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Theven<strong>in</strong> equivalents and impedances, or provide runtimemodels. Comb<strong>in</strong>ations are often used. Theven<strong>in</strong>models [11]-[13] assume the open-circuit voltage isconstant and use a series resistor and an RC parallelnetwork to track battery response to transient loads [8].An <strong>in</strong>crease <strong>in</strong> the number of parallel RC networks can<strong>in</strong>crease the accuracy of the predicted battery response.However, between the SOC and time-constantdependence on cycle number and temperature, predictionerrors <strong>for</strong> estimat<strong>in</strong>g run time and SOC tend to be high.Impedance-based models, like Theven<strong>in</strong> models, areaccurate only <strong>for</strong> a fixed SOC and temperature sett<strong>in</strong>g;hence their accuracy when predict<strong>in</strong>g dc response andbattery runtime is limited [14].Impedance spectroscopy can be used to fit acomplicated equivalent network to measured impedancespectra <strong>in</strong> order to validate the time constants found <strong>in</strong> theTheven<strong>in</strong> models. Runtime-based electrical models usecont<strong>in</strong>uous or discrete-time implementations to simulatebattery runtime and dc voltage response <strong>in</strong> SPICEcompatiblesimulations <strong>for</strong> constant current discharges.Inaccuracy <strong>in</strong>creases as the load currents vary [15].Comb<strong>in</strong>ations of these circuit models (<strong>in</strong> particular theTheven<strong>in</strong> and run-time models) can take advantage of thepositive attributes of each [8], [16], [17] such thataccurate SOC prediction, transient response, run-time,and temperature effects can be obta<strong>in</strong>ed.III. MODELThe model <strong>in</strong> [8] is capable of predict<strong>in</strong>g run time and I-V per<strong>for</strong>mance <strong>for</strong> portable electronics, but is notaccurate <strong>for</strong> the transient response to short-duration loads(less than 1 s). As a result, it does not predict accuratelythe SOC throughout drive cycles <strong>for</strong> HEV simulations.Fast time constants of Li-ion batteries have been shown<strong>in</strong> [13], [16], [17] and are necessary to determ<strong>in</strong>e thelosses with<strong>in</strong> a battery pack dur<strong>in</strong>g vehicle drive cycles.Accurate determ<strong>in</strong>ation of the discharge capacity, whichis a function of the discharge rate it (), temperaturef [ ( )] 2Tt , and cycle number f [ 3ncycle] [16], must also<strong>in</strong>clude a rate factor, f [()] it 1. The rate factor accounts<strong>for</strong> a decrease <strong>in</strong> capacity due to unwanted side reactions[8], [18] as the current <strong>in</strong>creases. The proposed model <strong>for</strong>predict<strong>in</strong>g SOC, term<strong>in</strong>al voltage, and power losses ofLi-ion, NiMH, and lead-acid batteries is shown <strong>in</strong> Figure1. It is governed by equations represent<strong>in</strong>g SOC and:V ter m<strong>in</strong> alSOC[(), i t T(), t ncycle,] t SOC<strong>in</strong>itial f1[()]i tt02 3term<strong>in</strong>al bat <strong>in</strong>t(1)f [ T( t)] f [ n ] i( t)dtcycleV Voc( SOC, T) i ( t) R ( SOC,T ) (2a)Rtransienti () t R ( , . )battransients m h1tR ( SOC) C ( SOC)s s ( R ( SOC) e (2b)s1tR ( SOC) C ( SOC)m mR ( SOC) e m1tR ( SOC) C ( SOC)h h R ( SOC) e )hEq. (1) <strong>for</strong> SOC can be modeled as the left circuit <strong>in</strong> Fig.1 when temperature and cycle number are given (e.g.short vehicle drive cycles at a low speed and grade).Here (1) is normalized to battery capacity, so V SOCliesbetween 0 and 100% and represents the SOC of thebattery [8]. I batteryis the battery load, modeled as acurrent source, while Rself dischargeand R cap _ fadeareparalleled to C capacityand represent normalized selfdischargeand battery capacity correction factor [16].V ter m<strong>in</strong> alrelates to the parameters shown <strong>in</strong> the rightcircuit of Figure 1, a multiple time-constant approach( sec, m<strong>in</strong>, and hour) <strong>for</strong> model<strong>in</strong>g the transientbehavior of the term<strong>in</strong>al voltage where each parameter isa function of the SOC [8]. This battery model has beenimplemented <strong>in</strong> the Simul<strong>in</strong>k environment.IV. DATAMeasurements of the circuit model parameters of Fig. 1<strong>for</strong> different batteries are found us<strong>in</strong>g a battery test<strong>in</strong>gapparatus which consists of data loggers, an electronicload, power supply, and other equipment. Eachcomponent is controlled via Labview 7.1, which is usedto program test sequences and analyze the recordedFigure 1 Proposed electrical battery model <strong>for</strong> use <strong>in</strong> HEV simulation at a constant temperature1337Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.


V OCmeasurements. The open circuit voltage ( ) andterm<strong>in</strong>al voltage versus SOC at room temperature wastested <strong>for</strong> five Panasonic CGR18650A 3.7 volt,2200mAh cyl<strong>in</strong>drical Li-ion batteries us<strong>in</strong>g a constantcurrent discharge profile at several different charge rates.Each of the parameters <strong>in</strong> the model of Fig. 1 is anonl<strong>in</strong>ear function of the various effects. For purposesof the model, each is represented as a polynomialfunction of SOC up to sixth order, with coefficientsgiven by:20 + 1* 2* ...Parameter a a SOC a SOC (3)The values <strong>in</strong> Table 1, when <strong>in</strong>serted <strong>in</strong>to (3), <strong>for</strong>mulatethe open-circuit voltage as the SOC changes. Theresult<strong>in</strong>g expressions can be used with<strong>in</strong> model<strong>in</strong>gprograms <strong>for</strong> efficient computation of the open-circuitvoltage.Estimates of m<strong>in</strong>(seconds/m<strong>in</strong>utes range), hour,and the correspond<strong>in</strong>g resistive and capacitive circuitparameters are shown <strong>in</strong> [8] and [13]. Both the secandm<strong>in</strong>time constants have been measured here us<strong>in</strong>gcharg<strong>in</strong>g and discharg<strong>in</strong>g currents at <strong>in</strong>tervals of 5%SOC. The series resistance and resistive and capacitivecomponents used to model secand m<strong>in</strong>are shown as afunction of SOC <strong>for</strong> discharg<strong>in</strong>g and charg<strong>in</strong>g currentswhen the values <strong>in</strong> Table 3 are <strong>in</strong>serted <strong>in</strong>to equation 3.(D) and (C) <strong>in</strong> Table 3 denote time constants measureddur<strong>in</strong>g discharg<strong>in</strong>g and charg<strong>in</strong>g current profiles,respectively. Determ<strong>in</strong>ation of the longest timeconstant, hour, and its resistive and capacitivecomponents is a time-consum<strong>in</strong>g process, hence thevalues found <strong>for</strong> discharg<strong>in</strong>g currents will be used tomodel hour<strong>for</strong> charg<strong>in</strong>g currents as well. The measuredResistance (ohms)0.10.080.060.040.02R seriesR secondsR m<strong>in</strong>utesR hours00.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1SOCFigure 2 Resistance values versusSOC <strong>for</strong> alldischarg<strong>in</strong>g current resistive circuit parametersvalues <strong>for</strong> Rseries , Rt_s, Rt_m, and R t_hdur<strong>in</strong>gdischarge currents are shown <strong>in</strong> Figure 2. Thefunctions of the resistive components versus SOC are<strong>in</strong>terpolated values between the measured data po<strong>in</strong>ts;model simulations may use either the <strong>in</strong>terpolated valuesbetween the measured po<strong>in</strong>ts (i.e. a look-up table) or thebest-fit polynomial functions from the data <strong>in</strong> Table 1.To check <strong>for</strong> time constants smaller than sec,which would be expected to have effects on dynamics ofvehicle power electronics, a buck converter switch<strong>in</strong>g at10 kHz was placed between a s<strong>in</strong>gle PanasonicCGR18650A cell and a load. Figure 3 depicts themeasured battery voltage, current, converter output, andswitch<strong>in</strong>g function <strong>for</strong> a load of 1.5 . The wave<strong>for</strong>mshows a voltage drop correspond<strong>in</strong>g to the switch<strong>in</strong>gfrequency, caused by the R seriescomponent of thebattery model. The voltage drops do not show evidenceof exponential behavior on this time scale. Hence timescales faster than secdo not impact the model.TABLE 1 CIRCUIT PARAMETER FUNCTION VALUES FOR THE OPEN-CIRCUIT VOLTAGE AND TIME CONSTANTSParameter a0a1a2a3a4a5a6Voc3 13.433 -90.038 284.33 -453.64 355.88 -108.97Rseries (D) 0.0482 0.144 -0.4577 0.4965 -0.1297 -0.049 0R (D) 0.1457 -1.0586 4.867 -10.131 9.5077 -3.3024 0t_sC (D) 0.7472 9.0675 -30.712 32.551 -7.358 -3.4621 0t_sR (D) 1.7423 -33.837 228.96 -712.75 1118.1 -859.2 -.12t_mC (D) 239.49 -14755 264236 -825025 947250 -371150 0t_mRseries (C) 0.051 0.2078 -1.1148 2.1656 -1.7766 0.5251 0R (C) 0.1134 0.9721 5.0929 -11.278 10.914 -3.845 0t_sC (C) 0.9936 14.521 -91.976 199 -179.67 -57.923 0t_sR (C) 1.6561 -35.02 246.62 -78559 1250.7 -970.92 292.72t_mC (C) 216.52 28308 -166348 431168 -491497 199631 0t_mR 0.1484 -1.1978 3.5946 -4.3618 1.8335 0 0t_hC 493923 3E+07 -1E+08 2E+08 -9E+07 0 0t_h1338Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.


Open Circuit Voltage (volts)4.243.83.63.43.2362.5 degrees Celcius27 degrees Celcius3 degrees CelciusFigure 3 <strong>Battery</strong> voltage (500 mV/ div), load current(500 mA/ div), converter dc output (5 V/div), and f switch(10 kHz), respectively.Determ<strong>in</strong>ation of the rate factor, f [()] it 1, is shown<strong>in</strong> Figure 3 <strong>for</strong> the 2C discharge rate. A reference curve<strong>for</strong> the 2C discharge rate is shown as the dotted l<strong>in</strong>e <strong>in</strong>Figure 4, and represents V OCwith <strong>in</strong>cluded battery<strong>in</strong>ternal voltage drops due to the <strong>in</strong>ternal resistance anddischarge rate, 2 Cref Voc R<strong>in</strong>t (i2 C iC/ 25).Variables a and b correspond to the SOC at which thevoltage reaches the m<strong>in</strong>imum (specified bymanufacturer) <strong>for</strong> 2Crefand 2Cdischarge curves,respectively. The ratio of b to a is equal to f [()] 1it <strong>for</strong>the correspond<strong>in</strong>g discharge current [16] and must betaken <strong>in</strong>to account to accurately predict SOC dur<strong>in</strong>gdrive cycles with large load transients. Tables 2 and 3<strong>in</strong>clude the measured values of the rate factors <strong>for</strong>discharg<strong>in</strong>g and charg<strong>in</strong>g currents, respectively, at ratesof C/25, C/5, C/2, and C.Trials of the Li-ion battery open circuit voltage at atemperature of 3°C, 27°C, and 62.5°C are shown <strong>in</strong>Figure 5. The temperature coefficient ( f [ Tt ( )])can2be found the same way the rate factor ( f [()] it 1 ) wasVoltage [volts]4.44.243.83.63.43.2C/25 DischargeCurve withresistive losses<strong>Battery</strong> Voltage Discharge CurvesC/25C/52CC/2 C30 0.2 0.4 0.6 0.8 1SOCbFigure 4 Determ<strong>in</strong>ation of rate factor, ( f [()] it 1 ), frommeasurements of voltage vs. SOC at different discharge rates.a2.810.80.6 0.4SOC0.2Figure 5 Open circuit voltage versus SOC at constant temperaturesof 3°C, 27°C and 62.5°C.found. At a higher temperature, there is very little alteration ofthe open-circuit voltage as compared to the room temperaturecase; a drop <strong>in</strong> open-circuit voltage can be seen <strong>for</strong> the 3°Ccase, and accurate results at low temperatures can be achievedby <strong>in</strong>clud<strong>in</strong>g a voltage drop equation with<strong>in</strong> the model. As thetemperature changes, a voltage versus SOC equation will beused to determ<strong>in</strong>e the voltage drop at a certa<strong>in</strong> temperature andSOC.TABLE 2 RATE FACTORS FOR VARIOUS DISCHARGE CURRENTSiload0.0808 0.4389 1.0886 2.1603f [ ] 1iload1 0.9946 0.96495 0.9232TABLE 3 RATE FACTORS FOR VARIOUS CHARGE CURRENTSiload-0.0838 -0.4386 -1.0988 -2.202f [ ] 1iload1 0.99324 0.9803 0.9665V. RESULTSTests have been per<strong>for</strong>med <strong>in</strong> Simul<strong>in</strong>k to ensureaccurate model per<strong>for</strong>mance dur<strong>in</strong>g driv<strong>in</strong>g schedules.Fig. 6 depicts the subcomponents of the vehiclesimulator, <strong>in</strong>clud<strong>in</strong>g new battery storage model, as wellas the flow of variables between each subcomponent.Simulations <strong>for</strong> four different HEV configurations,correspond<strong>in</strong>g to plug-<strong>in</strong> hybrids with Li-ion pack sizesof 25, 50, 75, and 100 kg were per<strong>for</strong>med on the FederalUrban Driv<strong>in</strong>g Schedule (FUDS). TCL PL-383562 850-mAh polymer Li-ion batteries were used <strong>in</strong> a series andparallel configuration to model the battery pack.Equations <strong>for</strong> all battery parameters (except sec) weresimulated with<strong>in</strong> the model and taken from [8]. Resultsof the four simulations are shown <strong>in</strong> Fig. 7. Fig. 7aconfirms that the model vehicle (see [3] <strong>for</strong> modeldetails) was able to follow the FUDS schedule dur<strong>in</strong>g thesimulations. The decrease <strong>in</strong> SOC (from an <strong>in</strong>itial SOCof 90%) is shown <strong>in</strong> Fig. 7b <strong>for</strong> each vehicle. The resultsare optimistic because [8] does not <strong>in</strong>clude a rate factor.Fig. 7c shows the resistive losses with<strong>in</strong> each01339Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.


Figure 6 High-level model of EV and PHEV simulators <strong>in</strong> the MATLAB environmentbattery pack, and Fig. 7d shows losses of all fourvehicles compared with the road power. The proposedbattery model successfully represents Li-ion batterieswith<strong>in</strong> a PHEV throughout driv<strong>in</strong>g schedules. Dataextracted from the results provide <strong>in</strong>sight on the effectsof various driv<strong>in</strong>g behaviors and the short-term transientson losses with<strong>in</strong> a battery pack. Simulations oncomputers with Intel’s Core 2 Duo processor takeapproximately 2 m<strong>in</strong> per 1 s of driv<strong>in</strong>g schedule; this isten times longer than driv<strong>in</strong>g simulation times with theprevious Theven<strong>in</strong>-based lead-acid battery model [2].This <strong>in</strong>crease is caused by algebraic loops <strong>in</strong>troduced<strong>in</strong>to the Simul<strong>in</strong>k model from differential equationsdescrib<strong>in</strong>g the three time constants.speed [m/s]30252015105a. Speed profileVEH 1FUDS 151000 500 1000 1500time [s]SOC [%]10.90.80.7VEH 1VEH 2VEH 3b. SOCVEH 40.60 200 400 600 800 1000 1200 1400Time [s]Power [W]15001000500c. <strong>Battery</strong> lossesVEH 1VEH 2VEH 3VEH 4Power [kW]x 10 4 d. VEH 1 road power and losses2Road Pow er<strong>Battery</strong> Losses1.510.500 20 40 60 80 100 120Time [s]00 20 40 60 80 100 120Time [s]Figure 7 (a-d) Simulation of VEH 1, 2, 3, and 4 on the FUDS with battery pack mass as the variable1340Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.


Results of verification of the Simul<strong>in</strong>k model aga<strong>in</strong>st theactual response of the tested Li-ion batteries are shown<strong>in</strong> Figures 8-11. Figure 8 depicts the simulated batteryterm<strong>in</strong>al voltage and measured voltage fluctuationsversus time when both the model and batteries are putthrough a simulated city/highway driv<strong>in</strong>g schedule. Afterthe 38 m<strong>in</strong>. driv<strong>in</strong>g schedule, the error between the actualand simulated term<strong>in</strong>al voltage is 0.199%. Thiscorrelates to a SOC deviation of the simulated model tothe actual of 1.00%. Figure 9 is the first 500 s of thesimulated driv<strong>in</strong>g schedule where the battery modelterm<strong>in</strong>al voltage tracks the measured LI-ion term<strong>in</strong>alvoltage. Discrepancies between the term<strong>in</strong>al voltage ofthe simulated and measured batteries near the upperpeaks of the voltage dur<strong>in</strong>g charg<strong>in</strong>g periods (simulatedregenerative break<strong>in</strong>g) are <strong>in</strong>conclusive. Although itwould appear that the resistive constants dur<strong>in</strong>g cyclecharg<strong>in</strong>g may be <strong>in</strong>accurate, the measured data po<strong>in</strong>tsoccur at approximately every second, while thesimulated driv<strong>in</strong>g schedule has the current charg<strong>in</strong>gpeaks at below one second time scales. Hence, themeasur<strong>in</strong>g apparatus is too slow to pick up all details offluctuations of the real battery dur<strong>in</strong>g the driv<strong>in</strong>gschedule. The lower term<strong>in</strong>al voltage peaks match upwell s<strong>in</strong>ce the driv<strong>in</strong>g schedule ma<strong>in</strong>ta<strong>in</strong>s the discharg<strong>in</strong>gcurrent peaks at a rate above one second.Figures 10 and 11 display the simulated road powerand measured Li-ion output power dur<strong>in</strong>g a trial us<strong>in</strong>gthe 22 m<strong>in</strong>.Federal Urban Driv<strong>in</strong>g Schedule. TheSimul<strong>in</strong>k Li-ion battery model, along with the measuredmodel circuit parameters shown previously was placed<strong>in</strong>to the University of Ill<strong>in</strong>ois <strong>Electric</strong> <strong>Vehicle</strong> Simulatorto run the driv<strong>in</strong>g schedule [3]. Figure 10 depicts theroad power divided by the number of batteries <strong>in</strong> theentire pack (<strong>in</strong> this case 6831 batteries) <strong>for</strong> both thesimulated and measured power <strong>in</strong>to and out of thebattery. Track<strong>in</strong>g of the measured battery output poweraga<strong>in</strong>st the Simul<strong>in</strong>k model road power per battery isaccurate. Figure 11 is a close-up of the output powerfrom 4000 to 5000 s of the FUDS and just as with Figure8 peak output power has a limited time fidelity.Term<strong>in</strong>al Voltage (Volts)4.254.24.154.14.05Simulated VoltageMeasured Voltage40 100 200 300 400 500Time (s)Figure 9 First 500 seconds of simulated and measured battery term<strong>in</strong>alvoltage versus time <strong>for</strong> city/highway driv<strong>in</strong>g scheduleThe simulated peak road power per battery occurs dur<strong>in</strong>g<strong>in</strong>tervals less than a second, hence the measurementapparatus will not pick up thosepeaks dur<strong>in</strong>g the measured Li-battery trial.VI. CONCLUSIONThe proposed battery model will accurately representlithium-ion battery behavior with<strong>in</strong> a dynamic HEVsimulator. Experimental parameters found from benchtests characterize Li-ion cells well at a constanttemperature and cycle life, and the effects on thoseparameters caused by fluctuat<strong>in</strong>g temperature can easilybe modeled <strong>in</strong> a dynamic simulator through open circuitvoltage characterization at a few temperatures. Simul<strong>in</strong>kmodels of battery pack/cell response to simulat<strong>in</strong>gdriv<strong>in</strong>g schedules have been verified us<strong>in</strong>g a hardware<strong>in</strong>-the-loopbattery cycle test<strong>in</strong>g apparatus; the simulatedSOC, term<strong>in</strong>al voltage and output power response to theFUDS and another <strong>for</strong>mulated city/highway driv<strong>in</strong>gschedule tracks the measured responses. Although boththe University of Ill<strong>in</strong>ois HEV simulator and the4.2514Term<strong>in</strong>al Voltage (Volts)4.24.154.14.0543.95Simulated VoltageMeasured VoltageRoad Power (Watts)121086420-2Simulated Road PowerMeasured Road Power3.9-43.850 500 1000 1500 2000 2500Time (s)Figure 8 Simulated and measured battery term<strong>in</strong>alvoltage versus time <strong>for</strong> city/highway driv<strong>in</strong>g schedule-60 200 400 600 800 1000 1200 1400Time (seconds)Figure 10 Simulated and measured road power perbattery versus time <strong>for</strong> FUDS1341Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.


Road Power (Watts)543210-1-2Simulated Road PowerMeasured Road Power-3800 850 900 950 1000Time (seconds)Figure 11 200 seconds of simulated and measured roadpower versus time <strong>for</strong> the FUDSproposed battery model are capable of provid<strong>in</strong>gsimulations which <strong>in</strong>clude self-discharge and batterycycl<strong>in</strong>gdegradation, the simulation times necessary toget results over these effects on various battery types arecurrently too long to validate the measured affects. Theaccurate response of the battery model now allows <strong>for</strong>extensive tests over the efficiency and losses with<strong>in</strong> thebattery pack dur<strong>in</strong>g various driv<strong>in</strong>g schedules andalteration <strong>in</strong> vehicle parameters.ACKNOWLEDGEMENTThis work was supported <strong>in</strong> part by the Power AffiliatesProgram at the University of Ill<strong>in</strong>ois.REFERENCES[1] K. B. Wipke, M. R. Cuddy, S. D. Burch, “ADVISOR 2.1: a userfriendlyadvanced powertra<strong>in</strong> simulation us<strong>in</strong>g a comb<strong>in</strong>ed backward/<strong>for</strong>wardapproach,” IEEE Trans. Vehicular Tech., vol. 48, no.6, pp. 1751-1761, November 1999.[2] D. L. Logue, P. T. Kre<strong>in</strong>, “<strong>Dynamic</strong> hybrid electric vehiclesimulation, version 1.0,” University of Ill<strong>in</strong>ois, Technical ReportUILUENG-98-0409, December 1998.[3] M. Amrhe<strong>in</strong>, P. T. Kre<strong>in</strong>, “<strong>Dynamic</strong> simulation <strong>for</strong> analysis ofhybrid electric vehicle system and subsystem <strong>in</strong>teractions, <strong>in</strong>clud<strong>in</strong>gpower electronics,” IEEE Trans. Vehicular Tech., vol. 54, no. 3, pp.825-836, May 2005.[4] D. W. Dennis, V. S. Battaglia, and A. Belanger, “Electrochemicalmodel<strong>in</strong>g of lithium polymer batteries,” J. Power Sources, vol. 110,no. 2, pp. 310-320, 2002.[5] L. Song and J. W. 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Rakhmatov, “<strong>Battery</strong> model<strong>in</strong>g <strong>for</strong>1342Authorized licensed use limited to: GOVERNMENT COLLEGE OF TECHNOLOGY. Downloaded on December 31, 2009 at 04:42 from IEEE Xplore. Restrictions apply.

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