Introduction to d-Block Chemistry - Wits Structural Chemistry

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Introduction to d-Block ChemistryCoordination Compounds:Types of Ligands and Complexes:The list of potential ligands is a long one.• Ligand must possess an unshared pair of electrons• This includes virtually all anions (e.g. F - , CN - , SCN - , NO 2- , etc)• A large number of neutral molecules (e.g. H 2 O, NH 3 , CO, amines,sulfides, ethers ...)• And even some cations (e.g. H 2 N-NHNH 3+ )
Introduction to d-Block ChemistryCoordination Compounds:Types of Ligands and Complexes:Ligands can be classified as monodentate, or polydentatePolydentate ligands can be bidentate, tridentate, etc.monodentatepolydentateNNNbidentateH 2 NNHtridentateAmbidentate ligands have more than one different potential donor atome.g. Thiocyanate (SCN - )z+Mz+MS C NN C SNH 2
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Introduction to d-Block Chemistry - Wits Structural Chemistry

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