Introduction to d-Block Chemistry - Wits Structural Chemistry
Introduction to d-Block Chemistry - Wits Structural Chemistry
Introduction to d-Block Chemistry - Wits Structural Chemistry
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<strong>Introduction</strong> <strong>to</strong> d-<strong>Block</strong> <strong>Chemistry</strong>IsomerismLinkage Isomerism• Same ligand that can link through different a<strong>to</strong>ms.• Eg. CN - , SCN - , NO-2• In the formula, the link-a<strong>to</strong>m is usually underlined, e.g. [Pt(SCN) 4 ] 2-• One can often predict the more stable linkage isomer on the basis of the hardsoftprinciple.
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