Introduction to d-Block Chemistry - Wits Structural Chemistry
Introduction to d-Block Chemistry - Wits Structural Chemistry
Introduction to d-Block Chemistry - Wits Structural Chemistry
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<strong>Introduction</strong> <strong>to</strong> d-<strong>Block</strong> <strong>Chemistry</strong>IsomerismGeometrical IsomerismOctahedral complexes:• For a complex having the general formula [MA 3B 3 3] there are two ways ofarranging the ligands, either facial (fac) or meridional (mer).• fac carries 3 A ligands in an equilateral triangle on one face of the octahedron,and 3 B ligands on the other face:fac-[MA 3 B 3 ]
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