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<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Content<br />
4<br />
Introduction 5<br />
Recycled aluminium 6<br />
Technology and service<br />
for our customers<br />
Quality Management 7<br />
Work safety and health 8<br />
protection<br />
Environmental protection<br />
<strong>Aluminium</strong> and aluminium 9<br />
casting alloys<br />
<strong>Aluminium</strong> – Material properties<br />
Recycling of aluminium<br />
Shaping by casting 10<br />
Product range and 11<br />
form of delivery<br />
Technical consultancy 12<br />
service<br />
Selecting aluminium 13<br />
casting alloys<br />
Criteria for the selection of 14<br />
aluminium casting alloys<br />
Infl uence of the 18<br />
most important alloying<br />
elements on aluminium<br />
casting alloys<br />
Infl uencing the 19<br />
microstructural formation of<br />
aluminium castings<br />
Grain refi nement 20<br />
Modifi cation of AlSi eutectic 21<br />
Refi nement of 23<br />
primary silicon<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Melt quality and melt cleaning 24<br />
Avoiding impurities 25<br />
Melt testing and 28<br />
inspection procedure<br />
Thermal analysis 30<br />
Selecting the casting process 31<br />
Pressure die casting 32<br />
process<br />
Gravity die casting process<br />
Sand casting process 34<br />
<strong>Casting</strong>-compliant design 35<br />
Solidifi cation simulation 37<br />
and thermography<br />
Avoiding casting defects 38<br />
Heat treatment of 40<br />
aluminium castings<br />
Metallurgy –<br />
fundamental principles<br />
Solution annealing 41<br />
Quenching<br />
Ageing 42<br />
Mechanical machining of 44<br />
aluminium castings<br />
Welding and joining 45<br />
aluminium castings<br />
Suitability and behaviour<br />
Applications in the<br />
aluminium sector<br />
Welding processes<br />
Weld preparation 47<br />
Weld fi ller materials<br />
Surface treatment: corrosion 48<br />
and corrosion protection<br />
Information on physical data, 50<br />
strength properties and<br />
strength calculations<br />
Notes on the casting 51<br />
alloy tables<br />
Overview: <strong>Aluminium</strong> casting 52<br />
alloys by alloy group<br />
Eutectic aluminium-silicon 59<br />
casting alloys<br />
Near-eutectic wheel 63<br />
casting alloys<br />
The 10 per cent aluminium- 66<br />
silicon casting alloys<br />
The 7 and 5 per cent 71<br />
aluminium-silicon<br />
casting alloys<br />
Al SiCu casting alloys 76<br />
AlMg casting alloys 81<br />
<strong>Casting</strong> alloys for special 87<br />
applications
Introduction<br />
Many of you have most certainly worked<br />
with the “old“ <strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Catalogue – over the years in thousands<br />
of workplaces in the aluminium industry,<br />
it has become a standard reference<br />
book, a reliable source of advice about<br />
all matters relating to the selection and<br />
processing of aluminium casting alloys.<br />
Even if you are holding this <strong>Aluminium</strong><br />
<strong>Casting</strong> <strong>Alloys</strong> Catalogue in your hands<br />
for the fi rst time, you will quickly fi nd your<br />
way around with the help of the following<br />
notes and the catalogue‘s detailed index.<br />
How is this <strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Catalogue structured? The catalogue<br />
consists of three separate parts. In the<br />
fi rst part, we provide details on our com-<br />
pany – a proven supplier of aluminium<br />
casting alloys.<br />
In the second part, all technical aspects<br />
which have to be taken into account in<br />
the selection of an aluminium casting alloy<br />
are explained in detail. All details are<br />
based on the DIN EN 1676: 2010 standard.<br />
The third part begins with notes on the<br />
physical data, tensile strength characteristics<br />
and strength calculations of<br />
aluminium casting alloys. Subsequently,<br />
all standardised aluminium casting alloys<br />
in accordance with DIN EN 1676 as well<br />
as common, non-standardised casting<br />
alloys are depicted in a summary table<br />
together with their casting/technical and<br />
other typical similarities in “alloy families”.<br />
The aim of this new, revised and redesigned<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> Catalogue<br />
is to give the user of aluminium<br />
casting alloys a clear, well laid-out companion<br />
for practical application. Should<br />
you have any questions concerning the<br />
selection and use of aluminium casting<br />
alloys, please contact our foundry consultants<br />
or our sales staff.<br />
You can also refer to www.aleris.com.<br />
We would be pleased to advise<br />
you and wish you every success<br />
in your dealings with aluminium<br />
casting alloys!<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
5
Recycled aluminium<br />
Technology and service for our customers<br />
Employing approx. 600 people, <strong>Aleris</strong><br />
Recycling produces high-quality casting<br />
and wrought alloys from recycled<br />
aluminium. The company‘s headquarters<br />
are represented by the “Erftwerk”<br />
in Grevenbroich near Düsseldorf which<br />
is also the largest production facility in<br />
the group. Other production facilities<br />
in Germany (Deizisau, Töging), Norway<br />
(Eidsväg, Raudsand) and Great Britain<br />
(Swansea) are managed from here. With<br />
up to 550,000 mt, <strong>Aleris</strong> Recycling avails<br />
of the largest production capacities in<br />
Europe and is also one of the world‘s<br />
leading suppliers of technology and<br />
services relating to aluminium casting<br />
alloys. <strong>Aleris</strong> Recycling also offers a wide<br />
range of high-quality magnesium alloys.<br />
<strong>Aluminium</strong> recycled from scrap and<br />
dross has developed to become a<br />
highly-complex technical market of the<br />
future. This is attributable to the steady<br />
increase in demand for raw materials,<br />
the sustainability issue, increased environmental<br />
awareness among producers<br />
and consumers alike and, not least, the<br />
necessity to keep production costs as<br />
low as possible.<br />
This is where aluminium offers some essential<br />
advantages. Recycled aluminium<br />
can be generated at only a fraction of the<br />
energy costs (approx. 5%) compared to<br />
primary aluminium manufactured from<br />
bauxite with the result that it makes a<br />
signifi cant contribution towards reduc-<br />
ing CO 2 emissions. This light-alloy metal<br />
can be recycled any number of times<br />
and good segregation even guarantees<br />
no quality losses.<br />
6<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Its properties are not impaired when<br />
used in products. The metallic value is<br />
retained which represents a huge economic<br />
incentive to collect, treat and melt<br />
the metal in order to reuse it at the end<br />
of its useful life.<br />
For this reason, casting alloys from <strong>Aleris</strong><br />
Recycling can be used for manufacturing<br />
new high-quality cast products such as<br />
crankcases, cylinder heads or aluminium<br />
wheels while wrought materials can be<br />
used for manufacturing rolled and pressed<br />
products, for example. Key industries<br />
supplied include:<br />
Rolling mills and extrusion plants<br />
Automotive industry<br />
Transport sector<br />
Packaging industry<br />
Engineering<br />
Building and construction<br />
Electronics industry<br />
as well as other companies in the<br />
<strong>Aleris</strong> Group.<br />
State-of-the-art production facilities and<br />
an extensive range of products made of<br />
aluminium in the form of scrap, chips or<br />
dross are collected and treated by <strong>Aleris</strong><br />
Recycling before melting in tilting rotary<br />
furnaces with melting salt, for example,<br />
whereby the salt prevents the aluminium<br />
from oxidising while binding contaminants<br />
(salt slag). Modern processing and<br />
melting plants at <strong>Aleris</strong> Recycling enable<br />
effi cient yet environmentally-friendly re-<br />
cycling of aluminium scrap and dross.<br />
The technology used is largely based on<br />
our own developments and – in terms of<br />
yield and melt quality – works signifi cantly<br />
more effi ciently than fi xed axis rotary<br />
furnaces and hearth furnaces. The melt<br />
gleaned from these furnaces has a very<br />
low gas content thanks to the special gas<br />
purging technique we use as well as<br />
being homogeneous and largely free of<br />
oxide inclusions and/or contaminants.<br />
The resulting high quality of <strong>Aleris</strong> alloys<br />
enables our customers to open up an increasing<br />
number of possible applications.<br />
All management processes and the entire<br />
process chain from procurement<br />
through production to sale are subject to<br />
systematic Quality Management. Combined<br />
with Quality Management certifi ed<br />
to ISO/TS 16949 and DIN EN ISO 9001,<br />
this guarantees that our clients‘ maximum<br />
requirements and increasing demands<br />
can be fulfi lled.<br />
The product range offered by <strong>Aleris</strong> Re-<br />
cycling comprises more than 250 differ-<br />
ent casting and wrought alloys. They can<br />
be supplied as ingots with unit weights<br />
of approx. 6 kg (in stacks of up to 1,300<br />
kg) as well as pigs of up to 1,400 kg or<br />
as liquid metal. Based on our sophisticated<br />
crucible technology and optimised<br />
transport logistics, <strong>Aleris</strong> Recycling supplies<br />
customers with liquid aluminium in<br />
a just-in-time process and at the appropriate<br />
temperature.
Due to its future-oriented corporate<br />
structure, <strong>Aleris</strong> Recycling supplies the<br />
market with an increasing number of<br />
applications involving high-quality secondary<br />
aluminium. This service is not restricted<br />
to the area of casting alloys but<br />
also applies for 3000- and 5000-grade<br />
wrought alloys, for example. <strong>Aleris</strong> Recycling<br />
is also capable of offering some<br />
6000-grade secondary aluminium alloys<br />
largely required by the automotive sector.<br />
For this so-called upgrade, <strong>Aleris</strong> applies<br />
special production technologies when<br />
it comes to manufacturing high-quality<br />
alloys from scrap.<br />
Recycled aluminium is increasingly be-<br />
coming a complex range at the interface<br />
between high-tech production, trade and<br />
service. In addition, customers demand<br />
intensive consulting as well as individual<br />
service. <strong>Aleris</strong> Recycling enjoys an excellent<br />
position in this regard.<br />
At its various locations, the company<br />
units offer a high degree of recycling expertise,<br />
manufacturing competence and<br />
delivery reliability for its customers. With<br />
the result that <strong>Aleris</strong> Recycling guarantees<br />
its customers a high level of effi ciency<br />
and added value while supporting their<br />
success on the market.<br />
Quality Management<br />
We believe that our most important cor-<br />
porate goal is to meet in full our custom-<br />
ers‘ requirements and expectations in<br />
terms of providing them with products<br />
and services of consistent quality. In order<br />
to meet this goal, our guidelines and<br />
integrated management system specifi -<br />
cations outline rules and regulations that<br />
are binding for all staff.<br />
As a manufacturer of aluminium casting<br />
alloys, we are certifi ed according to ISO/<br />
TS 16949. In addition, we operate according<br />
to DIN EN ISO 9001 standards.<br />
The principle of avoiding errors is para-<br />
mount in all our individual procedures and<br />
regulations. In other words, our priority<br />
is to strive to achieve a zero-error target.<br />
By effectively combating the sources of<br />
errors, we create the right conditions for<br />
reliability and high quality standards.<br />
We have also established a comprehen-<br />
sive process of continuous improvement<br />
(PMO, Best Practice, Six Sigma etc.) in<br />
our plants in response to the demands<br />
being placed on our company by the<br />
increasing trend towards business globalisation.<br />
This creates the right climate<br />
for creative thinking and action.<br />
All members of staff, within their own<br />
area of responsibility, endeavour to ensure<br />
that operational procedures are<br />
constantly improved, even if in small,<br />
gradual stages, with a clear focus on<br />
our customers‘ needs.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
7
Work safety and health protection<br />
Our staff are our most valuable asset. Work<br />
safety and health protection, therefore,<br />
have top priority for us, and also make<br />
a valuable contribution to the success<br />
of our company. Our “Work safety and<br />
health protection” programme is geared<br />
towards achieving a zero accident rate,<br />
and towards avoiding occupational illnesses.<br />
Depending on the respective<br />
location, we are certifi ed to OHSAS<br />
18001 or OHRIS.<br />
All management members and staff are<br />
obliged to comply with legal regulations<br />
and company rules at all times, to protect<br />
their own health and the health of<br />
other members of staff and, when engaged<br />
in any company operations, to<br />
do their utmost to ensure that accidents<br />
and work-related illnesses are avoided,<br />
as well as anything that might have a<br />
negative impact on the general company<br />
environment. Management provides the<br />
appropriate level of resources required<br />
to achieve these goals.<br />
There are regular internal and external<br />
training seminars on the topic of work<br />
safety, and detailed programmes to improve<br />
health protection. These help to<br />
maintain our comparatively low accident<br />
and illness rates.<br />
8<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Environmental protection<br />
Following the validation of our environ-<br />
mental management system in conformity<br />
with EMAS II and certifi cation to DIN EN<br />
ISO 14001, we have undertaken not only<br />
to meet all the required environmental<br />
standards, but also to work towards a<br />
fundamental, systematic and continual<br />
improvement in the level of environmental<br />
protection within the company.<br />
Our management system and environ-<br />
mental policy are documented in the<br />
company manual which describes all<br />
the elements of the system in easily<br />
understood terms, while serving as a<br />
reference for all regulations concerning<br />
the environment.<br />
The environmental impacts of our com-<br />
pany operations in terms of air purity,<br />
protection of water bodies, noise and<br />
waste are checked at regular intervals.<br />
By modifying procedures, reusing mate-<br />
rials and recycling residues, we optimise<br />
the use of raw materials and energy in<br />
order to conserve resources as effi ciently<br />
as possible.<br />
We pursue a policy of open information<br />
and provide interested members of the<br />
public with comprehensive details of<br />
the company‘s activities in a particular<br />
location, and an explanation of the<br />
environmental issues involved. For us,<br />
open dialogue with the general public,<br />
our suppliers, customers and other<br />
contractual partners is as much a part<br />
of routine operations as reliable co-operation<br />
with the relevant authorities and<br />
trade associations.<br />
Likewise, ecological standards are incorporated<br />
in development and planning<br />
processes for new products and production<br />
processes, as are other standards<br />
required by the market or society at large.<br />
Our staff is fully conscious of all environmental<br />
protection issues and is keen to<br />
ensure that the environmental policy is<br />
reliably implemented in day-to-day operations<br />
within the company.
<strong>Aluminium</strong> and aluminium casting alloys<br />
<strong>Aluminium</strong> – Material properties<br />
<strong>Aluminium</strong> has become the most widely<br />
used non-ferrous metal. It is used in the<br />
transport sector, construction, the pack-<br />
aging industry, mechanical engineering,<br />
electrical engineering and design. New<br />
fi elds of application are constantly open-<br />
ing up as the advantages of this material<br />
speak for themselves:<br />
<strong>Aluminium</strong> is light; its specifi c weight<br />
is substantially lower than other<br />
common metals and, at the same<br />
time, it is so strong that it can with<br />
stand high stress.<br />
<strong>Aluminium</strong> is very corrosionresistant<br />
and durable. A thin,<br />
natural oxide layer protects<br />
aluminium against decomposition<br />
from oxygen, water or chemicals.<br />
<strong>Aluminium</strong> is an excellent<br />
conductor of electricity,<br />
heat and cold.<br />
<strong>Aluminium</strong> is non-toxic, hygienic<br />
and physiologically harmless.<br />
<strong>Aluminium</strong> is non-magnetic.<br />
<strong>Aluminium</strong> is decorative and<br />
displays high refl ectivity.<br />
<strong>Aluminium</strong> has outstanding<br />
formability and can be<br />
processed in a variety of ways.<br />
<strong>Aluminium</strong> alloys are easy to cast<br />
as well as being suitable for all known<br />
casting processes.<br />
<strong>Aluminium</strong> alloys are<br />
distinguished by an excellent<br />
degree of homogeneity.<br />
<strong>Aluminium</strong> and aluminium<br />
alloys are easy to machine.<br />
<strong>Casting</strong>s made from aluminium<br />
alloys can be given an artifi cial,<br />
wear-resistant oxide layer<br />
using the ELOXAL process.<br />
<strong>Aluminium</strong> is an outstanding<br />
recycling material.<br />
Recycling of aluminium<br />
Long before the term “recycling” became<br />
popular, recycling circuits already exist-<br />
ed in the aluminium sector. Used parts<br />
made from aluminium or aluminium alloys<br />
as well as aluminium residue materials<br />
arising from production and fabrication<br />
are far too valuable to end up as landfi<br />
ll. One of the great advantages of this<br />
metal, and an added plus for its use as a<br />
construction material, is that aluminium<br />
parts, no matter the type, are extremely<br />
well suited to remelting.<br />
The energy savings made in<br />
recycling aluminium are<br />
considerable. Remelting requires<br />
only about 5 % of the energy<br />
initially required to produce<br />
primary aluminium.<br />
As a rule, aluminium recycling<br />
retains the value added to the<br />
metal. <strong>Aluminium</strong> can be recycled<br />
to the same quality level as the<br />
original metal.<br />
<strong>Aluminium</strong> recycling safeguards<br />
and supplements the supply of<br />
raw materials while saving<br />
resources, protecting the<br />
environment and conserving<br />
energy. Recycling is therefore also<br />
a dictate of economic reason.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
9
The experience accumulated over many<br />
decades, the use of state-of-the-art<br />
technology in scrap preparation, remelting<br />
and exhaust gas cleaning as well<br />
as our constant efforts to develop new,<br />
environmentally-sound manufacturing<br />
technology puts us in a position to<br />
achieve the best possible and effi cient<br />
recycling rates. At the same time, they<br />
also help us to make the most effi cient<br />
use of energy and auxiliary materials.<br />
10<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Shaping by casting<br />
<strong>Casting</strong> represents the shortest route<br />
from raw materials to fi nished parts – a<br />
fact which has been known for fi ve thou-<br />
sand years. Through continuous further<br />
development and, in part, by a selective<br />
return to classic methods such as the<br />
lost-form process, casting has remained<br />
at the forefront of technical progress.<br />
The most important advantage of the<br />
casting process is that the possibilities<br />
of shaping the part are practically limitless.<br />
<strong>Casting</strong>s are, therefore, easier and<br />
cheaper to produce than machined and/<br />
or joined components. The general waiving<br />
of subsequent machining not only<br />
results in a good density and path of<br />
force lines but also in high form strength.<br />
Furthermore, waste is also avoided. As a<br />
rule, the casting surface displays a tight,<br />
fi ne-grained structure and, consequently,<br />
is also resistant to wear and corrosion.<br />
The variety of modern casting processes<br />
makes it possible to face up to the<br />
economic realities, i.e. the optimisation<br />
of investment expenditure and costs<br />
in relation to the number of units. With<br />
casting, the variable weighting of production<br />
costs and quality requirements<br />
are also possible.<br />
When designing the shape of the cast-<br />
ing, further possibilities arise from the<br />
use of inserts and/or from joining the<br />
part to other castings or workpieces.<br />
In the last decade, aluminium has at-<br />
tained a leading position among cast<br />
metals because, in addition to its other<br />
positive material properties, this light<br />
metal offers the greatest possible variety<br />
of casting and joining processes.
Product range and form of delivery<br />
As ecological and economic trends sensibly<br />
move towards the development of<br />
closed material circuits, the clear dividing<br />
lines between the three classic quality<br />
grades of aluminium casting alloys are<br />
ever-decreasing. In future, people will<br />
simply talk about “casting alloys”. In<br />
practice, this is already the case. Metal<br />
from used parts is converted back into<br />
the same fi eld of application. The DIN<br />
EN 1676 and 1706 standards with their<br />
rather fl uid quality transitions take this<br />
trend into account.<br />
<strong>Aleris</strong> is one of only a few companies<br />
to produce a wide range of aluminium<br />
alloys; our product spectrum extends<br />
from classic secondary alloys to highpurity<br />
alloys for special applications.<br />
Production is in full compliance with<br />
the European DIN EN 1676 standard<br />
or international standards and in many<br />
cases, manufactured to specifi c cus-<br />
tomer requirements. We have also been<br />
offering several aluminium casting al-<br />
loys as protected brand-name alloys<br />
for many years, e.g. Silumin ®® , Pantal ®®<br />
and Autodur ® .<br />
Our casting alloys are delivered in the<br />
form of ingots with a unit weight of approx.<br />
6 kg or as liquid metal.<br />
We distinguish between ingots cast in<br />
open moulds and horizontal continu-<br />
ously cast ingots (so-called HGM). Ingots<br />
are dispatched in bundles of up to<br />
approx. 1,300 kg.<br />
The delivery of liquid or molten metal is<br />
useful and economic when large quanti-<br />
ties of one homogeneous casting alloy are<br />
required and the equipment for tapping<br />
and holding the molten metal containers<br />
is available. Supplying molten metal can<br />
lead to a substantial reduction in costs<br />
as a result of saving melting costs and<br />
a reduction in melting losses. The supply<br />
of liquid metal also provides a viable<br />
alternative in cases where new melting<br />
capacities need to be built to comply<br />
with emission standards or where space<br />
is a problem.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 11
Technical consultancy service<br />
The technical consultancy service is<br />
the address for questions relating to<br />
foundry technology. We provide assis-<br />
tance in clarifying aluminium casting alloy<br />
designations as stated in German and<br />
international standards or the temper<br />
conditions for castings. We also offer<br />
advice on the selection of alloys and can<br />
provide aluminium foundries or users of<br />
castings with information on:<br />
<strong>Aluminium</strong> casting alloys<br />
Chemical and physical properties<br />
<strong>Casting</strong> and solidifi cation<br />
behaviour<br />
<strong>Casting</strong> processes and details<br />
regarding foundry technology<br />
Melt treatment possibilities, such as<br />
cleaning, degassing, modifi cation<br />
or grain refi nement<br />
Possibilities of infl uencing the<br />
strength of castings by means<br />
of alloying elements or heat<br />
treatment<br />
Questions relating to surface<br />
fi nish and surface protection.<br />
12<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Technical consultants also provide as-<br />
sistance in evaluating casting defects or<br />
surface fl aws and offer suggestions with<br />
regard to eliminating defects. They sup-<br />
ply advice on the design of castings, the<br />
construction of dies, the casting system<br />
and the confi guration of feeders.<br />
Technical consultants also provide tech-<br />
nical support to aluminium foundries in<br />
the preparation of chemical analyses,<br />
microsections and structural analyses.<br />
Customer feedback coupled with exten-<br />
sive experience in the foundry sector fa-<br />
cilitates the continuous optimisation and<br />
quality improvement of our aluminium<br />
casting alloys.<br />
In co-operation with our customers, we<br />
are working on gaining wider acceptance<br />
of our aluminium casting alloys in new<br />
fi elds of application.<br />
Where required and especially where<br />
fundamental problems arise, we arrange<br />
contracts with leading research institutes<br />
in Europe and North America.
Selecting aluminium casting alloys<br />
To supplement and provide greater depth<br />
to our technical explanations, we refer<br />
you to standard works on aluminium<br />
and aluminium casting alloys. Further<br />
details on other specialist literature are<br />
available and can be requested at any<br />
time. We would be delighted to advise<br />
you in such matters.<br />
Should you have any queries or com-<br />
ments, which are always welcome,<br />
please contact our technical service.<br />
Standard works on aluminium and aluminium<br />
casting alloys:<br />
“<strong>Aluminium</strong>-Taschenbuch”, Verlag<br />
Beuth, Düsseldorf<br />
“<strong>Aluminium</strong> viewed from within -<br />
Profi le of a modern metal”, Prof.<br />
Dr. D. G. Altenpohl, Verlag Beuth,<br />
Düsseldorf.<br />
Once the requirements of a casting<br />
have been determined, the selection of<br />
the correct casting alloy from the multitude<br />
of possibilities often represents<br />
a problem for the designer and also for<br />
the foundryman. In this case, the “<strong>Aluminium</strong>-Taschenbuch”<br />
can be of great<br />
assistance.<br />
In the European DIN EN 1676 and DIN<br />
EN 1706 standards, the most important<br />
aluminium casting alloys have been collated<br />
in a version which is valid Europewide.<br />
Consequently, there are already<br />
more than 41 standard aluminium casting<br />
alloys available.<br />
<strong>Aluminium</strong> foundries should – according<br />
to their respective structure – limit themselves<br />
to as small a number of casting<br />
alloys as possible in order to use their<br />
melting equipment economically, to keep<br />
inventories as low as possible and to reduce<br />
the risk of mixing alloys.<br />
With regard to the quality of a casting,<br />
it is more sensible to process a casting<br />
alloy which is operational in use than one<br />
which displays slightly better properties<br />
on paper but is actually more diffi cult to<br />
process. The quality potential of a casting<br />
alloy is only exploited in a casting if<br />
the cast piece is as free as possible of<br />
casting defects and is suitable for subsequent<br />
process steps (e.g. heat treatment).<br />
Our sales team and technicians are on<br />
hand to provide foundries and users<br />
of castings with assistance in selecting<br />
the correct aluminium casting alloy.<br />
As far as possible, the use of common<br />
aluminium casting alloys is recommended.<br />
These involve well-known and proven<br />
casting alloys and we stand fully behind<br />
the quality properties of these casting<br />
alloys which are often manufactured in<br />
large quantities, are more cost-effective<br />
than special alloys and, in most cases,<br />
can be delivered at short notice.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 13
Criteria for the selection of<br />
aluminium casting alloys<br />
In the following section, we provide an<br />
insight into the chemical and physical<br />
potentials of aluminium casting alloys by<br />
describing their various properties. The<br />
standardisation provided here helps to<br />
establish whether a casting alloy is suitable<br />
for the specifi c demands placed<br />
on a casting.<br />
Degree of purity<br />
One important selection criteria is the de-<br />
gree of purity of a casting alloy. With the<br />
increasing purity of a casting alloy family,<br />
the corrosion resistance and ductility of<br />
the as-cast structure also increase; the<br />
selection of pure feedstock for making<br />
casting alloys, however, will necessarily<br />
cause costs to rise.<br />
The increasing importance of the closedcircuit<br />
economy means that, for the producer<br />
of aluminium casting alloys, the<br />
transition between the previous quality<br />
grades for aluminium casting alloys is<br />
becoming ever more fl uid.<br />
Due to their high purity, casting alloys<br />
made from primary aluminium display the<br />
best corrosion resistance as well as high<br />
ductility. By way of example, Silumin-Beta<br />
with max. 0.15 % Fe, max. 0.03 % Cu<br />
and max. 0.07 % Zn can be mentioned.<br />
In many countries, the Silumin trademark<br />
has already become a synonym for aluminium-silicon<br />
casting alloys.<br />
14<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Classifi cation of casting alloys acc. to strength properties 1)<br />
Table 1<br />
<strong>Casting</strong> alloy Temper Tensile Elongation Brinell<br />
strength hardness<br />
Rm [MPa]<br />
A5 [%] HB<br />
Strong Al Cu4Ti T6 330 7 95<br />
and ductile Silumin-Beta T6 290 4 90<br />
Al Si10Mg(a) T6 260 1 90<br />
Hard Al Si8Cu3 F 170 1 75<br />
Al Si18CuNiMg F 180 1 90<br />
Ductile Silumin F 170 7 45<br />
Other Al Mg3 F 150 5 50<br />
1) Typical values for permanent mould casting,<br />
established on separately-cast test bars.<br />
<strong>Casting</strong> alloys made from scrap are,<br />
with regard to ductility and corrosion<br />
resistance, inferior to other casting alloy<br />
groups due to their lower purity. They are,<br />
however, widely applicable and meet the<br />
set performance requirements.<br />
Strength properties<br />
Strength properties should be discussed<br />
as a further selection criterion (Table 1).<br />
A rough subdivision into four groups is<br />
practical:<br />
“strong and ductile”<br />
The most important age-hardenable<br />
casting alloys belong to this group. By<br />
means of different kinds of heat treatment,<br />
their properties can be adjusted<br />
either in favour of high tensile strength<br />
or high elongation. In Table 1, the typical<br />
combinations of R and A values for<br />
m<br />
different casting alloys are compared.<br />
These casting alloys are used for highgrade<br />
construction components, especially<br />
for critical parts.<br />
“hard”<br />
The casting alloys of this group must<br />
display a certain tensile strength and<br />
hardness without particular requirements<br />
being placed on the metal‘s elongation.<br />
First of all, Al SiCu alloys belong to this<br />
group. Due to their Cu, Mg and Zn content,<br />
these casting alloys experience a<br />
certain amount of self-hardening after<br />
casting (approx. 1 week). These alloys<br />
are particularly important for pressure<br />
die casting since it is in pressure die<br />
casting – except for special processes<br />
such as vacuum die casting – that process-induced<br />
structural defects occur,<br />
preventing high elongation values. Due<br />
to its particularly strong self-hardening<br />
characteristics, the Autodur casting al-
Table 2<br />
Classifi cation of casting alloys acc. to casting properties<br />
Fluidity Thermal<br />
crack<br />
susceptibility<br />
<strong>Casting</strong> alloy Type of solidifi cation<br />
High Low Silumin<br />
Al Si12<br />
Exogenous-shell forming<br />
Al S12(Cu) Exogenous-rough wall<br />
Al Si10Mg<br />
Silumin-Beta<br />
Al Si8Cu3<br />
Pantal 7<br />
Al Si5Mg<br />
Al Cu4Ti<br />
Endogenous-dendritic<br />
Al Mg3 Endogenous-globular<br />
Low High Al Mg5 Mushy<br />
loy represents a special case allowing<br />
hardness values of approx. 100 HB and<br />
a corresponding strength – albeit at very<br />
low ductility – in all casting processes.<br />
Hypereutectic AlSi casting alloys such<br />
as Al Si18CuNiMg and Al Si17Cu4Mg,<br />
for example, which display particularly<br />
high wear resistance due to their high<br />
silicon content, can also be classifi ed<br />
in this group.<br />
“ductile”<br />
<strong>Casting</strong> alloys which display particu-<br />
larly high ductility, e.g. Silumin-Kappa<br />
(Al Si11Mg), come under this general<br />
heading. This casting alloy is frequently<br />
used for the manufacture of automobile<br />
wheels.<br />
In this particular application, a high elongation<br />
value is required for safety reasons.<br />
“other”<br />
<strong>Casting</strong> alloys for more decorative purposes<br />
with lower strength properties, e.g.<br />
Al Mg3, belong to this category.<br />
<strong>Casting</strong> properties<br />
Further selection criteria comprise cast-<br />
ing properties such as the fl uidity or<br />
solidifi cation behaviour which sets the<br />
foundryman certain limits. Not every<br />
ideally-shaped casting can be cast in<br />
every casting alloy.<br />
A simplifi ed summary of the casting prop-<br />
erties associated with the most important<br />
casting alloys is shown in Table 2.<br />
Co-operation between the technical designer<br />
and an experienced foundryman<br />
works to great advantage when looking<br />
for the optimum casting alloy for a particular<br />
application.<br />
Given constant conditions, the fl uidity<br />
of a metallic melt is established by de-<br />
termining the fl ow length of a test piece.<br />
Theoretically, low fl uidity can be offset<br />
by a higher casting temperature; this is,<br />
however, linked with disadvantages such<br />
as oxidation and hydrogen absorption as<br />
well as increased mould wear. Eutectic<br />
AlSi casting alloys such as Silumin or<br />
Al Si12 display high fl uidity. Hypoeutectic<br />
AlSi casting alloys such as Pantal 7 have<br />
medium values. AlCu and AlMg casting<br />
alloys display low fl uidity.<br />
Hypereutectic AlSi casting alloys such<br />
as Al Si17Cu4Mg occupy a special posi-<br />
tion. In their case, very long fl ow paths<br />
are observed. This does not however<br />
necessarily lead to a drop in the melt<br />
temperature since primary silicon crystals<br />
already form in the melt. The melt<br />
still fl ows well because the latent heat<br />
of solidifi cation of the primary silicon<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 15
Selection criteria for aluminium casting alloys<br />
<strong>Casting</strong> properties Strength characteristics Corrosion<br />
resistance*<br />
Shrinkage Fluidity Thermal crack High strength Strong Ductile Hard<br />
formation susceptibility and ductile (T6) and ductile<br />
Coarse High Low Silumin<br />
Silumin-Kappa<br />
Silumin-Delta<br />
Al Si12<br />
Silumin-Beta<br />
Pantal 7<br />
Al Cu4Ti<br />
Al Si12(Cu)<br />
Al Si10Mg<br />
Al Si10Mg(Cu)<br />
Al Mg3Si<br />
Al Si12CuNiMg<br />
Al Si17Cu4Mg<br />
Al Si18CuNiMg<br />
Autodur<br />
Al Si8Cu3<br />
Al Mg3<br />
Al Mg5<br />
Fine Low High Al Mg9<br />
* Analogue to DIN EN 1706<br />
heats up the remainder of the melt. The<br />
already solidifi ed silicon, however, causes<br />
increased mould wear and very uneven<br />
distribution in the castings. In these<br />
casting alloys, high melting and holding<br />
temperatures are necessary so that a<br />
casting temperature of at least 720 °C<br />
for pressure die casting and 740 °C<br />
for sand and gravity die casting has to<br />
be attained.<br />
The susceptibility to hot tearing is almost<br />
the opposite of fl uidity (Tables 2 and 3).<br />
By hot tearing, we mean a separation of<br />
the already crystallised phases during<br />
16<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
solidifi cation, e.g. under the infl uence of<br />
shrinkage or other tensions which can<br />
be transmitted via the casting moulds.<br />
The cracks or tears arising can be healed<br />
by, among other things, the feeding of<br />
residual melt. Eutectic and near-eutectic<br />
AlSi casting alloys also behave particularly<br />
well in this case, while AlCu and AlMg<br />
casting alloys behave particularly badly.<br />
In practice, there are mixed forms and<br />
transitional forms of these solidifi cation<br />
modes. The solidifi cation behaviour is<br />
responsible for the formation of shrink-<br />
Table 3<br />
age cavities and porosity, for example,<br />
or other defects in the cast structure<br />
as it determines the distribution of the<br />
volume defi cit in the casting. To curb<br />
the aforementioned casting defects,<br />
casting/technical measures need to be<br />
taken: e.g. by making adjustments to<br />
the sprue system, the thermal balance<br />
of the mould or by controlling the gas<br />
content of the melt. A volume defi cit<br />
occurs during transition from liquid to<br />
solid state. This is quite small in high<br />
silicon casting alloys since the silicon<br />
increases in volume during solidifi cation.<br />
In any case, the volume defi cit incurred
needs to be offset as far as possible by<br />
casting/technical means (see also the<br />
section on “Avoiding casting defects”).<br />
Figure 1 indicates the main types of so-<br />
lidifi cation; each type is shown at two<br />
successive points in time. With regard<br />
to aluminium, only high-purity aluminium<br />
belongs to Solidifi cation Type A (“exogenous-shell<br />
forming”). The only casting<br />
alloy which corresponds to this type is<br />
the eutectic silicon alloy or Al Si12 with<br />
approx. 13 % silicon.<br />
The hypoeutectic AlSi casting alloys<br />
solidify according to Type C (“spongy”),<br />
AlMg casting alloys according to a mix-<br />
ture of Types D and E (“mushy” or “shellforming”).<br />
The remaining casting alloys<br />
also represent intermediate types. At high<br />
solidifi cation speeds, the solidifi cation<br />
types move upwards, i.e. in the direction<br />
of “exogenous-rough wall”.<br />
Shell-forming casting alloys with “smooth-<br />
wall” or “rough-wall” solidifi cation are sus-<br />
ceptible to the formation of macroshrink-<br />
age which can only be prevented to a<br />
limited extent by feeding. <strong>Casting</strong> alloys<br />
of a spongy-mushy type are susceptible<br />
to shrinkage porosity which can only be<br />
avoided to a limited extent by feeding.<br />
In castings which demand feeding by<br />
material accumulation in particular and<br />
Exogenous solidifi cation types<br />
A Smooth wall B Rough wall C Spongy<br />
Endogenous solidifi cation types<br />
D Mushy E Shell forming<br />
Mould<br />
Fluid<br />
Strong<br />
Picture 1<br />
which should be extensively pore-free –<br />
as well as pressure-tight – the preferred<br />
casting alloys are to be found at the top<br />
of Table 3.<br />
For complex castings whose geometry<br />
does not allow each material accumulation<br />
to be achieved with a feeder, the<br />
casting alloys listed in Table 3 offer advantages<br />
provided that a certain amount<br />
of microporosity is taken into account.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 17
i Fe<br />
Infl uence of the most important<br />
alloying elements on aluminium<br />
casting alloys<br />
Silicon<br />
improves the casting properties<br />
produces age-hardenability in<br />
combination with magnesium but<br />
causes a grey colour during anodisation<br />
in pure AlCu casting alloys (e.g.<br />
Al Cu4Ti), silicon is a harmful impurity<br />
and leads to hot tearing<br />
susceptibility.<br />
Iron<br />
at a content of approx. 0.2 % and<br />
above, has a decidedly negative<br />
infl uence on the ductility (elongation<br />
at fracture); this results in a<br />
very brittle AlFe(Si) compound in<br />
the form of plates which appear in<br />
micrographs as “needles”; these<br />
plates act like large-scale microstructural<br />
separations and lead to<br />
fracture when the slightest strain<br />
is applied<br />
at a content of approx. 0.4 % and<br />
above, reduces the tendency to<br />
stickiness in pressure die casting.<br />
18<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Copper<br />
increases the strength, also at<br />
high temperatures (hightemperature<br />
strength)<br />
produces age-hardenability<br />
impairs corrosion resistance<br />
in binary AlCu casting alloys, the<br />
large solidifi cation range needs to<br />
be taken into account from a<br />
casting/technical point of view.<br />
Manganese<br />
partially offsets iron‘s negative<br />
effect on ductility when iron<br />
content is > 0.15 %<br />
segregates in combination with<br />
iron and chromium<br />
reduces the tendency to stickiness<br />
in pressure die casting.<br />
Magnesium<br />
produces age-hardenability in<br />
combination with silicon,<br />
copper or zinc; with zinc also<br />
self-hardening<br />
improves corrosion resistance<br />
increases the tendency towards<br />
oxidation and hydrogen<br />
absorption<br />
binary AlMg casting alloys are<br />
diffi cult to cast owing to their large<br />
solidifi cation range.<br />
Zinc<br />
increases strength<br />
produces (self) age-hardenability<br />
in conjunction with magnesium.<br />
Nickel<br />
increases high-temperature<br />
strength.<br />
Titanium<br />
increases strength (solid-solution<br />
hardening)<br />
produces grain refi nement on its<br />
own and together with boron.
Infl uencing the microstructural<br />
formation of aluminium castings<br />
Measures infl uencing microstructural<br />
formation are aimed at improving the<br />
mechanical and casting properties. In<br />
practice, apart from varying the cooling<br />
speed by means of different mould<br />
materials, additions to the melt are usually<br />
used.<br />
Common treatment measures include:<br />
grain refi nement of the solid<br />
solution with Ti and/or B<br />
transformation of the eutectic Si<br />
from lamellar into granular form<br />
modifi cation of the eutectic Si<br />
with Na or Sr<br />
refi nement of the eutectic<br />
Si with Sb<br />
refi nement of the Si primary<br />
phase with P or Sb.<br />
The marked areas in Figure 1 denote<br />
where it makes sense to carry out the<br />
respective types of treatment on AlSi<br />
casting alloys.<br />
Some of these measures are explained<br />
in more detail in the following section.<br />
Types of treatment to infl uence grain structure Figure 1<br />
Temperature<br />
[°C]<br />
700<br />
600<br />
500<br />
400<br />
0 2 4 6 8 10 12 14 16 18 20 22 24<br />
Silicon [wt. – %]<br />
Primary Si refi nement<br />
Grain refi nement<br />
Modifi cation<br />
Melt<br />
+ Al 660 °C<br />
Al Al + Si<br />
Melt<br />
Melt + Si<br />
Eutectic temperature 577 C°<br />
Al Si5 Al Si7 Al Si9 Al Si12 Al Si18<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 19
Grain refi nement<br />
The solidifi cation of many aluminium<br />
casting alloys begins with the formation<br />
of aluminium-rich dendritic or equiaxed<br />
crystals. In the beginning, these solidifi ed<br />
crystallites are surrounded by the remain-<br />
ing melt and, starting from nucleation<br />
sites, grow on all sides until they touch<br />
the neighbouring grain or the mould wall.<br />
The characterisation of a grain is the<br />
equiaxed spatial arrangement on the<br />
lattice level. For casting/technical or<br />
optical/decorative reasons as well as<br />
for reasons of chemical resistance, it is<br />
often desirable to set the size of these<br />
grains as uniformly as possible or as fi nely<br />
as technically possible. To achieve this,<br />
so-called grain refi nement is frequently<br />
carried out. The idea is to offer the solidifying<br />
aluminium as many nucleating<br />
agents as possible.<br />
Since grain refi nement only affects the<br />
α-solid solution, it is more effective when<br />
the casting alloy contains little silicon,<br />
i.e. a lower fraction of eutectic (Figure 2).<br />
Grain refi nement is particularly important<br />
in AlMg and AlCu casting alloys in order<br />
to reduce their tendency to hot tearing.<br />
From a technical and smelting perspective,<br />
grain refi nement mostly takes place<br />
by adding special Al TiB master alloys.<br />
20<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
We pre-treat the appropriate casting alloys<br />
when producing the alloys so that<br />
grain refi nement in the foundry is either<br />
unnecessary or only needs a freshen-<br />
up. The latter can be done in the form of<br />
salts, pellets or preferably with titanium<br />
master alloy wire, following the manufacturer’s<br />
instructions.<br />
Effect of silicon content on grain<br />
refi nement with Al Ti5B1 master alloy<br />
Mean grain diameter <strong>Casting</strong> temperature 720 °C<br />
[µm]<br />
1400<br />
holding time 5 min<br />
1200<br />
1000<br />
800<br />
600<br />
400<br />
200<br />
0<br />
Columnar and<br />
equiaxed crystals<br />
Silicon [%]<br />
Without grain<br />
refi nement<br />
With grain refi nement<br />
Al Ti5B1: 2,0 kg/mt<br />
Since every alloying operation means<br />
more contaminants in the melt, grain<br />
refi nement should only be carried out<br />
for the reasons referred to above.<br />
Figure 2<br />
0 2 4 6 8 10 12<br />
To make a qualitative assessment of a<br />
particular grain refi nement treatment,<br />
thermal analysis can be carried out (see<br />
section on “Melt testing and inspection<br />
procedure”).
Modifi cation of AlSi eutectic<br />
(refi nement)<br />
By “modifi cation”, we mean the use<br />
of a specifi c melt treatment to set a<br />
fi ne-grained eutectic silicon in the cast<br />
structure which improves the mechanical<br />
properties (and elongation in particular)<br />
as well as the casting properties in many<br />
cases. As a general rule, modifi cation<br />
is carried out by adding small amounts<br />
of sodium or strontium. To facilitate an<br />
understanding of the possible forms of<br />
eutectic silicon, these are depicted in<br />
Figure 2 (a-e) for Al Si11 with a varying<br />
Na content:<br />
a) The lamellar condition only<br />
appears in casting alloys which<br />
are virtually free of phosphorous<br />
or modifi cation agents, e.g.<br />
Na or Sr.<br />
b) In granular condition which<br />
appears in the presence of<br />
phosphorous without Na or Sr, the<br />
silicon crystals exist in the form of<br />
coarse grains or plates.<br />
c) In undermodifi ed and<br />
d) to a great extent in fully-modifi ed<br />
microstructural condition, e.g.<br />
by adding Na or Sr, they are<br />
signifi cantly reduced in size,<br />
rounded and evenly distributed<br />
which has a particularly positive<br />
effect on elongation.<br />
e) In the case of overmodifi cation<br />
with sodium, vein-like bands with<br />
coarse Si crystals appear.<br />
Overmodifi cation can therefore<br />
mean deterioration as regards<br />
mechanical properties.<br />
Figures 3 and 4 depict the formation of<br />
microstructural conditions or the degree<br />
of modifi cation as a result of interaction<br />
between sodium and strontium and the<br />
phosphorous element. It can be ascer-<br />
tained that the disruption of modifi cation<br />
due to small amounts of phosphorous<br />
is relatively slight. In Sr modifi cation, a<br />
high phosphorous content can be offset<br />
by an increased amount of modifying<br />
agent. In aluminium casting alloys with a<br />
silicon content exceeding 7 %, eutectic,<br />
silicon takes up a larger part of the area<br />
of a metallographic specimen. From a<br />
silicon content of approx. 7 to 13 %,<br />
the type of eutectic formation, e.g.<br />
grained or modifi ed, thus plays a key<br />
role in determining the performance<br />
characteristics, especially the ductility<br />
Types of grain structure<br />
a) Lamellar b) Granular<br />
d) Modifi ed<br />
e) Overmodifi ed<br />
or elongation. When higher elongation is<br />
required in a workpiece, aluminium cast-<br />
ing alloys containing approx. 7 to 13 %<br />
silicon will thus be modifi ed by adding<br />
approx. 0.0040 to 0.0100 % sodium (40<br />
to 100 ppm).<br />
In casting alloys with approx. 11 % silicon,<br />
particularly for use in low-pressure die<br />
casting, strontium can also be used as a<br />
long-term modifi er since the melting loss<br />
behaviour of this element is substantially<br />
better than that of sodium. In this case,<br />
the recommended addition is approx.<br />
0.014 to 0.04 % Sr (140 to 400 ppm).<br />
With suitable casting alloys, the required<br />
amount of strontium can be added<br />
during alloy manufacture so that, as<br />
a rule, the modifi cation process step<br />
c) Undermodifi ed<br />
Picture 2<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 21
Microstructural formation in relation to<br />
the content of phosphorous and sodium Al Si7Mg<br />
Sodium Sand casting<br />
[ppm]<br />
140<br />
cooling rate 0.1 K/s<br />
120<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
Overmodifi ed<br />
Granular<br />
Modifi ed<br />
Lamellar<br />
can be omitted in the foundry. At low<br />
cooling rates, strontium modifi cation is<br />
less effective so that it is not advisable<br />
to use this in sand casting processes.<br />
To avoid the burn-off of strontium, any<br />
cleaning and degassing of Sr-modifi ed<br />
melts should be carried out with chlorine-<br />
free preparations only, preferably using<br />
argon or nitrogen. Strontium modifi cation<br />
is not greatly impaired even when<br />
remelting revert material. Larger losses<br />
22<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Phosphorous [ppm]<br />
Undermodifi ed<br />
Figure 3<br />
0 5 10 15 20 25 30 35 40 45 50 55 60<br />
can be offset by adding Sr master alloy<br />
wire in accordance with the respective<br />
manufacturer‘s instructions. At the right<br />
temperature, the addition of sodium to<br />
the melt is best done by charging standard<br />
portions. For easy handling, storage<br />
and proportioning, the manufacturer‘s<br />
recommendations and safety instructions<br />
should be followed.<br />
Since sodium burns off from the melt<br />
relatively quickly, subsequent modifi -<br />
Figure 4<br />
Microstructural formation in relation to<br />
the content of phosphorous and strontium Al Si7Mg<br />
Strontium Gravity die casting<br />
[ppm] gravity die cast test bar<br />
cooling rate 2.5 K/s<br />
450<br />
400<br />
350<br />
300<br />
250<br />
200<br />
150<br />
100<br />
50<br />
0<br />
0 10 20 30 40 50 60 70 80 90 100<br />
Phosphorous [ppm]<br />
Modifi ed Undermodifi ed Granular Lamellar<br />
cation must take place in the foundry<br />
at regular intervals. In melts modifi ed<br />
with sodium, any requested cleaning<br />
and degassing should be carried out<br />
with chlorine-free compounds only<br />
(argon or nitrogen). A certain amount<br />
of sodium burn-off is to be reckoned<br />
with, however, and needs to be taken<br />
into account in the subsequent addition<br />
of sodium. When absolutely necessary,<br />
the melt can be treated with chlorine-<br />
releasing compounds long before the
fi rst addition of sodium. If such treat-<br />
ment is carried out after adding sodium<br />
or strontium, chlorine may react with<br />
these elements and remove them from<br />
the melt, thereby preventing any further<br />
modifi cation.<br />
Modifi cation with sodium or strontium<br />
increases the tendency to gas absorption<br />
in the melt. As a result of the reaction<br />
of the precipitating hydrogen with<br />
the rapidly-forming oxides, defects can<br />
occur in the casting, especially cumulant<br />
microporosity. In many practical cases,<br />
this potential for micropore formation<br />
is even desirable. Then, the purpose<br />
of modification is also to offset the<br />
expected macroshrinkage by forming<br />
many micropores.<br />
An accurate assessment of the effects<br />
of modifi cation can only be made by<br />
means of metallographic examination.<br />
As a quick test, thermal analysis can be<br />
carried out if it is possible to establish by<br />
means of a preliminary metallographic<br />
examination which depression value is<br />
necessary to attain a suffi ciently-modi-<br />
fi ed grain structure (for more information<br />
on thermal analysis, please refer to the<br />
section on “Methods for monitoring the<br />
melt”). Under the same conditions, rapid<br />
determination of the modifi ed condition<br />
is also possible by measuring the electrical<br />
conductance of a sample.<br />
In aluminium casting alloys of the type<br />
Al Si7Mg, a refi nement of the eutectic<br />
silicon with antimony (Sb) is possible.<br />
A Sb content of at least 0.1 % is required.<br />
This treatment, however, only produces<br />
a fi ner formation of the lamellar eutectic<br />
silicon and is not really modifi cation<br />
in the traditional sense. The danger of<br />
contamination of other melts by closedcircuit<br />
material containing Sb exists as<br />
even a Sb content of approx. 100 ppm<br />
can disturb normal sodium or strontium<br />
modifi cation. What‘s more, refi nement<br />
with antimony can be easily disturbed<br />
by only a low level of phosphorous (a<br />
few ppm) (Figure 5). In contrast to modifi<br />
cation, refi nement with antimony can<br />
not be checked by means of thermal<br />
analysis of a melt sample.<br />
Figure 5<br />
Infl uence of antimony and phosphorous<br />
content on the form of the eutectic silicon of Al Si7Mg<br />
Antimony<br />
[%]<br />
0.30<br />
0.20<br />
0.10<br />
0.00<br />
Coarse-lamellar<br />
Acceptable Coarse-lamellar<br />
to granular<br />
Phosphorous [ppm]<br />
Refi nement of primary silicon<br />
In hypereutectic AlSi casting alloys<br />
(e.g. Al Si18CuNiMg), the silicon-rich,<br />
polygonal primary crystals solidify fi rst.<br />
To produce as many fi ne crystals as pos-<br />
sible in the as-cast structure, nucleating<br />
agents need to be provided.<br />
High-purity base<br />
0 2 4 6 8 10<br />
This is done with the aid of prepara-<br />
tions or master alloys which contain<br />
phosphorous-aluminium compounds.<br />
This treatment can also be carried out<br />
when the alloy is being manufactured<br />
and, in most cases, the foundryman<br />
does not need to repeat the process.<br />
If required, the quality of such primary<br />
refi nement can be checked by means<br />
of thermal analysis.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 23
Melt quality and melt cleaning<br />
All factors which come under the general<br />
term of “melt quality” have a direct<br />
effect on the quality of the casting to be<br />
produced. Inversely, according to DIN EN<br />
1706, the cast samples play a valuable<br />
role in checking the quality of the melt.<br />
Most problems in casting are caused by<br />
two natural properties of liquid melts, i.e.<br />
their marked tendency to form oxides<br />
and their tendency towards hydrogen<br />
absorption. Furthermore, other insoluble<br />
impurities, such as Al-carbides or<br />
refractory particles as well as impurities<br />
with iron, play an important role.<br />
As mentioned in other sections, the<br />
larger oxide fi lm can lead to a material<br />
separation in the microstructure and,<br />
consequently, to a reduction in the load-<br />
bearing cross-section of the casting.<br />
The solubility of hydrogen in aluminium<br />
decreases discontinuously during the<br />
transition from liquid to solid so that as<br />
solidifi cation takes place, precipitating<br />
gaseous hydrogen reacting with existing<br />
oxides can cause voids which can<br />
in turn take various forms ranging from<br />
large pipe-like blisters to fi nely-distributed<br />
micro-porosity.<br />
24<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Critical melting temperatures<br />
in relation to the segregation factor<br />
Temperature<br />
[°C]<br />
650<br />
640<br />
630<br />
620<br />
610<br />
600<br />
590<br />
0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2<br />
Segregation factor [(Fe)+2(Mn)+3(Cr)]<br />
Al Si8Cu3 Al Si6Cu4 Al Si12(Cu)<br />
To achieve good melt quality, the for-<br />
mation of oxides and the absorption<br />
of hydrogen have to be suppressed as<br />
much as possible on the one hand, while<br />
other hydrogen and oxides have to be<br />
removed from the melt as far as possible<br />
on the other, although this is only<br />
possible to a certain extent.<br />
Figure 6
Avoiding impurities<br />
Ingot quality<br />
An essential prerequisite for a good<br />
casting is good ingot quality. The metal<br />
should be cleaned effectively and the in-<br />
gots should display neither metallic nor<br />
non-metallic inclusions. The ingots must<br />
be dry (there is a risk of explosion when<br />
damp) and no oil or paint residue should<br />
be present on their surface. When using<br />
revert material, this should be in lumps,<br />
if possible, and well cleaned.<br />
Melting<br />
When melting ingots or revert material,<br />
it must be ensured that the metal is not<br />
exposed unnecessarily to the fl ame or<br />
furnace atmosphere. The pieces of metal<br />
should be melted down swiftly, i.e. follow-<br />
ing short preheating, immersed directly<br />
in the liquid melt.<br />
Large-volume hearth or crucible furnaces<br />
are best suited to melting. Furnaces with<br />
melting bridges are oxide producers and<br />
they lead to expensive, unnecessary and<br />
irretrievable metal losses.<br />
The type and state of the melt in contact<br />
with refractory materials are of particular<br />
importance in the melting and holding<br />
of aluminium.<br />
<strong>Aluminium</strong> and aluminium casting alloys<br />
in a molten state are very aggressive, especially<br />
when AlSi melts contain sodium<br />
or strontium as modifying agents. With<br />
an eye to quality, reactions, adherences,<br />
infi ltrations, abrasive wear and decompo-<br />
sition have to be kept within limits when<br />
using melting crucibles and refractory<br />
materials as well as during subsequent<br />
processing. The care and maintenance<br />
as well as cleanliness of equipment are<br />
equally important. Adhering materials<br />
can very easily lead to the undesired<br />
redissolving of oxides in the melt and<br />
cause casting defects.<br />
Melting temperature<br />
The temperature of the melt must be set<br />
individually for each alloy.<br />
Too low melting temperatures lead to<br />
longer residence times and, as a result,<br />
to greater oxidation of the pieces jut-<br />
ting out of the melt. The melt becomes<br />
homogeneous too slowly, i.e. local undercooling<br />
allows segregation to take<br />
place, even as far as tenacious gravity<br />
segregation of the FeMnCrSi type phases.<br />
The mathematical interrelationship for<br />
the segregation of heavy intermetallic<br />
phases is depicted in Figure 6.<br />
Furthermore, at too low temperatures,<br />
autopurifi cation of the melt (oxides rising)<br />
can not take place.<br />
When the temperature of the melt is too<br />
high, increased oxide formation and<br />
gassing can occur. Lighter alloying elements,<br />
e.g. magnesium, are subject to<br />
burn-off in any case; this must be offset<br />
by appropriate additions. Too high<br />
melting temperatures aggravate this loss<br />
by burning.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 25
Conducting the melting operation<br />
As long as the melt is in a liquid condi-<br />
tion, it has a tendency to oxidise and<br />
absorb hydrogen. Critical points during<br />
subsequent processing include decanta-<br />
tion, the condition or maintenance of the<br />
transfer vessel, possible reactions with<br />
refractory materials as well as transport<br />
or metal tapping. The addition of grain<br />
refi ners and modifying agents above the<br />
required amount can lead to an increase<br />
in non-metallic impurities and greater<br />
hydrogen absorption.<br />
To minimise an enrichment of iron in the<br />
melt, direct contact between ferrous<br />
materials and the melt is to be avoided.<br />
For this reason, steel tools and containers<br />
(casting ladles) must be carefully<br />
dressed. Similarly, but also on economic<br />
grounds, the feed tubes for low-pressure<br />
die casting – made from cast iron up to<br />
now – should be replaced by ceramic<br />
feed tubes.<br />
Even during the casting process itself<br />
and especially due to turbulence in the<br />
fl ow channel, oxide skins can once again<br />
form which in turn can lead to casting<br />
defects. <strong>Casting</strong> technology is thus required<br />
to fi nd ways of preventing the<br />
excessive oxidation of the melt, e.g. by<br />
means of intelligent runners and gating<br />
systems (please refer to the section on<br />
“Selecting the casting process”).<br />
26<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Figure 7<br />
Hydrogen content of various<br />
casting alloy melts after different types of treatment<br />
Hydrogen<br />
[ml/100g]<br />
0.50<br />
0.40<br />
0.30<br />
0.20<br />
0.10<br />
0.00<br />
After melting<br />
10 20 30 0.5 2 4 24 10 20<br />
Rotary<br />
degassing<br />
[min]<br />
Holding<br />
in [h]<br />
Type of melt treatment<br />
Al Si8Cu3 Pantal 7 Al Mg5<br />
Gassing<br />
Rotary<br />
degassing<br />
[min]<br />
24h
Cleaning and degassing the melt<br />
Our casting alloys consist of effectively<br />
cleaned metal. Since reoxidation always<br />
takes place during smelting, and in<br />
practice revert material is always used,<br />
a thorough cleaning of the melt is necessary<br />
prior to casting.<br />
Holding the aluminium melt at the cor-<br />
rect temperature for a long time is an ef-<br />
fective cleaning method. It is, however,<br />
very time-intensive and not carried out<br />
that often as a result. Foundrymen are<br />
thus left with only intensive methods, i.e.<br />
using technical equipment or the usual<br />
commercially available mixture of salts.<br />
In principle, melt cleaning is a physical<br />
process: the gas bubbles rising through<br />
the liquid metal attach oxide fi lms to their<br />
outer surfaces and allow hydrogen to dif-<br />
fuse into the bubbles from the melt. Both<br />
are transported to the bath surface by the<br />
bubbles. It is therefore clear that in order<br />
for cleaning of the melt to be effective, it<br />
is desirable to have as many small gas<br />
bubbles as possible distributed across<br />
the entire cross-section of the bath.<br />
Dross can be removed from the surface<br />
of the bath, possibly with the aid of oxide-binding<br />
salts.<br />
Inert-gas fl ushing by means of an im-<br />
peller is a widely-used, economical and<br />
environmentally-sound cleaning process.<br />
The gas stream is dispersed in the form<br />
of very small bubbles by the rapid turning<br />
of a rotor and, in conjunction with the<br />
good intermixing of the melt, this leads<br />
to very effi cient degassing. To achieve<br />
an optimum degassing effect, the various<br />
parameters such as rotor diameter<br />
and revolutions per minute, gas fl ow<br />
rate, treatment time, geometry and size<br />
of the crucible used as well as the alloy,<br />
have to be co-ordinated. The course of<br />
degassing and reabsorption of hydrogen<br />
is depicted for various casting alloys<br />
in Figure 7.<br />
When using commercially available salt<br />
preparations, the manufacturer‘s instruc-<br />
tions concerning use, proportioning,<br />
storage and safety should be followed.<br />
Apart from this, attention should also be<br />
paid to the quality and care of tools and<br />
auxiliary materials used for cleaning so<br />
that the cleaning effect is not impaired.<br />
If practically feasible, it is also possible<br />
to fi lter the melt using a ceramic foam<br />
fi lter. In the precision casting of high-<br />
grade castings, especially in the sand<br />
casting process, the use of ceramic<br />
fi lters in the runner to the sand mould<br />
has proved to be a success. Above all,<br />
such a fi lter leads to an even fl ow and<br />
can retain coarse impurities and oxides.<br />
In the gravity die casting of sensitive<br />
hydraulic parts, or when casting sub-<br />
sequently anodised decorative fi ttings<br />
in Al Mg3, ladling out of a device which<br />
is fi tted with in-line fi lter elements and<br />
separated from the remaining melt bath<br />
is very common.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 27
Melt testing and inspection procedure<br />
To assess the effectiveness of the clean-<br />
ing process or the quality of the melt, the<br />
following test and inspection methods<br />
can be used to monitor the melt:<br />
Reduced pressure test<br />
This method serves to determine the<br />
tendency to pore formation in the melt<br />
during solidifi cation. A sample, which<br />
can contain a varying number of gas<br />
bubbles depending on the gas content,<br />
is allowed to solidify at an underpressure<br />
of 80 mbar. The apparent density is then<br />
compared with that of a sample which<br />
is solidifi ed at atmospheric pressure.<br />
The so-called “Density Index” is then<br />
calculated using the following equation:<br />
DI = (dA - d80)/dA x 100 %<br />
DI = Density Index<br />
dA = density of the sample solidifi ed<br />
at atmospheric pressure<br />
d80 = density of the sample solidifi ed<br />
at under 80 mbar<br />
28<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
The Density Index allows a certain inference<br />
to be drawn about the hydrogen<br />
content of the melt. It is, however, strongly<br />
infl uenced by the alloying elements and,<br />
above all, by varying content of impurities<br />
so that the hydrogen content must not<br />
on any account be stated as a Density<br />
Index value (Figure 8).<br />
The assessment of melt quality by means<br />
of an underpressure density sample therefore<br />
demands the specifi c determination<br />
of a critical Density Index value for each<br />
casting alloy and for each application.<br />
The underpressure density method is,<br />
however, a swift and inexpensive method<br />
with the result that it is already used<br />
in many foundries for quality control.<br />
To keep results comparable, sampling<br />
should always be carried out according<br />
to set parameters.<br />
Determination of the hydrogen<br />
content in the melt<br />
Reliable instruments have been in operation<br />
for years for measuring the hydrogen<br />
content in aluminium melts. They work<br />
according to the principle of establishing<br />
equilibration between the melt and a<br />
measuring probe so that the actual gas<br />
content in the melt is determined and not<br />
in the solid sample. In this way, the effectiveness<br />
of the degassing treatment can<br />
be assessed quickly. The procurement of<br />
such an instrument for continuous quality<br />
monitoring is only worthwhile when it is<br />
used frequently; in small foundries, the<br />
hiring of an instrument to solve problems<br />
is suffi cient.
Determination of insoluble<br />
non-metallic impurities<br />
For determining the number and type<br />
of insoluble non-metallic impurities in<br />
aluminium melts, the Porous Disc Filtration<br />
Apparatus (PoDFA) method, among<br />
others, can be used. In this particular<br />
method, a precise amount of the melt<br />
is squeezed through a fi ne fi lter and<br />
the trapped impurities are investigated<br />
metallographically with respect to their<br />
type and number. The PoDFA method<br />
is one of the determination procedures<br />
which facilitates the acquisition, both<br />
qualitatively and quantitatively, of the<br />
impurity content. It is used primarily for<br />
evaluating the fi ltration and other clean-<br />
ing treatments employed and, in casting<br />
alloys production, is utilised at regular<br />
intervals for the purpose of quality control.<br />
This method is not suitable for making<br />
constant routine checks since it is very<br />
time-consuming and entails high costs.<br />
Correlation between the hydrogen content<br />
and density index in unmodifi ed Al Si9Mg alloy<br />
Density index Measurement acc. to Chapel<br />
[%]<br />
35<br />
at vacum 30 mbar<br />
30<br />
25<br />
20<br />
15<br />
10<br />
5<br />
0<br />
0 0.1 0.2 0.3 0.4 0.5 0.6<br />
Hydrogen content [ml/100g]<br />
Figure 8<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 29
Thermal analysis<br />
To evaluate the effectiveness of melt<br />
treatment measures, e.g. modifi cation,<br />
grain refi nement and primary silicon re-<br />
fi ning, thermal analysis has proved itself<br />
to be a fast and relatively inexpensive<br />
method in many foundries. The test<br />
method is based on the comparison of<br />
two cooling curves of the investigated<br />
melts (Figures 9 and 10).<br />
The undercooling effect (recalescence)<br />
occurring during primary solidifi cation<br />
allows conclusions to be made about<br />
the effectiveness of a grain refi nement<br />
treatment, whereby the recalescence<br />
values do not however allow conclusions<br />
to be drawn as regards the later grain<br />
size in the microstructure. Modifi cation is<br />
shown in thermal analysis by a decrease<br />
in the eutectic temperature (depression)<br />
in comparison to the unmodifi ed state.<br />
Here too, the level of the depression<br />
values depend strongly on the content<br />
of accompanying and alloying elements<br />
(e.g. Mg) and, consequently, the de-<br />
pression values required for suffi cient<br />
modifi cation must be established case<br />
by case, by means of parallel microstruc-<br />
tural investigations.<br />
30<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Thermal analysis for monitoring<br />
the grain refi nement of Al casting alloys<br />
Temperature<br />
[T]<br />
T L<br />
T L<br />
Time [t]<br />
With grain refi nement Without grain refi nement<br />
Liquidus temperature [T L ]<br />
Thermal analysis for monitoring<br />
the modifi cation of Al casting alloys<br />
Temperature<br />
[°C]<br />
585<br />
580<br />
577<br />
575<br />
570<br />
565<br />
560<br />
Figure 9<br />
0 10 20<br />
Time [sec]<br />
30 40 50<br />
Modifi ed Undermodifi ed Eutectic temperature<br />
Figure 10
Selecting the casting process<br />
As mentioned in the introduction, the<br />
entire “casting” process is the shortest<br />
route from molten metal to a part which<br />
is almost ready for use. All sections of<br />
this catalogue contain advice on how the<br />
entire experience should be carried out.<br />
The casting process is selected according<br />
to various criteria such as batch<br />
size, degree of complexity or requisite<br />
mechanical properties of the casting.<br />
Some examples:<br />
The sand casting process is used<br />
predominantly in two fi elds of appli-<br />
cation: for prototypes and small-scale<br />
production on the one hand and for the<br />
volume production of castings with a<br />
very complex geometry on the other.<br />
For the casting of prototypes, the main<br />
arguments in favour of the sand casting<br />
process are its high degree of fl exibility<br />
in the case of design changes and the<br />
comparably low cost of the model. In volume<br />
production, the level of complexity<br />
and precision achieved in the castings<br />
are its main advantages.<br />
When higher mechanical properties are<br />
required in the cast piece, such as higher<br />
elongation or strength, gravity die cast-<br />
ing, and to a limited extent pressure die<br />
casting, are used. In gravity die casting,<br />
there is the possibility of using sand<br />
cores. Large differences in wall thick-<br />
nesses can be favourably infl uenced<br />
with the help of risers. Cylinder heads<br />
for water-cooled engines represent a<br />
typical application.<br />
In the low-pressure gravity die process<br />
with its upward and controllable cavity<br />
fi lling, the formation of air pockets is re-<br />
duced to a minimum and, consequently,<br />
high casting quality can be achieved. In<br />
addition to uphill fi lling, the overpressure<br />
of approx. 0.5 bar has a positive effect<br />
on balancing out defects caused by<br />
shrinkage. The low-pressure die casting<br />
process is particularly advantageous in<br />
the casting of rotationally symmetrical<br />
parts, e.g. in the manufacture of passenger<br />
vehicle wheels.<br />
Pressure die casting is the most widely<br />
used casting process for aluminium<br />
casting alloys. Pressure die casting is<br />
of particular advantage in the volume<br />
production of parts where the requirement<br />
is on high surface quality and the<br />
least possible machining. Special applications<br />
(e.g. vacuum) during casting<br />
enable castings to be welded followed<br />
by heat treatment which fully exploits<br />
the property potential displayed by the<br />
casting alloy.<br />
In addition to conventional pressure die<br />
casting, thixocasting is worthy of mention<br />
since heat-treatable parts can also<br />
be manufactured using this process.<br />
The special properties are achieved<br />
by shaping the metal during the solidliquid<br />
phase.<br />
Squeeze-casting is another casting pro-<br />
cess to be mentioned; here, solidifi cation<br />
takes place at high pressure. In this way,<br />
an almost defect-free microstructure<br />
can be produced even where there are<br />
large transitions in the cross-section<br />
and insuffi cient feeding.<br />
Other special casting processes include:<br />
Precision casting<br />
Evaporative pattern casting<br />
Plaster mould casting<br />
Vacuum sand casting<br />
Centrifugal casting.<br />
The considerations above concern casting<br />
as an overall process.<br />
In the following notes on casting prac-<br />
tice, the actual pouring of the molten<br />
metal into prepared moulds and the<br />
subsequent solidifi cation control are<br />
looked at in more detail.<br />
From the numerous casting processes,<br />
which differ from one another in the type<br />
of mould material (sand casting, per-<br />
manent dies etc.) or by pressurisation<br />
(pressure die casting, low-pressure die<br />
casting etc.), a few notes are provided<br />
here on the most important processes.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 31
Pressure die casting process<br />
This process takes up the largest share.<br />
The hydraulically-controlled pressure<br />
die casting machine and the in-built<br />
die make up the central element of the<br />
process. The performance, the precise<br />
control of the hydraulic machine, the<br />
quality of the relatively expensive tools<br />
made from hot work steel are the decisive<br />
factors in this process. In contrast,<br />
the fl ow properties and solidifi cation<br />
of the aluminium casting alloys play a<br />
rather subordinate role in this “forced”<br />
casting process.<br />
The pouring operation in horizontal pressure<br />
die casting begins with the casting<br />
chamber being fi lled with metal. The<br />
fi rst movement, i.e. the slow advance of<br />
the plunger and the consequent pile-up<br />
of metal until the sleeve is completely<br />
fi lled, is the most important operation.<br />
In doing this, no fl ashover of the metal<br />
or other turbulence may occur until all of<br />
the air in the sleeve has been squeezed<br />
out. Immediately afterwards, the actual<br />
casting operation begins with the rapid<br />
casting phase. High injection pressure is<br />
essential to achieve high fl ow velocities<br />
in the metal. In this way, the die can be<br />
fi lled in a few hundredths of a second.<br />
Throughout the casting operation, the<br />
liquid metal streams are subject to the<br />
laws of hydrodynamics. Sharp turns<br />
and collisions with the die walls lead<br />
to a clear division of the metal stream.<br />
32<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Parts generated using the horizontal<br />
pressure die casting process are lightweight<br />
as low wall thicknesses can be<br />
achieved. They have a good surface<br />
fi nish, high dimensional accuracy and<br />
only require a low machining allowance<br />
in their design. Many bore holes can be<br />
pre-cast.<br />
The melting and casting temperatures<br />
should not be too low and should be<br />
checked constantly. Pre-melting alu-<br />
minium casting alloys is useful. The melt<br />
can thus be given a good clean in order<br />
to keep the melt homogeneous and to<br />
avoid undesirable gravity segregation<br />
(see Figure 6). From a statistical point<br />
of view, more casting defects arise from<br />
cold metal than from hot. It is particu-<br />
larly important to keep a suffi ciently high<br />
melting temperature, even with hypere-<br />
utectic alloys. These comments are also<br />
valid for other casting processes.<br />
Gravity die casting process<br />
The gravity die casting which includes<br />
the well-known low-pressure die casting<br />
process is applied. The main fi elds of<br />
application are medium- or high-volume<br />
production using high-grade alloys, and<br />
also low to medium component weight<br />
using heat-treatable alloys. Compared<br />
with sand casting, the aluminium castings<br />
display very good microstructural<br />
properties as well as good to very good<br />
mechanical properties which result from<br />
the rapid cooling times and the other<br />
easily-controlled operating parameters.<br />
The castings have high dimensional accuracy<br />
and stability as well as a good<br />
surface fi nish, are heat-treatable and<br />
can also be anodised.<br />
The basis for good quality castings is,<br />
not least, the right melt treatment and<br />
the appropriate casting temperature (see<br />
section on “Melt quality and melt cleaning”).<br />
For castings with high surface or<br />
microstructural quality requirements,<br />
such as in decorative or subsequently<br />
anodised components or in pressuretight<br />
hydraulic parts, it is useful to fi lter<br />
the melt before casting.
Demands on the casting system<br />
To keep disadvantages and defects –<br />
which constantly arise from an oxide<br />
skin forming on the melt – within limits,<br />
the gating system must guarantee low<br />
turbulence in the metal stream and also<br />
a smooth, controlled fi lling of the die<br />
cavity. With the transition from a liquid<br />
to a solid condition, volume contraction<br />
occurs; this can amount to up to 7 %<br />
of the volume. This shrinkage is controllable<br />
when the solid-liquid interface<br />
runs – controlled or directed – through<br />
the casting, mostly from the bottom to<br />
the top. This task, namely to effect a<br />
directed solidifi cation, can be achieved<br />
with a good pouring system.<br />
The castings are usually arranged “upright”<br />
in the die. The greatest mass can<br />
thus be placed in the bottom of the die.<br />
Quality requirements can be, for example,<br />
high strength, high-pressure tightness or<br />
decorative anodising quality.<br />
One example of an “ideal” gating system<br />
which meets the highest casting requirements<br />
is the so-called “slit gate system”.<br />
Here, the metal is conducted upwards<br />
continuously or discontinuously to the<br />
casting via a main runner. During mould<br />
fi lling, the melt is thus superimposed layer<br />
upon layer with the hotter metal always<br />
fl owing over the already solidifying metal.<br />
The standpipe ends in the top riser and<br />
supplies it with hot metal. This way, the<br />
solidifi cation can be directed from below,<br />
possibly supported by cooling, towards<br />
the top running through the casting and<br />
safeguarding the continuous supply of<br />
hot metal. When there is a wide fl are in<br />
the casting, the gating system has to be<br />
laid out on both sides. This symmetry en-<br />
sures a division of the metal and also an<br />
even distribution of the heat in the die.<br />
In low-pressure die casting, directing<br />
the solidifi cation by means of the gating<br />
system is not possible. Nor is there<br />
any great possibility of classic feeding.<br />
Directional solidifi cation is only possible<br />
by controlling the thermal balance of the<br />
die during casting. This mostly requires<br />
the installation of an expensive cooling-<br />
heating system.<br />
Simulation calculations for die fi lling and<br />
solidifi cation can be useful when laying<br />
out and designing the die and possibly<br />
the cooling. In actual production, the<br />
cooling and cycle time can be optimised<br />
by means of thermography (see section<br />
on “Solidifi cation simulation and ther-<br />
mography”).<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 33
Sand casting process<br />
This process is used especially for in-<br />
dividual castings, prototypes and small<br />
batch production. It is, however, also<br />
used for the volume production of cast-<br />
ings with a very complex geometry (e.g.<br />
inlet manifolds, cylinder heads or crank-<br />
cases for passenger vehicle engines).<br />
During shaping and casting, most large<br />
sand castings display in-plane expan-<br />
sion. With this fl at casting method, gating<br />
systems like those which are normal in<br />
gravity die casting for directing solidifi ca-<br />
tion are often not applicable. If possible,<br />
a superimposed fi lling of the die cavity<br />
should be attempted here.<br />
34<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Another generally valid casting rule for<br />
correct solidifi cation is to arrange risers<br />
above the thick-walled parts, cooling (e.g.<br />
by means of chills) at opposite ends. This<br />
way, the risers can perform their main<br />
task longer, namely to conduct the supply<br />
of molten metal into the contracted<br />
end. Insulated dies are often helpful.<br />
The cross-section ratio in the sprue system<br />
should be something like the following:<br />
Sprue :<br />
Sum of the runner cross-section :<br />
Sum of the gates:<br />
like 1 : 4 : 4.<br />
This facilitates keeping the run-in laun-<br />
der full and leads to a smoother fl ow<br />
of the metal. This way, the formation of<br />
oxides due to turbulence can be kept<br />
within limits. The main runner must lie<br />
in the drag, the gates in the cope. In the<br />
production of high-grade castings, it is<br />
normal to install ceramic fi lters or sieves<br />
made from glass fi bre. The selection of<br />
the casting process and the layout of<br />
the casting system should be carried<br />
out in close co-operation between the<br />
customer, designer and foundryman (see<br />
section on “<strong>Casting</strong>-compliant design”).
<strong>Casting</strong>-compliant design<br />
The following notes on the design of<br />
aluminium castings are provided to help<br />
exploit in full the advantages and design<br />
possibilities of near net shape casting.<br />
They also align practical requirements<br />
with material suitability.<br />
<strong>Aluminium</strong> casting alloys can be processed<br />
in practically all conventional<br />
casting processes, whereby pressure die<br />
casting accounts for the largest volume,<br />
followed by gravity die casting and sand<br />
casting. The most useful casting process<br />
is not only dependent on the number and<br />
weight of pieces but also on other technical<br />
and economic conditions (see section<br />
on “Selecting the casting process”).<br />
To fi nd the optimum solution and produce<br />
a light part as cheaply and rationally as<br />
possible, co-operation between the designer,<br />
caster and materials engineer is<br />
always necessary. Knowledge concerning<br />
the loads applied, the distribution of<br />
stress, the range of chemical loading and<br />
operation temperatures is important.<br />
In the valid European standard, DIN EN<br />
1706 for aluminium castings, there are<br />
strength values only for separately-cast<br />
bars using sand and gravity die casting.<br />
For samples cut from the cast piece,<br />
a reduction in the 0.2 % proof stress<br />
and ultimate tensile strength values of<br />
up to 70 % and a decrease in elongation<br />
of up to 50 % from the test bar can<br />
be anticipated. When the alloy and the<br />
casting process are specifi ed, so too is<br />
the next point within the framework of<br />
the design, i.e. determination of the die<br />
parting line. Die parting on one level is<br />
not only the cheapest for patterns and<br />
dies but also for subsequent working and<br />
machining. Likewise, every effort should<br />
be made to produce a casting without<br />
undercuts. This is followed by designing<br />
and determining the actual dimensions<br />
of the part. The constant guideline must<br />
be to achieve a defect-free cast structure<br />
wherever possible.<br />
Only through good cast quality can the<br />
technical requirements be met and the<br />
full potential of the casting alloy be exploited.<br />
Every effort and consideration<br />
must be made therefore to design a light,<br />
functionally effi cient part whose manu-<br />
facture and machining can be carried out<br />
as effi ciently as possible. For this and<br />
subsequent considerations, the use of<br />
solidifi cation simulation is available (see<br />
section on “Solidifi cation simulation and<br />
thermography”).<br />
<strong>Casting</strong> alloys shrink during solidifi ca-<br />
tion, i.e. their volume is reduced. This<br />
increases the risk of defects in the cast<br />
structure, such as cavities, pores or<br />
shrinkage holes, tears or similar. The<br />
most important requirement is thus to<br />
avoid material accumulations by hav-<br />
ing as even a wall thickness as possible.<br />
In specialist literature, the following lower<br />
limits for wall thickness are given:<br />
Sand castings: 3-4 mm<br />
Gravity die castings: 2-3 mm<br />
Pressure die castings: 1-1.5 mm.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 35
The minimum values are also dependent<br />
on the casting alloy and the elongation of<br />
the casting. In pressure die casting, the<br />
minimum wall thickness also depends<br />
on the position of and distance to the<br />
gate system.<br />
Generally speaking, the wall thickness<br />
should be as thin as possible and only<br />
as thick as necessary. With increasing<br />
wall thickness, the specifi c strength of<br />
the cast structure deteriorates.<br />
Determining casting-compliant wall<br />
thicknesses also means, especially with<br />
sand and gravity die casting, that the die<br />
must fi rst of all be fi lled perfectly. During<br />
subsequent solidifi cation, a dense cast<br />
structure can only occur if the shrinkage<br />
is offset by feeding from liquid melt. Here,<br />
a wall thickness extending upwards as a<br />
connection to the riser may be necessary.<br />
36<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Another possible way of avoiding material<br />
accumulations is to loosen the nodes.<br />
At points where fi ns cross, a mass accumulation<br />
can be prevented by staggering<br />
the wall layout.<br />
The corners where walls or fi ns meet<br />
should be provided with as large transi-<br />
tions as possible. Where walls of different<br />
thickness meet, the transitions should<br />
be casting-compliant.<br />
Where the casting size and process<br />
permit, bores should be pre-cast. This<br />
improves the cross-section ratio and<br />
structural quality.<br />
Apart from the points referred to above,<br />
a good design also takes account of<br />
practical points and decorative appear-<br />
ance as well as the work procedures<br />
and machining which follow the actual<br />
casting operation.<br />
Fettling the casting, i.e. removing the<br />
riser and feeders, must be carried out as<br />
effi ciently as possible. Grinding should<br />
be avoided where possible. Reworking<br />
and machining should also be easy to<br />
carry out. Machining allowances are to<br />
be kept as small as possible.<br />
Essential inspections or quality tests<br />
should be facilitated by constructive<br />
measures.
Solidifi cation simulation and thermography<br />
Solidifi cation simulation<br />
A basic aim in the manufacture of cast-<br />
ings is to avoid casting defects while<br />
minimising the amount of material in the<br />
recycling circuit.<br />
Optimisation of the manufacture of cast-<br />
ings with regard to casting geometry,<br />
gating and feeding system and cast-<br />
ing parameters can be achieved via<br />
numerical simulation of die fi lling and<br />
the mechanisms of solidifi cation on the<br />
computer. <strong>Casting</strong> defects can thus be<br />
detected in good time and the casting<br />
design and casting system optimised<br />
before the fi rst casting operation takes<br />
place. In principle, fl ow and thermal con-<br />
duction phenomena which occur during<br />
casting can be calculated numerically<br />
using simulation programmes.<br />
In calculation models, the casting and<br />
die geometry – which fi rst of all must be<br />
available in a CAD volume model – is thus<br />
divided into small volume elements (Finite<br />
Difference Method). The fl ow velocities<br />
and temperatures in the individual volume<br />
elements are then calculated using<br />
a numerical method.<br />
Possible positive effects of simulation<br />
calculations include:<br />
Optimisation of the casting before<br />
casting actually takes place<br />
Avoiding casting defects<br />
Optimisation of the feeding system<br />
(reducing material in the recycling<br />
circuit)<br />
Optimisation of the casting<br />
process (reducing cycle times)<br />
Increasing process stability<br />
Visualisation of the die-fi lling and<br />
solidifi cation process.<br />
A simulation programme does not opti-<br />
mise on its own and can not, and should<br />
not, replace the experienced foundry-<br />
man. To exploit the potential of die-fi lling<br />
and solidifi cation simulation to the full,<br />
it should be applied as early as possible,<br />
i.e. already at the design stage of<br />
the casting.<br />
Thermography<br />
Even after a casting goes into volume<br />
production, it is often desirable and nec-<br />
essary to optimise the casting process<br />
and increase process stability. Besides<br />
the aforementioned solidifi cation simula-<br />
tion, periodic thermal monitoring of the<br />
dies by means of thermography is used<br />
in particular.<br />
In this process, a thermogramme of the<br />
die or casting to be investigated is made<br />
with the aid of an infrared camera. This<br />
way, the effectiveness of cooling, e.g. in<br />
pressure or gravity die casting, can be<br />
checked or optimised and the optimum<br />
time for lifting determined.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 37
Avoiding casting defects<br />
As shown in Table 4, there are two<br />
phenomena which – individually or in<br />
combination – can lead to defects in<br />
emergent castings:<br />
1. The continuous (new) formation of<br />
oxides in the liquid state and<br />
2. volume contraction during the transition<br />
from liquid to solid state.<br />
During transition from liquid to solid<br />
state, the dissolved hydrogen in the melt<br />
precipitates and, on interacting with oxides,<br />
causes the well-known problem of<br />
microporosity or gas porosity.<br />
The task of melt management and<br />
treatment is to keep oxide formation<br />
and, consequently, the dangers to cast<br />
quality within limits. Information about<br />
this is provided in the sections on “Melt<br />
38<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
quality and melt cleaning” as well as<br />
“Methods for melt monitoring” and “Se-<br />
lecting the casting process”. Here are a<br />
few key points:<br />
Use good quality ingots<br />
Quality-oriented melting technology<br />
and equipment<br />
Correct charging of the ingots<br />
(dry, rapid melting)<br />
Temperature control during<br />
melting and casting<br />
Melt cleaning and melt control<br />
Safety measures during treatment,<br />
transport and casting<br />
Volume contraction during the transition<br />
from liquid to solid state can - depending<br />
on the casting alloy - be up to 7 %<br />
volume. Under unfavourable conditions,<br />
part of this volume difference can be the<br />
cause of defects in castings, e.g. shrink<br />
marks, shrink holes, pores or tears. To<br />
produce a good casting, the possibility<br />
of feeding additional molten metal into<br />
the contracting microstructure during<br />
solidifi cation must exist. In pressure<br />
casting processes, this occurs by means<br />
of pressurisation; in gravity die casting,<br />
this is done primarily by feeding.<br />
The type of solidifi cation is also impor-<br />
tant when considering suitable casting/<br />
technical measures. In AlSi casting al-<br />
loys with approx. 13 % Si, a frozen shell<br />
forms during solidifi cation while, in hy-<br />
poeutectic AlSi casting alloys as well<br />
as in AlMg and AlCu casting alloys, a<br />
predominantly dendritic or globular so-<br />
lidifi cation occurs.<br />
In gravity die casting processes, the<br />
feeders are laid out in particularly critical<br />
or thick areas of the casting. The feed-<br />
ers require hot metal in appropriately<br />
large volumes to execute their task. The<br />
combination of feeding and cooling is<br />
useful. Heat removal to accelerate and<br />
control solidifi cation at the lower end<br />
of the casting or in solid areas can be<br />
effected by means of metal plates or<br />
surface chills (cooling elements).
As already shown in the section on cast-<br />
ing processes, an uncontrolled or tur-<br />
bulent fi lling of the die cavity can have a<br />
negative infl uence on the quality of the<br />
casting. A gating system which allows<br />
the solidifi cation front to be controlled<br />
upwards through the casting from the<br />
bottom up to the feeder is helpful. A<br />
good casting system, e.g. side stand<br />
pipe-slit gate, begins the fi lling in the<br />
lower part of the die and always layers<br />
the new hot metal on the lower, already<br />
solidifi ed part and also supplies the<br />
feeder with hot metal.<br />
A casting system of this type can par-<br />
tially cushion the negative effect caused<br />
by volume contraction while conducting<br />
the molten metal in such a way that fresh<br />
oxidation of the melt due to turbulence<br />
is avoided.<br />
Classifi cation of casting defects<br />
Source of defect Consequences Optimisation<br />
for the casting possibilities<br />
Oxidation and Pores Melt treatment<br />
hydrogen- Aeration and degassing<br />
absoption Inclusions Melting and<br />
Leakiness casting temperature<br />
Surface defects Filter<br />
Machining<br />
Loss of strength<br />
and elongation<br />
Volume contraction Cavity Gating system<br />
Shrinkage Solidifi cation control<br />
Aeration Feeding<br />
Leakiness Grain refi nement<br />
Loss of strength Modifi cation<br />
and elongation<br />
Two methods can be used to reduce<br />
the number of defective parts due to<br />
porosity: In hot isostatic pressing (HIP),<br />
porous castings are subjected to high<br />
pressure at elevated temperatures so<br />
that shrinkage and pores inside the castings<br />
are reduced; they do not, however,<br />
completely disappear. A second and<br />
less costly possibility is the sealing of<br />
castings by immersing them in plastic<br />
solutions. The shrinkage and pores,<br />
which extend to the surface, are fi lled<br />
with plastic and therefore sealed.<br />
Table 4<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 39
Heat treatment of aluminium castings<br />
Heat treatment gives users of castings<br />
the possibility of specifi cally improv-<br />
ing the mechanical properties or even<br />
chemical resistance. Depending on the<br />
casting type, the following common and<br />
applied methods for aluminium castings<br />
can be used:<br />
Stress relieving<br />
Stabilising<br />
Homogenising<br />
Soft annealing<br />
Age-hardening.<br />
The most important form of heat treatment<br />
for aluminium castings is artifi cial<br />
ageing. Further information is provided<br />
below.<br />
40<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Ageing time [h]<br />
Metallurgy – fundamental principles<br />
For age-hardening to take place, there<br />
must be a decreasing solubility of a par-<br />
ticular alloy constituent in the α-solid so-<br />
lution with falling temperature. As a rule,<br />
age-hardening comprises three steps:<br />
In solution annealing, suffi cient amounts<br />
of the important constituents for age-<br />
hardening are dissolved in the α-solid<br />
solution.<br />
With rapid quenching, these constituents<br />
remain in solution. Afterwards, the parts<br />
are relatively soft.<br />
Figure 11.1<br />
Yield strength of<br />
gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />
Yield strength R p0,2<br />
[MPa]<br />
280<br />
240<br />
200<br />
160<br />
120<br />
0<br />
0 2 4 6 8 10 12 14 16<br />
160 °C 180 °C 200 °C<br />
As-cast state<br />
In ageing, mostly artifi cial ageing, precipitation<br />
of the forcibly dissolved components<br />
takes place in the form of small<br />
sub-microscopically phases which cause<br />
an increase in hardness and strength.<br />
These tiny phases, which are technically<br />
referred to as “coherent or semicoherent<br />
phases”, represent obstacles<br />
to the movement of dislocations in the<br />
metal, thereby strengthening the previously<br />
easily-formable metal.<br />
The following casting alloy types are<br />
age-hardenable:<br />
Al Cu<br />
Al CuMg<br />
Al SiMg<br />
Al MgSi<br />
Al ZnMg.<br />
Figure 11.2<br />
Elongation of<br />
gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />
Elongation A5 [%]<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0<br />
0 2 4 6 8 10 12 14 16<br />
Ageing time [h]<br />
160 °C 180 °C 200 °C<br />
As-cast state
Solution annealing<br />
To bring the hardened constituents into<br />
solution as quickly as possible and in a<br />
suffi cient amount, the solution anneal-<br />
ing temperature should be as high as<br />
possible with, however, a safety margin<br />
of approx. 15 K to the softening point<br />
of the casting alloy in order to avoid incipient<br />
fusion. For this reason, it is often<br />
suggested that casting alloys containing<br />
Cu should undergo step-by-step solution<br />
annealing (at fi rst 480 °C, then 520 °C).<br />
The annealing time depends on the wall<br />
thickness and the casting process. Com-<br />
pared with sand castings, gravity die cast-<br />
ings require a shorter annealing time to<br />
dissolve the constituents suffi ciently due<br />
to their fi ner microstructure. In principle,<br />
an annealing time of around one hour<br />
Figure 11.3<br />
Tensile strength of<br />
gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />
Tensile strength Rm [MPa]<br />
360<br />
320<br />
280<br />
240<br />
200<br />
160<br />
0 2 4 6 8 10 12 14 16<br />
Ageing time [h]<br />
160 °C 180 °C 200 °C<br />
As-cast state<br />
suffi ces. The normally longer solution<br />
annealing times of up to 12 hours, as<br />
for example in Al SiMg alloys, produce<br />
a good spheroidising or rounding of the<br />
eutectic silicon and, therefore, a marked<br />
improvement in elongation.<br />
The respective values for age-hardening<br />
temperatures and times for the individual<br />
casting alloys can be indicated on the<br />
respective data sheets.<br />
During the annealing phase, the strength<br />
of the castings is still very low. They must<br />
also be protected against bending and<br />
distortion. With large and sensitive castings,<br />
it may be necessary to place them<br />
in special jigs.<br />
Quenching<br />
Hot castings must be cooled in water as<br />
rapidly as possible (5-20 seconds de-<br />
pending on wall thickness) to suppress<br />
any unwanted, premature precipitation of<br />
the dissolved constituents. After quench-<br />
ing, the castings display high ductility.<br />
This abrupt quenching and the ensuing<br />
increase in internal stresses can lead<br />
to distortion of the casting. Parts are<br />
often distorted by vapour bubble pressure<br />
shocks incurred during the rapid<br />
immersion of hollow castings. If this is<br />
a problem, techniques such as spraying<br />
under a water shower or quenching in<br />
hot water or oil have proved their value<br />
as a fi rst cooling phase.<br />
Nevertheless, any straightening work<br />
necessary at this stage should be carried<br />
out after quenching and before ageing.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 41
Ageing<br />
The procedure of ageing brings about<br />
the decisive increase in hardness and<br />
strength of the cast structure through<br />
the precipitation of the very small hardening<br />
phases. Only after this does the<br />
part have its defi nitive service properties<br />
and its external shape and dimensions.<br />
Common alloys mostly undergo artifi cial<br />
ageing. The ageing temperatures and<br />
times can be varied as required. In this<br />
Figure 11.4<br />
Brinell hardness of<br />
gravity die cast test bars (Diez die) in Al Si10Mg alloy<br />
Brinell hardness<br />
[HB]<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
0 2 4 6 8 10 12 14 16<br />
42<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Ageing time [h]<br />
160 °C 180 °C 200 °C<br />
As-cast state<br />
way, for example, the mechanical prop-<br />
erties can be adjusted specifi cally to at-<br />
tain high hardness or strength although,<br />
in doing this, relatively lower elongation<br />
must be reckoned with. Conversely, high<br />
elongation can be also achieved while<br />
lower strength and hardness values will<br />
be the result. When selecting the ageing<br />
temperatures and times, it is best to<br />
refer to the ageing curves which have<br />
been worked out for many casting alloys<br />
(Figures 11.1-11.4).<br />
Infl uence of Magnesium<br />
on the tensile strength (Diez bars)<br />
In Al SiMg casting alloys, a further possibility<br />
of specifi cally adjusting strength<br />
and elongation arises from varying the<br />
Mg content in combination with different<br />
heat treatment parameters (Figure 12).<br />
Tensile strength Rm Alloy Al Si7 auf 99.9 base<br />
[MPa]<br />
300<br />
+ 200 ppm Sr + 1 kg/mt Al Ti3B1<br />
n=5<br />
250<br />
200<br />
150<br />
100<br />
50<br />
0<br />
0 0.1 0.2 0.3 0.4 0.5 0.6<br />
8 h to 525 °C, H 2 O +6 h to 160 °C<br />
Magnesium [%]<br />
8 h to 525 °C, H 2 O As-cast state<br />
Figure 12
If the heat treatment does not work fi rst<br />
time, it can be repeated beginning with<br />
solution annealing. By doubling the solution<br />
time, a coarsening of the eutectic<br />
silicon can arise in the grain structure.<br />
Since the solution treatment is performed<br />
close to the alloy‘s melting temperature<br />
and the precipitation rate is highly sensitive<br />
to variations in ageing temperature,<br />
it is essential that a high degree<br />
of consistency and control is assured.<br />
Procedures used in artifi cial ageing 1)<br />
Regular maintenance, especially of the<br />
measuring and control equipment, is<br />
therefore absolutely essential.<br />
For slightly higher hardness or strength<br />
requirements, there is the non-standard<br />
possibility of “simplifi ed age-hardening”.<br />
This can be used in gravity die casting<br />
and pressure die casting when age-<br />
hardenable alloys are being poured.<br />
Decisive here is a further rapid cooling<br />
after ejection from the die, e.g. by immediately<br />
immersing the part in a bath<br />
Table 5<br />
<strong>Casting</strong> type Example Solution heat treatment Age-hardening<br />
Temperature Time Temperature Time<br />
[°C] [h] [°C] [h]<br />
Al SiMg Al Si10Mg 530 4 - 10 160 - 170 6 - 8<br />
Al SiCu Al Si9Cu3 480 6 - 10 155 - 165 6 - 2<br />
Al MgSi Al Mg3Si 550 4 - 10 155 - 175 8 - 0<br />
Al CuMg 530* 8 - 18 140 - 170 6 - 8<br />
1) Typical temperature and time values<br />
* Poss. gradual annealing at approx. 480 °C / approx. 6 h<br />
of water. Artifi cial ageing in a furnace at<br />
approx. 170 °C brings about the desired<br />
increase in hardness and strength.<br />
The procedure used in artifi cial ageing as<br />
well as typical temperatures and times<br />
are shown in Table 5.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 43
Mechanical machining of aluminium castings<br />
In general, parts made from aluminium<br />
casting alloys are easy-machinable.<br />
This also applies for all metal-cutting<br />
processes. Low cutting force allows a<br />
high volume of metal to be removed. The<br />
surface fi nish of the cast piece depends<br />
on the machining conditions, such as<br />
cutting speed, cutting geometry, lubrication<br />
and cooling.<br />
The high cutting speeds required in aluminium<br />
to achieve minimum roughness<br />
necessitate, with regard to processing<br />
machines and tools, stable, vibrationfree<br />
construction and good cutting tools.<br />
Besides the microstructure – including<br />
defects, pores or inclusions – the silicon<br />
content of the casting has a strong effect<br />
on tool wear. Modifi ed, hypoeutectic<br />
AlSi casting alloys have, e.g. the highest<br />
tool time, while hypereutectic aluminium-<br />
silicon piston casting alloys can cause<br />
very considerable tool wear.<br />
44<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
With softer materials and also with most<br />
hypoeutectic AlSi casting alloys, narrow<br />
tools, i.e. with a large rake angle, cause<br />
the least possible surface roughness.<br />
These casting alloys produce narrow-<br />
spiral or short-breaking turnings. When<br />
machining aluminium, suitable emul-<br />
sions with water are used as cooling<br />
agents and lubricants. Friable and chips<br />
and fi ne to powdery Si dust arise when<br />
machining hypereutectic casting alloys.<br />
In combination with the lubricant, this<br />
powder produces an abradant which is<br />
often processed when dry. In some respects,<br />
the machining of these casting<br />
alloy types is similar to grey cast iron.<br />
With workpieces made from Al Si12<br />
casting alloys with their very soft matrix,<br />
a large volume of long curly spirals are<br />
produced. In addition, the plastic material<br />
tends to build up edges on the tool.<br />
This leads to lubrication and, as a result,<br />
a poor surface appearance. When this<br />
occurs, it often gives the machinist the<br />
subjective impression of bad machinability<br />
although tool wear is not the cause<br />
in this case.<br />
High-speed steel and hard metal or<br />
ceramic plates are used as cutting tool<br />
materials; for microfi nishing, diamonds<br />
are often utilised.<br />
The following machining allowances are<br />
given for the main casting processes:<br />
sand castings: 1.5-3 mm<br />
gravity die castings: 0.7-1.5 mm<br />
pressure die castings: 0.3-0.5 mm.<br />
In order to minimise value losses, turnings<br />
and chips should be sorted out according<br />
to casting alloy type and stored possibly<br />
in briquettes. In addition, dampness,<br />
grease and free iron reduce the value of<br />
chips and turnings. <strong>Aluminium</strong> chips and<br />
turnings are not hazardous materials and<br />
there is no risk of fi re during storage.<br />
When grinding aluminium parts, explosion-<br />
proof separation of the dust is stipulated.
Welding and joining aluminium castings<br />
Suitability and behaviour<br />
Similar to most wrought aluminium alloys,<br />
castings made from aluminium casting<br />
alloys can, in principle, also be joined by<br />
means of fusion welding. Near-eutectic<br />
and hypoeutectic aluminium-silicon cast-<br />
ing alloys are the best to weld. Poor to<br />
unweldable are parts made from Al Cu4Ti<br />
alloys types since the Cu-content can<br />
cause the casting alloy to crack during<br />
welding. In AlMg casting alloys, the ten-<br />
dency to tearing must be counteracted<br />
by selecting a suitable weld fi ller.<br />
Applications in the aluminium sector<br />
Although near net shape casting gives<br />
the designer the greatest possible freedom<br />
in the design of castings, welding is<br />
becoming increasingly important for the<br />
joining of aluminium cast components,<br />
either for welding two or more easy-tocast<br />
parts (e.g. half shells) – whereas<br />
they would be diffi cult to cast as one –<br />
to form hollow bodies on the one hand<br />
or for joining extruded sections or sheet<br />
to castings to give a subassembly on<br />
the other, such as the case in vehicle<br />
construction, lamp posts, lamp fi ttings<br />
and heat exchangers.<br />
The production welding sector should<br />
not be underestimated, e.g. for repairing<br />
defects in castings. Besides casting<br />
defects, there is also the possibility of<br />
correcting dimensional discrepancies,<br />
removing wear by build-up welding and<br />
repairing broken components.<br />
Welding processes<br />
The most frequently used fusion weld-<br />
ing processes for joining castings are<br />
metallic-insert-gas welding (MIG weld-<br />
ing) and Tungsten-inert-gas welding<br />
(TIG welding).<br />
Metal inert-gas welding (MIG welding)<br />
In MIG welding, an inert-gas arc weld-<br />
ing process, a continuous arc burns<br />
between a melting wire electrode and<br />
the workpiece. The process works with<br />
direct current, the wire electrode acting<br />
as the positive pole. The process is carried<br />
out under an inert gas in order to<br />
protect the melt area from the hazardous<br />
infl uences of the oxygen contained<br />
in air and moisture. Argon and/or helium,<br />
both inert gases, are used as shielding<br />
gases. Normally, it is cheaper to weld<br />
using argon. The process is suitable<br />
for both manual welding and for fully-<br />
mechanised and automatic welding. In<br />
fully-mechanised and automatic welding,<br />
both the power source and burner are<br />
water-cooled. With the wire electrode<br />
acting as the positive pole, the energy<br />
density is so high that it is able to break<br />
open the tenacious and high-melting<br />
oxide layer by means of local, explosive<br />
metal vaporisation underneath the oxide.<br />
With appropriate heat conduction,<br />
it is possible to achieve a relatively narrow<br />
heat-affected zone with satisfactory<br />
strength and elongation values.<br />
A further development of MIG welding is<br />
represented by MIG pulse welding. Here,<br />
the welding current alternates between a<br />
so-called pulsed current and background<br />
current. Using this process, it is possible<br />
to carry out diffi cult tasks, i.e. thin wall<br />
thicknesses (1 mm) and out-of-position<br />
work (overhead).<br />
Today, MIG welding is the most frequently<br />
used aluminium welding process because,<br />
in addition to its easy manipulation,<br />
the investment and running costs<br />
are favourable.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 45
Tungsten-insert-gas welding<br />
(TIG welding)<br />
In TIG welding, an inert-gas shielded<br />
arc welding process, an arc burns continuously<br />
between a non-consumable<br />
electrode made of a tungsten alloy and<br />
the casting. Alternating current is normally<br />
used when welding aluminium. The<br />
welding fi ller is fed in separately from<br />
outside either by hand or mechanically.<br />
The process is carried out under an inert<br />
gas in order to protect the melt area<br />
from the hazardous infl uences of the<br />
oxygen contained in air and moisture.<br />
Argon and/or helium, both inert gases,<br />
are used as shielding gases. Welding is<br />
usually carried out with alternating current<br />
and argon which is cheaper. This is<br />
primarily a manual welding process but<br />
there is a possibility to work with a full<br />
degree of mechanisation. In TIG welding,<br />
the power source and the burner are<br />
both water-cooled. By using alternating<br />
current, the tenacious and high-melting<br />
oxide layer is broken open during welding,<br />
similar to the MIG process. Welding<br />
normal diameter material with direct<br />
current and a reverse-polarity tungsten<br />
electrode would lead to destruction due<br />
to electric overload. The electrode diameter,<br />
however, can not be increased since<br />
the current density required for welding<br />
is no longer suffi cient.<br />
46<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
In one process variant, which has an<br />
electrode with negative polarity as in the<br />
welding of steel, welding is carried out<br />
using direct current under a helium shield.<br />
Compared with argon, helium displays<br />
better thermal conductivity so that less<br />
current is required to break open the oxide<br />
layer. Consequently, the electrode is<br />
not overloaded. In TIG welding, there are<br />
also process variants which work with<br />
the pulsed-current technique.<br />
With regard to freedom from porosity,<br />
the cleanest seams can be achieved<br />
using TIG welding. One disadvantage<br />
of the TIG welding process, however, is<br />
the high local energy input. This leads<br />
to considerable softening of the zone<br />
adjacent to the weld which is also the<br />
case with MIG welding. TIG welding, for<br />
example, is an excellent process for the<br />
repair of small casting defects. Compared<br />
with the MIG process, however,<br />
TIG welding operates at lower speeds.<br />
Other thermal joining processes<br />
The group of so-called “pressure welding<br />
processes” also includes friction stear<br />
welding (FSW) which is frequently used<br />
for welding aluminium castings. Since this<br />
welding process works without any fi ller<br />
material, it is possible to join materials<br />
together which are not fusion-weldable<br />
since they would form brittle inter-metallic<br />
phases. By means of friction welding,<br />
aluminium and steel, for example, can<br />
be joined together.<br />
The principle behind the process is to heat<br />
the workpieces up to a pasty condition<br />
followed by subjecting them to strong<br />
compression. A weld upset is thus developed<br />
and, if necessary, subsequently<br />
machined. The heating is done by rotating<br />
one or both parts and fi nally pressing<br />
them against each other until they<br />
stop moving. It even allows workpieces<br />
of circular and square cross-sections to<br />
be joined together.<br />
As a result of the rotary movement and<br />
in order to keep the compression load<br />
from increasing too much, a certain crosssectional<br />
area may not be exceeded.<br />
Another welding process is represented<br />
by electron beam welding. Particular interest<br />
is being shown in this process at<br />
the moment for the welding of aluminium<br />
pressure die castings.
The process operates mostly under high<br />
vacuum. There are also process variants<br />
which work under partial vacuum and<br />
atmosphere although in these the advan-<br />
tages of this welding process, namely the<br />
production of narrower seams even with<br />
thick workpieces, are extensively lost.<br />
The welding of workpieces takes place<br />
without fi ller material. The welding energy<br />
is imparted by means of a bundled<br />
electron beam which is directed at the<br />
welding point. The electron beams are<br />
generated like those of a cathode ray<br />
tube (television) in a high vacuum. Using<br />
electron-optical focussing, different distances<br />
to the workpiece can be had with<br />
this equipment, even when the workpiece<br />
has undulating contours. Welding inside<br />
closed containers is possible.<br />
In addition to diffi cult-to-weld pressure<br />
die castings, e.g. inlet manifolds, this<br />
process has been successfully used with<br />
cast semi-fi nished products in heat exchangers<br />
and in the welding of pistons<br />
for internal combustion engines.<br />
Weld preparation<br />
To produce a sound weld, it is necessary<br />
to observe certain “rules”. Weld preparation<br />
must match the welding process<br />
being used and the wall thicknesses to<br />
be joined. Excessive oxide formation is<br />
worked off by metal-cutting. When grinding,<br />
resin-bonded grinding discs may<br />
not be used (danger of pore formation).<br />
Another possible way of removing oxides<br />
is to etch the component. Grease<br />
and dirt in the welding area have to be<br />
removed using suitable means (danger<br />
of pore formation). Components with<br />
greater wall thicknesses to be joined<br />
should be pre-heated before welding.<br />
Weld fi ller materials<br />
Weld fi ller materials are standardised.<br />
The selection of weld fi ller materials is<br />
guided by the materials of the parts to<br />
be joined. For the most commonly used<br />
aluminium materials, such as near- and<br />
hypoeutectic AlSi casting alloys as<br />
well as age-hardenable Al Si10Mg and<br />
Al Si5Mg variants, S-Al Si12 and S-Al Si5<br />
weld fi ller materials are recommended.<br />
A great danger in welding is the tendency<br />
of many materials to form cracks during<br />
the transition from liquid to solid state.<br />
The cause of these cracks is weld shrink-<br />
age stresses which occur during cooling.<br />
Often the low melting point phases of<br />
the weld fi ller materials are insuffi cient<br />
to “heal” the cracks arising. Through the<br />
selection of a softer weld fi ller material<br />
with a larger share of low melting point<br />
phases, this danger is reduced. In doing<br />
this, however, the optimum strength<br />
properties in the weld seam must be<br />
frequently foregone.<br />
The decorative anodisation of a welded<br />
joint with the aforementioned fi ller materials<br />
is not possible because the weld<br />
seam would appear dark. Technical anodic<br />
oxidation for protective and adhesive<br />
purposes is, however, always possible.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 47
Surface treatment: corrosion<br />
and corrosion protection<br />
<strong>Aluminium</strong> casting alloys – like wrought<br />
aluminium alloys – owe their corrosion<br />
resistance to a thin, tenacious coating<br />
layer of oxides and hydroxides. In the pH<br />
range from 4.5 to 8.5, this oxide layer is<br />
practically insoluble in aqueous media<br />
and aluminium casting materials suffer<br />
only negligible mass disappearance.<br />
This passivity can, however, be annulled<br />
locally at weak points in the oxide layer<br />
due to the action of water containing<br />
chloride. Since the aqueous medium,<br />
e.g. weather, only acts periodically, a<br />
protective oxide layer forms again at<br />
small, local corrosion sites, e.g. repassivation<br />
occurs. Deep pitting corrosion<br />
can only arise when there is a long-term<br />
effect from aggressive water containing<br />
chloride (e.g. sea water). Beside the<br />
chloride content, the amount of oxygen<br />
in the water also plays a role; corrosion<br />
reaction can only occur in neutral media<br />
(pH = 4.5-8.5) in the presence of<br />
oxygen. The remedy for this can come<br />
in the form of passive protection by<br />
coating or by means of active cathodic<br />
corrosion protection using a sacrifi cial<br />
anode, for example.<br />
Magnesium as an alloying element<br />
causes the formation of a thicker oxide<br />
layer containing MgO and, consequently,<br />
provides greater corrosion protection<br />
against water containing chlorides and<br />
48<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
slightly alkaline media (e.g. ammonia<br />
solutions) since magnesium oxide in<br />
contrast to aluminium oxide is insoluble<br />
in alkaline solutions.<br />
Copper as an alloying element causes<br />
a deterioration in corrosion properties.<br />
This increases slightly with a rising Cu-<br />
content in the range below 0.2 % copper,<br />
above 0.2 to 0.4 % more strongly.<br />
Already with a Cu-content of 0.2 %,<br />
permanent action from aqueous solutions<br />
containing chlorine can have a very<br />
negative effect on corrosion behaviour.<br />
The negative infl uence of iron on cor-<br />
rosion behaviour is not as distinctive<br />
as that of copper. With an Fe-content<br />
of up to 0.6 %, there is no signifi cant<br />
deterioration in the corrosion behaviour<br />
of casting alloys.<br />
The surface treatment of aluminium cast<br />
products is carried out to improve their<br />
corrosion resistance, for decorative<br />
purposes or to increase the strength<br />
of the components.<br />
A homogeneous, non-porous cast struc-<br />
ture free from shrink holes and cracks<br />
makes coating easier. The quality of the<br />
coating is infl uenced decisively by the<br />
pre-treatment.<br />
Wiping, immersion and steam degreasing<br />
(in that order) produce increasingly<br />
grease-free surfaces without removing<br />
the surface oxide fi lm. Grinding, brush-<br />
ing, abrasive blasting or polishing do not<br />
remove the oxide fi lm completely and,<br />
as a rule, act as a preparation to further<br />
surface treatment. Possible sources of<br />
defects leading to subsequent faults<br />
comprise the use of brushes made of<br />
brass or non-stainless steel as well as<br />
sand or steel shot.<br />
When grinding, the use of ceramic<br />
grinding elements without further pretreatment<br />
frequently leads to good paint<br />
adhesion. One precondition is that no<br />
fi nes from the grinding elements are<br />
pressed into the surface of the casting.<br />
Chemical degreasing agents with<br />
a pickling or etching effect remove the<br />
oxide layer and, as a consequence, all<br />
impurities. It is also worth mentioning<br />
that there is also matt or bright pickling<br />
before anodic oxidation to produce a<br />
special surface fi nish.<br />
Following the alkaline pickling of AlMg<br />
or AlSi casting alloys, the pickling fi lm<br />
must be removed by means of an acid<br />
after-treatment with nitric acid, nitric/<br />
hydrofl uoric acid or sulphuric/hydrofl<br />
uoric acid. Instead of alkaline pickling<br />
with fi nal dipping, it is more benefi cial<br />
to use an acidic fl uoride-containing<br />
pickling solution immediately.
Despite careful acid cleaning, a lacquered<br />
aluminium surface can still display<br />
adhesive failure after a certain time<br />
due to environmental effects. Firstly,<br />
a conversion layer, which forms as a<br />
result of the reaction between chemicals<br />
containing chrome and the metal,<br />
passivates the aluminium surface and<br />
protects it from the water diffused by<br />
each layer of lacquer. With respect to<br />
the promotion of adhesion and corrosion<br />
inhibition, the almost equivalent<br />
green and yellow chromate coatings<br />
have proved their worth over many<br />
years. A clear chromate coating, preferably<br />
used under clear lacquer, offers<br />
slightly less corrosion protection due<br />
to the layer being thinner. Cr-VI-free<br />
chromate-phosphate coatings meet the<br />
requirements of food processing and<br />
distribution laws and are permitted for<br />
the pre-treatment of aluminium which<br />
is used in food production, processing<br />
and packaging.<br />
A chrome-free epoxy primer should<br />
be mentioned as a possible but also<br />
qualitatively less favourable alternative.<br />
A precondition for the effectiveness of<br />
this alternate process, however, is also<br />
the removal of the aluminium oxide layer<br />
by chemical or mechanical means.<br />
Of the unlimited number of application<br />
techniques used for volume lacquering,<br />
electrostatic powder coating, whirl sin-<br />
tering and electrophoretic dip coating<br />
are to be stressed in particular because<br />
of their environmental soundness, in<br />
addition to the dip coating and spray-<br />
ing (air, airless and electrostatic) of wet<br />
paint containing solvents.<br />
With the aid of anodic oxidation, the<br />
fi nish achieved using mechanical or<br />
chemical surface treatment can be con-<br />
served permanently. These anodically<br />
produced oxide layers are connected<br />
solidly to the aluminium and, in contrast<br />
to lacquering, the surface structure of<br />
the original metal is unchanged. This<br />
can prove disadvantageous, especially<br />
in pressure die casting. In today‘s<br />
widely-used sulphuric acid anodising<br />
process, the anodically-formed oxide<br />
layers become resistant to touch (e.g.<br />
fi nger marking) and abrasion resistant<br />
after sealing in hot water and possess<br />
good electric strength. The appearance<br />
of anodically-oxidised aluminium castings<br />
is considerably infl uenced by the<br />
alloy composition and the microstructural<br />
condition. For decorative purposes,<br />
Al Mg3H, Al Mg3, Al Mg3Si, Al Mg5,<br />
Al Mg5Si and Al 99.5 and/or Al 99.7<br />
casting alloys have proved their worth.<br />
A decorative anodic oxidation of alloys<br />
with an Si-content > 1 % is not possible<br />
(with the exception of Al Si2MgTi).<br />
The possibility of producing coloured<br />
oxide layers also exists by means of dip<br />
painting, electrolytic colouring and integral<br />
colouring in special electrolytes<br />
(integral process).<br />
For surfaces which have to meet particular<br />
requirements with regard to hardness,<br />
resistance to abrasion and wear, sliding<br />
capacity and electric strength, the<br />
special possibility of using hard anodising<br />
should be taken into consideration.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 49
Information on physical data, strength properties<br />
and strength calculations<br />
The SI unit for force is the Newton (N).<br />
Strength, or proof stress, is expressed in<br />
“MPa” (Mega Pascal). The Brinell hard-<br />
ness of aluminium parts is excluded from<br />
this regulation.<br />
For the tensile strength, 0.2 proof stress,<br />
elongation and Brinell hardness of cast-<br />
ings, DIN EN 1706 contains only binding<br />
minimum values at room temperature<br />
for separately-cast test bars using sand<br />
casting, gravity die casting and invest-<br />
ment casting. The mechanical values<br />
for pressure die cast samples are not<br />
binding and are included only for information.<br />
The values for fatigue strength<br />
or endurance are valid for the best available<br />
casting process and again are only<br />
for information. For samples taken from<br />
the casting, DIN EN 1706 sets out the<br />
following: with respect to the 0.2 proof<br />
stress and tensile strength, the values<br />
reached in castings can be above the<br />
set values in the tables (for separatelycast<br />
test pieces) but not below 70 % of<br />
these set values. With regard to elongation,<br />
the values determined for the<br />
castings can be above the set values<br />
in the tables (for separately-cast test<br />
pieces) or at certain critical points up<br />
to 50 % below these values. Individual<br />
details about the mechanical, physical<br />
and other properties as well as the approximate<br />
working fi gures can be taken<br />
from the casting alloy sheets.<br />
50<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
The actual values reached in the casting<br />
depend on the casting/technical measures<br />
taken, the solidifi cation speed and<br />
also, where applicable, the heat treat-<br />
ment. When the end product has to meet<br />
special requirements, an appropriate<br />
casting alloy is required which, corre-<br />
spondingly, also incurs higher casting/<br />
technical expenses. A few details for<br />
calculating the strength of constructions<br />
which are subjected to static stress are<br />
given below. With dynamic stress, lower<br />
values are estimated.<br />
Surface pressure:<br />
p = approx. 0.8 R [MPa]<br />
p0,2<br />
Shear strength:<br />
B = approx. 0.5 R [MPa]<br />
p0,2<br />
Modulus of elasticity in shear:<br />
G = approx. 0.4 modulus of<br />
elasticity [GPa]<br />
Modulus of elasticity:<br />
E = approx. 70 GPa<br />
Yield strength of gravity die cast samples<br />
Strength at varying temperatures<br />
At low temperatures, the strength and<br />
elongation values of aluminium parts<br />
scarcely change. Due to the crystal<br />
structure of aluminium alloys, no sharp<br />
decrease in impact ductility can occur<br />
at low temperatures – as can happen<br />
with some ferrous metals.<br />
At higher temperatures, the strength and<br />
hardness values decrease while elongation<br />
increases. Up to approx. +150 °C,<br />
these changes are relatively small. With<br />
further increases in temperature, strength<br />
and hardness decrease even more and<br />
elongation rises. Table 6 depicts the 0.2<br />
proof stress values for gravity die cast<br />
samples at various test temperatures.<br />
Table 6<br />
Alloy / Temper Yield strength Rp0,2 [MPa]<br />
-100 °C +20 °C +100 °C +200 °C +250 °C<br />
Al Mg3Si T6 160 150 140 60 30<br />
Silumin F 120 80 60 40 30<br />
Al Si12Cu F 110 90 80 35 30<br />
Al Si8Cu3 F 120 100 90 50 25<br />
Silumin-Kappa F 90 80 70 50 30<br />
Al Mg5Si T6 130 120 110 100 70<br />
Al Si18CuNiMg F 180 170 150 100 80<br />
Al Si12CuNiMg F 200 190 170 100 70<br />
Al Si10MgCu T6 220 200 170 80 35<br />
Pantal 7 T6 215 210 180 80 30<br />
Silumin-Beta T6 220 210 200 80 30<br />
Pantal 5 T6 220 210 200 80 30
Notes on the casting alloy tables<br />
The following tables contain all standard-<br />
ised casting alloys in accordance with<br />
DIN EN 1676 as well as other common<br />
non-standardised alloys with details of<br />
their chemical composition. Provided that<br />
deviations are envisaged for castings,<br />
the corresponding details (in conformity<br />
with DIN EN 1706) are shown in brackets.<br />
Where available, the well-known and very<br />
commonly used VDS numbers (e.g. 231,<br />
226 etc.) are given in these lists.<br />
The aluminium casting alloys are arranged<br />
into seven families according to their typical<br />
casting and alloying similarities. The<br />
data, properties, rankings and standard<br />
values of the casting alloys, or the castings<br />
subsequently made from them, have been<br />
taken from DIN EN 1676 and 1706 or are<br />
based on these standards in the case of<br />
non-standardised alloys. The details are<br />
included for information only and do not<br />
represent any guarantees.<br />
Thermal and electrical conductivity are<br />
dependent on the chemical composition<br />
within the given specifi cation, solidifi ca-<br />
tion conditions and temper. In order to<br />
produce a casting with high conductivity,<br />
it is necessary to keep the content of alloying<br />
and accompanying elements low<br />
within the specifi cation.<br />
The following designation<br />
abbreviations are used in DIN EN 1676:<br />
A <strong>Aluminium</strong><br />
B Ingots (solid or liquid metal)<br />
In DIN EN 1706, the following<br />
abbreviations refer to product<br />
designations:<br />
A <strong>Aluminium</strong> casting alloy<br />
C <strong>Casting</strong><br />
The following abbreviations are used<br />
for the various casting processes:<br />
S Sand casting<br />
K Gravity die casting<br />
D Pressure die casting<br />
L Precision casting<br />
In DIN EN 1706, the following symbols<br />
apply for material conditions:<br />
F as cast<br />
O annealed<br />
T1 controlled cooling from casting<br />
and naturally aged<br />
T4 solution heat-treated and naturally<br />
aged where applicable<br />
T5 controlled cooling from casting<br />
and artifi cially aged or over-aged<br />
T6 solution heat-treated and fully<br />
artifi cially aged<br />
T64 solution heat-treated and artifi cially<br />
under-aged<br />
T7 solution heat-treated and artifi cially<br />
over-aged (stabilised)<br />
Chemical composition<br />
(all data in wt.-%)<br />
<strong>Casting</strong> characteristics and<br />
other properties<br />
Physical properties<br />
Mechanical properties at room<br />
temperature +20 °C<br />
Heat treatment of aluminium<br />
castings<br />
Mechanical properties of gravity<br />
die cast samples<br />
Processing guidelines<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 51
Overview: <strong>Aluminium</strong> casting alloys<br />
by alloy group<br />
Eutectic aluminium-silicon casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin min 12.5<br />
max 13.5 0.15 0.02 0.05 0.05 0.07 0.15 0.03 0.10 Na<br />
Al Si12(a) min 10.5<br />
max 13.5 0.40 0.03 0.35 0.10 0.15 0.05 0.15 Na<br />
(0.55) (0.05)<br />
44200 / 230<br />
Al Si12(b) min 10.5<br />
max 13.5 0.55 0.10 0.55 0.10 0.10 0.15 0.10 0.15 0.05 0.15<br />
(0.65) (0.15) (0.20)<br />
44100<br />
Al Si12(Fe)(a) min 10.5 0.45<br />
max 13.5 0.9 0.08 0.55 0.15 0.15 0.05 0.25<br />
(1.0) (0.10)<br />
44300 / 230D<br />
Al Si12(Fe)(b) min 10.0 0.45<br />
max 13.5 0.9 0.18 0.55 0.40 0.30 0.15 0.05 0.25<br />
(1.0) (0.20)<br />
44500<br />
Al Si12(Cu) min 10.5 0.05<br />
max 13.5 0.7 0.9 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />
(0.8) (1.0) (0.20)<br />
47000 / 231<br />
Al Si12Cu1(Fe) min 10.5 0.6 0.7<br />
max 13.5 1.1 1.2 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />
(1.3) (0.20)<br />
47100 / 231D<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
Near-eutectic wheel casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin-Kappa Sr min 10.5 0.05<br />
max 11.0 0.15 0.02 0.10 0.25 0.07 0.15 0.03 0.10 Sr<br />
Silumin-Beta Sr min 9.0 0.20<br />
max 10.5 0.15 0.02 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />
Al Si11 min 10.0<br />
max 11.8 0.15 0.03 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />
(0.19) (0.05)<br />
44000<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
52<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
The 10 per cent aluminium-silicon casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin-Beta / Al Si9Mg min 9.0 0.30<br />
(0.25)<br />
max 10.0 0.15 0.03 0.10 0.45<br />
(0.19) (0.05) (0.45) 0.07 0.15 0.03 0.10 Na<br />
43300<br />
Al Si10Mg(a) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.40 0.03 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15 Na<br />
(0.55) (0.05) (0.45)<br />
43000 / 239<br />
Al Si10Mg(b) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.45 0.08 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />
(0.55) (0.10) (0.45)<br />
43100<br />
Al Si10Mg(Fe) min 9.0 0.45 0.25<br />
(0.20)<br />
max 11.0 0.9 0.08 0.55 0.50 0.15 0.15 0.15 0.05 0.15 0.05 0.15<br />
(1.0) (0.10) (0.50) (0.20)<br />
43400 / 239D<br />
Al Si10Mg(Cu) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.55 0.30 0.55 0.45 0.15 0.35 0.10 0.15 0.05 0.15<br />
(0.65) (0.35) (0.45) (0.20)<br />
43200 / 233<br />
Al Si9 min 8.0<br />
max 11.0 0.55 0.08 0.50 0.10 0.05 0.15 0.05 0.05 0.15 0.05 0.15<br />
(0.65) (0.10)<br />
44400<br />
Silumin-Delta min 9.0 0.3 0.3<br />
max 10.5 0.4 0.02 0.4 0.03 0.07 0.15 0.03 0.10<br />
Silumin-Gamma min 9.0 0.4 0.15<br />
max 11.3 0.15 0.02 0.9 0.6 0.10 0.15 0.03 0.10 Sr<br />
Al Si10MnMg min 9.0 0.40 0.15<br />
(0.10)<br />
max 11.5 0.20 0.03 0.80 0.60 0.07 0.15 0.05 0.15 Sr<br />
(0.25) (0.05) (0.60) (0.20)<br />
43500<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 53
Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />
The 7 und 5 per cent aluminium-silicon casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Pantal 7 / Al Si7Mg0.3 min 6.5 0.30<br />
(0.25)<br />
max 7.5 0.15 0.03 0.10 0.45 0.07 0.18 0.03 0.10 Na / Sr<br />
(0.19) (0.05) (0.45) (0.25)<br />
42100<br />
Al Si7Mg0.6 min 6.5 0.50<br />
(0.45)<br />
max 7.5 0.15 0.03 0.10 0.70 0.07 0.18 0.03 0.10<br />
(0.19) (0.05) (0.70) (0.25)<br />
42200<br />
Al Si7Mg min 6.5 0.25<br />
(0.20)<br />
max 7.5 0.45 0.15 0.35 0.65 0.15 0.15 0.15 0.05 0.20 0.05 0.15<br />
(0.55) (0.20) (0.65) (0.25)<br />
42000<br />
Pantal 5 min 5.0 0.40 0.05<br />
max 6.0 0.15 0.02 0.10 0.80 0.07 0.20 0.03 0.10<br />
Al Si5Mg min 5.0 0.40 0.05<br />
max 6.0 0.3 0.03 0.4 0.80 0.10 0.20 0.05 0.15<br />
- / 235<br />
Al Si5Cu1Mg min 4.5 1.0 0.40<br />
(0.35)<br />
max 5.5 0.55 1.5 0.55 0.65 0.25 0.15 0.15 0.05 0.20 0.05 0.15<br />
(0.65) (0.65) (0.25)<br />
45300<br />
Al Si7Cu0.5Mg min 6.5 0.2 0.25<br />
(0.20)<br />
max 7.5 0.25 0.7 0.15 0.45<br />
(0.45)<br />
0.07 0.20 0.03 0.10<br />
45500<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
54<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Al SiCu casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total<br />
Al Si8Cu3 min 7.5 2.0 0.15 0.15<br />
(0.05)<br />
max 9.5 0.7 3.5 0.65 0.55 0.35 1.2 0.25 0.15 0.20 0.05 0.25<br />
(0.8) (0.55) (0.25)<br />
46200 / 226<br />
Al Si9Cu3(Fe) min 8.0 0.6 2.0 0.15<br />
(0.05)<br />
max 11.0 1.1 4.0 0.55 0.55 0.15 0.55 1.2 0.35 0.15 0.20 0.05 0.25<br />
(1.3) (0.55) (0.25)<br />
46000 / 226D<br />
Al Si11Cu2(Fe) min 10.0 0.45 1.5<br />
max 12.0 1.0 2.5 0.55 0.30 0.15 0.45 1.7 0.25 0.15 0.20 0.05 0.25<br />
(1.1) (0.25)<br />
46100<br />
Al Si7Cu3Mg min 6.5 3.0 0.20 0.35<br />
(0.30)<br />
max 8.0 0.7 4.0 0.65 0.60 0.30 0.65 0.15 0.10 0.20 0.05 0.25<br />
(0.8) (0.60) (0.25)<br />
46300<br />
Al Si9Cu1Mg min 8.3 0.8 0.15 0.30<br />
(0.25)<br />
max 9.7 0.7 1.3 0.55 0.65 0.20 0.8 0.10 0.10 0.18 0.05 0.25<br />
(0.8) (0.65) (0.20)<br />
46400<br />
Al Si9Cu3(Fe)(Zn) min 8.0 0.6 2.0 0.15<br />
(0.05)<br />
max 11.0 1.2 4.0 0.55 0.55 0.15 0.55 3.0 0.35 0.15 0.20 0.05 0.25<br />
(1.3) (0.55) (0.25)<br />
46500 / 226/3<br />
Al Si7Cu2 min 6.0 1.5 0.15<br />
max 8.0 0.7 2.5 0.65 0.35 0.35 1.0 0.25 0.15 0.20 0.05 0.15<br />
(0.8) (0.25)<br />
46600<br />
Al Si6Cu4 min 5.0 3.0 0.20<br />
max 7.0 0.9 5.0 0.65 0.55 0.15 0.45 2.0 0.30 0.15 0.20 0.05 0.35<br />
(1.0) (0.25)<br />
45000 / 225<br />
Al Si5Cu3Mg min 4.5 2.6 0.20<br />
(0.15)<br />
max 6.0 0.50 3.6 0.55 0.45 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />
(0.60) (0.45) (0.25)<br />
45100<br />
Al Si5Cu3 min 4.5 2.6<br />
max 6.0 0.50 3.6 0.55 0.05 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />
(0.60) (0.25)<br />
45400<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
Others<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 55
Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />
AlMg casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Al Mg3(H) min 2.7<br />
max 0.45 0.15 0.02 0.40 3.2 0.07 0.02 0.03 0.10 B/Be<br />
Al Mg3 min 2.7<br />
(2.5)<br />
max 0.45 0.40 0.03 0.45 3.5 0.10 0.15 0.05 0.15 B/Be<br />
(0.55) (0.55) (0.05) (3.5) (0.20)<br />
51100 / 242<br />
Al Mg3(Cu) min 2.5<br />
max 0.60 0.55 0.15 0.45 3.2 0.30 0.20 0.05 0.15 B/Be<br />
- / 241<br />
Al Mg3Si(H) min 0.9 2.7<br />
max 1.3 0.15 0.02 0.40 3.2 0.07 0.15 0.03 0.10 B/Be<br />
Al Mg5 min 4.8<br />
(4.5)<br />
max 0.35 0.45 0.05 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />
(0.55) (0.55) (0.10) (6.5) (0.20)<br />
51300 / 244<br />
Al Mg5(Si) min 4.8<br />
(4.5)<br />
max 1.3 0.45 0.03 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />
(1.5) (0.55) (0.05) (6.5) (0.20)<br />
51400 / 245<br />
Al Mg9(H) min 1.7 0.2 8.5<br />
max 2.5 0.50 0.02 0.5 10.5 0.07 0.15 0.03 0.10 B/Be<br />
Al Mg9 min 0.45 8.5<br />
(8.0)<br />
max 2.5 0.9 0.08 0.55 10.5 0.10 0.25 0.10 0.10 0.15 0.05 0.15 B/Be<br />
(1.0) (0.10) (10.5) (0.20)<br />
51200 / 349<br />
Al Mg5Si2Mn min 1.8 0.4 5.0<br />
(4.7)<br />
max 2.6 0.20 0.03 0.8 6.0 0.07 0.20 0.05 0.15<br />
(0.25) (0.05) (6.0) (0.25)<br />
51500<br />
Al Si2MgTi min 1.6 0.30 0.50 0.07<br />
(0.45) (0.05)<br />
max 2.4 0.50 0.08 0.50 0.65 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />
(0.60) (0.10) (0.65) (0.20)<br />
41000<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
56<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Casting</strong> alloys for special applications<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
High-strength casting alloys<br />
Al Cu4Ti min 4.2 0.15<br />
(0.15)<br />
max 0.15 0.15 5.2 0.55 0.07 0.25 0.03 0.10<br />
(0.18) (0.19) (0.30)<br />
21100<br />
Al Cu4MgTI min 4.2 0.20 0.15<br />
(0.15) (0.15)<br />
max 0.15 0.30 5.0 0.10 0.35 0.05 0.10 0.05 0.05 0.25 0.03 0.10<br />
(0.20) (0.35) (0.35) (0.30)<br />
21000<br />
Al Cu4MnMg min 4.0 0.20 0.20<br />
(0.15)<br />
max 0.10 0.15 5.0 0.50 0.50 0.03 0.05 0.03 0.03 0.05 0.03 0.10<br />
(0.20) (0.50) (0.05) (0.10) (0.10)<br />
21200<br />
Al Cu4MgTiAg min 4.0 0.01 0.15 0.5 Ag<br />
0.4<br />
max 0.05 0.10 5.2 0.50 0.35 0.05 0.35 0.03 0.10 1.0<br />
Al Cu5NiCoSbZr min 4.5 0.1 1.3 0.15 ****<br />
max 0.20 0.30 5.2 0.3 0.10 1.7 0.10 0.30 0.05 0.15<br />
Piston casting alloys<br />
Al Si12CuNiMg min 10.5 0.8 0.9<br />
(0.8)<br />
0.7<br />
max 13.5 0.6 1.5 0.35 1.5 1.3 0.35 0.20 0.05 0.15 P<br />
(0.7) (1.5) (0.25)<br />
48000 / 260<br />
Al Si18CuNiMg min 17.0 0.8 0.8 0.8<br />
max 19.0 0.3 1.3 0.10 1.3 1.3 0.10 0.15 0.05 0.15 P<br />
****) Co 0.10-0.40 Sb 0.10-0.30 Zr 0.10-0.30<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
Continuation of the table on the next page.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 57
Overview: <strong>Aluminium</strong> casting alloys by alloy group<br />
<strong>Casting</strong> alloys for special applications<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg* min 16.0 4.0 0.5<br />
max 18.0 0.3 5.0 0.15 0.65 0.10 0.10 0.20 0.05 0.15 P<br />
Al Si17Cu4Mg** min 16.0 4.0 0.45<br />
(0.25)<br />
max 18.0 1.0 5.0 0.50 0.65 0.3 1.5 0.15 0.20 0.05 0.25<br />
(1.3) (0.65) (0.25)<br />
48100<br />
Self-hardening casting alloys<br />
Autodur min 8.5 0.3 9.5<br />
max 9.5 0.15 0.02 0.05 0.5 10.5 0.15 0.03 0.10<br />
Autodur (Fe)* min 8.5 0.3 9.5<br />
max 9.5 0.40 0.02 0.30 0.5 10.5 0.15 0.03 0.10<br />
Autodur (Fe)** min 7.5 0.25<br />
(0.20)<br />
9.0<br />
max 9.5 0.27 0.08 0.15 0.5 10.5 0.15 0.05 0.15<br />
(0.30) (0.10) (0.5)<br />
71100<br />
Rotor-<strong>Aluminium</strong><br />
Al 99.7E*** min<br />
max 0.07 0.20 0.01 0.005 0.02 0.004 0.04 Mn+Cr+ 0.03<br />
V+ Ti=<br />
0.02<br />
B 0.04<br />
Al 99.6E*** min<br />
max 0.10 0.30 0.01 0.007 0.02 0.005 0.04 Mn+Cr+ 0.03<br />
V+Ti=<br />
0.030<br />
B 0.04<br />
*) Non-standardised version<br />
**) According to DIN EN 1706: 2010<br />
***) According to DIN EN 576<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
58<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Eutectic<br />
aluminium-silicon casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin min 12.5<br />
max 13.5 0.15 0.02 0.05 0.05 0.07 0.15 0.03 0.10 Na<br />
Al Si12(a) min 10.5<br />
max 13.5 0.40 0.03 0.35 0.10 0.15 0.05 0.15 Na<br />
(0.55) (0.05)<br />
44200 / 230<br />
Al Si12(b) min 10.5<br />
max 13.5 0.55 0.10 0.55 0.10 0.10 0.15 0.10 0.15 0.05 0.15<br />
(0.65) (0.15) (0.20)<br />
44100<br />
Al Si12(Fe)(a) min 10.5 0.45<br />
max 13.5 0.9 0.08 0.55 0.15 0.15 0.05 0.25<br />
(1.0) (0.10)<br />
44300 / 230D<br />
Al Si12(Fe)(b) min 10.0 0.45<br />
max 13.5 0.9 0.18 0.55 0.40 0.30 0.15 0.05 0.25<br />
(1.0) (0.20)<br />
44500<br />
Al Si12(Cu) min 10.5 0.05<br />
max 13.5 0.7 0.9 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />
(0.8) (1.0) (0.20)<br />
47000 / 231<br />
Al Si12Cu1(Fe) min 10.5 0.6 0.7<br />
max 13.5 1.1 1.2 0.55 0.35 0.10 0.30 0.55 0.20 0.10 0.15 0.05 0.25<br />
(1.3) (0.20)<br />
47100 / 231D<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 59
Eutectic aluminium-silicon casting alloys<br />
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
Silumin<br />
Al Si12(a)<br />
Al Si12(b)<br />
Al Si12(Fe)(a)<br />
Al Si12(Fe)(b)<br />
Al Si12(Cu)<br />
crack<br />
stability<br />
tightness state resistance anodisation<br />
Al Si12Cu1(Fe)<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Silumin 2.68 75,000 0.91 ~ 577 21 18 - 24 140 - 170<br />
Al Si12(a) 2.68 75,000 0.90 ~ 577 20 17 - 24 140 - 170<br />
Al Si12(b) 20 16 - 23 130 - 160<br />
Al Si12(Fe)(a) 2.68 75,000 0.90 ~ 577 20 16 - 22 130 - 160<br />
Al Si12(Fe)(b) 20 16 - 22 130 - 160<br />
Al Si12(Cu) 2.70 75,000 0.89 ~ 577 20 16 - 22 130 - 150<br />
Al Si12Cu1(Fe) 2.70 75,000 0.89 ~ 577 20 15 - 20 120 - 150<br />
60<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Silumin F Sand casting 150 70 6 45 60 - 90<br />
Al Si12(a) F Sand casting 150 70 5 50 60 - 90<br />
Al S12(b) F Sand casting 150 70 4 50<br />
Al Si12(Cu) F Sand casting 150 80 1 50 60 - 90<br />
Silium F Gravity die casting 170 80 7 45 60 - 90<br />
Al Si12(a) F Gravity die casting 170 80 6 55 60 - 90<br />
Al Si12(Cu) F Gravity die casting 170 90 2 55 60 - 90<br />
Al Si12(Fe)(a) F Pressure die casting 240 130 1 60 60 - 90<br />
Al Si 12(Fe)(b) F Pressure die casting 240 140 1 60<br />
Al Si12Cu1(Fe) F Pressure die casting 240 140 1 70 60 - 90<br />
The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />
as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Silumin 220 180 150 110 120 80 60 40 6 8 10 12 50 50 45 35<br />
Al Si12(a) 220 180 150 110 120 80 60 40 2,5 3 4 10 50 50 45 35<br />
Al Si12(b) 220 180 150 110 120 80 60 40 2.5 3.4 10 10 50 50 45 35<br />
Al Si12(Cu) 190 170 110 100 80 35 1 3 8 55 45 25<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Silumin 670 - 740 670 - 740 620 - 660 1.0 - 1.2 0.5 - 0.8<br />
Al Si12(a) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si12(Fe)(a) 620 - 660 0.4 - 0.6<br />
Al Si12(Cu) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si12Cu1(Fe) 620 - 660 0.4 - 0.6<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 61
Eutectic aluminium-silicon casting alloys<br />
Application notes<br />
Universal aluminium casting alloy with<br />
medium strength; in part, very good elon-<br />
gation and very good fl ow properties.<br />
Suitable for thin-walled, complicated,<br />
pressure-tight, vibration- and impact-<br />
resistant constructions.<br />
Properties and processing<br />
From the range of AlSi casting alloys,<br />
this type of alloy containing 13 % silicon<br />
has the best fl uidity. In some respects,<br />
the behaviour of the casting alloys in this<br />
range represents a special case. Some<br />
advice is provided below.<br />
In the case of free solidifi cation, e.g. a<br />
dense, bevel-shaped surface, the so-<br />
called “hammer blow”, forms on the top<br />
of the ingot. This type of solidifi cation is<br />
“shell-forming”, i.e. the crystallisation of<br />
the subsequent casting begins with the<br />
formation of a solid shell which then grows<br />
towards the middle of the cast wall. In<br />
this type of casting alloy, there are only<br />
two states, i.e. “solid” and “liquid”. Full<br />
solidifi cation of a casting takes place<br />
at the eutectic temperature of approx.<br />
577 °C). During the solidifi cation process,<br />
the volume can contract by up to 7 %.<br />
62<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
The shell thickness does not decrease.<br />
If the fl ow of liquid metal is interrupted<br />
in the middle wall region during feeding,<br />
a coarse cavity can evolve. (Additional<br />
notes also provided in the sections entitled<br />
“Infl uencing the microstructural<br />
formation of aluminium castings” and<br />
“Avoiding casting defects”.)<br />
This type of aluminium casting alloy can<br />
only be modifi ed with sodium. Sodium<br />
modifi cation is indicated for sand cast-<br />
ings and gravity die castings if particular<br />
requirements are placed on elongation<br />
of the microstructure (see Figure 2). As<br />
a general rule, casting alloys for use in<br />
sand and gravity die casting are offered<br />
in a slightly modifi ed version. Chemical<br />
resistance as well as resistance to weath-<br />
ering and a marine climate increase with<br />
the purity of the casting alloy used. A pri-<br />
mary silicon casting alloy thus meets the<br />
highest requirements in a variety of fi elds<br />
of application, e.g. in the food industry<br />
or in shipbuilding. The elongation of the<br />
cast structure is signifi cantly determined<br />
by the iron content and other impurities.<br />
The demand for high proof stress values<br />
in the casting often requires the use of<br />
primary casting alloys with the lowest<br />
possible content of iron and impurities.<br />
Heat treatment<br />
In the case of sand and gravity die cast-<br />
ings made from casting alloys low in<br />
Cu and Mg, a selective improvement<br />
in ductility can be achieved. This is ef-<br />
fected by means of solution annealing at<br />
520-530 °C with subsequent quenching<br />
in cold water.<br />
Comments<br />
The DIN EN 1676 and DIN EN 1706<br />
standards allow a very wide range of<br />
major alloying elements – silicon from<br />
10.5 to 13.5 %. The practical range for<br />
the silicon content is from 12.5 to 13.5<br />
and, in a slightly hypoeutectic range of<br />
10.5 to 11.2 %. However, these two alloys<br />
display entirely different solidifi cation<br />
behaviour. The intermediate range, with<br />
approx. 11.5 to 12.5 % silicon, runs the<br />
risk of shrinkage cavities. <strong>Casting</strong> alloys<br />
in this critical range are not offered. Even<br />
a blend of these different yet similarsounding<br />
alloys is not recommended.
Near-eutectic<br />
wheel casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin-Kappa Sr min 10.5 0.05<br />
max 11.0 0.15 0.02 0.10 0.25 0.07 0.15 0.03 0.10 Sr<br />
Silumin-Beta Sr min 9.0 0.20<br />
max 10.5 0.15 0.02 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />
Al Si11 min 10.0<br />
max 11.8 0.15 0.03 0.10 0.45 0.07 0.15 0.03 0.10 Sr<br />
(0.19) (0.05)<br />
44000<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
crack<br />
stability<br />
tightness state resistance anodisation<br />
Silumin-Kappa Sr<br />
Silumin-Beta Sr<br />
Al Si11<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Silumin-Kappa Sr 2.68 74,000 0.91 600 - 555 21 20 - 26 150 - 180<br />
Silumin-Beta Sr 2.68 74,000 0.91 600 - 550 21 20 - 26 150 - 180<br />
Al Si11 2.68 74,000 0.91 600 - 550 21 18 - 24 140 - 170<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 63
Near-eutectic wheel casting alloys<br />
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Silumin-Kappa Sr F Gravity die casting 170 80 6 45 60 - 90<br />
Silumin-Beta Sr F Gravity die casting 170 90 5 50 60 - 90<br />
T6 Gravity die casting 290 210 4 90 60 - 90<br />
T64 Gravity die casting 250 180 6 80 60 - 90<br />
Al Si11 F Gravity die casting 170 80 7 45 60 - 90<br />
The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />
as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
Silumin-Kappa Sr T4 520 - 535 4 - 10 20 160 - 170 6 - 8<br />
Silumin-Beta Sr T4 520 - 535 4 - 10 20 150 - 160 2 - 3<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
64<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Silumin-Kappa Sr F 180 170 160 120 90 80 70 50 5 6 6 10 65 45 45 40<br />
Silumin-Beta Sr T64 260 250 210 120 200 180 170 80 4,5 6 7 10 85 80 75 60<br />
Al Si11 F 230 170 160 130 130 80 70 50 3 7 7 10 65 45 40 35<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Silumin-Kappa Sr 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Silumin-Beta Sr 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si11 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8
Application notes<br />
These casting alloy types have been<br />
developed primarily for the casting of<br />
car wheels by means of low-pressure<br />
die casting processes.<br />
Properties and processing<br />
These casting alloys have good fl uidity;<br />
the grain structure displays very high<br />
ductility and good corrosion resistance.<br />
The casting alloy Silumin-Kappa has an<br />
optimum silicon content of 10.5 to 11.0 %.<br />
In Silumin-Beta, the silicon content ranges<br />
from 9.0 and 10.5 % silicon. As a rule,<br />
these casting alloys already undergo a<br />
long-lasting strontium modifi cation (HV)<br />
during production of the ingots. The<br />
strontium addition is approx. 0.020 to<br />
0.030 %. Normally, this smelter modifi -<br />
cation does not need to be repeated at<br />
the foundry. The modifi cation of eutectic<br />
silicon, i.e. the formation of a modifi ed<br />
microstructure, is a necessity since the<br />
ductility of the cast structure of the wheels<br />
produced from these casting alloys meas-<br />
ured by means of the elongation value,<br />
for example, plays a vital role. The level<br />
of the iron content and the level of the<br />
other additions are particularly important<br />
quantities for the ductility or elongation<br />
of the cast structure. On request, these<br />
casting alloys can have a magnesium<br />
content of between 0.05 and 0.45 %.<br />
With an increasing Mg content, the alloys‘<br />
strength can be improved slightly,<br />
their elongation decreases a little with the<br />
level of the Mg content, their machinability<br />
– with respect to chip formation, chip<br />
removal and surface appearance – is<br />
improved, the resistance of the casting<br />
to chemical attack increases, lacquer<br />
adherence, however, can be impaired<br />
by the magnesium content. Only some<br />
of the Silumin-Beta casting alloys are<br />
age-hardenable. The age hardening of<br />
wheels made from alloys of the Silumin-<br />
Kappa type is not recommended. It could<br />
cause partial embrittlement which would<br />
reduce the fatigue strength of the material.<br />
For wheels which have to be heat-treated,<br />
casting alloys of the Al Si7Mg (Pantal 7)<br />
type are recommended. The solidifi cation<br />
characteristics of these casting alloys<br />
are hypoeutectic. During solidifi cation,<br />
the transition is from pasty to mushy.<br />
In the course of subsequent solidifi cation,<br />
aluminium dendrites grow into the<br />
liquid melt. They form an interconnecting<br />
network whose intervening spaces<br />
are then fi lled with the highly-fl uid AlSi<br />
eutectic which then solidifi es. If feeding<br />
is incomplete or the highly-fl uid eutectic<br />
is drawn to another place, defects such<br />
as sinks or microporosity occur. The so-<br />
lidifi cation range is approx. 30 to 45 K.<br />
With this type of casting alloy, cleaning<br />
the melt can only be effected by means<br />
of inert gas or using a vacuum. Cleaning<br />
agents containing chlorine would remove<br />
strontium from the melt. In practice, the<br />
use of purging lances or impeller equipment<br />
have proven their worth.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 65
The 10 per cent aluminium-silicon<br />
casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Silumin-Beta / Al Si9Mg min 9.0 0.30<br />
(0.25)<br />
max 10.0 0.15 0.03 0.10 0.45<br />
(0.19) (0.05) (0.45) 0.07 0.15 0.03 0.10 Na<br />
43300<br />
Al Si10Mg(a) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.40 0.03 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15 Na<br />
(0.55) (0.05) (0.45)<br />
43000 / 239<br />
Al Si10Mg(b) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.45 0.08 0.45 0.45 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />
(0.55) (0.10) (0.45)<br />
43100<br />
Al Si10Mg(Fe) min 9.0 0.45 0.25<br />
(0.20)<br />
max 11.0 0.9 0.08 0.55 0.50 0.15 0.15 0.15 0.05 0.15 0.05 0.15<br />
(1.0) (0.10) (0.50) (0.20)<br />
43400 / 239D<br />
Al Si10Mg(Cu) min 9.0 0.25<br />
(0.20)<br />
max 11.0 0.55 0.30 0.55 0.45 0.15 0.35 0.10 0.15 0.05 0.15<br />
(0.65) (0.35) (0.45) (0.20)<br />
43200 / 233<br />
Al Si9 min 8.0<br />
max 11.0 0.55 0.08 0.50 0.10 0.05 0.15 0.05 0.05 0.15 0.05 0.15<br />
(0.65) (0.10)<br />
44400<br />
Silumin-Delta min 9.0 0.3 0.3<br />
max 10.5 0.4 0.02 0.4 0.03 0.07 0.15 0.03 0.10<br />
Silumin-Gamma min 9.0 0.4 0.15<br />
max 11.3 0.15 0.02 0.9 0.6 0.10 0.15 0.03 0.10 Sr<br />
Al Si10MnMg min 9.0 0.40 0.15<br />
(0.10)<br />
max 11.5 0.20 0.03 0.80 0.60 0.07 0.15 0.05 0.15 Sr<br />
(0.25) (0.05) (0.60) (0.20)<br />
43500<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
66<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
crack tightness state resistance anodisation<br />
stability<br />
Silumin-Beta / Al Si9Mg<br />
Al Si10Mg(a)<br />
Al Si10Mg(b)<br />
Al Si10Mg(Fe)<br />
Al Si10Mg(Cu)<br />
Al Si9<br />
Silumin-Delta<br />
Silumin-Gamma<br />
Al Si10MnMg<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Silumin-Beta / Al Si9Mg 2.68 74,000 0.91 600 - 555 21 20 - 26 150 - 180<br />
Al Si10Mg(a) 2.68 74,000 0.91 600 - 550 21 19 - 25 150 - 170<br />
Al Si10Mg(b) 2.68 74,000 0.91 600 - 550 21 18 - 25 140 - 170<br />
Al Si10Mg(Fe) 2.68 74,000 0.91 600 - 550 21 16 - 21 130 - 150<br />
Al Si10Mg(Cu) 2.68 74,000 0.91 600 - 550 21 16 - 24 130 - 170<br />
Al Si9 2.69 74,000 0.91 605 - 570 21 16 - 22 130 - 150<br />
Silumin-Delta 2.69 74,000 0.91 605 - 570 21 18 - 26 130 - 170<br />
Silumin-Gamma 2.68 74,000 0.91 610 - 560 21 20 - 26 140 - 180<br />
Al Si10MnMg 21 19 - 25 140 - 170<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 67
The 10 per cent aluminium-silicon casting alloys<br />
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Silumin-Beta / Al Si9Mg F Sand casting 150 80 2 50<br />
T6 Sand casting 230 190 2 75<br />
Al Si10Mg(a) F Sand casting 150 80 2 50<br />
T6 Sand casting 220 180 1 75<br />
Al Si10Mg(b) F Sand casting 150 80 2 50<br />
T6 Sand casting 220 180 1 75<br />
Al Si10Mg(Cu) F Sand casting 160 80 1 50<br />
T6 Sand casting 220 180 1 75<br />
Silumin-Beta / Al Si9Mg T6 Gravity die casting 290 210 4 90 80 - 110<br />
T64 Gravity die casting 250 180 6 80 80 - 110<br />
Al Si10Mg(a) F Gravity die casting 180 90 2.5 55 80 - 110<br />
T6 Gravity die casting 260 220 1 90 80 - 110<br />
T64 Gravity die casting 240 200 2 80<br />
Al Si10Mg(b) F Gravity die casting 180 90 2.5 55 80 - 110<br />
T6 Gravity die casting 260 220 1 90 80 - 110<br />
T64 Gravity die casting 240 200 2 80<br />
Al Si10Mg(Cu) F Gravity die casting 180 90 1 55 80 - 110<br />
T6 Gravity die casting 240 200 1 80 80 - 110<br />
Al Si10Mg(Fe) F Pressure die casting 240 140 1 70 60 - 90<br />
Al Si9 F Pressure die casting 220 120 2 55 60 - 90<br />
Silumin-Delta F Pressure die casting 220 120 4 55 60 - 90<br />
Silumin-Gamma F Pressure die casting 240 120 5 70 80 - 90<br />
T6 Pressure die casting 290 210 7 100<br />
The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />
as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />
68<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
Silumin-Beta / Al Si9Mg T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />
T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />
Al Si10Mg(a) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />
T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />
Al Si10Mg(b) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />
T64 520 - 535 4 - 10 20 150 - 160 2 - 3<br />
Al Si10Mg(Cu) T6 520 - 535 4 - 10 20 160 - 170 6 - 8<br />
Silumin-Gamma T6 500 - 530 4 - 8 20 150 - 170 2 - 6<br />
T64 500 - 530 4 - 8 20 180 - 340 2 - 6<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
Typical process parameters<br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Silumin-Beta / Al Si9Mg T6 290 290 260 120 220 210 200 80 3.5 4 4 10 90 90 80 60<br />
Al Si10Mg(a) T6 280 260 230 120 220 220 170 80 1 1 2 8 85 90 80 60<br />
Al Si10Mg(Cu) T6 280 240 210 120 220 200 180 90 1 1 2 7 85 80 75 45<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Silumin-Beta / Al Si9Mg 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si10Mg(a) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si10Mg(b) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si10Mg(Fe) 620 - 660 0.4 - 0.6<br />
Al Si10Mg(Cu) 670 - 740 670 - 740 1.0 - 1.2 0.5 - 0.8<br />
Al Si9 660 - 740 660 - 740 620 - 700 0.5 - 0.8 0.4 - 0.6<br />
Silumin-Delta 620 - 700 0.4 - 0.6<br />
Silumin-Gamma 620 - 730 0.4 - 0.6<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 69
The 10 per cent aluminium-silicon casting alloys<br />
Application notes<br />
This important group of casting alloys<br />
is used for castings with medium wall<br />
thicknesses which require higher, to the<br />
highest strength properties. The fi elds of<br />
application comprise mechanical and<br />
electrical engineering, the food industry<br />
as well as in engine and motor vehicle<br />
construction. Silumin-Beta casting alloys<br />
are also used for car wheels. Silumin-<br />
Gamma is a heat-treatable high-pressure<br />
die casting alloy. However, successful<br />
treatment requires the use of an adequate<br />
casting process (e.g. vacuum-assisted<br />
high-pressure die casting).<br />
70<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Properties and processing<br />
The fl uidities of these casting alloys are<br />
still good. Heat-treatable castings made<br />
from alloys containing magnesium dis-<br />
play particularly good machinability. With<br />
increasing purity, the ductility of the cast<br />
structure also increases. Where the requirements<br />
on corrosion resistance are<br />
high, high-purity grades are selected.<br />
Sand and gravity die castings can be<br />
artifi cially aged. In doing so, however,<br />
ductility decreases. The solidifi cation<br />
characteristics of this group of casting<br />
alloys are hypoeutectic. During the solidifi<br />
cation process, aluminium dendrites<br />
grow into the melt fi rst. The highly-fl uid<br />
AlSi eutectic then penetrates the intervening<br />
spaces of the network and clamps<br />
the microstructural framework together.<br />
If the feeding of the remaining eutectic<br />
melt is hindered in any way, defects such<br />
as sinks or micro/macrocavities occur.<br />
This causes porous areas and also leads<br />
to a weakening of the structural crosssection.<br />
During casting, therefore, attention<br />
must be paid to ensure good feeding<br />
and, as far as possible, controlled<br />
solidifi cation. The solidifi cation range<br />
amounts to approx. 45 K.<br />
Where requirements on elongation or<br />
ductility are higher, modifi cation of the<br />
melt is recommended. The casting alloys<br />
for use in gravity die casting are modifi<br />
ed with sodium or strontium. For sand<br />
casting, modifi cation with sodium only<br />
is recommended. As a general rule, the<br />
casting alloys for sand and gravity die<br />
casting are offered in versions which can<br />
be easily modifi ed.
The 7 and 5 per cent aluminium-silicon<br />
casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Pantal 7 / Al Si7Mg0.3 min 6.5 0.30<br />
(0.25)<br />
max 7.5 0.15 0.03 0.10 0.45 0.07 0.18 0.03 0.10 Na / Sr<br />
(0.19) (0.05) (0.45) (0.25)<br />
42100<br />
Al Si7Mg0.6 min 6.5 0.50<br />
(0.45)<br />
max 7.5 0.15 0.03 0.10 0.70 0.07 0.18 0.03 0.10<br />
(0.19) (0.05) (0.70) (0.25)<br />
42200<br />
Al Si7Mg min 6.5 0.25<br />
(0.20)<br />
max 7.5 0.45 0.15 0.35 0.65 0.15 0.15 0.15 0.05 0.20 0.05 0.15<br />
(0.55) (0.20) (0.65) (0.25)<br />
42000<br />
Pantal 5 min 5.0 0.40 0.05<br />
max 6.0 0.15 0.02 0.10 0.80 0.07 0.20 0.03 0.10<br />
Al Si5Mg min 5.0 0.40 0.05<br />
max 6.0 0.3 0.03 0.4 0.80 0.10 0.20 0.05 0.15<br />
- / 235<br />
Al Si5Cu1Mg min 4.5 1.0 0.40<br />
(0.35)<br />
max 5.5 0.55 1.5 0.55 0.65 0.25 0.15 0.15 0.05 0.20 0.05 0.15<br />
(0.65) (0.65) (0.25)<br />
45300<br />
Al Si7Cu0.5Mg min 6.5 0.2 0.25<br />
(0.20)<br />
max 7.5 0.25 0.7 0.15 0.45<br />
(0.45)<br />
0.07 0.20 0.03 0.10<br />
45500<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 71
The 7 and 5 per cent aluminium-silicon casting alloys<br />
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
crack tightness state resistance anodisation<br />
stability<br />
Pantal 7 / Al Si7Mg0.3<br />
Al Si7Mg0.6<br />
Al Si7Mg<br />
Pantal 5<br />
Al Si5Mg<br />
Al Si5Cu1Mg<br />
Al Si7Cu0.5Mg<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Pantal 7 / Al Si7Mg0.3 2.66 73,000 0.92 625 - 550 22 21 - 27 160 - 180<br />
Al Si7Mg0.6 2.66 73,000 0.92 625 - 550 22 20 - 26 150 - 180<br />
Al Si7Mg 2.66 73,000 0.92 625 - 550 22 19 - 25 150 - 170<br />
Pantal 5 2.67 72,000 0.92 625 - 550 23 21 - 29 150 - 180<br />
Al Si5Mg 2.67 72,000 0.92 625 - 550 23 21 - 26 150 - 180<br />
Al Si5Cu1Mg 2.67 72,000 0.92 625 - 550 22 19 - 23 140 - 150<br />
Al Si7Cu0.5Mg 22 16 - 22 150 - 165<br />
72<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Pantal 7 / Al Si7Mg0.3 T6 Sand casting 230 190 2 75<br />
Al Si7Mg0.6 T6 Sand casting 250 210 1 85<br />
Al Si7Mg F Sand casting 140 80 2 50<br />
T6 Sand casting 220 180 1 75<br />
Pantal 5 T6 Sand casting 240 220 2 80<br />
T4 Sand casting 200 150 4 75<br />
Al Si5Mg T6 Sand casting 240 220 1 80<br />
T4 Sand casting 200 150 3 75<br />
Al Si5Cu1Mg T6 Sand casting 230 200
The 7 and 5 per cent aluminium-silicon casting alloys<br />
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
Pantal 5 T4 520 - 535 4 - 10 20 20 - 30 120<br />
T6 520 - 535 4 - 10 155 - 165 6 - 10<br />
Al Si5Mg T4 520 - 535 4 - 10 20 20 - 30 120<br />
T6 520 - 535 4 - 10 155 - 165 6 - 10<br />
Al Si5Cu1Mg T4 520 - 535 4 - 10 20 20 - 30 120<br />
T6 520 - 535 4 - 10 155 - 165 6 - 10<br />
Pantal 7 / Al Si7Mg0.3 T6 520 - 545 4 - 10 155 - 165 6 - 10<br />
T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />
Al Si7Mg0,6 T6 520 - 545 4 - 10 155 - 165 6 - 10<br />
T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />
Al Si7Mg T6 520 - 545 4 - 10 155 - 165 6 - 10<br />
T64 520 - 545 4 - 10 20 150 - 160 2 - 5<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
74<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Pantal 7 / Al Si7Mg0.3 T6 290 290 240 120 210 210 180 80 3 4 6 10 90 90 75 45<br />
Pantal 5 T6 280 260 200 120 250 240 170 80 1 2 3 7 90 90 80 45<br />
Al Si5Mg T6 280 260 200 120 250 240 170 80 0.5 1 2 7 90 90 80 45<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Pantal 7 / Al Si7Mg0.3 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />
Al Si7Mg0.6 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />
Al Si7Mg 680 - 750 680 - 750 1.0 - 1.2 0.7 - 1.1<br />
Pantal 5 690 - 760 690 - 760 1.1 - 1.2 0.8 - 1.1<br />
Al Si5Mg 690 - 760 690 - 760 1.1 - 1.2 0.8 - 1.1<br />
Al Si5Cu1Mg 690 - 760 690 - 760 1.0 - 1.2 0.8 - 1.1
Application notes<br />
These casting alloys are used in the<br />
motor vehicle industry (chassis components,<br />
motor car and lorry wheels), for<br />
components in the aerospace industry,<br />
for parts in mechanical engineering, for<br />
hydraulic elements, in the food industry,<br />
in shipbuilding, for fi ttings and apparatus<br />
as well as for fi re extinguisher compo-<br />
nents. Their use makes particular sense<br />
when the castings undergo age harden-<br />
ing. As a result of age hardening, these<br />
casting alloys are used in structures<br />
requiring high strength. In addition, the<br />
cast structure – particularly of primary<br />
casting alloys – still displays remarkable<br />
toughness and ductility. Resistance to<br />
chemical attack increases with purity<br />
and is very good in the case of primary<br />
casting alloys.<br />
Properties and processing<br />
Owing to the low silicon content, fl uidity<br />
is only moderate. <strong>Casting</strong>s with very<br />
thin walls can not, therefore, be cast in<br />
these alloys. This group of casting alloys<br />
containing around 7 % silicon is in<br />
some respects an exception. Looking<br />
at a micrograph, it can be seen that the<br />
proportion by area of light matrix (i.e.<br />
the aluminium-rich solid solution) and<br />
the proportion by area or eutectic silicon<br />
(i.e. the dotted grey areas) each amount<br />
to approx. 50 %. Like in all hypoeutectic<br />
AlSi casting alloys, solidifi cation takes<br />
place in phases. First of all, the dendritic<br />
network made up of aluminium-rich solid<br />
solution grows into the still liquid melt.<br />
The remaining highly-fl uid eutectic melt<br />
infi ltrates this sponge and locks the struc-<br />
ture together like in a two-component<br />
composite. By means of age-harden-<br />
ing, the aluminium-rich solid solution<br />
in particular is strengthened while the<br />
connecting eutectic remains ductile. In<br />
this way, the ideal microstructure occurs,<br />
giving the highest possible strength with<br />
still acceptable elongation. The variable<br />
magnesium content which ranges from<br />
0.20 to 0.70 % gives the user the possibility<br />
of adjusting the elongation of the<br />
castings to the particular requirements.<br />
With a low magnesium content of around<br />
0.25 %, relatively high elongation values<br />
can be achieved. Where greater hardness<br />
is required, casting alloys with a magnesium<br />
content of 0.70 % can be used.<br />
The group of casting alloys with approx.<br />
5 % silicon displays many sequences<br />
and properties which are similar to the<br />
7 per cent group. The solidifi cation range<br />
is slightly greater, fl uidity is slightly less.<br />
Due to the lower silicon content, the effect<br />
of the aluminium-rich solid solution<br />
dominates. The casting alloy variants<br />
with low copper content display the best<br />
possible corrosion-resistance behaviour<br />
of all aluminium-silicon casting alloys.<br />
<strong>Casting</strong>s made from these alloys fi nd<br />
application in such areas as the food<br />
industry, in domestic appliances or in<br />
parts for the food processing industry.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 75
Al SiCu casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Al Si8Cu3 min 7.5 2.0 0.15 0.15<br />
(0.05)<br />
max 9.5 0.7 3.5 0.65 0.55 0.35 1.2 0.25 0.15 0.20 0.05 0.25<br />
(0.8) (0.55) (0.25)<br />
46200 / 226<br />
Al Si9Cu3(Fe) min 8.0 0.6 2.0 0.15<br />
(0.05)<br />
max 11.0 1.1 4.0 0.55 0.55 0.15 0.55 1.2 0.35 0.15 0.20 0.05 0.25<br />
(1.3) (0.55) (0.25)<br />
46000 / 226D<br />
Al Si11Cu2(Fe) min 10.0 0.45 1.5<br />
max 12.0 1.0 2.5 0.55 0.30 0.15 0.45 1.7 0.25 0.15 0.20 0.05 0.25<br />
(1.1) (0.25)<br />
46100<br />
Al Si7Cu3Mg min 6.5 3.0 0.20 0.35<br />
(0.30)<br />
max 8.0 0.7 4.0 0.65 0.60 0.30 0.65 0.15 0.10 0.20 0.05 0.25<br />
(0.8) (0.60) (0.25)<br />
46300<br />
Al Si9Cu1Mg min 8.3 0.8 0.15 0.30<br />
(0.25)<br />
max 9.7 0.7 1.3 0.55 0.65 0.20 0.8 0.10 0.10 0.18 0.05 0.25<br />
(0.8) (0.65) (0.20)<br />
46400<br />
Al Si9Cu3(Fe)(Zn) min 8.0 0.6 2.0 0.15<br />
(0.05)<br />
max 11.0 1.2 4.0 0.55 0.55 0.15 0.55 3.0 0.35 0.15 0.20 0.05 0.25<br />
(1.3) (0.55) (0.25)<br />
46500 / 226/3<br />
Al Si7Cu2 min 6.0 1.5 0.15<br />
max 8.0 0.7 2.5 0.65 0.35 0.35 1.0 0.25 0.15 0.20 0.05 0.15<br />
(0.8) (0.25)<br />
46600<br />
Al Si6Cu4 min 5.0 3.0 0.20<br />
max 7.0 0.9 5.0 0.65 0.55 0.15 0.45 2.0 0.30 0.15 0.20 0.05 0.35<br />
(1.0) (0.25)<br />
45000 / 225<br />
Al Si5Cu3Mg min 4.5 2.6 0.20<br />
(0.15)<br />
max 6.0 0.50 3.6 0.55 0.45 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />
(0.60) (0.45) (0.25)<br />
45100<br />
Al Si5Cu3 min 4.5 2.6<br />
max 6.0 0.50 3.6 0.55 0.05 0.10 0.20 0.10 0.05 0.20 0.05 0.15<br />
(0.60) (0.25)<br />
45400<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
76<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
crack tightness state resistance anodisation<br />
stability<br />
Al Si8Cu3<br />
Al Si9Cu3(Fe)<br />
Al Si11Cu2(Fe)<br />
Al Si7Cu3Mg<br />
Al Si9Cu1Mg<br />
Al Si9Cu3(Fe)(Zn)<br />
Al Si7Cu2<br />
Al Si6Cu4<br />
Al Si5Cu3Mg<br />
Al Si5Cu3<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Al Si8Cu3 2.77 75,000 0.88 600 - 500 21 14 - 18 110 - 130<br />
Al Si9Cu3(Fe) 2.76 75,000 0.88 600 - 500 21 13 - 17 110 - 120<br />
Al Si11Cu2(Fe) 2.75 75,000 0.88 600 - 500 20 14 - 18 120 - 130<br />
Al Si7Cu3Mg 2.77 75,000 0.88 600 - 500 21 14 - 17 110 - 120<br />
Al Si9Cu1Mg 2.76 75,000 0.88 600 - 500 21 16 - 22 130 - 150<br />
Al Si9Cu3(Fe)(Zn) 2.76 75,000 0.88 600 - 500 21 13 - 17 110 - 120<br />
Al Si7Cu2 2.77 75,000 0.88 600 - 500 21 15 - 19 120 - 130<br />
Al Si6Cu4 2.80 74,000 0.88 630 - 500 22 14 - 17 110 - 120<br />
Al Si5Cu3Mg 2.79 74,000 0.88 630 - 500 22 16 - 19 130<br />
Al Si5Cu3 2.79 74,000 0.88 630 - 500 22 16 - 19 120 - 130<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 77
Al SiCu casting alloys<br />
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Al Si8Cu3 F Sand casting 150 90 1 60<br />
Al Si7Cu3Mg F Sand casting 180 100 1 80<br />
Al Si9Cu1Mg F Sand casting 135 90 1 60<br />
Al Si7Cu2 F Sand casting 150 90 1 60<br />
Al Si6Cu4 F Sand casting 150 90 1 60<br />
Al Si5Cu3Mg T4 Sand casting 140 70 1 60<br />
T6 Sand casting 230 200
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
Al Si5Cu3Mg T4 480 6 - 10 20 - 60 20 - 30 120<br />
T6 480 6 - 10 20 160 6 - 12<br />
Al Si5Cu3 T4 480 6 - 10 20 - 60 20 - 30 120<br />
Al Si9Cu1Mg T6 480 6 - 10 20 160 6 - 12<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Al Si8Cu3 F 170 160 120 80 100 90 50 25 1 1 2 5 75 65 45 35<br />
Al Si6Cu4 F 170 160 130 100 100 90 60 30 1 1 1.5 4 75 65 50 40<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Al Si8Cu3 680 - 750 680 - 750 630 - 680 1.0 - 1.2 0.6 - 1.0 0.4 - 0.6<br />
Al Si9Cu3(Fe) 630 - 680 0.4 - 0.7<br />
Al Si11Cu2(Fe) 630 - 680 0.4 - 0.8<br />
Al Si7Cu3Mg 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />
Al Si9Cu1Mg 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />
Al Si9Cu3(Fe)(Zn) 630 - 680 0.4 - 0.7<br />
Al Si7Cu2 680 - 750 680 - 750 1.0 - 1.2 0.6 - 1.0<br />
Al Si6Cu4 690 - 750 690 - 750 640 - 690 1.0 - 1.2 0.6 - 1.0 0.4 - 0.6<br />
Al Si5Cu3Mg 690 - 750 690 - 750 1.0 - 1.2 0.6 - 1.0<br />
Al Si5Cu3 690 - 750 690 - 750 1.0 - 1.2 0.6 - 1.0<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 79
Al SiCu casting alloys<br />
Application notes<br />
The alloys in this group are among the<br />
most commonly used aluminium casting<br />
alloys around. They are regarded<br />
as universal casting alloys for the most<br />
important casting processes and are<br />
widely used in pressure die casting in<br />
particular. They are easily cast and are<br />
suitable for parts which are subjected<br />
to relatively high loads. They are heat<br />
resistant and, as such, are used for engine<br />
components and cylinder heads.<br />
80<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Properties and processing<br />
<strong>Aluminium</strong> casting alloys with approx. 6<br />
to 8 % silicon, 3 to 4 % copper as well<br />
as 0.3 to 0.5 % magnesium have the<br />
optimum high-temperature strength.<br />
The cast structure hardens on its own<br />
within a week of casting. Afterwards, the<br />
mechanical machinability of the casting<br />
is very good. Age hardening is some-<br />
times possible. Treatment of the melt:<br />
In sand castings or thick-walled grav-<br />
ity die castings, sodium modifi cation is<br />
possible. Often, grain refi nement is also<br />
carried out. The casting and solidifi ca-<br />
tion behaviour usually poses no problem.<br />
The type of solidifi cation is hypoeutectic.<br />
During the transition from liquid to<br />
solid state, there is a wide solidifi cation<br />
range of a pasty-mushy character. Attention<br />
must be paid to controlling the<br />
solidifi cation and feeding of the metal.<br />
There is no distinctive tendency to hot<br />
cracking or draws.<br />
Heat treatment<br />
With castings made from these casting<br />
alloys, age hardening is possible when<br />
the Cu and Mg content is appropriate. It<br />
is, however, seldom carried out. In these<br />
castings, due to the Cu content in connection<br />
with the Mg and Zn content, an<br />
independent structural hardening occurs.<br />
This process is complete within about a<br />
week. Only then should the castings be<br />
fi nished followed by checking the mechanical<br />
properties. To achieve thermal<br />
and dimensional stability in parts suitable<br />
for high-pressure applications, e.g.<br />
crankcases, cylinder heads or pistons,<br />
solution annealing with artifi cial ageing<br />
beyond the peak aged condition is sug-<br />
gested (T7). This process is also known<br />
as “stabilising” or “overageing”.
AlMg casting alloys<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Al Mg3(H) min 2.7<br />
max 0.45 0.15 0.02 0.40 3.2 0.07 0.02 0.03 0.10 B/Be<br />
Al Mg3 min 2.7<br />
(2.5)<br />
max 0.45 0.40 0.03 0.45 3.5 0.10 0.15 0.05 0.15 B/Be<br />
(0.55) (0.55) (0.05) (3.5) (0.20)<br />
51100 / 242<br />
Al Mg3(Cu) min 2.5<br />
max 0.60 0.55 0.15 0.45 3.2 0.30 0.20 0.05 0.15 B/Be<br />
- / 241<br />
Al Mg3Si(H) min 0.9 2.7<br />
max 1.3 0.15 0.02 0.40 3.2 0.07 0.15 0.03 0.10 B/Be<br />
Al Mg5 min 4.8<br />
(4.5)<br />
max 0.35 0.45 0.05 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />
(0.55) (0.55) (0.10) (6.5) (0.20)<br />
51300 / 244<br />
Al Mg5(Si) min 4.8<br />
(4.5)<br />
max 1.3 0.45 0.03 0.45 6.5 0.10 0.15 0.05 0.15 B/Be<br />
(1.5) (0.55) (0.05) (6.5) (0.20)<br />
51400 / 245<br />
Al Mg9(H) min 1.7 0.2 8.5<br />
max 2.5 0.50 0.02 0.5 10.5 0.07 0.15 0.03 0.10 B/Be<br />
Al Mg9 min 0.45 8.5<br />
(8.0)<br />
max 2.5 0.9 0.08 0.55 10.5 0.10 0.25 0.10 0.10 0.15 0.05 0.15 B/Be<br />
(1.0) (0.10) (10.5) (0.20)<br />
51200 / 349<br />
Al Mg5Si2Mn min 1.8 0.4 5.0<br />
(4.7)<br />
max 2.6 0.20 0.03 0.8 6.0 0.07 0.20 0.05 0.15<br />
(0.25) (0.05) (6.0) (0.25)<br />
51500<br />
Al Si2MgTi min 1.6 0.30 0.50 0.07<br />
(0.45) (0.05)<br />
max 2.4 0.50 0.08 0.50 0.65 0.05 0.10 0.05 0.05 0.15 0.05 0.15<br />
(0.60) (0.10) (0.65) (0.20)<br />
41000<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 81
AlMg casting alloys<br />
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
Al Mg3(H)<br />
Al Mg3<br />
Al Mg3(Cu)<br />
Al Mg3Si(H)<br />
Al Mg5<br />
Al Mg5(Si)<br />
Al Mg9(H)/Fe<br />
Al Mg9<br />
Al Mg3(Zr)<br />
Al Mg5Si2Mn<br />
Al Si2MgTi<br />
crack<br />
stability<br />
tightness state resistance anodisation<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
Al Mg3(H) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />
Al Mg3 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />
Al Mg3(Cu) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />
Al Mg3Si(H) 2.68 70,000 0.93 650 - 600 24 17 - 22 130 - 140<br />
Al Mg5 2.66 69,000 0.94 630 - 550 24 15 - 21 110 - 130<br />
Al Mg5(Si) 2.66 69,000 0.94 630 - 550 24 15 - 21 110 - 140<br />
Al Mg9(H)/Fe 2.63 68,000 0.94 620 - 520 24 11 - 14 60 - 90<br />
Al Mg9 2.63 68,000 0.94 620 - 520 24 11 - 14 60 - 90<br />
Al Mg5Si2Mn 24 14 - 16 110 - 130<br />
Al Si2MgTi 23 19 - 25 140 - 160<br />
82<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Al Mg3(H) F Sand casting 140 70 5 50<br />
Al Mg3 F Sand casting 140 70 3 50<br />
Al Mg3(Cu) F Sand casting 140 70 2 50<br />
Al Mg3Si(H) F Sand casting 140 70 3 50<br />
Al Mg5 F Sand casting 16 90 3 55<br />
Al Si2MgTi F Sand casting 140 70 3 50<br />
T6 Sand casting 240 180 3 85<br />
Al Mg5(Si) F Sand casting 160 100 3 60<br />
Al Mg3(H) F Gravity die casting 150 70 5 50 60 - 90<br />
Al Mg3 F Gravity die casting 150 70 5 50 60 - 90<br />
Al Mg3(Cu) F Gravity die casting 150 70 3 50 60 - 90<br />
Al Mg3Si(H) F Gravity die casting 150 70 3 50 70 - 80<br />
T6 Gravity die casting 220 150 4 75 70 - 90<br />
Al Mg5 F Gravity die casting 180 100 4 60 60 - 90<br />
Al Si2MgTi F Gravity die casting 140 70 3 50<br />
T6 Gravity die casting 240 180 3 85<br />
Al Mg5(Si) F Gravity die casting 180 110 3 65 60 - 90<br />
T6 Gravity die casting 210 120 4 70 70 - 90<br />
Al Mg3 F 140 70 3 50<br />
Al Mg5 F 160 90 3 55<br />
Al Mg5(Si) F 180 110 3 65<br />
Al Mg9(H)/Fe F Pressure die casting 200 140 1 70 60 - 90<br />
Al Mg9 F Pressure die casting 200 130 1 70 60 - 90<br />
Al Si2MgTi F Gravity die casting 170 70 5 50<br />
Al Si2MgTi T6 Gravity die casting 260 180 5 85<br />
The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />
as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
Al Mg3Si(H) T6 545 - 555 4 - 10 20 160 - 170 8 - 10<br />
Al Mg5(Si) T6 540 - 550 4 - 10 20 160 - 170 8 - 10<br />
Al Si2MgTi T6 520 - 535 4 - 10 20 155 - 165 7 - 10<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 83
AlMg casting alloys<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
84<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Al Mg3Si(H) T6 220 210 120 80 150 140 60 30 4 4 5 14 75 45 40 20<br />
Al Mg5(Si) T6 210 200 170 140 120 110 100 70 4 4 5 8 70 70 60 30<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
Al Mg3(H) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg3 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg3(Cu) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg3Si(H) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg5 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg5(Si) 700 - 750 700 - 750 1.0 - 1.5 0.7 - 1.2<br />
Al Mg9(H)/Fe 680 - 640 0.5 - 0.7<br />
Al Mg9 680 - 640 0.5 - 0.7
Application notes<br />
We produce Al Mg3-type casting alloys<br />
for handles, window handles or security<br />
covers in decorative anodised quality.<br />
For structures in the chemical industry, in<br />
shipbuilding or the food industry, which<br />
demand the highest possible resistance<br />
to chemical attack and the infl uences of<br />
maritime climates, Al Mg5-type cast-<br />
ing alloys are suitable. Heat-resistant<br />
Al Mg5Si-type casting alloys are suit-<br />
able for high-temperature applications<br />
such as engine construction. In France,<br />
the Al Si2MgTi alloy is used for handles.<br />
For pressure die castings with good corrosion<br />
resistance, Al Mg9-type casting<br />
alloys are used.<br />
Properties and processing<br />
The highest requirements are placed on<br />
the quality of these casting alloys – particularly<br />
for decorative parts which are<br />
anodised. The manufacture of these casting<br />
alloys represents a special challenge<br />
for smelters requiring much experience,<br />
the best raw materials and quality-oriented<br />
work.<br />
Notes about surface treatment<br />
As a pre-treatment, the surfaces of cast-<br />
ings made from Al Mg3, for example, are<br />
mechanically machined as well as often<br />
being chemically polished. In the anodis-<br />
ing process (electrolytically-oxidised alu-<br />
minium), a protective oxide layer, which<br />
grows inwards and is essentially more<br />
impervious, thicker, more wear resistant<br />
and more homogeneous than a natural<br />
oxide skin, is produced on the surface<br />
of a casting. On pure aluminium and on<br />
aluminium alloys which are low in precipitates,<br />
these layers are transparent.<br />
All defects such as precipitated intermetallic<br />
phases, inclusions, heterogeneities,<br />
oxide fi lms, wrinkles and other<br />
casting defects lead to disturbances in<br />
the growth of the layer formation and,<br />
consequently, impairment of the decorative<br />
appearance.<br />
As the electro-chemically formed oxide<br />
layer is also the possible carrier of discolouring<br />
substances, defects near the<br />
surface can lead to the parts having a<br />
blemished, non-decorative appearance.<br />
Hollow spaces such as wrinkles or pores<br />
which have been cut can be taken up<br />
by the aqueous solutions or electrolyte<br />
during treatment. Even later, due to a<br />
secondary reaction, the remainder of this<br />
medium can lead to local decomposition<br />
of the anodised or colour coating.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 85
AlMg casting alloys<br />
The following alloying constituents can<br />
have an infl uence on the quality and ap-<br />
pearance of anodised layers:<br />
Silicon<br />
With Si concentrations higher than<br />
0.6 %, the precipitated silicon or Mg2Si<br />
impairs transparency. The anodised layer<br />
loses its brilliance.<br />
Iron, chromium and manganese<br />
The sum total of these elements can<br />
have a yellowing effect on the anodised<br />
layer. Limiting concentrations can not<br />
be established. Their infl uence depends<br />
on the phase composition and chemical<br />
back-dissolution during anodising.<br />
Copper<br />
It has no negative infl uence when found<br />
in normal concentrations. In the case of<br />
higher additions, the layer becomes softer<br />
and the composition rougher.<br />
Zinc<br />
This element has no infl uence on the<br />
anodising process or pigmentation.<br />
Titanium<br />
Concentrations of Ti above 0.02 % have<br />
a negative effect on the electrolytic colouration<br />
of aluminium castings.<br />
86<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Notes on casting techniques<br />
To avoid the tendency to hot tearing<br />
during casting and particularly for deco-<br />
rative reasons, the cast structure must<br />
be fi ne-grained. This fi ne-grained struc-<br />
ture can already be achieved during the<br />
production of the ingots by means of<br />
intensive grain refi nement. As a general<br />
rule, this grain refi nement does not have<br />
to be repeated during pouring. Should<br />
grain refi nement decrease as a result<br />
of prolonged holding, we recommend<br />
that it be freshened up using TiB grain<br />
refi ning wire. Melt cleaning or keeping<br />
the melt clean is important in order to<br />
produce a cast piece of good quality.<br />
We recommend that only those refi n-<br />
ing fl uxes which are specifi cally suited<br />
to AlMg casting alloys be used.<br />
Bale-out vessels with ceramic fi lter ele-<br />
ments have also proven their worth. Dur-<br />
ing casting, only the fi ltrate is baled out;<br />
the ladle remainder and subsequently<br />
charged metal enter into the outside<br />
areas of the melting or holding crucible.<br />
The casting operation requires particular<br />
care in order to produce a sound casting<br />
despite the constant risk of forming<br />
oxides and shrinkage. In doing this, the<br />
confi guration of the dies and the casting<br />
system play an important role. The<br />
type of solidifi cation is globular-mushy.<br />
A good feeding system is an essen-<br />
tial prerequisite for producing a dense<br />
structure.
<strong>Casting</strong> alloys for special applications<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) /<br />
VDS-No.<br />
Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
High-strength casting alloys<br />
Al Cu4Ti min 4.2 0.15<br />
(0.15)<br />
max 0.15 0.15 5.2 0.55 0.07 0.25 0.03 0.10<br />
(0.18) (0.19) (0.30)<br />
21100<br />
Al Cu4MgTI min 4.2 0.20 0.15<br />
(0.15) (0.15)<br />
max 0.15 0.30 5.0 0.10 0.35 0.05 0.10 0.05 0.05 0.25 0.03 0.10<br />
(0.20) (0.35) (0.35) (0.30)<br />
21000<br />
Al Cu4MnMg min 4.0 0.20 0.20<br />
(0.15)<br />
max 0.10 0.15 5.0 0.50 0.50 0.03 0.05 0.03 0.03 0.05 0.03 0.10<br />
(0.20) (0.50) (0.05) (0.10) (0.10)<br />
21200<br />
Al Cu4MgTiAg min 4.0 0.01 0.15 0.5 Ag<br />
0.4<br />
max 0.05 0.10 5.2 0.50 0.35 0.05 0.35 0.03 0.10 1.0<br />
Al Cu5NiCoSbZr min 4.5 0.1 1.3 0.15 ****<br />
max 0.20 0.30 5.2 0.3 0.10 1.7 0.10 0.30 0.05 0.15<br />
Piston casting alloys<br />
AlSi12CuNiMg min 10.5 0.8 0.9<br />
(0.8)<br />
0.7<br />
max 13.5 0.6 1.5 0.35 1.5 1.3 0.35 0.20 0.05 0.15 P<br />
(0.7) (1.5) (0.25)<br />
48000 / 260<br />
Al Si18CuNiMg min 17.0 0.8 0.8 0.8<br />
max 19.0 0.3 1.3 0.10 1.3 1.3 0.10 0.15 0.05 0.15 P<br />
****) Co 0.10-0.40 Sb 0.10-0.30 Zr 0.10-0.30<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
Continuation of the table on the next page.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 87
<strong>Casting</strong> alloys for special applications<br />
Chemical composition (all data in wt.-%)<br />
Alloy<br />
Numerical Other<br />
denomination 1) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti indiv. total Others<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg* min 16.0 4.0 0.5<br />
max 18.0 0.3 5.0 0.15 0.65 0.10 0.10 0.20 0.05 0.15 P<br />
Al Si17Cu4Mg** min 16.0 4.0 0.45<br />
(0.25)<br />
max 18.0 1.0 5.0 0.50 0.65 0.3 1.5 0.15 0.20 0.05 0.25<br />
(1.3) (0.65) (0.25)<br />
48100<br />
Self-hardening casting alloys<br />
Autodur min 8.5 0.3 9.5<br />
max 9.5 0.15 0.02 0.05 0.5 10.5 0.15 0.03 0.10<br />
Autodur (Fe)* min 8.5 0.3 9.5<br />
max 9.5 0.40 0.02 0.30 0.5 10.5 0.15 0.03 0.10<br />
Autodur (Fe)** min 7.5 0.25<br />
(0.20)<br />
9.0<br />
max 9.5 0.27 0.08 0.15 0.5 10.5 0.15 0.05 0.15<br />
(0.30) (0.10) (0.5)<br />
71100<br />
Rotor-<strong>Aluminium</strong><br />
Al 99.7E*** min<br />
max 0.07 0.20 0.01 0.005 0.02 0.004 0.04 Mn+Cr+ 0.03<br />
V+ Ti=<br />
0.02<br />
B 0.04<br />
Al 99.6E*** min<br />
max<br />
*) Non-standardised version<br />
0.10 0.30 0.01 0.007 0.02 0.005 0.04 Mn+Cr+ 0.03<br />
V+Ti=<br />
0.030<br />
B 0.04<br />
**) According to DIN EN 1706: 2010<br />
***) According to DIN EN 576<br />
Values in brackets are valid for castings according to DIN EN 1706: 2010<br />
1) According to DIN EN 1676: 2010<br />
88<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
<strong>Casting</strong> characteristics and other properties of castings<br />
Alloy Fluidity Thermal Pressure As-cast Ageability Corrosion Decorative Weldability Polishability<br />
crack tightness state resistance anodisation<br />
stability<br />
High-strength casting alloys<br />
Al Cu4Ti<br />
Al Cu4TiMgTi<br />
Al Cu4TiMgAg<br />
Al Cu5NiCoSbZr<br />
Piston casting alloys<br />
Al Si12CuNiMg<br />
Al Si18CuNiMg<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg 1)<br />
Al Si17Cu4Mg 2)<br />
Self-hardening casting alloys<br />
Autodur<br />
Autodur(Fe)<br />
Al Zn10Si8Mg 1)<br />
Rotor-<strong>Aluminium</strong><br />
Al 99.7E<br />
Al 99.6E<br />
1) Non-standardised version<br />
2) According to DIN EN 1706: 2010<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 89
<strong>Casting</strong> alloys for special applications<br />
Physical properties<br />
Alloy Density E-Modulus Thermal Solidifi cation Coeffi cient Electrical Thermal<br />
capacity temperature of thermal conductivity conductivity<br />
at 100 °C expansion<br />
g/cm3 MPa J/gK °C 10-6 /K<br />
293 K - 373 K<br />
MS/m W/(m . k)<br />
High-strength casting alloys<br />
Al Cu4Ti 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />
Al Cu4MgTi 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />
Al Cu4TiMgAg 2.79 72,000 0.91 640 - 550 23 16 - 23 120 - 150<br />
Al Cu5NiCoSbZr 2.84 76,000 0.91 650 - 550 23 18 - 24 120 - 155<br />
Piston casting alloys<br />
Al Si12CuNiMg 2.68 77,000 0.90 600 - 540 20 15 - 23 130 - 160<br />
Al Si18CuNiMg 2.68 81,000 0.90 680 - 520 19 14 - 18 115 - 140<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg 1) 2.73 81,000 0.89 650 - 510 19 14 - 18 115 - 130<br />
Al Si17Cu4Mg 2) 18 14 - 17 120 - 130<br />
Self-hardening casting alloys<br />
Autodur 2.85 75,000 0.86 640 - 550 21 15 - 20 115 - 150<br />
Autodur(Fe) 2.85 75,000 0.86 640 - 550 21 15 - 20 115 - 150<br />
Al Zn10Si8Mg 2) Rotor-<strong>Aluminium</strong><br />
21 17 - 20 120 - 130<br />
Al 99.7E 2.70 70,000 0.94 660 24 34 - 36 180 - 210<br />
Al 99.6E 2.70 70,000 0.94 660 24 32 - 34 180 - 210<br />
1) Non-standardised version<br />
2) According to DIN EN 1706: 2010<br />
90<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
High-strength casting alloys<br />
Al Cu4Ti T6 Sand casting 300 200 3 95<br />
T64 Sand casting 280 180 5 85<br />
Al Cu4TiMg T4 Sand casting 300 200 5 90<br />
Al Cu4TiMgAg T6 Sand casting 460 - 510 410 - 450 7 130 - 150<br />
T64 Sand casting 370 - 430 200 - 270 14 - 18 105 - 120<br />
Al Cu5NiCoSbZr T7 Sand casting 180 - 220 145 - 165 1 - 1.5 85 - 95 90 - 100<br />
T5 Sand casting 180 - 220 160 - 180 1 - 1.5 80 - 90 90 - 100<br />
Al Cu4Ti(H) T6 Gravity die casting 330 220 7 95 80 - 110<br />
T64 Gravity die casting 320 180 8 90<br />
Al Cu4MgTi T4 Gravity die casting 320 200 8 95 80 - 110<br />
Al Cu4TiMgAg T6 Gravity die casting 460 - 510 410 - 460 8 130 - 150 100 - 110<br />
Piston casting alloys<br />
Al Si12CuNiMg F Sand casting 140 130 ≤1 80<br />
T6 Sand casting 220 190 ≤1 90<br />
T5 Sand casting 160 140 ≤1 80<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg F Sand casting 140 130 ≤1 80<br />
T6 Sand casting 240 23 ≤1 110<br />
T5 Sand casting 230 220 ≤1 100<br />
Al Si18CuNiMg F Sand casting 140 130 ≤1 85<br />
T6 Sand casting 230 210 ≤1 100<br />
Piston casting alloys<br />
Al Si12CuNiMg F Gravity die casting 200 190 ≤1 90 80 - 110<br />
T6 Gravity die casting 280 240 ≤1 100<br />
T5 Gravity die casting 200 185 ≤1 90<br />
Al Si17Cu4Mg F Gravity die casting 180 170 ≤1 100 80 - 110<br />
T6 Gravity die casting 280 270 ≤1 130<br />
T5 Gravity die casting 165 160 ≤1 105<br />
Al Si18CuNiMg F Gravity die casting 180 170 ≤1 90 80 - 110<br />
T6 Gravity die casting 280 270 ≤1 120<br />
T5 Gravity die casting 180 170 ≤1 90<br />
Continuation of the table on the next page.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 91
<strong>Casting</strong> alloys for special applications<br />
Mechanical properties at room temperature +20 °C<br />
Alloy / Temper <strong>Casting</strong> method Tensile strength R Yield strength R Elongation A m p0,2 Brinell<br />
hardness HB<br />
Fatigue<br />
resistance<br />
MPa MPa % MPa<br />
min min min min<br />
Piston casting alloys<br />
Al Si12CuNiMg F Pressure die casting 240 140 ≤1 90<br />
T5 Pressure die casting 240 140 ≤1 90<br />
Al Si17Cu4Mg 1) F Pressure die casting 220 200 ≤1 100<br />
T5 Pressure die casting 230 210 ≤1 100<br />
Al Si18CuNiMg F Pressure die casting 210 180 ≤1 100<br />
Self-hardening casting alloys<br />
Autodur T1 Sand casting 210 190 ≤1 90<br />
Al Zn10Si8Mg T1 Sand casting 210 190 1 90<br />
Autodur T1 Gravity die casting 260 210 ≤1 100 80 - 100<br />
Autodur(Fe) T1 Pressure die casting 290 230 ≤1 100<br />
Rotor-<strong>Aluminium</strong><br />
Al 99.7E F Gravity die casting 60 20 30 14<br />
Al 99.6E F Gravity die casting 60 20 30 14<br />
Al 99.7E F Pressure die casting 80 20 10 15<br />
Al 99.6E<br />
1) Non-standardised version<br />
F Pressure die casting 80 20 10 15<br />
The values apply for separately-cast sample bars in sand and gravity die casting. Mechanical properties of pressure die casting samples are not binding and merely serve<br />
as information. The values representing vibration testing and/or fatigue strength apply for the best available casting process and merely serve as information.<br />
92<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
Heat treatment of aluminium castings<br />
Alloy / Temper Solution heat Annealing time Water Ageing Ageing time<br />
treatment temperature tempetarure<br />
temperature for quenching<br />
°C h °C °C h<br />
High-strength casting alloys<br />
Al Cu4TiMg T4 520 - 530 8 - 16 20 - 80 15 - 30 > 120<br />
Al Cu5NiCoSbZr T5 Air 345 - 355 8 - 10<br />
T7 535 - 545 10 - 15 20 - 80 210 - 220 12 - 16<br />
Al Cu4Ti T6 515 - 535 8 - 18 20 - 80 170 - 180 6 - 8<br />
Al Cu4TiMgAg T6 525 - 535 8 - 18 20 - 80 170 - 180 6 - 7<br />
Al Cu4Ti(H) T64 515 - 535 8 - 18 20 - 80 135 - 145 6 - 8<br />
Piston casting alloys<br />
Al Si12CuNiMg T5 Air quenching None 210 - 230 10 - 14<br />
T6 520 - 530 5 - 10 20 - 80 165 - 185 5 - 10<br />
Al Si18CuNiMg T5 Air quenching None 225 - 235 7 - 12<br />
T6 495 - 505 7 - 10 20 - 80 165 - 185 7 - 10<br />
T7<br />
Hyper eutectic casting alloys<br />
495 - 505 7 - 10 20 - 80 225 - 235 7 - 10<br />
Al Si17Cu4Mg 1) T5 Air quenching None 225 - 235 7 - 12<br />
T6 495 - 505 7 - 10 20 - 80 165 - 185 7 - 10<br />
T7 495 - 505 7 - 10 20 - 80 225 - 235 7 - 10<br />
1) Non-standardised version<br />
Mechanical properties of gravity die casting samples 1)<br />
Alloy / Temper Tensile strength R m Yield strength R p0,2 Elongation A Brinell hardness HB<br />
MPa MPa %<br />
-100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C -100°C +20°C +100°C +200°C<br />
Piston casting alloys<br />
Al Si12CuNiMg F 200 200 160 100 190 170 100 70 ≤ 1 1.5 2.5 3 90 85 60 35<br />
Al Si18CuNiMg F 180 180 160 120 170 150 100 80 ≤ 1 1 2 3 90 90 70 50<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg 2) F 180 180 160 120 170 150 100 80 ≤ 1 1 2 3 100 90 70 50<br />
1) Mechanical properties in minimum values / values after long-term maintenance of the respective temperature.<br />
2) Non-standardised version<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 93
<strong>Casting</strong> alloys for special applications<br />
Typical process parameters<br />
Alloy <strong>Casting</strong> temperature Contraction allowance<br />
Sand Gravity Pressure Sand Gravity Pressure<br />
casting die casting die casting casting die casting die casting<br />
°C °C °C % % %<br />
High-strength casting alloys<br />
Al Cu4Ti 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />
Al Cu4MgTi 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />
Al Cu4TiMgAg 690 - 750 690 - 750 1.1 - 1.5 0.8 - 1.2<br />
Al Cu5NiCoSbZr<br />
Piston casting alloys<br />
690 - 750 690 - 750 1.1 - 1.5<br />
Al Si12CuNiMg 670 - 740 670 - 740 620 - 660 1.0 - 1.2 0.5 - 1.0 0.4 - 0.6<br />
Al Si18CuNiMg 730 - 760 730 - 760 730 - 760 0.6 - 1.0 0.4 - 0.8 0.3 - 0.6<br />
Hyper eutectic casting alloys<br />
Al Si17Cu4Mg 1) 720 - 760 720 - 760 720 - 760 0.6 - 1.0 0.4 - 0.8 0.3 - 0.6<br />
Self-hardening casting alloys<br />
Autodur 740 - 690 740 - 690 1.0 - 1.2 0.8 - 1.0<br />
Autodur(Fe) 700 - 650 0.5 - 0.8<br />
Rotor-<strong>Aluminium</strong><br />
Al 99.7E 700 - 730 700 - 730 690 - 730 1.5 - 1.9 1.2 - 1.6 1.0 - 1.4<br />
Al 99.6E<br />
1) Non-standardised version<br />
700 - 730 700 - 730 690 - 730 1.5 - 1.9 1.2 - 1.6 1.0 - 1.4<br />
94<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
High-strength casting alloy<br />
Application notes<br />
These casting alloys are used for parts<br />
which – compared to all other aluminium<br />
casting alloys – require maximum strength.<br />
Where their reduced corrosion resistance<br />
represents no obstacles, these casting<br />
alloys can be used to manufacture high-<br />
strength components, for example, for<br />
the defence industry, aerospace, automotive,<br />
rail vehicles, mechanical engineering<br />
and the textile industry.<br />
Properties and processing<br />
The use of these relatively demanding<br />
casting alloys only makes sense if the<br />
component undergoes heat treatment.<br />
Only then, can the potential of these<br />
casting alloys be fully utilised. Following<br />
heat treatment, the castings still have excellent<br />
elongation as well as displaying<br />
the highest possible strength and hardness.<br />
This combination of high strength<br />
and good elongation values gives these<br />
casting alloys the highest possible Quality<br />
Index “Q”.<br />
By means of special heat treatment,<br />
hardness and elongation values can be<br />
adjusted within determined limits. There<br />
are other variants of these aluminium<br />
casting alloys, e.g. with nickel and cobalt<br />
being added to optimise their strength.<br />
Furthermore, there are also casting alloy<br />
types which contain silver so as to<br />
meet the maximum strength requirements.<br />
The corrosion resistance of cast<br />
pieces is reduced, however, due to the<br />
high copper content.<br />
The casting technique for these alloys is<br />
demanding. Most defects in the castings<br />
stem from “contamination” with silicon.<br />
The silicon content should be kept as<br />
low as possible and always lower than<br />
the iron content. An excess of silicon<br />
produces a low melting phase and increases<br />
the susceptibility to hot tearing<br />
during solidifi cation. Even slight impedi-<br />
ments to solidifi cation shrinkage can<br />
lead to structural separation. The most<br />
important requirement in the foundry is<br />
therefore cleanliness to prevent the takeup<br />
of silicon. Here are some recommendations:<br />
The melting crucible must not<br />
contain any remainder of silicon alloys.<br />
It also makes good sense to melt several<br />
batches of an alloy which is low in silicon<br />
in a new crucible to free the crucible<br />
material of silicon. There are users who,<br />
for this reason, use melting crucibles<br />
made of graphite or cast iron for these<br />
casting alloys. Return material should<br />
also be checked very strictly and stored<br />
separately; residual sand and other return<br />
material must be painstakingly removed<br />
from all sprues. From practical experience,<br />
some users recommend having a<br />
separate foundry department for these<br />
casting alloys. Melt cleaning and degassing<br />
can be carried out without any trouble<br />
using normal means. Melt treatment<br />
is restricted to grain refi nement which,<br />
among other things, slightly counteracts<br />
the susceptibility to hot cracking. Inten-<br />
sive grain refi nement is already performed<br />
by us so it does not usually need to be<br />
repeated in the foundry. The fl uidity of<br />
these casting alloys is comparable with<br />
other hypoeutectic AlSi casting alloys.<br />
The solidifi cation characteristics are best<br />
described as being globular-mushy. At<br />
approx. 90 K, the solidifi cation range is<br />
relatively high. Using a good fi lling system<br />
in conjunction with steered or controlled<br />
solidifi cation and suitable feeding, opti-<br />
mum structural qualities can be achieved<br />
with the sand and gravity die casting<br />
processes. Thanks to their good struc-<br />
tural quality and optimum heat treatment,<br />
these high-strength casting alloys are<br />
suitable for the manufacture of castings<br />
whose unmatched mechanical properties<br />
comply with maximum demands.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 95
High-strength casting alloy<br />
Heat treatment<br />
The heat treatment of castings is another<br />
important step in the production of quality<br />
cast parts. Exact temperature regulation<br />
of the annealing furnace, good tempera-<br />
ture distribution by means of circulating<br />
air and the correct positioning of the<br />
casting in the baskets, holders or racks<br />
are essential prerequisites for success.<br />
In solution annealing, the temperature<br />
increase should be moderate in order<br />
to allow enough time for temperature<br />
equalisation to take place in the castings<br />
and to avoid incipient fusion. The relief<br />
of casting strain, the removal of microstructural<br />
inhomogeneity and the diffusion<br />
of hardening constituents require<br />
longer periods of time. In these casting<br />
alloys, especially in thick-walled, slowsolidifying<br />
castings, stepped annealing<br />
96<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
is recommended. First of all, the cast<br />
pieces undergo preliminary annealing<br />
at 480 to 490 °C for between 4 and 8<br />
hours; they are then given a solution heat<br />
treatment at approx. 515 to 535 °C for a<br />
further 6 to 10 hours. To avoid distortion,<br />
quenching of the casting after annealing<br />
can be effected by means of a water<br />
shower followed by immersion in warm<br />
water at temperatures of up to 80 °C.<br />
Fully-annealed Al Cu4TiMg castings have<br />
a susceptibility to stress corrosion. This<br />
condition is therefore not standardised<br />
for this casting alloy. Such parts are only<br />
used in naturally-aged condition (T4).
Piston alloys<br />
Application notes<br />
These casting alloys are used for cast-<br />
ings with wear-resistant surfaces and for<br />
structures which have to possess good<br />
strength properties at high temperatures.<br />
The main applications comprise: pistons<br />
for combustion engines, crankcases<br />
without additional cylinder liners, pump<br />
casings, valve casings, valve slides, gear<br />
elements etc.<br />
Properties and processing<br />
The wear resistance of these casting al-<br />
loys is due to many hard, rectangular or<br />
polygonal primary silicon crystals which<br />
are embedded in the ductile base mate-<br />
rial and jut out of the surface of the track<br />
with an edge (while the neighbouring<br />
troughs act as reservoirs for lubricant).<br />
In addition, alloying elements such as<br />
Cu, Mg or Ni give these casting alloys<br />
remarkable high-temperature strength.<br />
In order to produce as many small and<br />
evenly-distributed silicon crystals as<br />
possible in the cast structure, phosphorous<br />
is added. This treatment is already<br />
carried out during production of the ingots<br />
in our secondary smelters and, as<br />
a rule, does not need to be repeated by<br />
the foundry. The fl uidity of these types<br />
of casting alloy is very good. In spite of<br />
this, silicon crystals forming in the melt<br />
at too low casting temperatures are to<br />
be avoided because of their abrasive effect.<br />
Additional information is provided<br />
in the section on “Selecting aluminium<br />
casting alloys”.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 97
Self-hardening aluminium-silicon-zinc<br />
casting alloys<br />
Application notes<br />
These casting alloys are used in the<br />
manufacture of models, foamed shapes,<br />
wearing parts or the bases of electric<br />
irons, for example. The use of these<br />
casting alloys is not recommended for<br />
machine parts which are subject to alternating<br />
or impact stress, are obliged<br />
to absorb bending and shearing stress<br />
or requiring a specifi c ductility.<br />
98<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong><br />
Properties and processing<br />
The fl uidity of Autodur in particular is very<br />
good. Solidifi cation behaviour is similar<br />
to that of other casting alloys containing<br />
approx. 9 % silicon. <strong>Alloys</strong> of this type<br />
are self-hardening, i.e. after casting, the<br />
castings are stored at room tempera-<br />
ture and within approx. 10 days reach<br />
their service properties. This hardening<br />
takes place as a result of precipitation<br />
of the complex Al ZnMg. The advantage<br />
of these casting alloys lies exclusively<br />
in their saving of heat treatment costs.<br />
There are, however, disadvantages in<br />
using these casting alloys. The following<br />
information should serve as a warning:<br />
Under unfavourable conditions whilst<br />
molten, the zinc content is reduced due<br />
to its high vapour pressure. The resistance<br />
of Autodur to corrosion is sharply<br />
reduced as a result of its high zinc content<br />
of around 10 %.<br />
In cases where the exposure to corrosion<br />
is great or where parts made from Autodur<br />
are assembled with other castings or<br />
parts made from other aluminium alloys,<br />
or indeed fi tted to steel parts, there is a<br />
strong tendency to contact corrosion.<br />
Compared with all other aluminium cast-<br />
ing alloys, castings made from these al-<br />
loys display the lowest high-temperature<br />
strength. (Precipitation treatment carried<br />
out at room temperature to increase hard-<br />
ness has no clearly defi nable effect.) Ex-<br />
perience shows that castings, even after<br />
many years, can fracture spontaneously<br />
under the slightest impact or shock load.<br />
Over time, the microstructure appears to<br />
be embrittled.
Rotor aluminium<br />
Application notes<br />
This pure aluminium is mostly used in<br />
pressure die casting and goes into the<br />
manufacture of rotors (short-circuit armatures)<br />
and stators for the electric motor<br />
sector. It can also be cast into other<br />
construction elements which require<br />
high electrical and thermal conductivity.<br />
Properties and processing<br />
There is a particular hurdle in the near<br />
net shape casting of pure aluminium,<br />
i.e. sensitivity to hot tearing. The most<br />
important prerequisite for keeping this<br />
problem within limits is to maintain the<br />
correct ratio between iron and silicon. The<br />
silicon content must be as low as possible<br />
and the iron content must always be at<br />
least double the silicon content. Molten<br />
pure aluminium readily absorbs silicon<br />
from any standing material it comes into<br />
contact with. This can easily lead to an<br />
“imbalanced ratio”. Cleanliness is therefore<br />
important during processing and it<br />
is also essential to check tools and the<br />
melting crucible. In extreme emergencies<br />
when silicon enrichment occurs, it<br />
helps to increase the iron content within<br />
the permitted tolerance range.<br />
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong> 99
<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
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Alloy Catalogue. Please do not hesitate<br />
to contact us if you require more<br />
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support at short notice, please refer<br />
to our contact details on the back<br />
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<strong>Aluminium</strong> <strong>Casting</strong> <strong>Alloys</strong>
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