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Introduction to d-Block Chemistry - Wits Structural Chemistry

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<strong>Introduction</strong> <strong>to</strong> d-<strong>Block</strong> <strong>Chemistry</strong>IsomerismGeometrical IsomerismExampleThe two square planar isomers of[PtBrCl(PMe 3 ) 2 ] give the following 31 P NMRspectra. Which is which?Br PMe 3PtBrClPtPtMe 3 PClMe 3 P PMe 3

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