue<br />

resistance<br />

MPa MPa % MPa<br />

min min min min<br />

Piston casting alloys<br />

Al Si12CuNiMg F Pressure die casting 240 140 ≤1 90<br />

T5 Pressure die casting 240 140 ≤1 90<br />

Al Si17Cu4Mg 1) F Pressure die casting 220 200 ≤1 100<br />

T5 Pressure die casting 230 210 ≤1 100<br />

Al Si18CuNiMg F Pressure die casting 210 180 ≤1 100<br />

Self-hardening casting alloys<br />

Autodur T1 Sand casting 210 190 ≤1 90<br />

Al Zn10Si8Mg T1 Sand casting 210 190 1 90<br />

Autodur T1 Gravity die casting 260 210 ≤1 100 80 - 100<br />

Autodur(Fe) T1 Pressure die casting 290 230 ≤1 100<br />

Rotor-<strong>Aluminium</strong><br />

Al 99.7E F Gravity die casting 60 20 30 14<br />

Al 99.6E F Gravity die casting 60 20 30 14<br />

Al 99.7E F Pressure die casting 80 20 10 15<br />

Al 99.6E<br />

1) Non-standardised version<br />

F Pressure die casting 80 20 10 15<br />

The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />

as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />

92<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


Heat treatment of aluminium castings<br />

Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />

treatment temperature tempetarure<br />

temperature for quenching<br />

°C h °C °C h<br />

High-strength casting alloys<br />

Al Cu4TiMg T4 520 - 530 8 - 16 20 - 80 15 - 30 > 120<br />

Al Cu5NiCoSbZr T5 Air 345 - 355 8 - 10<br />

T7 535 - 545 10 - 15 20 - 80 210 - 220 12 - 16<br />

Al Cu4Ti T6 515 - 535 8 - 18 20 - 80 170 - 180 6 - 8<br />

Al Cu4TiMgAg T6 525 - 535 8 - 18 20 - 80 170 - 180 6 - 7<br />

Al Cu4Ti(H) T64 515 - 535 8 - 18 20 - 80 135 - 145 6 - 8<br />

Piston casting alloys<br />

Al Si12CuNiMg T5 Air quenching None 210 - 230 10 - 14<br />

T6 520 - 530 5 - 10 20 - 80 165 - 185 5 - 10<br />

Al Si18CuNiMg T5 Air quenching None 225 - 235 7 - 12<br />

T6 495 - 505 7 - 10 20 - 80 165 - 185 7 - 10<br />

T7<br />

Hyper eutectic casting alloys<br />

495 - 505 7 - 10 20 - 80 225 - 235 7 - 10<br />

Al Si17Cu4Mg 1) T5 Air quenching None 225 - 235 7 - 12<br />

T6 495 - 505 7 - 10 20 - 80 165 - 185 7 - 10<br />

T7 495 - 505 7 - 10 20 - 80 225 - 235 7 - 10<br />

1) Non-standardised version<br />

Mechanical properties of gravity die casting samples 1)<br />

Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />

MPa MPa %<br />

-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />

Piston casting alloys<br />

Al Si12CuNiMg F 200 200 160 100 190 170 100 70 ≤ 1 1.5 2.5 3 90 85 60 35<br />

Al Si18CuNiMg F 180 180 160 120 170 150 100 80 ≤ 1 1 2 3 90 90 70 50<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg 2) F 180 180 160 120 170 150 100 80 ≤ 1 1 2 3 100 90 70 50<br />

1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />

2) Non-standardised version<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 93


<strong>Casting</strong> alloys for special applications<br />

Typical process parameters<br />

Alloy <strong>Casting</strong> temperature Contraction allowance<br />

Sand Gravity Pressure Sand Gravity Pressure<br />

casting die casting die casting casting die casting die casting<br />

°C °C °C % % %<br />

High-strength casting alloys<br />

Al Cu4Ti 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />

Al Cu4MgTi 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />

Al Cu4TiMgAg 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />

Al Cu5NiCoSbZr<br />

Piston casting alloys<br />

690 - 750 690 - 750 1.1 - 1.5<br />

Al Si12CuNiMg 670 - 740 670 - 740 620 - 660 1.0 - 1.2 0.5 - 1.0 0.4 - 0.6<br />

Al Si18CuNiMg 730 - 760 730 - 760 730 - 760 0.6 - 1.0 0.4 - 0.8 0.3 - 0.6<br />

Hyper eutectic casting alloys<br />

Al Si17Cu4Mg 1) 720 - 760 720 - 760 720 - 760 0.6 - 1.0 0.4 - 0.8 0.3 - 0.6<br />

Self-hardening casting alloys<br />

Autodur 740 - 690 740 - 690 1.0 - 1.2 0.8 - 1.0<br />

Autodur(Fe) 700 - 650 0.5 - 0.8<br />

Rotor-<strong>Aluminium</strong><br />

Al 99.7E 700 - 730 700 - 730 690 - 730 1.5 - 1.9 1.2 - 1.6 1.0 - 1.4<br />

Al 99.6E<br />

1) Non-standardised version<br />

700 - 730 700 - 730 690 - 730 1.5 - 1.9 1.2 - 1.6 1.0 - 1.4<br />

94<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


High-strength casting alloy<br />

Application notes<br />

These casting alloys are used for parts<br />

which – compared to all other aluminium<br />

casting alloys – require maximum strength.<br />

Where their reduced corrosion resistance<br />

represents no obstacles, these casting<br />

alloys can be used to manufacture high-<br />

strength components, for example, for<br />

the defence industry, aerospace, automotive,<br />

rail vehicles, mechanical engineering<br />

and the textile industry.<br />

Properties and processing<br />

The use of these relatively demanding<br />

casting alloys only makes sense if the<br />

component undergoes heat treatment.<br />

Only then, can the potential of these<br />

casting alloys be fully utilised. Following<br />

heat treatment, the castings still have excellent<br />

elongation as well as displaying<br />

the highest possible strength and hardness.<br />

This combination of high strength<br />

and good elongation values gives these<br />

casting alloys the highest possible Quality<br />

Index “Q”.<br />

By means of special heat treatment,<br />

hardness and elongation values can be<br />

adjusted within determined limits. There<br />

are other variants of these aluminium<br />

casting alloys, e.g. with nickel and cobalt<br />

being added to optimise their strength.<br />

Furthermore, there are also casting alloy<br />

types which contain silver so as to<br />

meet the maximum strength requirements.<br />

The corrosion resistance of cast<br />

pieces is reduced, however, due to the<br />

high copper content.<br />

The casting technique for these alloys is<br />

demanding. Most defects in the castings<br />

stem from “contamination” with silicon.<br />

The silicon content should be kept as<br />

low as possible and always lower than<br />

the iron content. An excess of silicon<br />

produces a low melting phase and increases<br />

the susceptibility to hot tearing<br />

during solidifi cation. Even slight impedi-<br />

ments to solidifi cation shrinkage can<br />

lead to structural separation. The most<br />

important requirement in the foundry is<br />

therefore cleanliness to prevent the takeup<br />

of silicon. Here are some recommendations:<br />

The melting crucible must not<br />

contain any remainder of silicon alloys.<br />

It also makes good sense to melt several<br />

batches of an alloy which is low in silicon<br />

in a new crucible to free the crucible<br />

material of silicon. There are users who,<br />

for this reason, use melting crucibles<br />

made of graphite or cast iron for these<br />

casting alloys. Return material should<br />

also be checked very strictly and stored<br />

separately; residual sand and other return<br />

material must be painstakingly removed<br />

from all sprues. From practical experience,<br />

some users recommend having a<br />

separate foundry department for these<br />

casting alloys. Melt cleaning and degassing<br />

can be carried out without any trouble<br />

using normal means. Melt treatment<br />

is restricted to grain refi nement which,<br />

among other things, slightly counteracts<br />

the susceptibility to hot cracking. Inten-<br />

sive grain refi nement is already performed<br />

by us so it does not usually need to be<br />

repeated in the foundry. The fl uidity of<br />

these casting alloys is comparable with<br />

other hypoeutectic AlSi casting alloys.<br />

The solidifi cation characteristics are best<br />

described as being globular-mushy. At<br />

approx. 90 K, the solidifi cation range is<br />

relatively high. Using a good fi lling system<br />

in conjunction with steered or controlled<br />

solidifi cation and suitable feeding, opti-<br />

mum structural qualities can be achieved<br />

with the sand and gravity die casting<br />

processes. Thanks to their good struc-<br />

tural quality and optimum heat treatment,<br />

these high-strength casting alloys are<br />

suitable for the manufacture of castings<br />

whose unmatched mechanical properties<br />

comply with maximum demands.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 95


High-strength casting alloy<br />

Heat treatment<br />

The heat treatment of castings is another<br />

important step in the production of quality<br />

cast parts. Exact temperature regulation<br />

of the annealing furnace, good tempera-<br />

ture distribution by means of circulating<br />

air and the correct positioning of the<br />

casting in the baskets, holders or racks<br />

are essential prerequisites for success.<br />

In solution annealing, the temperature<br />

increase should be moderate in order<br />

to allow enough time for temperature<br />

equalisation to take place in the castings<br />

and to avoid incipient fusion. The relief<br />

of casting strain, the removal of microstructural<br />

inhomogeneity and the diffusion<br />

of hardening constituents require<br />

longer periods of time. In these casting<br />

alloys, especially in thick-walled, slowsolidifying<br />

castings, stepped annealing<br />

96<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

is recommended. First of all, the cast<br />

pieces undergo preliminary annealing<br />

at 480 to 490 °C for between 4 and 8<br />

hours; they are then given a solution heat<br />

treatment at approx. 515 to 535 °C for a<br />

further 6 to 10 hours. To avoid distortion,<br />

quenching of the casting after annealing<br />

can be effected by means of a water<br />

shower followed by immersion in warm<br />

water at temperatures of up to 80 °C.<br />

Fully-annealed Al Cu4TiMg castings have<br />

a susceptibility to stress corrosion. This<br />

condition is therefore not standardised<br />

for this casting alloy. Such parts are only<br />

used in naturally-aged condition (T4).


Piston alloys<br />

Application notes<br />

These casting alloys are used for cast-<br />

ings with wear-resistant surfaces and for<br />

structures which have to possess good<br />

strength properties at high temperatures.<br />

The main applications comprise: pistons<br />

for combustion engines, crankcases<br />

without additional cylinder liners, pump<br />

casings, valve casings, valve slides, gear<br />

elements etc.<br />

Properties and processing<br />

The wear resistance of these casting al-<br />

loys is due to many hard, rectangular or<br />

polygonal primary silicon crystals which<br />

are embedded in the ductile base mate-<br />

rial and jut out of the surface of the track<br />

with an edge (while the neighbouring<br />

troughs act as reservoirs for lubricant).<br />

In addition, alloying elements such as<br />

Cu, Mg or Ni give these casting alloys<br />

remarkable high-temperature strength.<br />

In order to produce as many small and<br />

evenly-distributed silicon crystals as<br />

possible in the cast structure, phosphorous<br />

is added. This treatment is already<br />

carried out during production of the ingots<br />

in our secondary smelters and, as<br />

a rule, does not need to be repeated by<br />

the foundry. The fl uidity of these types<br />

of casting alloy is very good. In spite of<br />

this, silicon crystals forming in the melt<br />

at too low casting temperatures are to<br />

be avoided because of their abrasive effect.<br />

Additional information is provided<br />

in the section on “Selecting aluminium<br />

casting alloys”.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 97


Self-hardening aluminium-silicon-zinc<br />

casting alloys<br />

Application notes<br />

These casting alloys are used in the<br />

manufacture of models, foamed shapes,<br />

wearing parts or the bases of electric<br />

irons, for example. The use of these<br />

casting alloys is not recommended for<br />

machine parts which are subject to alternating<br />

or impact stress, are obliged<br />

to absorb bending and shearing stress<br />

or requiring a specifi c ductility.<br />

98<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />

Properties and processing<br />

The fl uidity of Autodur in particular is very<br />

good. Solidifi cation behaviour is similar<br />

to that of other casting alloys containing<br />

approx. 9 % silicon. <strong>Alloys</strong> of this type<br />

are self-hardening, i.e. after casting, the<br />

castings are stored at room tempera-<br />

ture and within approx. 10 days reach<br />

their service properties. This hardening<br />

takes place as a result of precipitation<br />

of the complex Al ZnMg. The advantage<br />

of these casting alloys lies exclusively<br />

in their saving of heat treatment costs.<br />

There are, however, disadvantages in<br />

using these casting alloys. The following<br />

information should serve as a warning:<br />

Under unfavourable conditions whilst<br />

molten, the zinc content is reduced due<br />

to its high vapour pressure. The resistance<br />

of Autodur to corrosion is sharply<br />

reduced as a result of its high zinc content<br />

of around 10 %.<br />

In cases where the exposure to corrosion<br />

is great or where parts made from Autodur<br />

are assembled with other castings or<br />

parts made from other aluminium alloys,<br />

or indeed fi tted to steel parts, there is a<br />

strong tendency to contact corrosion.<br />

Compared with all other aluminium cast-<br />

ing alloys, castings made from these al-<br />

loys display the lowest high-temperature<br />

strength. (Precipitation treatment carried<br />

out at room temperature to increase hard-<br />

ness has no clearly defi nable effect.) Ex-<br />

perience shows that castings, even after<br />

many years, can fracture spontaneously<br />

under the slightest impact or shock load.<br />

Over time, the microstructure appears to<br />

be embrittled.


Rotor aluminium<br />

Application notes<br />

This pure aluminium is mostly used in<br />

pressure die casting and goes into the<br />

manufacture of rotors (short-circuit armatures)<br />

and stators for the electric motor<br />

sector. It can also be cast into other<br />

construction elements which require<br />

high electrical and thermal conductivity.<br />

Properties and processing<br />

There is a particular hurdle in the near<br />

net shape casting of pure aluminium,<br />

i.e. sensitivity to hot tearing. The most<br />

important prerequisite for keeping this<br />

problem within limits is to maintain the<br />

correct ratio between iron and silicon. The<br />

silicon content must be as low as possible<br />

and the iron content must always be at<br />

least double the silicon content. Molten<br />

pure aluminium readily absorbs silicon<br />

from any standing material it comes into<br />

contact with. This can easily lead to an<br />

“imbalanced ratio”. Cleanliness is therefore<br />

important during processing and it<br />

is also essential to check tools and the<br />

melting crucible. In extreme emergencies<br />

when silicon enrichment occurs, it<br />

helps to increase the iron content within<br />

the permitted tolerance range.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 99


<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


We have taken the relevant specialist<br />

literature into consideration while<br />

drawing up this <strong>Aluminium</strong> <strong>Casting</strong><br />

Alloy Catalogue. Please do not hesitate<br />

to contact us if you require more<br />

detailed literary explanations.<br />

If you require any additional data or<br />

support at short notice, please refer<br />

to our contact details on the back<br />

of this brochure or simply visit us<br />

online at www.aleris.com.<br />

<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>


www.aleris.com<br />

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Protective charge: 18 Euro Issue 12/11 · 1st release

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