MICROWAVE SPECTRAL TABLES Diatomic Molecules

ScienceDocs.DBS MONOGRAPH 70—VOLUME IMICROWAVE SPECTRAL TABLESDiatomic MoleculesU.S. DEFMHENT OF COMM,NATIONAL BUREAU OF STANDARDS

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UNITED STATES DEPARTMENT OF COMMERCE • Luther H. Hodges, SecretaryNATIONAL BUREAU OF STANDARDS • A. V. Astin, DirectorMICROWAVE SPECTRAL TABLESDiatomic MoleculesPaul F. Wacker, Masataka Mizushima, Jean D. Peterson, and Joe R. BallardNational Bureau of Standards Monograph 70—Volume IIssued December 1, 1964For sale by the Superintendent of Documents, U.S. Government Printing OfficeWashington, B.C., 20402 - Price $ 2

ContentsPage1. Introduction __________________________________________________ in2. Description of tables_____ ___-_____-___-______-____..____________ iv3* Symbols used in tabulations.____________________^_____,____,__^ v4. Computation of intensities._____________________________________ xTable 1. Molecules listed alphabetically.__________________________ 1Table 2. Casimir's function and hyperfine intensities.____________ 87Bibliography. ___ _ _____________________________-____________„_ 123Library of Congress Catalog Card Number: 63-62235ii

Microwave Spectral TablesVolume I: Diatomic MoleculesPaul F. Wacker, Masataka Mizushima, Jean D. Petersen, and Joe R. BallardFor about 1500 spectral lines of diatomic molecules observedby coherent radiation techniques, measured frequencies, assignedmolecular species, assigned quantum numbers, and newly computedintensities are given. Molecular data, such as rotational constants,dipole moments, and various coupling constants, determined by suchtechniques,are also tabulated, as are other molecular constants usedin the intensity computations. References are given for all includeddata. For determination of hyper fine spectra, both Casimir's functionand the intensity splitting factor are given for both integral and halfintegralquantum numbers J and I, permitting application to additionalmolecules with unclosed electronic shells and with hyperfine splittingproduced by more than one nucleus.1. IntroductionThese tables represent the first volume of a revision of Kisliuk and Townes ' "Molecular Microwave Spectra Tables, " published as National Bureau of Standards Circular 518 [1] .The spectral lines reported are not restricted to those in a given frequency range or to thoseobserved by conventional microwave spectroscopy, but rather include those observed by anycoherent radiation technique, including molecular beam techniques. However, the lines reported have been restricted to those measured in or extrapolated to negligible external fieldsand to those applying to relatively isolated molecules and radicals. Nevertheless, molecularparameters describing field-dependent data are included, particularly for paramagnetic gasesand when given in articles reporting field-independent data.Physics Abstracts, Chemical Abstracts, Physical Review, Journal of Chemical Physics, and Reviews of Modern Physics were searched through the end of I960. All the originalsources so located plus various unpublished reports have been studied. The authors would liketo receive information regarding any errors, misinterpretations, and omissions (of data notlikely to be listed in abstract journals dated after I960), as well as reports on further unpublished work, addressed to the Radio Standards Laboratory, National Bureau of Standards,Boulder, Colorado.^fcNumbers in brackets indicate references listed on page XVII.Ill

In order to reduce transcription errors, all tabular material (except for the bibliography, molecular constants not used for computations, and a few exceptional cases) wasprinted automatically as computer output and reproduced photographically. The computer input was punched on cards and the cards verified by a second operator. Such verification isbetter than proofreading, since two independent operations are compared electrically.2. Description of TablesFor each spectral line, there are given the measured frequency and its uncertainty,the assigned "isotopic molecular species, " the assigned initial and final quantum numbers, areference, and intensities computed for 300° and 195° Kelvin. ("Isotopic molecular species"is used here to indicate a molecular species in which the isotopic species of each individualatom is specified. ) In table 1, the lines are listed alphabetically according to the International Union of Chemistry name of the compound [10] and cross-indexed according to all othercommonly used names. The listing is subdivided first according to the isotopic molecularspecies and then according to the major quantum numbers for the transitions. Within thesesubdivisions, hyperfine components and incompletely identified transitions are listed according to frequency. For each molecule, a table of molecular constants, such as line widths,rotational constants, dipole moments, and various coupling constants, is also given. Theseconstants comprise essentially all those reported in articles which include line frequencies*as well as all other constants used for the computations. The latter constants are commonlytaken from standard tabulations and, if necessary, adjusted with simple relations (see Computation of Intensities). The internuclear distances are given diagrammatic ally. Thedistance given is r , the distance to the minimum in the potential energy curve.Ordinarily, the frequencies and uncertainties given are those reported in the sourcedeemed most accurate. Because the uncertainties reported in so many of the papers are notprecisely defined, no attempt was made to reduce them to a common basis. The reader interested in precise estimates of both random and consistent error is referred to the originalpapers or to the authors themselves. If two or more sources seemed to be of comparable accuracy, an average of the frequencies was used. In general, the molecular constants aregiven as reported in the original article; it is not implied that the values are accurate to oneunit in the last reported digit. If insufficient data were available for computation of intensities,unknown factors (see Computation of Intensities) were put equal to unity and the values markedR for relative. No intensity was computed for ''forbidden" lines. For each group of unresolved lines, both the individual intensities and their sums are given. Being direct computer- 8output, the intensities are written, e.g. , in the form 41. E-08, meaning 41.xlOIV

Casimir's function and the hyperfine intensity splitting factor are given in table 2 (seeintroduction to table 2 and Computation of Intensities) [2: pages 151 and 499] . All the angular momenta are given for half-integral as well as integral values, permitting application toadditional molecules with unclosed (electronic) shells or, for the intensity, to additionalmolecules with hyperfine splitting caused by more than one nucleus.The four-digit numbers refer to the bibliography at the end of this volume. Apart fromthe numbers above 1725, the reference numbers are arranged according to year and thenalphabetically according to the first author. When constants obtained from non-microwavesources have been used in fitting parameters to microwave data, reference is commonlymade to the microwave paper rather than to the original source. The bibliography includesreferences to articles of possible interest, even to those giving no data suitable for inclusionin these tables.The spectral lines will be ordered according to frequency only in a final volume,along with lines from non-diatomic molecules.3. Symbols Used in TabulationsThe sources of some of the molecular constant data are indicated by small lettersimmediately following the individual values. The significances are as follows:Line width field:Dipole moment field:a rough average of values for many linesm microwave spectroscopic measurementc computed by assuming polarizable ions (for alkali halides)i computed from intensity and line widthm microwave Stark or electric resonance beam measurementp computed from polarization dataRotational constant field:c computed from another isotopic species assuming inverse proportionality to the reduced massm microwave measurement for the given isotopic speciesv computed from measured frequency neglecting centrifugal stretchingThe notations [2: equations (1-50)], [4: page 201], etc. , indicate equation (1-50) ofreference 2, page 201 of reference 4, etc. Most of the references given here are tostandard sources where both a general background and references to the original literaturemay be found.

y value listed is Dunham's Y rather than the constant BVibrational frequency field:c computed from another isotopic species assuming inverse proportionality to the square root of the reduced mass{ ] measurement not attributed to a specific isotopic molecular species( ) from simple theoretical relations and measured quantities[ 1 from extrapolation of related dataThe following spectroscopic symbols are used in the tabulations. In some cases, agiven symbol has become relatively standard for more than one quantity. Rather than introduce new symbols in the tabulations, the literature designations are used together with distinguishing words for the less common usages.', " used to distinguish upper (') and lower (") energy levels in atransition+ , - used as subscripts on integers denoting oxygen lines. The integerdenotes the unchanging quantum number N, while the subscripts +and - indicate that the J value changes from N+l to N and N-lto N, respectively, in absorption.+, - as right superscripts to an electronic state designation, indicatethat the electronic wave function is symmetric and antisymmetric,respectively, with respect to reflection in a plane containing theinternuclear axis [5: page 217]. For NO or OH, designations areequivalent to Mulliken's c and d designations.a, \ coefficients in the power series for the rotational constantB V = B - a(v + 1/2) + Y(V + 1/2) 2 +.....a, p, \ the i- uncoupling constantsandIIrespectively, where L, t is the component of electronic orbitalangular momentum about an axis perpendicular to the internuclearVI

axis, II indicates the II electronic ground state, £ indicates agiven S electronic state, E indicates the energy difference between the given S state and the ground state, and the summationis taken over all Z states (reference [12]; reference [13], whichintroduces the a, p, \ notation, omits the factor 4 from thedefinitions of p and y» Yet uses the values of [12] for them).a ,P A-doubling constants; a = p + 2q and p = q.P xr r •** •*' r •**•Xmultiplet splitting constant A/BX.^, \See textual material on oxygen.IJLelectric dipole moment|JL , JJL See textual material on oxygen.vAv/pmeasured line frequencyhalf-width (of spectral line) at half-maximum intensity per unitpressure.SIIX^ (0)GOstate for which the axial component of the electronic orbitalangular momentum is zero, A right subscript g indicates symmetry of the electronic wave function with respect to inversion inthe center of the molecule. For other auxiliary notations, see Hand + , - .state for which the axial component of the electronic orbitalangular momentum is h/27T. The left superscript is 2S+1 whereSh/2?T is the resultant electronic spin angular momentum and thenumerical right subscript is 2;r /h times the sum of the axialcomponents of the electronic orbital and spin angular momenta.the angle between the internuclear axis and the radius vector fromthe nucleus to the electron.density of the unpaired electrons at the given nucleus.fundamental vibrational frequencyoo x coefficient in the power series expansion for the vibrational energyh [o>e(v+l/2) - coe Xe (v+l/2) Z + . . ] .Amultiplet splitting constant, namely the coefficient in the expression hA S • A for the coupling energy between the resultantelectronic spin and the axial component of the orbital angularmomentum [2; page 186],VII

a,b,c,d, magnetic hyperfine coupling constants, namely [11]a . l.. „ . -U + 16c = ,v " , lnd d =r j yavwhere U = |i p. /I, JJL is the absolute value of the Bohr magneton,|JL is the nuclear magnetic moment, and I is the nuclear spin in .units of h/2?T.B, D coefficients in the power series expansion for the rotational energy2 2h[BJ{J+l) - DJ (J+l) + ... ] [2: page 1-36], A numerical subscriptgenerally indicates the vibrational quantum number v, but for oxygen see the textual material relating to this compound. For OH2and NO, B and B indicate the B values for the lowest II and2 P S2 electronic states, respectively. For small spin uncoupling, theeffective B value includes electronic effects [textual material onOH; 2: page 186; 12: page 1728].C coefficient in the expression hC I- J for the magnetic hyperfinecoupling energy of a diatomic molecule [2: equation 8-40]. Thenucleus involved is indicated in parentheses,e as a subscript, indicates the minimum in the vibrational potentialcurve.eQq quadrupole coupling constant. With Feld's normalization used here,the quadrupolar energy for a linear molecule is -heQq f(I, J, F)where f(I, J, F) is Casimir's function [table 2; 2: pages 150, 151,499]. The mean field gradient q is taken along the internuclearaxis. The nucleus involved is indicated in parentheses."> /O ' xe Q(—— 3 ^ \ quadrupole coupling constant with the field gradient taken perpendicular to the internuclear axis. Occurs for OH and NO.F, F quantum number such that Fh/27T is the total resultant angularmomentum including nuclear spin. The quantum number F excludes nuclear spins except that for the nucleus most closelycoupled to the non-nuclear angular momentum.g,g, Zeeman splitting factor. For a paramagnetic molecule gj is defined by the expression for the Zeeman energy - u g J- H, where« U JVIII

Z = the sum of the Boltzmann factors, exp(-E/kT), over the set P ofinitial states of the hypothetical molecule. Constant terms areregularly omitted from the (relative) energy E. Note that the nuclear spin factors (21 +1) do not occur, since the definition is inmterms of the hypothetical molecule. Z is approximated as the product Z Z , where Z depends only on the vibrational quantumnumbers and Z depends only upon the rotational (and sometimeselectronic) quantum numbers.Q = the sum of Z's over all atates of the hypothetical molecule. Thefractional number f of hypothetical molecules in the initial setP of states is Z/Q. Like Z, Q is approximated as the product ofa vibrational factor Q and rotational-electronic factor Q .v rH = the hyperfine structure intensity splitting-factor. This factor contains both dipole moment and population factors such that the product of a given H with the intensity for the hypothetical moleculeis equal to the intensity of a given hyperfine component of the givenspectral line. Values for specific cases are discussed on pagesXIV and XV,The absorption coefficient may now be written asmax= G{jj.2s/Q Q }Z Z VHv 2 , (2)Ll^ r vj r v o 'where G depends only upon the line width and temperature, the factor in brackets for ourpurpose depends only upon the molecular species and temperature, and the remaining factors depend at least upon the line involved.^3/4For computational purposes, it is assumed the Av is proportional to pT [2:pages 24, 368-369; 4: page 196] and we write(Av/p) for the value of Av/p at 300°K.Thus-3/4Av/p = (Av/p) 30Q (T/300) ' .Then for an ideal gasN/Av = N/[p(Av/p) 30() (T/300)" 374] = 273. !6sLo /[760T (Av/p)^ (T/300)" 3/4 ] .In case no value for Av is known, 25 Mc/rnmHg = (Av/p)« nn , is used as a standard value,yielding a standard G, G , in equation (2). When an experimental value is known for Av,XII

G'/(Av/p) replaces G in the latter equation, yieldingV = G'{;j.2s/Q Q (Av/p)-..} Z Z VHv 2 ,max l r v r 300 J r v o(3)where G 1 = G (Av/p) . To simplify computations, only one line width parameter wasstd 30Ustclused for each molecule; the value used is given in the appropriate molecular constant table.1 RExpressing the dipole moment in Debye units (10* esu) and the frequency in megacycles, the following values were obtained for the G's:T = 300°K T = 195°Kstd2.730 X 10 -11 4.677 X 10 -116.825 X 10 -10 1. 169 X 10 -9The quotient s of the number of molecules belonging to a given isotopic molecularspecies divided by the total number of molecules, regardless of isotopic species, is givenbys =where (cr/cr.) is two for the heteronuclear oxygen molecules but unity for the other isotopicmolecular species of this tabulation [7: introduction]. The symbols a and a represent,for the first and second atoms respectively, the natural terrestial ratio of the abundance ofthe given nuclide to the total abundance of all the nuclides with the given atomic number.The abundances are taken from the American Institute of Physics Handbook [6: pages 8-5 to8-18], Rather than report zero intensity for the tritium halides, the abundance of tritiumwas taken as 100 percent and the resulting intensities marked R for relative. Equation (4)neglects the slight differences in chemical stability of the isotopic molecular species.For the vibrational partition function, the harmonic oscillator approximationQ =!/[!- exp( -cot)] (5)-1was used, where u> is the fundamental vibrational frequency in cm . (For the gallium andXIII

(11)J««-J transition,F^ ; i.j.r)s -' J+FH-Itz"Jtr- I^'i'J-r-tI'' J- F- 1- 1 > UB . (12), J. F; 1. J. F) . ZF(F+1) BandH(I. J.F-l; I. J.F) = -(J+F+I+lKJ+F-IHJ-F+mKJ-F-I) ^ § (M)where co and cx> are normalization constants such that y y H(I, J',F'; I, J", F") equals9unity. Substituting the expressions for the sums given in Condon and Shortley (equations 2 6)shows thatand4(2JU)(2I-fl)(J+l)(2J+3)toA = 14(2J+l)(2I+l)(J-fl)Jco_ = 1JD(Attention is called to a typographical error in Townes and Schawlow's expression for thetransition J, F-*-J-l,F (2: page 152). Since these expressions assume only that the J's andF's are good quantum numbers and that the hyperfine splittings are small compared to kT,they apply for the molecules with unclosed shells as well as with closed shells. These H f sare given in table 2 of this volume for both integral and half-integral values of J (see nextparagraph).For hyperfine splitting associated with two nuclei, the following treatment was used.If the hyperfine splittings are small compared to kT and if the spin I of the first nucleuscombines with J to form a good (angular momentum) quantum number F , the previous Hfactors can be applied with I , J, F substituted for I, J, F, then again with I ? , F , F substituted for I, J, F. In this tabulation, two nuclei contribute to hyperfine splitting only for closedshell molecules; in this case the preceding quantum number condition is obeyed provided thequadrupole coupling constant eQq for I is large in absolute value compared to that for I(and both large compared to the small magnetic couplings) [2: page 172], Rather than carryingout the tedious computations for intermediate coupling [2: page 172] or reporting no hyperfineXV

intensities in some cases, the preceding successive factors were used in all cases and a footnote concerning accuracy added when the couplings were not widely different. In any event,for fixed initial and final J's and F's, the sums over all possible initial and final F 's areaccurate according to the principle of spectroscopic stability [9: pages 137-142, equation 42],the J's, I's, and F's being good quantum numbers.All computations were carried out on a digital computer so that there are few, if any,random computational errors. There are inaccuracies due to the approximations mentionedand due to inaccurate molecular constants. All constants used in the computations are given inthe molecular constant tables, so that correction can be made for improvement in such constants. Further, the ratios of intensities are often better than the intensities themselves.The tables of Casimir ! s function and the hyperfine splitting factors are described indetail immediately preceding the tabular material itself.We wish to acknowledge the assistance of Dr. Robert L. Wallis, Thomas E. Kilpatrick,Marlene R. Pratto, and William L. Longley, Jr.XVI

BrCl Bromine monochloride 2.. IsotopicMolecularSpeciesBr79Cl35Br 79 Cl 37Br81Cl 35Br81Cl 37Av/pMe/mmHDebye0.57B eMe/sec4570.92 m4499.84 m4536.14 m4365.01 mu ocm'1[43ol[43 0][430][430]a eMe/ sec23.2221.9422.9521.67eqQ(Br)Me/sec+876.8+876.8+732.9+732.9eqQ(Cl)Me/ sec-103.6- 81.14-103.6- 81.14References036303639901036303630363IsotopicMolecularSpeciesRotation1 MJ *- JVibrationV¥lF fFlitFVMe/ secIntensity cm300° 195°RefBr79 Cl35li-Oground1/223/238899.5012.F-09 36.fc-0903635/233/239063.7752.E-10 15.E-095/223/239074.9137.E-11 li.fc-105/243/239080.7333.E-09 96.t-095/213/209088.6156.E-10 16.fc-093/233/239291.6122.E-09 63.E-093/223/239307,965

IsotopicMolecularSpecies-Br79F19Rotationt nJ *-J1«-0VibrationV1'1 F"1/2nFlnF3/2VMe/ sec20828.9Intensity cm300° 195°ii.E-08 53. £-09Ref03625/23/221045.633. £-08 I6.t-08Br81F191+-0ground3/21/23/23/221319.420928.423.e-OB H.fc-0827.E-07 73.fe-0703623/23/221110.482.6-07 22.E-063/23/221337.556*t-07 I5.fc-0611/23/220772.3li.E-08 51. £-0903625/23/220954.632.P-08 16. £-083/23/221181.722.E-06 11. £-08csCarbon monosulfide-—•©IsotopicMolecularSpeciesC 12 S32C 12 S33C 12 S34C 13 S32Av/pMe/mm|XDeb ye1.97 mB eMe/ sec24584.35m24381.01m24190.20m23205.22mu ecm"11285a eMe/sec+177.544eqQ(S)McAec+12.835as>Me/ sec0.019AdditionalMicrowaveReferences150214630659ReferencesIsotopicMolecularSpeciesC 12 S 32Rotationt *iJ «-J1^010421042VibrationVground9900*; F'1042IIF lIIF1042VMe/ sec104248991.000 ±.006Intensity cm"300° 195°94.E-G5 25, E-04Ref1042C 12 S 331«-01ground1/23/248635.912 ±.04048583.264 +.01019. £-07 19. £-0812. £-07 32. £-07104210425/23/248585.906 ±.01036.E-07 9b.E-07

IsotopicMolecularSpeciesC 12 S33C 13 S32C 12 S34Rotationt nJ «-J1*-01+-01*-0VibrationvgroundgroundgroundFlF*3/2tt nF i F3/2VMe/sec48589.068 ±.01046247.472 +.02048206.948 ±.006Intensity cm"300° 195°24.E-07 63.fc-0788.E-07 23.E-0640.E-06 IO.E-05Ref104210421042CO Carbon monoxide /. I2L8Z A—-©IsotopicMolecularSpeciesC 12 0 16C 12 0 17C 12 0 18C 130 16C 130 18C 14 0 16ReferencesAv/pMe/mmM-Debye0.112 m1436B 0Me/ sec57635. 9im1641"ecm^121709900eqQ(O)Me/sec•1-4.431367D oIce/sec183.81641gnuclearmagnetons-0.26910-0.25622-0.25704-0.246641501B eMe/ sec57898.56856432,67555135.44955346.44752583.28853166.9361641VMe/ sec525.24Footnote: #*#(below) This value is a weighted average of values presented in the following papers:1144, 0422, 1436, 0285, 1641,1045, 1501, 1306.1641IsotopicMolecularSpeciesC 120 16C 12 0 17C 12 0 18C 13 0 16C 130 18Rotationi «J

IsotopicMolecular Rotation VibrationF* nMVIntensity cmSpeciest «J *-JvKF i FMe/sec300° 195°RefC 140 16IK)ground105871.110 ±.004 35.E-06 93.E-06 1722ClBr Chlorine monobromide (see Bromine monochloride)C1F Chlorine monofluoride (see Fluorine chloride)C1I Chlorine monoiodide (see Iodine monochloride)CsBr Cesium bromide -> n7?olMolecularIsotopeCs133Br79Cs 133Br81Av/pMe/mmM-Debye9.974 pB eMe/ sec1081.343m1064. 58 5yCOcm~&94][194JY01Me/ sec1081.33921064.5853a eMe/sec3.71753.6313Yekc/sec3.13.1Dekc/sec0.27J eICT^gcm 2467.5039References08580858990008580858085808580858069906990699069906990699MolecularIsotopeCs 133Br79Rotationf nJ *•>!10*-9Vibrationvground*; F' nFlF" VMe/ sec21588.57 ±0.10Intensity cm300° 195°66.E-05- 22.E-0*Ref0858121514.48 ±0.2026.E-05 51.E-050858221440.65 ±0.2010.E-05 12,fc-050858321366.36 ±0.2040.E-06 29.E-060858421292.40 ±0.2016.E-06 69.E-070858521218.66 ±0.2061.E-07 16.E-07085811^10gro und23747.17 ±0.1072(-05) 25(-04)0858123665.60 ±0.203

IsotopicMolecularSpeciesC3133Br79Cs 133Br81Rotationf nJ *-J11«-1012«-1110*-911«-101'2«-11VibrationV78123groundground1234gro und'1F* nFinFVMc/sec23178.25 ±0.2023097.97 ±0.2025816.53 ±0.2025648.95 ±0.2025550.22 ±0.2021254.44 ±0.1023379.53 ±0,1023299.79 ±0.2023220.22 ±0.2023140.61 ±0.2023061.38 ±0.2025504.69 ±0.10Intensity cm300° 195°12.E-07 12.E-0849.E-08 29.E-0944.E-05 88.E-0517.E-05 2L.E-0568.fc-06 ^9.fc-0662.E-05 20.E-0482.E-05 27.E-0432.E-05 64.E-0513*E-05 15.fc-0549.E-06 36.E-0619.E-06 85.E-07ll.E-04 35.b-0^Ref085808580858085808580858085808580858085808580858CsCl Cesium chloride 2,IsotopicMolecularSpeciesCS133C135CS 133 C137ReferencesAv/PMe/mmP-Debye10.40 m0858B cMc/sec2161.208m2068. 761y0858tt ecm'12400858¥01Me/sec2161.1952068.7610858aeMe/sec10.0859.460858Yetec/sec7.10858JelO^gcm2233.91180858leqQ|Hc/sec(cs) (ci)

IsotopicMolecularSpeciesCS 133C135CS 133C1 37Rotationi »J «-J6«-56«-5Vibrat ionV12345678ground124*; p 1 HF lIIFvMc/sec25752.16 ±.2025631.58 ±.2025511.25 +.2025390.36 ±.4025270.0 ±.625150.1 ±.625031.0 ±.624911.2 ±.624767.86 ±.1024654.86 +.3024541.40 ±.5024337.9* ±1.5Intensity cm300° 195°66.E-05 U.e-OV21.6-05 19.E-056*.E-06 32.E-0620.E-06 54.E-07.63.E-07 91. £-0820.t-07 15.E-0862.E-08 26.E-0919.E-08 43.E-1059.E-Oi> 19.fc-0*19.6-05 33.E-0561.E-06 58*E-0663.6-07 18.t-07Footnote *-This line is apparently 30 Me/sec too high, but was not remeasured as were all the otherlines for this isotope. [o621, 0699]CsF Cesium fluoride 2.3VS3 A>--©Ref0699069906990699 ,06990699069906990699069906990621IsotopicMolecularSpeciesCs 133 p 19ReferencesWpMe/mmM-Debye7.875 m1244BeMc/sec5527.34 m0858

IsotopicMolecularSpeciesCS 133F 19Rotationt «J «-J2«-lVibrationV2F'i F 1 11 nFi FVMe/ sec21757.58 ±.60Intensity cm"1300° 195°77.6-06 60.6-06Ref0858321617.09 ±.6021.6-06 81. 6-070858421477.5 ±1.056.6-07 11.6-070858Csl Cesium iodide-—-©IsotopicMolecular. SpeciesCs 133! 127Av/pMe/mmu-Deb ye12.1 mB eMe/ sec708.3579mtoecm'1142Y01Me/ sec708.3568aeMe/sec2.0441^ekc/sec1.45Dekc/sec0.152JelO^gcm2713.6686References085808589900085808580858Q8580858IsotopicMolecularSpeciesCs 133 ! 127Rotationt «J +316*-15VibrationVgroundFlF 1FlF" VMe/sec22632.26 ±0.'10Intensity cm"300° 195°18.6-04 61.6-04Ref0858122567.02 ±0.1090.6-05 21.6-04085817-1-16ground24046.40 ±0.1021.6-04 73.fc*OA0858123976.96 ±0.1011.6*04 25.fc-040858223907.70 ±0.1054.6-05 88.t-050858323838'. 47 ±0.10-27.6-05 31.6-05085818-17ground25460.53 ±0.1025.E-04 86.6-040858125387.04 ±0.1013.6-04 30.6-040858225313.66 ±0.1064.6-05 10.fc-04085810

FBr Fluorine monobromide (see Bromine monofluoride)FC1 Fluorine chloride I.LZ8I A-—•©IsotopicMolecularSpeciesF19 C135F19 C13TReferencesAv/pMe/mmu-Debye0.881 m0190B eMe/sec15483.69m15189.22m0190W ecm"17939900eqQ(Cl)Me/sec-145.837-114.9771731C (Cl)kc/sec+22±3+18+31731aMe/ sec130.666126.9570190Je10^°gcm254.182255.23260190Dekc/sec26.325.30190Addnl.Micro.Refs.0284IsotopicMolecularSpeciesF19C135Rotationi «J -KT1

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IsotopicMolecularSpeciesGa69Br79Rotation1 "J *-J5«-4VibrationV1*I7/2F f2Fl5/2nF1VMe/ sec24673.55 ±0.20Intensity cm300° 195°42.E-09R66.E-09Ref14257/235/2224673.55 ±0.2060.E-09R95.E-097/245/2324673.55 ±0.2084.E-09R13.E-089/29/29/29/211/211/211/211/213/213/213/2345645675677/27/27/27/29/29/29/29/211/211/211/22345345645624673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2024673.55 ±0.2065.E-09R10.E-0884.E-09R13.E-08ll.E-08R17.E-0814.E-08R2UE-0891.E-C79R14.E-08li.fc-08R17.E-0813.E-08R21.E-0816.E-08R26.t-0812.E-08R19.E-0814.E-08R22.E-0817.E-OBR26.E-0813/2811/2724673.55 ±0.2019.E-08R31.E-0827/27/27/29/29/29/29/211/211/211/211/213/22343456456755/25/25/27/27/27/27/29/29/29/29/211/2123234534564total intensity24576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2024576.08 ±0.2017.E-07R27.E-0712.E-09R93.E-1017.E-09R13.E-0923.E-09R19.E-0918.E-09R15.E-0923.E-09R19.E-0930.fc-09R24.E-0938.E-09R30.E-0925.E-09R20.E-093UE-09R25.E-0937.E-09R30.E-0945.E-09R36.E-0933.E-09R27.E-09142513

IsotopicMolecularSpeciesGa69Br79Ga6V81Rotationt tiJ «-J5*-45*-4VibrationV2groundFi13/213/213/27/27/27/27/29/29/29/29/211/211/211/211/213/213/213/213/2F'6785234345645675678'I11/211/211/25/25/25/25/27/27/27/27/29/29/29/29/211/211/211/211/2nF5674123234534564567VMe/sec24576.08 ±0.2024576.08 ±0.2024576.08 ±0.20total intensity24483.58 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.2024486.56 ±0.20Intensity cm300° 195°39.E-09R3l.t-0946.E-09R37.E-0954.E-09R43.t-0947.t-08R38.£-0839.E-08R12.E-0714.t-08R44.E-0820.E-08R64.E-0828.E-08R89.t-0822.E-08R69.E-0828.E-08R89.t-0836.E-08Rll.t-0746.E-08R14.t-0731.E-08R96.t-0837.E-08R12.E-0745.E-08R14.E-0755.f-08Rl7.E-0741.E-08R13.E-0748.E-08ftl5.E-0756.E-08R18.E-0766.E-08R21.E-07Ref1425142517/27/27/29/29/29/29/223434565/25/25/27/27/27/27/21232345total intensity24390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2057.E-07R18.E-0640.E-09R63.E-0957.E-09R90.t-0980.E-09R13.E-0862.E-09R99.E-0980.E-09R13.t-0810.E-08R16.E-08l3.e-08R20.t-08142514

IsotopicMolecularSpeciesGa69Br81Ga71Br79Rotation1 nJ *"J54-45«-4Vibrationv12ground*i11/21V21V211/213/213/213/213/27/27/27/29/29/29/29/211/211/211/211/213/213/213/213/27/27/27/2F'45675678234345645675678234nFl9/29/29/29/211/211/211/211/25/25/25/27/27/27/27/29/29/29/29/211/211/211/211/25/25/25/2F"34564567123234534564567123VMc/sec24390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.2024390.37 ±0.20total intensity24294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.2024294.26 ±0.20total intensity24399.00 ±0.2024399.00 ±0.2024399.00 ±0.20Intensity cm300° 195°86.F-09R14.t-0810.E-08R17.E-08l3,t-08R20.t-0815.E-08R24.E-0811.E-08R18.E-0813.E-08R21.t-0816.E-08R25.t-0818.E-08R29.E-0816.E-07R26.E-0711.E-09R90.E-1016.E-09R13.E-0922.E-09R18.E-0917.E-09R14.E-0922.E-09R18.t-0929.E-09R23.t-0936.E-09R29.E-0924.6-09R20.E-0929.E-09R24.t-0936.E-09R29.E-0943.E-09R35.E-0932.E-09R26.t-0938.E-09R30.E-0944.e-09R36.E-0952.E-09R42.E-0945.E-08R37.t-0895.E-09R30.E-0814.E-08R42.E-0819.E-08R60.t-08Ref14251425142515

IsotopicMolecularSpeciesGa71Br79Rotationf HJ «-J5*-4VibrationVground*;9/29/29/29/211/211/2F'345645nFl7/27/27/27/29/29/2TtF234534VMe/ sec24399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.20Intensity cm"300° 195°i5.E-08R46.t-0819.E-08R59.E-0824.E-08R76.E-0831.E-08H96.E-0820.E-08R64.E-0825.E-08R78.E-08Ref1425to71Br815«-4ground11/2U/213/213/213/213/27/27/27/29/29/29/29/211/211/211/211/213/213/213/213/26756782343456456756789/29/211/211/211/211/25/25/25/27/27/27/27/29/29/29/29/211/211/211/211/256456712323453456456724399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.2024399.00 ±0.20total intensity24114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.2024114.08 ±0.20total intensity30.E-08R95.E-0837.E-08Rli.E-0727.E-08R85.E-0832.E-08ROO.E-0837.E-08R12*.£~0744.E-08R14.E-0738.E-Q7R12.E-0689.E-09R28.E-0813.E-08R40.E-0818.E-08R56.E-0814.6-08R44.E-0818.E-08R56.E-0823.E-08R72.E-0829.E-08R91.E-Od19.E-08R61.E-0823.E-08R74.E-0829.E-08R90.E-0834.E-08RIUE-0726.E-08R80.E-0830.E-08R94.E-0835.E-08R11.E-0741.E-08R13.E-0736.E-07R11.E-06142516

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IsotopicMolecularSpeciesGa69 Cl35Rotationt nJ *-J2«-lVibrationvground*;1/2P f1TtFl1/2nF1VMe/sec17928.55 ±0.20Intensity cm"300° 195°25.E-09R73.E-09Ref14257/245/2417928.55 ±0.2057.E-09R17.E-085/233/2217928.55 ±0.2023.E-08R69.E-085/223/2217928.55 ±0.2072.E-09R2l.E-08totP.l intensity75.E-08R22.E-077/255/2417930.57 ±0.2065.E-08R19.E-077/245/2317930.57 ±0.2047.E-08R14.E-077/235/2317930.57 ±0.2074.E-09R22.E-087/235/2217930.57 ±0.2034.E-08R10.E-077/225/2217930.57 ±0.2056.E-09R17.E-087/225/2117930.57 ±0.2024.E-08R70.E-085/243/2317930.57 ±0.2037.E-08Rii.E-075/233/2317930.57 ±0.2058.E-09R17.E-085/223/2117930.57 ±0.2013.E-08R39.E-085/213/2117930.57 ±0.2056.E-09R17.E-085/213/2017930.57 ±0.2062.E-09R18.E-08total intensity25.E-07R74.E-073/333/2217942.92 ±0.4044.E-09Ri3.E-083/23/2213/2•3/22217942.92 ±0.4017942.92 ±0.4063.E-09R19.E-0850.E-09Ri5.E-08total intensity16.E-08R47.E-083/233/2317946.83 ±0.3018.E-08R53.E-083/223/2317946.83 ±0.3044.E-09R13.E-083/223/2117946.83 ±0.3050.E-09Ri5.E-083/213/2117946.83 ±0.3013.E-09R38.fc-093/213/2017946.83 ±0.3032.E-09R94.E-093/203/2117946.83 ±0.3032.E-09R94.E-09total intensity35.E-08RIO.E-0718

IsotopicHolecularSpeciesGa 69Cl35Rotationf "J *-J2«-lVibrationV1'I7/2F*5^5/2F"4VMe/ sec17837.00 ±0.50Intensity cm""300° 195°ii.E-08R13.fc-08Ref14257/245/2317837.00 ±0.5082.E-09R94.t-097/27/2335/25/23217837.00 ±0.5017837.00 ±0.5013.E-09R15.E-0958.E-09R67.E-097/225/2217837.00 ±0,5097.E-10R1UE-097/225/2117837.00 ±0.504i.E-09R47.E-095/243/2317837.00 ±0.5064.E-09R74.E-095/233/2317837.00 ±0.5099.E-10R12.E-095/2s/2213/23/21117837.00 ±0.5017837.00 ±0.5022.t-09R26.E-0996.E-10Rll.E-095/213/2017837.00 ±0.50ll.E-09Ri2.E-09total intensity43.E-08R50.t-0827/255/2417743.96 ±0.5019.E-09R87.E-1014257/245/2317743.96 ±0.5014.E-09R63.E-107/235/2317743.96 ±0.5022.E-10R98.E-117/235/2217743.96 ±0.50OO.E-10R45.E-107/225/2217743.96 ±0.5017.E-10R75.E~117/225/2117743.96 ±0.5070.E-10R31.E-105/243/2317743.96 ±0.50ll.E-09R50.E-105/233/2317743.96 ±0.5017.E-iOR77.fc-ll5/223/2117743.96 ±0.5038.E-10R17.t-105/213/2117743.96 ±0.5016.E-iOR74.E-ll5/213/2017743,96 ±0.50total intensity18.E-lOR83.E-ii74.E-09R33.E-0937/255/2417650.97 ±0.5033.E-10R58.E-1114257/245/2317650.97 ±0.5024.E-10R42.t-ll7/235/2317650.97 ±0.5037.E-ilR66.E-127/2. 35/2217650.97 ±0.5017.E-10R30.E-1119

TsotopicMolecularSpeciesGa69 Cl35Rotationi nJ «-J2«-lVibrationV3FI7/27/2F'22nFl5/25/2nF21VMe/ sec17650.97 ±0.5017650.97 +0.50Intensity cm300° 195°29.E-UR50.E-1212.E-10R2i.E-llRef14255/243/2317650.97 ±0.5019.E~10R33.E-llGa69 Cl372«-lground5/25/25/25/27/27/27/27/27/27/25/25/25/25/25/23211543322432113/23/23/23/25/25/25/25/25/25/23/23/23/23/23/231104332213311017650.97 ±0.5017650.97 ±0.5017650.97 ±0.5017650.97 ±0.50total intensity17289.15 ±0.50*17289.15 ±0.5017289.15 ±0.5017289.15 ±0,5017289.15 ±0.5017289.15 ±0.5017289.15 ±0.5017289.15 ±0.5017289.15 ±0.5017289.15 ±0.5017289.15 ±0.5029.E-11R52.E-1266.E-11R12.E-1128.E-11R50.E-123i.E-llR55.E-1213.E-09R22.E-1020.E-08R58.E-08l

IsotopicMolecularSpeciesGa71Cl35Rotationt «J «-J2

IsotopicMolecularSpeciesGa71Cl37RotationjVj"2«-lVibrationVground'I7/27/27/27/27/27/25/25/2?/25/25/2F'54332243211itpi5/25/25/25/25/25/23/23/23/23/23/2nF43322133110VMe/ sec17118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.5017118.24 ±0.50total intensityIntensity cm""300° 195°13.E~08R38.E-0893.E-09R28.E-0814.E-09R43.E-0966.E-09R20.E-0811.E-09R33.E-0946.E-09R14.E-0873.E-09R22.E-08ll.E-09R34.E-0925.E-09R76.E-0911.E-09R32.E-0912.E-09R36.E-0949.E-08R15.E-07Ref1425Gal Gallium monoiodide 2.5747 A©-----©IsotopicMolecularSpeciesGa69 x127to71!127ReferencesAv/pMe/mmM-DebyeBeMe/sec1706.86 m1675.73 m1425wecm"12169900eqQ(I)Me/sec-5491425eqQ(Ga)Me/sec-661425aeMe/ sec5.6675.5351425Dekc/sec0.471425AdditionalMicrowaveReferences1192, 1341Footnote: Intensities for those components of degenerate lines were not computed if they involvedforbidden transitions, in this case , AF^ = 3.22

IsotopicMolecularSpec ie£Ga69 !127RotationjVj"7«-6VibrationVground1'I9/211/211/213/213/217/29/29/29/213/215/215/215/217/215/213/217/219/219/219/219/217/215/213/2F*44767835656787989891011798nFl7/29/29/211/215/211/27/27/27/211/213/213/213/211/213/215/215/217/217/217/217/211/213/215/2nF3365672454567687878910687VMe/sec23851.47 ±0.2023851.47 ±0.2023851.47 ±0.2023851.47 ±0.2023851.47 ±0.20total intensity23853.25 ±0.2023853.25 ±0.2023853.25 ±0.2023853.25 ±0.2023853.25 ±0.20total intensity23855.66 ±0.2023855.66 ±0.2023855.66 ±0.20total intensity23857.29 ±0.2023857.29 ±0.2023857.29 ±0.2023857.29 ±0.2023857.29 ±0.2023857.29 ±0.2023857.29 ±0.2023857.29 ±0.20total intensity23778.29 ±0.2023778.29 ±0.2023778.29 ±0.20Intensity cm""1300° 195°23.E-06R76.E-0824.E-08R77.E-0843.E-08R14.E-0735.E-08R1UE-072i.E-14R69.E-1413.E-07R4l.E-0718.E-08R59.E-0830.E-08R97.E-0838.E-08R12.E-0730.E-06R97.E-0812.E-07R38.E-0737.E-08R12.E-0742.E-08R14.E-0749.E-08R16.E-0713.E-07R4l.E-0756.E-08R18.E-0719.E-14R60.E-1457.E-08R18.E-0753.E-08R17.fc-0759.E-08R19.E-0766.E-08K21.e-0773.E-08R24.E-0736.E-07R12.E-0620.E-08R36.E-0866.E-15R12.e-14Ref14251425

IsotopicMolecularSpeciesto69 !127Rotationt nJ «-J7«-6Vibrationv1'i17/2F'9Fl15/2F"8VMe/ sec23778.29 ±0.20Intensity cm"300° 195°20.E-D8R37.fc-08Ref142519/2817/2723778.29 ±0.2019.E-08R34.E-0819/2917/2823778.29 ±0.202l.E-G8R3fl.E-0819/21017/2923778.29 ±0.2023.E-08R43.E-0819/21117/21023778.29 ±0.2026.E-OBR47.E-08217/2711/26total intensity23698.78 ±0.3013.E-07R24.t-07142515/2913/2823698.78 ±0.3069.E-09R73.E-0913/217/28915/215/27823698.78 ±0.3023698.78 ±0.3023.E-15R24.fc-1570.E-09R74.E-0919/2817/2723698.78 ±0.306b.E-09R69.t-0919/2917/2823698.78 ±0.3073.E-09R77.E-0919/21017/2923698.78 ±0.3081.E-09R86.fc-0919/21117/21023698.78 ±0.3090.E-09R95.E-09Ga71 !1277*-6ground17/2711/26total intensity23421.95 ±0.2045.E-08R47.6-081425115/213/217/219/219/219/219/217/215/29898910117913/215/215/217/217/217/217/211/213/2878789106823421.95 ±0.2023421.95 ±0.2023421.95 ±0.2023421.95 ±0.2023421.95 ±0.2023421.95 ±0.2023421.95 ±0.20total intensity23344.45 ±0.3023344.45 ±0.3035.E-08R11.E-0712.E-14R38.E-1436.E-08R12.E-0734.E-08R11.E-0737.E-08R12.E-0742.E-08R14.E-0746.E-08R15.E-0723.E-07R75.E-0713.E-08R23.E-08142513/2815/2723344.45 ±0.3042.E-15R78.E-1517/2915/2823344.45 ±0.3013.E-08R24.E-0624

IsotopicMolecularSpeciesGa71!127Rotation? ftJ «-J7«-6Vibrat ionV1'i19/2F*8nFl17/2nF7vMe/ sec23344.45 +0.30Intensity cm""300° 195°77.E-09R1*.E-08Ref142519/2917/2823344.45 +0.3086.E-09R16.E-0819/21017/2923344.45 ±0.3095*E-09R18.E-0819/21117/21023344.45 +0.30ll.E-08R20.E-08total intensity62.E-08Ril.E-07HBr Hydrogen bromide (hydrobromic acid) i.itis- A©-—-IsotopicMolecularSpeciesH^r 79HV 1H2Br 79H2Br81H3Br 79H3Br81ReferencesIsotopicMolecularSpeciesH2Br 79Av/pMe/mmRotationf t!J 4-J1*-0M-Debye0.83 m0.83 m1530B*Me/sec128600 m128500 m86947.2 m86868.8 m14410971VibrationVgroundwecm'1[2650}{2650}9900*; F'1/2eqQ(Br)Me/sec+530.65+443.29+527.6+442.11529106111FlnF3/2nuclearmagnetons+0.181+0.1841529VMe/ secC(Br)0.150.161441254571.661 ±.050AdditionalMicrowaveReferences1 0845Intensity cm300° 195°aeMe/sec25152512139013891441097131.E-08 82.E-08Ref14415/23/2254678.380 +.05094.E-08 25.E-07H2Br811*0ground3/21/23/23/2254810.634 ±.050254437.641 ±.05063.E-08 I6.t-0731.E-08 80.E-0814415/23/2254526.984 +.05092.E-08 24.t-0725

IsotopicMolecularSpeciesH2Br81H3Br79Rotationt "J «"J1*O1«K)Vibrat ionVgroundground*; p'3/25/2nFinP3/23/2vMe/ sec254637.448 ±.050172472.72 ±.40Intensity cm"300° 195°61.E-08 16.E-0728.fc-04R75.fc-04Ref14411061H3Br811+-0ground3/25/23/23/2172604.60 ±.40172320.96 ±.4019.E-04R50.E-0428.E-0*R73.E-0410613/23/2172431.49 ±.4019.fc-04R*9.E-04HC1 Hydrogen chloride (hydrochloric acid)IsotopicMolecularSpeciesH^l35H^l37Av/pMe/mmP-Deb yeBeMe/ secw ecm'12990eqQ(Cl)Me/secC(C1)kc/seca eMe/secacm'1H2 C135H2 C13?H3 C135H3 C137References1.12 m1.12 m1530163340.1m162859.0m112032.0m111550.6m12840971209099019900-67.3-53.0-67.0-53.0144109710.030.0014411912189809710.11230.11181284IsotopicMolecularSpeciesH2 C135Rotationt nJ ^11*0Vibrat ionVgroundF*'I3/2IIFltlF3/2VMe/sec323282.28 ±.13Intensity cm""300° 195°35.6-07 91.E-07Ref14415/23/2323299.17 ±.1352.E-07 14.E-06H2C1371*-0ground1/23/23/23/2323312.52 ±.13322339.09 ±.1317.E-07 46.E-07IUE-07 29.t-0714415/23/2322352.33 ±.1317*E-07 *4.E-07Z6

IsotopicMolecularSpeciesH2C137I^Cl35H3C1 37Rotationi «J -Kl1*K)1*-01«-0VibrationVgroundgroundground'1 ?'1/23/25/21/23/25/21/2FlnF3/23/23/23/23/23/23/2VMe/sec322362.94 ±.13222130.32 ±.4222147.23 ±.4222160.50 ±.4221184.82 ±.4221198.00 +.4221208.69 ±.4Intensity cm""300° 195°56. £-08 15.E-0760.E-04Ri6.t-0390.t-04R24.t-0330.E-04R79.fc-0*19.E-04R5l.t-0429.E-04R77.fc-0497.6-05R26.t-04Ref144109710971HI Hydrogen iodide (hydroiodic acid)IsotopicMolecularSpeciesH 1 ! 127H2 ! 127H3 ! 127ReferencesAv/pMe/mmM-Debye0.445 m1530B«Me/sec195229.1m98447 m65750.88v112414411061"ecm'123109900eqQ(I)Me/sec-1831-1823.3-1822.6112414411061C(I)kc/sec0.260.1711241441aeMe/sec18201441aC.T10.17151125IsotopicMolecularSpeciesH1!127H2!127Rotationi «J

IsotopicMolecularSpeciesH2 !127H3 !127Rotation» *J +-J1+-01«-0Vibrationvgroundground*; F 13/25/27/2nFinF5/25/25/2VMe/ sec195322.706 ±.04131210.20 ±.25131592.95 ±.25Intensity cm~300° 195°ll.E-08 28*E-0817.E-O^R^^,E-OA22.E-O^R59,fc-04Ref1441106128

OH Hydroxyl radical2The electronic ground state of the hydroxyl radical is designated IT, i.e. t the spinS is 1/2 and the projection A of the orbital angular momentum on the internuclear axis isequal to unity. For low rotational states, S and A couple vectorially according to Hund'scase (a), giving a projection fi of the total angular momentum (excluding nuclear spin) equalto 1/2 or 3/2. However, for high rotational states, S couples according to Hund's case (b)to the vector sum of A and the orbital angular momentum 0 due to nuclear motion (molecularrotation).Using Hill and Van Vleck's formula [2: equation 7-12; 5: equation V, 28] for intermediate coupling, but neglecting centrifugal distortion, the small interaction constant ybetween S and tf, and a constant term in the energy, one obtainsZ = (2J + l)e"X[J(J + 1}± ^(J + 1/2) 2 +w].Here, w = M x - 4)/4, ^= V^, and A = -137.76 cm""1 is the interaction constant betweenS and A (energy * AS*A). For low values of J and negative A, the upper and lower signs2 2apply to the ni/2 and ^3/2 staJ|:es respectively [5: pages 232]; for large J thesesigns apply to the sets of states for which J = N-l/2 and J = N+l/2 respectively, whereN is the resultant of the electronic orbital angular momentum and the angular momentum ofmolecular rotation [5: pages 232-4;2: page 186], Note: Townes and Schawlow's equations(7—13) should have absolute value signs about AA, otherwise they are incorrect for — ^»+l,the case for OH. Since the series converges rather rapidly, the state sum Qr was obtained by direct summation over the two sets of Z 's, with J taking on the half integralvalues from fl to infinity. An additional factor of two was introduced into Q , since A-doubling multiplies the number of states by two. (The factor of two does not occur inZr , since absorption occurs only from the lower member of a doublet in the A-doublingspectrum observed for OH.)29

Since V depends only upon the coupling of angular momentum, V for OH (AJ = 0) may beobtained from that for a symmetric top, namely(o. "i^V= effJ(J + 1)[2: equation 3 - 41; 5: equation IV, 81], where 2gff is the effective value of 2.2eff = 5Q 1 * e22 'where2 X = 1/2, 22 = 3/2 ,6 = (+z-2 + ^)/2z ,e = (Tz+2 - ^)/2z ,andz = V4CJ+1/2) 2 + ^(^-4) ,and the upper and lower signs are correlated as before [1141,0982]*Note: Townes and Schawlow's equations (7 - 20) and (2 - 16), as well as those in Dousmanis,Sanders, and Townes's [0982] section 4(e) are in error. Equation [2: 2 -16] is not identicalwith that of a slightly asymmetric top, as may be seen in equation [2: 3 - 41]. Relative tothe statement on page [2:34], the analog of the state J,-^, does not occur for £ = 0.30

HO Hydroxyl radical 0. 970t> KIsotopicMolecularSpeciesHV6H 2 0 16HV 8Av/pMe/mm-8.0 mu-Debye1.54 *Becm'118.87110.016"ecm"137353735A-type doubling parametersX= VB Me/Sec Me/sec-7.444 -2361.37 576.18-13.954 -1548.99 161.94Docm"10.001870.000520.00187B =rot. const.s in 2 Z stateCM-116.9619.0316.961Addnl.Micro.Refs.07640832References09821863990199000982 0982 098211320982IsotopicMolecularSpeciesHV 6H2016HV 8Magnetic hfs constants Me/seca b c d48.710.5 113.610.6 -25.15. 57.011.58.6910.16av!024 cm-30.61610.006(fecosx-iy^lO^cm-1(-0.21±0.04)¥ 2 (0)10 24 cm-3(0.184±0.004)4in2 X)/r3)av10 24 cm-3(0.49010.013).(0.48610.009)References1693 1693 1693 09821693169316930982IsotopicMolecularSpeciesH^ 16H2 0 16H^ 18-

IsotopicMolecularSpeciesHV 6H20 16RotationJ,N*3/2,25/2,37/2,39/2,411/2,55/2,37/2,4VibrationvgroundgroundgroundgroundgroundgroundgroundEleotronic2 n1/22 n1/2X/22V22 "3/22 "l/22 n1/2*;F ?1223344455563/25/27/25/27/29/2nFlF"12233A5454563/25/27/25/27/29/2VMe/ sec7760.36 ±0.157819.92 ±0.108135.51 ±0.158188.94 ±0.1013434.62 ±0.0513441.36 ±0.0523806.5 ±0.523818.18 ±0.0523826.90 ±0.0523837.8 ±0.336983.47 ±0.1536994.43 ±0.158110.20 ±0.108117.69 ±0.108127.64 ±0.159578.51 ±0.159586.03 ±0.109595.26 ±0.10Intensity cm300° 195°37.E-07 59.E-0767.E-07 ll.E-0622.E-07 28.E-0733.E-07 41.E-07V2.E-06 67. £-0660.E-06 93.E-0612.E-07 12.E-0753.E-06 53.F-0665.E-06 6«>*F-0612.F-07 12.E-07?40.E-06 25*E-0647.E-06 30.E-06ll.E-11 17.E-1115.E-11 24.E-1I23.E-11 37.E-1110.E-11 14.E-1113.E-11 17.E-1118.E-11 24.E-11Ref098209820982098209820982098232

IsotopicMolecularSpeciesH20 16HV8nV6Rotation9/2,511/2,611/2,513/2,615/2,717/2,89/2,43/2VibrationVgroundgroundgroundgroundgroundgroundgroundgroundElectronic\/2.\/2\/22 "3/22 "3/22 V2S/22 n3/2'iF*7/29/211/29/211/213/29/211/213/211/213/215/213/215/217/215/217/219/24521nFlF"7/29/211/29/211/213/29/211/213/211/213/215/213/215/217/215/217/219/24521VMe/ sec10191.64 ±0.1010199.10 ±0.1010208.14 ±0.109914.39 ±0.109921.53 ±0.109929.88 ±0.108672.36 ±0.108672.36 ±0.108672.36 ±0.10total intensity12918.01 ±0.1012918.01 ±0.1012918.01 ±0.10total intensity18009.60 ±0.1018009.60 ±0.1018009.60 ±0.10total intensity23907.12 ±0.1023907.12 ±0.1023907.12 ±0.10total intensity23469.5 ±0.523479.1 ±0.51667.34 ±0.031665.46 ±0.10Intensity cm300° 195°70.F-12 74.F-1285.E-12 90.E-12ll.F-11 11.F-1137.E-12 28.E-1243.E-12 33.E-1252.E-12 40.E-1241.E-11 52.E-1148.E-11 61.E-1158.E-11 74.E-1115.E-10 19.E-1043.E-11 39.E-1149.E-11 44.E-11S7.E-11 52.E-1115.E-10 14.E-1036.E-11 23.E-1140.F-11 26.F-1146.E-11 29.E-1112.E-10 78.E-1125.E-11 ll.E-1128.E-11 12.E-1132.E-11 13.E-1185.E-11 36.E-1152.E-12 13.E-1164.E-12 17.E-11Ref0982098209820982098209820982196133

InBrIndium bromide(L.}-----IsotopicMolecularSpeciesIn 115Br79Av/pMe/mmM-DebyeBeMe/ sec1670.14 m%cm- 1224 ceqQ(In)Me/sec-642eqQ(Br)Me/sec138aeMe/sec5.706Dekc/sec0.43AdditionalMicrowaveReferences1106, 0965References142599001425142514251425Footnote:For validity of computed intensities see introductory remarks on hyperfine splitting.IsotopicMolecularSpeciesIn 115Br79Rotationf nJ *-J7«-6VibrationVgroundK19/2F'10»Fl19/2nF10VMe/ sec23308,30 ±0.20Intensity cm"300° 195°34.E~09fUl.t-08Ref1425,19/21119/21123308.30 ±0.2038.E-09Rl2.t-08total intensity72.t-09R23.t-0813/2511/2423328.97 ±0.20ll.E-08R36.E-0811/249/2323328.97 ±0.2087.t-09R28.t-0811/279/2623328.97 ±0.2016.E-08R50.E-08total intensity36.E-08Rll.t-079/267/2523331.51 ±0.20l3.E-08R42.t-089/237/2223331.51 ±0.2063.E-09R20.t-087/225/2123331.51 ±0.20

IsotopicMolecularSpeciesIn115Br79Rotation1 nJ

IsotopicMolecularSpeciesIn115Br79RotationjW7*-6VibrationVground'I17/217/215/219/219/215/215/25/25/25/217/2F'1097988732110nFi15/215/217/213/213/217/213/23/23/23/215/2F"98887762109VMe/ sec23339.12 ±0.2023339.12 ±0.2023339.12 ±0.20total intensity23341.01 ±0.2023341.01 ±0.2023341.01 ±0.2023341.01 ±0.2023341.01 ±0.2023341.01 ±0.2023341.01 ±0.2023341.01 ±0.20Intensity cm300° 195°25.E-08R81.E-0822.E-08R72.t-0822.E-IOR70.E-1076.E-08R24.t-0736.E-14R12.E-1316.E-08R53.E-0863.E-09R20.E-0835.E-09Rll.E-0817.E-09R54.t-0925.E-08R81.t-08Ref142517/215/223/223/223/223/221/221/221/2971312111012111015/217/221/221/221/221/219/219/219/28812111091110923341.01 ±0.2023341.01 ±0.20total intensity23343.33 ±0.2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.2022.E-08R72.t-0822.E-10R70.E-1076.E-08R24.E-0739.E-08R13.b-0736.E-08R12.E-0733.E-08R11.E-0730.E-08R97.t-0834.E-08R11.E-073i.E-08ROO.E-0828.E-08R90.t-0821/219/219/217/217/215/29111099919/217/217/215/215/217/2810998823343.33 ±0.2023343.33 ±0,2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.2023343.33 ±0.20total intensity26.E-08R82.E-0829.E-08R95.E-0826.E-08R85.E-0845.E-lOR14.t-0922.E-08R72.t-0832.E-14R10.E-1334.E-07Rli.t-0636

IsotopicMolecularSpeciesIn 115Br79Rotation1 nJ «-J7+-6VibrationVground'[23/2F'13nFl21/2tiF12VMe/ sec23345.07 ±0.20Intensity cm300° 195°39.E-08R13.E-07Ref142523/21221/21123345.07 ±0.2036.E-08R12.E-0723/21121/21023345.07 ±0.2033.E-08R11.E-0723/21021/2923345.07 ±0.2030.E-08R97.E-0821/21219/21122345.07 ±0.2031*E-08R10.E-0721/21119/21023345.07 ±0.2031.E-08ROO.fc-0821/21019/2923345.07 ±0.2028.E-08R90.t-0821/2919/2823345.07 ±0.2026.E-08R82.t-0819/21117/21023345.07 ±0.2029.E-08R95.E-0819/21017/2923345.07 ±0.2026.E-08R8b.t-0617/2915/2923345.07 ±0.2045.E-10R14.E-0917/2915/2823345.07 ±0.2022.E-08R72.E-0815/2917/2823345.07 ±0.2032.E-14RiO.t-13total intensity33.E-07Rli.t-0623/21321/21223346.51 ±0.2039.E-08R13.t-0723/21221/21123346.51 ±0.2036.E-08R12.E-0723/21121/21023346.51 ±0.2033.E-08Rll.t-0723/21021/2923346.51 ±0.2030.E-08R97.t-0821/21219/21123346.51 ±0.2034.E-08Rll.t-072f/21119/21023346.51 ±0.2031.E-08ROO.t-0821/21019/2923346.51 ±0.2028.E-08R90.E-0821/2919/2823346.51 ±0.2026.E-08R82.t-0819/21117/21023346.51 ±0.2029.E-08R95.E-0819/21017/2923346.51 ±0.2026.E-08R85.t-0817/2815/2723346.51 ±0.2020.E-08R64.E-0817/2915/2923346.51 ±0.2045.E-10R14.t-0915/2917/28.23346.51 ±0.2032.E-14R10.E-13total intensity33.t-07Rli.t-0637

IsotopicMolecularSpeciesIn 115Br79RotationjVj"7«-6VibrationVgroundFi15/215/2F'86nFl15/215/2nF86VMe/ sec23353.40 ±0.2023353.40 ±0.20Intensity cm"300° 195°49.E-09R16.E-0838.E-09R12.E-08Ref142513/213/213/213/2876513/213/213/213/2876523353.40 ±0.2023353.40 ±0.20total intensity23358.74 ±0.2023358.74 ±0.2058.E-09R19.E-0849.E-09R16.E-0619.E-08R62.E-0842.E-09Rl4.t-0837.E-09R12.E-085/219/213/213/249745/217/217/213/2487423358.74 ±0.2023358.74 ±0.20total intensity23361.35 ±0.2023361.35 ±0.2025.E-09R80.E-0924.E-08R77.E-0834.E-08Rll.E-0734.E-09Rll.E-0813/27/211/211/213/213/213/27/211/211/211/211/29/2357474357465513/27/211/211/217/213/213/27/211/211/211/211/29/2357474357465523361.35 ±0.2023361.35 ±0.2023361.35 ±0.2023361.35 ±0.20total intensity23362.70 ±0.2023362.70 ±0.2023362.70 ±0.2023362.70 ±0.2023362.70 ±0.2023362.70 ±0.20total intensity23365.60 ±0.2023365.60 ±0.20total intensity23367.97 ±0.2034.E-09Rll.t-08 .40.E-09R13.E-0856.E-09R18.E-0833.E-09R11.E-0820,E-08R63*£-0834.E-09R11.E-0834.E-09Rll.E-084Q.E-09R13.t-0856.E-09R18.t-0833.E-09Rll.fc-0820.E-08R64.E-0646.E-09R15.t-0838.E-09R12.E-0884.E-09R27.t-0839.E-09R13.t-0838

IsotopicMolecularSpeciesIn115Br79Rotationi nJ *-J7«-6VibrationVground'i9/27/2F'44Fl9/27/2n44VMe/ sec23367.97 ±0.2023367.97 ±0.20Intensity cm""1300° 195°3l.E-09R99.E-0929.E-09R92.fc-09Ref142517/219/219/2310117/219/219/23101123367.97 ±0.20total intensity23228.68 ±0.2023228.68 ±0.20total intensity2i.E-09R67.E-0912.E-08R38.E-0812.E-09R21.E-0913.E-09R24.E-0925.E-09R45.E-09142523/223/223/223/21312111021/221/221/221/2121110923263.76 ±0.2023263.76 ±0.2023263.76 ±0.2023263.76 ±0.2013.E-08R24.E-0812.E-08R22.E-0811.E-08R20.E-0810.E-08R19.E-0821/21219/21123263^76 ±0.2012.E-08R21.E-0821/221/221/219/2111091119/219/219/217/210981023263.76 ±0.2023263.76 ±0.2023263.76 ±0.2023263.76 ±0.2011.E-08R19.E-0896.E-09Rl7.t-0887.E-09R16.E-0810.E-08R18.t-0819/217/217/215/213/213/25/219/213/213/21089965497417/215/215/217/213/213/25/217/217/213/2979865487423263.76 ±0.2023263,76 ±0.2023263.76 ±0.2023263.76 ±0.20total intensity23279.09 ±0.2023279.09 ±0.2023279.09 ±0.2023279.09 ±0.20total intensity23282.61 ±0.2023282.61 ±0.2090.E-09R16.fc-0868.E-09R12.E-0815.E-10R28.E-1011.E-14R20.E-1411.E-07R2UE-0714.E-09R26.E-0913.E-09R23.E-0985.E-10R15.E-0981.E-09Rib.E-0812.E-08R21.E-0812.E-09R21.E-0939

IsotopicMolecularSpeciesIn 115Br79RotationI ttJ «-J7«-6VibrationV1K13/2F 13Fl13/2tiF3VMe/ sec23282.61 ±0.20Intensity cm"300° 195°l2.E-09R21.t-09Ref14257/257/2523282.61 ±0.2014.E-09R2b.E-0911/2711/2723282.61 ±0.20i9.E-09R35.t-0911/2411/2423282.61 ±0.20ll.E-09R20.t-09total intensity67.E-09R12.t-0811/2611/2623285.37 ±0.20l6.fc-09R28.t-0911/2511/2523285.37 ±0.2013.E-09R24.E-099/259/2523287.37 ±0.2013,E-09R24.t-099/249/2423287.37 ±0.20ll.E-09R19.t-097/247/2423287.37 ±0.2097.E-lOR18.fc-097/237/2323287.37 ±0.207l,E-10R13.t-09total intensity69.E-09R13.t-08InCl Indium chloride I. HOI\ I©•—-€>IsotopicMolecularSpeciesIn 115Cl 35In 115Cl 37Av/pMe/mmV-DebyeB eMe/ sec3269.47 m

MtoOlSpeciesMolecular Isotopic«-JtnVE?MMCOOl¥ to10.70&73737373X73XB7:&X73&7373JQ7;X>*i7373}073797S73l1 1 1 1 1 1 1 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 10 oooooooooooooooooooooooooooo-J OCCDCDCCCrOCOiOD-«4CDCrCDO;CrCCXCOODCt)COCOCCCOODO3CDODGDtototototoiototo wtototototototo totototo toto toto-JO5Ol£*-IO5Ol»P"-3O5Ol*». £* 00 tO r-» rfJ^CO O) Oltotototototototo totototototototo totototo toto toto-JO5Olif5>.O5Ol*J>CO — JOiOI^OSOlit^OO rf^ 00 tO M OOtO Ol J>o cocococoeocococoo cocococococococoo cocococoo cocoo cocorf OlOlOlOlOlOlOlOlrfOlOlOlOIOlOlOlOlrfOlOlOlOirfOlOlrfOlOlO5O5O5O5O5O5O5O5JM Ol.OlOlOlOlOlOlOlr^COOOOOCOOOOOCOOOH*COCOCOCOH»--IO5O5O5O5O5O5O5O5ji}OOCOCOCOjl} tOlOP lOtOH- COOOCX)COOOOOCOOO r*'COCOCOCDcO«OCOCOH-O5O5O15O5H---l-^H«tOtOrfrf rf rf rftp3 1+ 1+ 1+ 1+ 1+ 1+ 1+ 1+ 3 1+ 1+ 1+ 1+ 1+ 1+ 1+ 1+ 3 1+ 1+ 1+ 1+ 3 1+1+3 1+ 1+U) OOOOOOOOO) OOOOOOOOOJ OOOOW O O 01 OOrf tOtOtO^tJ^tOtOrftO^tOtO^tOWtOrflObOtOlOrftOtOr+tOtOOOOOOOOOO OOOOOOOOO OOOO«o 3COM-rfCOOl Oo afl?

IsotopicMolecularSpeciesIn 115Cl35RotationI nJ +>J3*-2Vibrationvground*;7/2F'2Fi7/2nF2VMe/ sec19570.25 ±0.20Intensity cm"300° 195°86.E-09R26.t-08Ref14257/237/2319570.25 ±0.20li.E-08R33.t-Ofl7/247/2419570.25 ±0.20l5.E-08R45.t-087/257/2519570.25 ±0.2021.E-08R63.E-08total intensity55.E-08R17.E-0715/2613/2519578.36 ±0.2041.E-08Ri3.E-0715/2713/2619578.36 ±0.2048.E-08Ri4.E-0715/2813/2719578.36 ±0.2055.E-08R17.E-0715/2913/2819578.36 ±0.2063.E-08R19.E-07total intensity21.E-07K63.t-079/239/2319584.56 ±0.2012.E-08R35.fc-089/249/2419584.56 ±0.2014.E-08R42.t-089/259/2519584.56 ±0.2018.E-08R53.E-089/269/2619584.56 ±0.2023.E-08R69.fc-083/205/2119584.56 '±0.2033.E-09R10.E-083/215/2219584.56 ±0.2069.E-09R2i.t-083/225/2319584.56 ±0.2012.E-08R37.E-083/235/2419584.56 ±0.2020.E-08R60.t-0813/2711/2619584.56 ±0.2037.E-08Rll.t-07total intensity14.E-07R44.t-0713/2511/2419589.08 ±0.2027.E-08R81.E-0813/2611/2519589.08 ±0.2031.E-08R95.t-0813/2811/2719589.08 ±0.2043.E-08R13.t-07total intensity10.E-07R3i.E-075/217/2219621.36 ±0.2047.E-09Rl4.b-085/227/2319621.36 ±0.2067.E-09R21.t-085/237/2419621.36 ±0.2095.E-09R29.E-085/247/2519621.36 ±0.2013.f-08R40.E-08total intensity34.E-08R10.t-07

MM^>tocnM o l-»M cno MCOCn!s o§ a.< < < rVt nRotationVibration^H* -*$J.**}3S

Inl Indium iodide 2,75-39 AIsotopicMolecularSpeciesIn 115! 127Av/pMe/mmM-DebyeB eMe/ sec1104.95 mwecm-1177Q(In)10-24 cm20.84aeMe/sec3.117Dekc/sec0.19AdditionalMicrowaveReferences1106References14259900001514251425IsotopicMolecularSpeciesin 115!127Rotationt «J «^J11*-10Vibrat ionVgroundF' npi FinFvMe/sec24275.39 ±0.20Intensity cm300° 195°17.E-06R56.E-06Ref142524278.01 ±0.2017.E-06R56.E-0624279.23 ±0.2017.E-06R56.E-0624280.42 ±0.2017.E-06R56.L-0624282.48 ±0.20i7.E-06K56.E-06124206.89 ±0.2071.E-07R15.E-06142524209.36 ±0.2071.E-07R15.E-0624210.68 ±0.207l.E-07R15.E-0624211.78 ±0.207i.E-07R15.E-0624213.78 ±0.2071.E-07R15.E-06224140.91 ±0.2030.E-07R4Q.E-07142524143.30 ±0.2030.E-07R40.t-0744

IC1 Iodine monochloride 2.3207 A©--—-©IsotopicMolecularSpeciesjl27cl 35X127C1 37Av/pMe/mm9.79 ro9.79 mM-Debye0.65 iB eMe/ sec3422.300mw ecm'1384eqQ(I)Me/sec-2930.0eqQ(Cl)Me/sec-82.1a eMe/sec16.060AdditionalMicrowaveReferences0322, 01650109, 0162References01&3016301639900016301630163Footnote: Measured half-^width of 13/2

IsotopicMolecularSpecies1^38Rotat ioni nJ *-J4«-3Vibrationvground1'I9/29/211/211/213/213/213/213/211/211/211/211/211/211/211/213/2F'6676854455766'I9/27/27/29/211/211/211/211/27/29/27/29/29/27/29/211/2F"5565743344655VMe/sec27295.0527295.05total intensity27333.8527333.85total intensity27336.6827336.68total intensity27337.3827337.38total intensity27346.3127346.31total intensity27354.7127354.71total intensity27356.5827357.7327357.73total intensity27208.54Intensity cm300° 195°30.E-06 89.E-0630.E-05 89.E-0661.E-06 18.E-0515.E-07 45.L-0715.E-07 45.E-0720.E-07 60.E-0717.E-07 51.E-0738.E-07 ll.E-0624.E-07 70.E-0715.E-07 43.fc-0739.E-07 ll.E-0610.E-07 31.E-07li.E-07 3UE-0713.E-07 37.fc-0713.E-07 37.E-0719.E-07 55.fc-0715.E-07 46.E-0715.E-07 46.E-0748.E-07 52.E-07Ref0163016346

LiBr Lithium bromide 2. I70¥ X©-(SIso topicMolecularSpeciesLi6Br81Li7Br79Li 7Br81Av/pMe/mmM-Debye6.19 m».Me/ sec19162.32m16651.19m16617.62m">ecm"1[480]YoiMe/sec19161.51116650.57016650.002aeMe/ sec(208.75)169.09168.58Yekc/sec(868)656653Dekc/sec[109][82][82]"e*eem'1[1.7]JelO^gcm230.36012References085808580858085808580858085808580858IsotopicMolecularSpeciesLi6Br81eqQ(Br)Me/secv = 0 v = 1eqQ(Li)Me/secLi7Br 79Li 7Br81ReferencesIsotopicMolecularSpeciesLi 6Br81Li7Br79+37.20-1-30.71 +33.190858Rotationi wJ «-J1+-01*-0Vibrationvgroundground+0.1840858*; p 15/21/2ftFlF"3/23/2vMe/sec38112.72 ±0.1033122.44 ±0.30Intensity cm300° 195°79.E-06 22. £-0521.E-05 61*£-05Ref085808585/23/233130.30 ±0.1064.E-05 I8.fc-043/23/233139.50 ±0.1043.E-05 i2»t-04Li7Br811«-02ground5/21/23/23/232461.52 ±0.1033057.54 ±0.2562.E-07 15.fc-0721.E-05 59.t-03085808585/23/233063.96 ±0.1062.E-05 18.t-043/23/233071.53 ±0.1042.E-05. L2.t-0^11/23/232722.60 ±0.1021.E-06 I7.fc-0608585/23/232729.14 ±0.1062.E-06 51.t-063/23/232737.53 ±0.10^UE-06 3^.fc-0625/23/232397.13 ±0.1062.E-07 15.E-07085847

Lithium iodide 1.3919 AIsotopicMolecularSpeciesLi6 ! 127U 7!127ReferencesAv/pMe/mmVDebye6.25 m0858BeMe/ sec15381.99m13286.78m0858*>ecm'14500858Y01Me/sec15381.44813286.3860858a eMe/sec152.59122.620858Dekc/sec(69.0)(51.5)0858Yekc/sec(610)4550858*elO^gc*238.047990858eqQ(Li)Me/sec+0.1720858IsotopicMolecularSpeciesLi6 !127Li 7 ! 127ReferenceseqQ(I)v = 0-199.43-198.15Me/secv = 1 v = 2-206.8-206.5 -212.60858IsotopicMolecularSpeciesLi6 ! 127Rotationt itJ +-J1+-0VibrationvgroundFiF'5/2Fl11F5/2vMe/ sec30578.28 ±0.10Intensity cm300° 195°54.E-06 16.E-05Ref08587/25/230620.17 ±0.1073.F-06 21.t-0513/27/25/25/230638.10 ±0.1530317.79 ±0.2036.E-06 LO.E-0582.E-07 74.E-070858Li7!1271«-0ground3/25/25/25/230336.40 ±0.4026418.44 ±0.1041.E-07 37. £-0743.6-05 12.E-0408587/25/226460.14 ±0.1058.E-05 17.E-043/25/226477.88 ±0.1029.E-05 83.6-0515/25/226173.72 ±0.1049.E-06 44. £-0608587/25/226217.11 ±0.1065.E-06 59.E-0623/25/25/25/226235.65 ±0.1025931.21 ±0.2033.E-06 29.E-0655.E-07 I6.t-0708587/25/225975.62 ±0.2074.E-07 2UE-073/25/225995.48 ±0.4037.E-07 10. £-0748

NO Nitric oxideoThe electronic state of nitric oxide, like that of the hydroxyl radical, is a nstate with coupling intermediate between Hund's cases (a) and (b). However, since B ismuch smaller than for OH, |K| is much larger and the coupling is more nearly Hund's case(a). (See the discussion of Zp and Qr for the hydroxyl radical.) For +w»(J + 1/2) 2 ,the first order binomial expansion of V(J + 1/2) + w yieldsWhere £ = Vw" + l/(8Vw). Hence,Z =

Hence, the approximationwas used.Since the maximum J value involved in an observed microwave transition is 5/2, Hund'scase (a) provides a rather good approximation for computing V. For the transition J+1+-J,[2: equation 3-40].. o oY = (J + ir-*r(J + 1)(2J + 1)50

Nitric oxide1.1508 A————IsotopicMolecularSpeciesJf140 16N150 16Av/pMe/mmVDebye0.158 mB0Mc/sec50848.42m49043.86m%cm-11904eff 2ni/2Mc/sec50121.1548375.04e\'Veff n3/2Mc/sec51571.6149689.35BeMc/sec51109.5149298.14Do.2>2Mc/sec0.0340.017Do.Kn3/2Mc/sec0.3190.261References17391547990011411547, 11411141114111410992IsotopicMolecularSpeciesN140 16N150 16DoMc/sec0.1770.139Q(N)I0-24 cm20.016*oI0^°gcm216.50517.101hlO^W14.41617.019aecm'10.01810.0171Acm'1122.14eqp(N)Mc/sec-2e 2 Q/3 sin 2y\rXJ22 ± 9 Mc/secReferences11411673114111411141154715471547IsotopicMolecularSpeciesK14 0 16N 150 16ReferencesA -doubling, ^-uncouplingconstants, Mc/secPA' P IA-Y a-H76.15 +1.15 +3216.99+170.45 +0.71 +3224.791141magnetic hfs constantsMc/secabed a-(b+c)/283.82 68.49 - 86.34 112.60 92.74-116.94 -96.63 +122.82 -157.88 -130.031547, 114151

IsotopicMolecularSpeciesM14 0 16K15016References, a + (b+c)/2Mc/aec74,8951547— g in Bohr magnetons**2 n+/2 , j = 1/2 2n-/2 , j = 1/2 2 n*/2 , j = 3/2 2 n~/2 , j = 3/2.0007 + a .0007 - a g + (2/5)a g - (2/5)a1041Footnote: ** a = +0.0025, g = -0.0230. For the n3 / 2 state, see 0809, theoreticaltreatment in 1029, and parameters listed here.IsotopicMolecularSpeciesN140 16RotationI nJ *-J3/2+-1/2VibrationVgroundElectronicX/21 -'5/23/2nFlnF3/21/2VMe/sec150176.30 ±0.25150198.52 ±0.25Intensity cm""300° 195°26.E-06 80.E-0698.E-07 29.E-06Ref11413/23/2150218.57 ±0.2578.E-07 24.E-061/21/2150225.47 ±0.2578.E-07 24.E-062 n-/21/21/23/23/2150245.38 ±0.25150375.02 ±0.2598.E-C8 29.E-0798.E-08 29.E-073/23/2150438.72 ±0.2578.E-07 24.E-065/21/23/23/21/21/2150546.25 ±0.25150580.38 ±0.25150644.11 ±0.2526.E-06 80.E-0678.E-07 24.E-0698.E-07 29.E-065/2^3/2groundX/27/25/25/23/2250435.60 ±0.50250439.20 ±0.50ll.E-05 33.E-0572.E-06 21.E-OS11413/21/2250447.16 ±0.5043.F-06 12.F-055Z

IsotopicMolecularSpeciesN140 16Rotationt nJ +-J5/2«-3/2VibrationVgroundElectronicX/ 22 n~/2'IF'3/25/25/2I!FltfF3/25/25/2vMe/ sec250474.02 ±0.50250481.52 ±0.50250707.12 ±0.50Intensity cm"360° 195°14.F-06 40.F-0614.E-06 40.E-0614.E-06 40.E-06Ref11413/23/2250752.61 ±0.5014.E-06 40*E-067/25/2250794.99 ±0.50ll.E-05 33-E-055/23/2250814.64 ±0.5072.E-06 21.E-055/2«-3/2ground2 n£/23/27/21/25/2250816.24 ±0.50257822.06 ±0.343.E-06 12.E-0544.E-06 97.E-0615475/23/2257852.87 ±0.328.E-06 61.E-063/21/2257867.67 ±0.317.E-06 37.E-062jl3/27/25/2257825.02 ±0.344.E-06 97.F-065/23/2257855.36 ±0.328.E-06 61.E-06N150 163/2«-l/2groundX/23/2111/210257870.35 ±0.3144927.81 ±0.25144946.34 ±0.2517.E-06 37.E-0622.F-09 64.E-0944.F-09 13.F-OB11412n-/22110144976.00 ±0.25145236.09 ±0.25ll.E-08 32.E-0844.E-09 13.E-0821145307.81 ±0.25ll.E-08 32.E-085/2«-3/2ground2nI/21211145428.07 ±0.25241715.40 ±0.5022.E-09 64.E-0931.E-08 91.E-0811412 n~/23221241723.79 ±0.50242046.03 ±0.5049.E-08 14.E-0731.E-08 93*E-0832242060.35 ±0.50•49.E-08 14.E-0753

0 2 Oxygen3 —The ground electronic state of the oxygen molecule is a £ state. The spinS = 1 couples to the angular momentum N of nuclear motion according to Hund f s case (b),yielding three sets of levels for which J = N+l, N, and N-l respectively, where N is zero(in the first case only for which J = S = 1) or a positive integer [5: page 222?. Forintensity computations, the energies may in general be adequately approximated by BK(N + D-X,,BN(N + 1)+0, and BN(N + D-X, for J = N+l, N, and K-l respectively, where X. is approximately60,000 Me/sec; however, for the N = 1, J = 0 level the energy is BN(N + D-2X [2: figure 7-6and equation 7-6], Adding the constant +X. to the previous energies, the Zr values for heter—onuclear molecules are given by Zr exp(+XN(N + 1)) = 2N + 3, (2N + l)exp(-xw), and 2N - 1, except for the additional factor exp(+KW) for the N = 1, J = 0 state. Correcting for the missingtwo N = 0 states and the state of exceptional energy and combining the first and last sets ofstates, the Kulholland approximation yieldsQr = (3 - YMl/X + 1/3 + X/15) + 2XKfor the heteronuclear molecules.For homonuclear molecules, the Pauli exclusion principle must be satisfied for interchange of the nuclei as well as for interchange of electrons. Since the electronic wave function1 fi 1 ftof oxygen is antisymmetric with respect to interchange of the nuclei and the spins of 0 and 0are zero, the statistical weights of O^ 6 and O^ 8 are normal for odd N and zero for even N. Consequently, the heteronuclear Zr t s are multiplied by 1 or 0 for Og 6 and Og 8 , for odd or even N respectively. To the required accuracy, Qr for the (hypothetical) homonuclear molecules is half thatfor the heteronuclear molecules.54

The values of V areandN(2N + 3)/(2N + 1)(N + 1)(N + 1)(2N - l)/tf(2N + 1)for the transitions N, N+l and N, N-l respectively, where the magnetic dipole moment is2 Bohr magnetons [2: equation 7-6 in which the direction of the arrows indicate emission].The resonant frequencies of oxygen are given by»(N, J = N*-N, J = N ± 1) = K Q + fi 0/2 - 6^/2' + n + 2)+[(2n + 1)/B0 + 2B 1 (n 2 -f n6n3 + 13n 2 + lOn + 4) - f(n)whereI) 2 ,[f(n)] 2 = [(2n + 1){(B0 -+B9 (3n4 + 6n3 + 13n 2 + lOn + 4)} - l!tl* J 22n + 12 9 25n + 2)1 f2\n + 2x 1 (n^ + n + 1)]——————Jn = N + 1,and the parameters are given in the molecular constant table under reference number 1958.( The s's in the published expression for f(n) should be entered as 5 f s as above.)55

Oxygen 1.2074 1--©IsotopicMolecularSpecieso 2160»0 16 0 170 160 18ReferencesAv/pMe/mm2.00 a2.00 a2.00 a2.00 a*•M-Deb yeBOMe/sec43100.5 m48488.2 c44406.5 c45794.8 c1958wecm"115809900eqQMe/ sec2.70736BlMe/ sec-0.1.4701958B2Me/sec0±10"51958X 0Me/ sec59501.3321958x iMe/ sec0.05858a: Rough average of several experimental values. See material below on line width parameter.1958»J*Me/ sec-126.29301958IsotopicMolecularSpecieso^ 60»0 160"o 16 o 18u^/2Me/ sec-0.000117Magnetic hfs constantsMe/secb c-102 140^cos2 x-]y 2 r3) av10 24 cnT3-8.9(l/r 3)av10 25 em-34.45¥ 2(o)10 24 cm-31.26AdditionalMicrowaveReferences0172, 0273, 0293,0381,0385, 0409, 0422,0507,0539, 0545, 0650,0736,0752, 0972, 0973,1077,1078, 1120, 1144,1411,1499, 1713, 1744.References19580737073807380738Footnotes: Miscellaneous references on absorption coefficients, high pressure line widths, foreign gasbroadening and line shapes include: 0036, 0049, 0105, 0138, 0139, 0246, 0797, 1036, 1094,1511, 1682, and 1684.** Rough averages of discordant results, where g g , g|, g^, g^ are the splitting factors forthe free electron, the electron spin in the molecule, the molecular electronic orbital moment, and the molecular rotational moment, respectively.Two lines were observed in the range 60,170-60,180 Me/sec and theoretical computation gave60,172 and 60,179 for the respective lines.Frequency reported 60240-250 Me/sec, while theory gave 60250, 60251 for the respective lines.Line width parameter is a weighted average from 0500, 0797, and 1958.56

Line WidthsLinel+3+5+7+9 +ll+13+15+17+19+21+23+Me/mm2.082.031.771.881.681.781.541.771.501.581.26300 °KLine Me/mm1_ 1.973_ 1.945_ 1.827_ 1.849_ 1.8611_ 1.9713_ 1.8615_ 1.9917_ 1.7919_ 1.7721_ 1.2623_ 1.49Values averaged from 1958,0797, 0500, 0855, 1959, 1960193 °K Magnetic Resonance WidthsAv/P in Me/mmTransitionN J M1 1 -1-K)1 2 l-»21 2 0-*11 2 -1-K)3 2 0-»-l3 4 -1-K)5 4 0-*-l5 6 -1-K)Av/P°2at300°K2.35±0.102.20±0.102.23±0.142.00±0.101079Av/P°2 at78 °K6.13±0.36.00±0.25.92±0.36.20±0.15.93±0.35.70±0.36.0±0.55.5±0.3Av/Pair at78 °K6.13±0.36.02±0.36.21±0.26.63±0.36.12±0.3Zeeman constants ##g s' l /a g s — 18^/g sgr/g s-1.6x10^1.5xlO~36.4X10"51959, 1960 , 1078, 0855MolecularIsotopeRotationft M l»1,1-0,13,3«-2,35 , 5*-4 , 57,7«-6,7VibrationvgroundgroundgroundgroundElectF 1 n nFi Fronic32-VV 3zgVMe/ sec118750.5 ±0.562486.255 ±0.01060306.044 ±0.01059164.215 ±0.010Intensity cm"1300° 195°71.E-0? 19.E-06ll.E-06 27.E-0616.E-06 38.E-0619.E-06 40.E-06Ref090019581958195857

IsotopicMolecularSpecieso216° 2180 16 0 17Rotationt I rt nJ,N 4-j,tf9,94-8,911,114-10,1113,134-12,1315,15*-14,1517,174-16,1719,194-18,1923,234-22,2325,254-24,251,14-2,13,34-4,35 , 5^-6 , 57 , 74-8 , 79,94-10,911,114-12,1113,134-14,1315,154-16,1517 f 17*-18 f 1719,19*-20,1921,21*-22,2123,234-24,233,34-4,35,54-6,55 , 54-4 , 57,74-6,74,44-5,45 , O4— D , DVibrationVgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundgroundElect3z;3*;%-%-3*;%-%-3*-K3z;%-**-*^3 *;3\ 3s«^*\^%-5\8se3^3^3z «^3*-sronic'1 F'11/213/25/27/2nFinF13/215/27/29/2VMe/sec58323.885 ±0.01057611.4 ±0.256970.8 ±0.456364.1 ±0.455784.6 ±0.455221.6 ±0.454129.4 ±0.453599.4 ±0.856265.4 ±0.658446.580 ±0.01059590.978 ±0.01060434.776 ±0.01061150.570 ±0.01061800.155 ±0.01062411.223 ±0.01062996.6 ±0.263568.520 ±0.01064128'.0 ±0.864678.2 ±0.265224.120 ±0.258900 ±3359810 ±259875 ±258965 ±259250593985935959431Intensity cm300° 195°19.E-06 36.E-0617.E-06 27.E-0614.E-06 19.E-06ll.E-06 12.E-0676.E-07 64.E-0750.E-07 32.E-0718.E-07 61.E-0897.E-08 23.E-0863.E-07 17.E-0616.E-06 4-1.E-0622.E-06 53»E-0625.E-06 54.E-0626.E-06 48.E-0623.E-06 38.E-0620.E-06 26.E-0615.E-06 16.E-06ll.E-06 93.E-0775.E-07 48.E-0747.E-07 23.E-0728.E-07 96.E-0863.E-12 15*E*1190.E-12 21*E-1160.E-12 15.E-1172.E-12 15.E-1114.E-10 35.E-1018.E-10 43.E-1073.E-11 17.E-1089.E-11 21.E-10Ref1958096009000900090009000900090009001958195819581958195819580900195809000900195804450445044504450737073758

IsotopicMolecularSpecies0 160 17JRotat ionit ft nvr - T -a, a ^\l , Js5,5-6,5VibrationVgroundElectronic3zTFi'•11/2F"'i13/2VMe/sec59627Intensity cm300° 195°13.E-10 31.E-10Ref073713/215/25974816.E-10 37.E-106,6-7,6ground3s~15/27/217/29/2598895979019.E-10 45.E-1090.E-11 20.E-10073711/213/25995612»E-10 28.E-109/211/25986411»E-10 24.E-1013/215/26006015.E-10 33.E-107,7-8,75,5-4,5groundground3*s3 Z~15/29/215/217/211/213/260180601705998917.E-10 38.E-1010.E-10 22.E-1014.E-10 33.E-10073707376,6-5,6ground3z-13/217/211/215/26013059385ll.E-10 27.E-1015.E-10 33.E-10073713/211/25963810. £-10 23.E-107,7-6,7ground3 Z~11/211/29/29/2597375932286.E-11 19.E-1082.E-11 18.E-1007376,6-5,65,5-6,5groundground3 2g"Zg"9/215/29/27/213/211/259390595195951970.E-11 15.E-1012.E-10 28.E-1011*E-10 26.E-10073707375,5-4,57,7-8,7groundground32R3Sg"11/211/29/213/2602456024590.E-11 21.E-1012.E-10 25.E-10073707370160 183,3-4,34,4-5,4O , 5— D , O6,6-5,67,7-6,78,8-7,8groundgroundgroundgroundgroundground3z~3Z~3Z~3 2~3z;3 z~58650 ±259220 ±259685 ±259540 ±259075 ±258670 ±232.E-09 61.E-0939. €-09 95.E-0944.E-09 10.E-0835. £-09 79.E-0937.E-09 80.E-0938. £-09 77. £-0904450445044504450445044559

TsotopicMolecularSpecies0 160 18RotationII M ftJ,N *-J,N9,9*-8,9VibrationvgroundElectronic3zgp; F' FIF" VMe/ sec58310 ±2Intensity cm"300° 195°38.E-09 72.E-09Ref044560

KBr Potassium bromide t,B207IsotopicMolecularSpeciesK39Br 79K39 Br81Av/pMe/mmP-Debye10.41 mBeMc/sec2434.953m2415.081m%cm'1{231}{231}yoiMc/sec2434.9472415.075Y02Mc/sec0.0010.001•Tll«eMc/sec12.13611.987Y21Mc/sec0.0230.022eqQ(K) Mc/secv = 0-5.003-5.002References06840684990006840684068406840684IsotopicMolecularSpeciesK39Br 79K39Br81ReferenceseqQ(K) Mc/secv = 1 v = 2-^4.894 ^4.9150684eqQ(Br) Mc/secv=0 v=l v=2+10.244 +11.224 +12.204+ 8.5550684Footnote: For validity ofcomputed intensities seeintroductory remarks onIsotopicMolecularSpeciesK39Br 79Rotationt 11J «-J1+-0Vibrationvground'13/2F f2nFi3/211F3vMc/sec4854.856Intensity cm300° 195°25.E-08 80. £-08Ref06843/233/234856.588OO.E-08 32.E-075/223/234857.38318.E-09 57.E-095/243/234857.50216.e-07 52.6-075/233/234859.74025.E-08 80.fc-OB1/223/234860.52363.E-Q8 20.fc-0713/223/234830.46382.E-09 14.t-0806843/233/234832.36233.E-08 58.t-085/223/234833.14358.E-10 10.fc-095/243/234833.27052.E-08 93.E-085/233/234835.74382.E-09 14.E-081/223/234836.53020. £-08 36.E-0823/223/234806.15327.E-09 26.fc-0906843/233/234808.24711.6-08 iO.t-0861

Iso topicMolecularSpeciesK^Br79K^Br81RotationjW!*•

IsotopicMolecularSpeciesK^Cl35ic^ci37K^Cl35eqQ(K) Me/secv = 2 v = 3-5.571 -5.511|eqQ(Cl)| Me/secv = 0 v = 1 v=2 v=3

IsotopicMolecularSpeciesK^Cl35Rotation1 "J «-J1*-0VibrationV1*;5/2F'1«Fl3/2F"0vMe/ sec7642.200Intensity cm300° 195*46.E-08 69.E-08Ref07225/223/237642.20030.E-09 46.C-095/233/237642.20043.E-08 64.E-065/243/237642.20027.E-07 41.E-07total intensity37.E-07 55.E-071/213/207643.31615.E-08 23.E-081/223/237643.3161UE-07 16.E-07total intensity12.E-07 18.E-0723/213/207593.83079.E-09 58.E-0907223/223/237593.830ll.E-08 81.fc-093/233/237593.83044.E-08 32.E-08total intensity63.E-08 46.k-083/213/207593.86879.E-09 58.E-093/223/237593.868ll.E-08 81.E-093/233/237593.868V».E-08 32.t-08total intensity63.E-08 A6.t-081/213/207596.34739.E-09 29.E-091/223/237596.34726.E-U8 20.C-08total intensity31*E-06 23.E-0833/213/207547.0732G,E-09 72.fc-1007223/223/237547.07328.E-09 10.t-093/233/237547.073li.E-08 4G.fc-09total intensity16.E-08 58.E-093/213/207547.13620.E-09 72.E-103/223/237547.13628.E-09 10.E-093/233/237547.136ll.E-08 40.t-09total intensity16.E-08 58.E-091/213/207549.569lO.t-09 36.E-1G64

Iso topicMolecularSpeciesK^Cl35Rotation1 nJ +rf1*0VibrationV3'1V2F f2nFx3/2nF3VMe/sec7549.569Intensity cm""1300° 195°71.E-09 25.fc-09Ref0722total intensity8UE-09 29.E-093«-2ground23067.5 ±0.515.E-04 47.E-040938122925.4 ±0.539.E-05 59.E-050938222785.2 ±1.010. £-05 7«.t-060938322644.0 ±2.026»E-06 93.E-07093813*-12ground99929.450 ±.016ll.E-02 33.E-021452K39C1371«-01ground3/203/2099316.456 ±.0167469.37029.E-03 42.E-030. 0.145207223/213/207469.37035.6-08 ll.E-073/223/237469.37049.E-08 15.E-073/233/237469.37020.E-07 62.E-07total intensity28.E-07 88.E-075/213/207470.77653.E-08 17.E-075/223/237470.77635.E-09 li.fc-085/233/237470.77649.E-08 15.E-075/243/237470.77632.E-07 99.E-07total intensity42.E-07 13.E-06V213/207471.91718.E-08 55.E-081/223/237471.91712.E-07 39.E-07total intensityl^.E-07 44.t-0711/213/207426.75446.E-09 69.E-090722V223/237426.75432.E-08 48. £-08total intensity36.E-08 55.E-083«-2ground22410.3 ±1.546.E-05 14.E-040938K^Cl351*-01ground3/203/2022278.0 ±3.07510.55512.E-05 18.E-050. 0.093807223/213/207510.555B2.E-09-25.fc-0865

IsotopicMolecularSpeciesK^Cl36RotationI "J «-J1

IsotopicMolecularSpeciesK39ji27RotationI nJ *>J5«-4Vibrationv1FiF* nFlF" VMe/ sec18129.61 ±0.20Intensity cm"300° 195°34.6-05 64,t-05Ref08586

IsotopicMolecularSpeciesRb85Br79Rotat ionV nJ +39«-8Vibrationvground'i P' WFlnFVMc/sec25596.03 ±0.10Intensity cm"300° 195°75.E-05 25.E-04Ref0858125495.98 ±0.1031.E-05 6!>.6-050858225396.14 +0.1013.E-05 17.fc-050858325296.52 ±0.1054.E-06 4A.E-060858Rb85Br819«-84ground25197.32 ±0.1025268.84 +0.1023.E-06 I2.t-0671.E-05 24.fc-0

IsotopicMolecularSpeciesRb85Cl35Rotationr NJ «-J1«-0Vibrat ionVgroundFi5/2F*3Fl5/2nF4VMe/sec5232.671 ±.002Intensity cm"1300° 195°lA^f-Qil 46.t-0aRef09445/225/215232.750 ±.00213.E-08 43,t-085/245/245232.809 ±.00212.E-C7 3B.t-075/215/215232.889 ±.00231,fc-C8 99,t-0£'7/27/2255/25/2145243.745 ±.0025243.788 ±.0026C.E-08 i.9..fc-0?16. £-07 52.t-077/235/245243.855 ±.02253.E-10 I7*t-097/245/245243.905 ±.00214,fc-08 46. £-083/215/215248.566 ±.00213.E-C8 43.fc-083/235/245248.566 ±.0029C*t-a£ .^.9*E-Q7total intensity1C.E-C7 33.t-073/225/215248.596 ±.002JS.fc-C9 48,£-OS17/225/215216.630 +.002lfi.E-06 29.E-0809447/255/245216.440 ±.00246.8-08 SC.E-Ob7/235/245216.712 ±.00216.F-10 26.E-107/245/245216.752 ±.00242.E-09 7C.I— 093/235/245221.395 ±.00226.E-08 4A.t-083/215/215221.395 ±.0024C.fc-09 6^.E-09total intensity3C.E-C8 5C.fc-083/225/215221.421 ±.0024A.E-10 73.E-1027/225/215189.587 ±.002552. €-09 44.fc-0909447/255/245189.616 ±.0025U.E-08 12.E-087/235/245189.656 ±.002546.E-11 40.fc-ii7/245/245189.681 ±.002512.E-09 ll.t-093/215/215194.306 ±.002512.F-09 I0.fc-0969

IsotopicMolecularSpeciesRb85Cl35RotationjVj"1«-0Vibrat ionV2'13/2F 13nFl5/2nF4VMe/ sec5194.306 ±.0025Intensity cm"1300° 195°7A.E-09 67, t- 09Ref0944Rb87Cl351«-0ground3/233/23total intensity5201.032 +.00289.E-C9 77.E-0947.E-08 15.E-0709443/213/205201.032 ±.00285.E-09 27.E-08total intensity56.E-08 lB.t-075/223/235207.389 ±.00285.E-10 27.E-091/22.3/235212.474 ±.00230. £^08 94.t-081/213/205212.474 ±.00243.E-09 13.E-085/243/23.total intensity5247.332 ±,00234*E-08 11. £-0778.E-08 25.E-07Rbl Rubidium iodide 3.1769 AIsotopicMolecularSpeciesRb85 ! 127Rb87 !127ReferencesAv/pMe/mmP-Debye9.762 c0858B eMe/ sec984.3166m970.7601y0858weem'11470858Y01Me/ sec984.3137970.76010858aeMe/sec3.28063.21350858Yekc/sec2.980858Dekc/sec0.2340858wexecm0.250858JelO-^gcm2513.58830858IsotopicMolecularSpeciesRb85! 127Rotationf "J «-J11«-10Vibrat ionVgroundFliFnFiMFVMe/ sec21617.58 ±0.10Intensity cm300° 195°76.E-05 26.E-04Ref085812-H-ll123503.98 ±0.1048.E-05 ll.e-04085813«-122ground123425.51 ±0.1025547.52 ±0.1025462.28 ±0.1024.E-05 38.t-0512. £-04 42.E-0461.E-05 14.E-04085808580858225377.33 ±0.1030.E-05 48.E-05085870

IsotopicMolecularSpeciesRb85!127Rotationt nJ *-J13*>12VibrationV3»;F' nFinFVMe/sec25292.65 ±0.10Intensity cm*"300° 195°1!>.E-05 16.E-05Ref0858425207.88 ±0.2072.E-06 54.E-060858525123.45 ±0.1035.E-06 lB.b-060858Rb87!12713^-126ground25038.99 ±0.1025196.01 ±0.1017.E-06 6C.E-07V6.E-05 16.E-OA08580858125112.84 ±0.1023.E-05 53*6*050858225029.38 ±0.10il.E-05 IB. £-050858NaBr Sodium bromidez. 5-020 AIsotopicMolecularSpeciesKa 23Br79Na23Br81Av/pMe/mmV-Debye7.959 cB€Me/sec4534.52 m4509.35 mwecm"1{315}{315}Y01Me/sec4534.514509.34aeMe/sec28.2528.06Yefee/sec' kc/sec85±30[84]De7±3(4.13)eqQ(Br)

IsotopicMolecularSpecieslfa23Br79Rotationf "J *-J2«-lVibrationV1Fl F'5/2FInF5/2VMe/ sec17082.5 ±.8Intensity cm""1300° 195°57.E-07 77, £-07Ref0858total intensityll.E-06 15.6-067/25/217963.42 ±.2028.E-06 38.6-065/23/217968.42 ±.2015.E-06 20.6-06total intensity43.6-06 58. £-0627/25/25/23/217856.57 ±.1017856.57 ±.1061.E-07 37.E-0732.E-07 19.E-0708583*-219/27/27/25/2total intensity26952.98 ±.1026952.98 ±.1093.E-07 56.E-0784.6-06 11.6-0558.E-06 78.E-060858total intensity14.E-05 19.6-055/23/23/21/226956.30 ±.3026956.30 +.3038.E-06 51.fc-0624.fc-06 32.E-0629/27/27/25/2total intensity26785.63 ±.1026785.63 ±.1062.6-06 83.t-0618.6-06 ll.fc-0613.6-06 76.6-070858total intensity31.6-06 19.6-065/23/226789.51 ±.3083.6-07 49.6-073/21/226789.51 ±.3052.6-07 31.6-07total intensity13.6-06 80.6-0739/27/27/25/226621.8 ±.826621.8 ±.840.E-07 11.6-0728.6-07 73.6-080858total intensity68.6-07 16.6-0749/27/27/25/226455.8 ±.826455.8 ±.888.6-08 10.6-0860.6-08 71.6-090858Na23Br812«-lground3/27/23/25/2total intensity17971.0 ±.517980.48 ±.2015.6-07 17.6-0833.6-06 lO.t-0512.6-05 38.6-05085872

IsotopicMolecularSpeciesSa 23Br81RotationJ 1^"2«-lVibrationVgroundFlF f5/2it nFi p3/2VMe/sec17980.48 ±.20Intensity cm300° 195°65.E-06 20.E-03Ref0858total intensity19.E-05 58.E-0517/25/217868.49 ±.1027.E-06 37.fc-0608585/23/217868.49 ±.1014.E-06 19. £-06total intensity4KE-06 56.t-063«-219/27/226803.55 ±.1081.E-06 11. £-0508587/25/226803.55 ±.1056.E-06 75.t-06total intensityU.E-0* 19.t-055/23/226806.32 ±.4036.E-06 49.E-063/21/226806.32 ±.4023.E-06 31.E-06total intensity59.E-06 8C.t-0629/27/226639.9 ±.818.E-06 ll.E-0608587/25/226639.9 ±.812.E-06 73.fc-07total intensity30.E-06 18.t-065/23/226643.2 ±.880.E-07 48.fc-073/21/226643.2 ±.850.E-07 30.E-07total intensity13.E-06 77.E-0739/27/226475.0 ±.839. £-07 10.t-0708587/25/226475.0 ±.827.E-07 70.E-08total intensity6^.E-07 17.t-07Nad Sodium chlorideZ.IsotopicHolecularSpeciesNa 23Cl 35Av/pMe/mmM-Debye8.5 mB eMe/sec6537.07 m10 ecm'1[380}Y01Me/sec6536.86aeMe/sec48.28Yekc/sec[145]Dekc/sec(8.60) .eqQ(Na) JeMe/sec lO^Vm2-5.4077.3331AddnlMicroRefs062173

laotopicMolecularSpeciesSa23Cl37ReferencesAv/pMe/mmM-Debye08580858BMe/ sec:-»{380}9900V7-Me/ sec0858aeMe/ sec0858Yekc/sec0858Dekc/sec(8.24)0858eqQ(Na) XeMe/sec10^°gcm2-5.4008580858AddnlMicroRefs09381357IsotopicMolecularSpeciesNa 23 Cl35Na 23Cl37Rotationt nJ «-J2^-17*-62*-!VibrationVground123groundground12'[F' MFlnFVMe/ sec26051.1 ±0.7525857.6 ±0.7525666.5 ±0.7525473.9 ±0.7591170.45 ±0.0425493.9 ±0.7525307.5 ±0.7525120.3 ±0.75Intensity cm"300° 195°18.E-04 52.E-0428.E-05 31.fc-0545.E-06 19. £-0671.E-07 11.6-0773.E-03 21.E-0255.E-05 16. £-0486.E-06 97.E-0614.8-06 58.E-07Ref08580858085808581452085808580858Kal Sodium iodide 2.7115- AIsotopicMolecularSpeciesNa23l 127ReferencesIsotopicMolecularSpeciesNa23 !127ReferencesAv/pMe/mmP-Debye7.993 c0858BeMe/ sec3531.778m0858eqQ(I) Me/secwecm'12869900Y01Me/sec3531.7590858v=0 v=l v=2 v=3-259.87 -264.52 -267.59 -271.030858aeMe/sec19.4390858YeIce/sec46.90858Dekc/sec(2.39)0858eqQ(Na)Me/sec-3.880858IloXcm2143.138085874

IsotopicMolecularSpeciesSa23 !127Rotationt nJ «-J3*-2VibrationVground123F''!3/25/27/211/29/27/23/25/29/27/29/27/29/25/27/211/29/27/25/29/25/27/211/29/27/2nFittFV23/25/29/27/27/23/25/29/25/27/27/29/23/25/29/27/27/25/29/23/25/29/27/27/2VMe/ sec21108.64 ±.2021111.67 ±,2021124.58 ±.2Q21135.35 ±.2021137.49 ±.2021137.49 ±.20total intensity21141.93 ±.2021148.85 ±.2020970.52 ±.2021008.40 ±.2021021.50 ±.2021021.50 ±.20total intensity20854.59 ±.2020879.61 ±.2020892.92 ±.2020903.62 ±.2020906.05 ±.2020906.05 ±.20total intensity20917.89 ±.2020738.98 ±.2020764.43 +.4020777.70 ±.2020788.73 ±.2020791.24 ±.2020791.24 ±.20total intensityIntensity cm"300° 195°98.6-05 30.fc-0498-6-05 30.6-0498.E-05 30.E-0498.E-05 30.E-0498.E-05 30.E-0498.E-05 30.6-0420.E-04 6U6-0498.E-05 30.E-0498.E-05 30.E-0425*6-05 36.E-0525.E-05 36.E-0525.6-05 36.E-0525.6-05 36.E-0549.E-05 73.fc-0562.E-06 44.6-0662.6-06 44.6-0662.E-06 44.6-0662.6-06 44.6-Q662.6-06 44.6-0662.6-06 44.6-0612.6-05 87.6-0662.6-06 44.6-0615.6-06 52.6-0715.6-06 52.6-0715.6-06 52.6-0716.6-06 52.6-0716.E-06 52.6-0716.6-06 52.6-0731.6-06 I0.t-06Ref085808580858085875

IsotopicMolecularSpecies«a23I127RotationjVj"34-2Vibrationv3F*'15/2tlFlIIP5/2vMc/sec20803.00 ±.20Intensity cm300° 195°16.E-06 52.E-07Ref085847/25/220663.68 ±.239.6-07 63.E-08085811/29/220674.43 ±.239.E-07 63.fc-OC9/27/220676.96 ±.239.E-07 63. £-087/27/220676.96 ±.239.6-07 63.t-08total intensity78.E-07 13.E-07TIBr Thallium bromide Z.6f£|IsotopicMolecularSpeciesT1203Br79Tl203Br81Tl205Br79T1205Br81Av/pMe/mmHDeb ye4,49 p4,49 p4.49 p4*49 pBOMc/sec1297.409m1274.382m1293.879m1270.805m°>ecm"1192}192}192}192}aeMe/sec3.9343.8723.9323.824Dkc/sec0.247BoMe/sec1295.4421272.4561291.9121268.894eqQ(Br) Mc/secv=0 v=l v=2124.5103.1125.2 123.8 125,8105.2 104.5 106.2References1732144999001449144914491449IsotopicMolecularSpeciesT1 203Br79T1203Br81Tl 205Br79T1 205Br81ReferenceseqQ(Br) Mc/secv = 3 v = 4132.8 125.8104.1 105.51449AdditionalMicrowaveReferences1035134176

IsotopicMolecularSpeciesT1203Br79RotationjVj"4«-3Vibrationvground'IP f11/2PlF"9/2vMe/sec10362.63 ±0.03Intensity cm300° 195°15.E-07 48.E-07Ref14499/27/210362.63 ±0.0311.6-07 37.E-07total intensity26.E-07 86.E-077/25/210366.24 ±0.0484.E-08 28.E-075/23/210366.24 ±0.0463.E-06 21.E-07total intensity15.E-07 49.E-07111/29/210331.16 ±0.0458.E-08 12.t-0714499/27/210331.16 ±0.0444.E-08 89.E-08total intensity10.E-07 21.fc-079«-8ground23317.65 ±0.1049.E-06 16-t-Ob1425123246.83 ±0.2020.E-06 39.E-061425T1203Br814«-32ground11/29/223175.68 ±0.2010178.87 ±0.0477.E-07 94.E-0714*E-07 45.E-07142514499/27/210178.87 ±0.04IO.E-07 34.t-07total intensity24.E-07 79.E-077/25/210181.86 ±0.0678.E-08 26.E-075/23/210181.86 ±0.0658.E-08 I9.t-07total intensity1*.E-07 45.C-07111/29/210147.89 ±0.0454.E-08 ll.E-0714499/27/210147.89 ±0.0441.E-08 83.fc-08total intensity95.E-08 19.E-079+-8ground22903.48 ±0.1046.E-06 15.E-051425Tl205Br794

IsotopicMolecularSpeciesTl205Br79Rotationt nJ +-J4*-3VibrationV1F*'111/2FlnF9/2VMe/ sec10302.91 ±0.03Intensity cm"1300° 195°14. £-07 28.E-07Ref14499/27/210302.91 ±0.0310.6-07 21. £-07total intensity24. £-07 49.E-077/25/25/23/210306.50 ±0.0310306.50 ±0.0379.E-08 16. £-0759.E-08 12.E-07211/29/2total intensity10271.55 ±0.0314.E-07 28.t-0754.E-08 67.E-0814499/27/210271.55 ±0.0341. £-08 51. £-0837/25/211/29/25/23/29/27/2total intensity10275.20 ±0.0310275.20 ±0.03total intensity10240.21 ±0.0310240.21 ±0.0396.E-08 12. £-0731.E-08 38.fc-0823.E-08 29.E-0854. £-08 67. £-0821.E-08 16. £-0816.E-08 12. £-0814497/25/25/23/2total intensity10243.80 ±0.0310243.80 ±0.0338. £-08 28.E-0812. £-08 92. £-0992.E-09 69.E-09itotal intensity22.E-08 16. £-08411/29/29/27/210208.93 ±0.0310208.93 ±0.03total intensity85.E-09 39.E-0965.E-09 30.E-0915.E-08 68. £-0914497/25/25/23/210212.58 ±0.0410212.58 ±0.0449. £-09 22. £-0936.E-09 17.E-096«-5ground15/213/213/211/2total intensity15502.55 ±0,1015502.55 ±0.1085, £-09 39. £-09ll.E-06 36. £-0691. £-07 30. £-06.142511/29/2total intensity15503.79 ±0.2020.E-06 66.t-0676.E-07 25.t-0678

IsotopicMolecularSpeciesTl205Br79Tl 205Br81Rotation6-5.4*-3Vibrationvgroundground123groundK''9/211/29/27/25/2n*; F7/29/27/25/23/2vHe/ sec15503.79 ±0.20total intensity23254.06 ±0.0523183.49 ±0.1023112.80 ±0.1023042.54 ±0.1010150.36 ±0.0310150.36 ±0.03total intensity10153.41 ±0.0310153.41 ±0.03Intensity cm300° 195°64.E-07 21.t-0614.E-06 46. £-0612.E-05 39.E-0546.E-06 93. £-0618.E-06 22. £-0672.E-07 54. £-0732.E-07 11. £-0625.E-07 81.E-0757.E-07 19. £-0618. £-07 61. £-0714.E-07 46. £-07Ref142514251425142514251449111/29/29/27/2total intensity10119.78 ±0.0310119.78 ±0.0332.E-07 11. £-0613.E-07 26. £-0797.E-08 20. £-071449total intensity22.E-07 45. £-077/25/210122.81 ±0.0373.E-08 15. £-075/23/210122.81 ±0.0355.E-08 11. £-072311/29/27/25/211/29/27/29/27/25/23/29/27/25/2total intensity10089.30 ±0.0310089.30 ±0.03total intensity10092.38 ±0.0310092.38 ±0.03total intensity10058.68 ±0.0310058.68 ±0.03total intensity10061.70 ±0.0313. £-07 26. £-0750.E-08 62. £-0838.E-08 47. £-0889. £-08 11. £-0729.E-08 36*€-0822.E-08 27. £-0851.E-08 62. £-0820.E-08 15.£-0e15.E-08 11. £-0835.E-08 26. £-0811. £-08 86. £-091449144979

IsotopicMolecularSpeciesTl205Br81Rotation4*-3VibrationV3*i F'5/2'IP"3/2VMe/ sec10061.70 ±0.03Intensity cm300° 195°85.E-09 64.E-09Ref1449total intensity20.E-08 15.E-08411/29/210028.30 ±0.0379.E-09 36.E-0914499/27/210028.30 ±0.0360.E-09 27.E-09total intensity14.E-08 63.E-097/25/210031.36 ±0.0445.E-09 21.E-095/23/210031. S6 ±0.0434.E-09 15.E-09total intensity79.E-09 36.t-09511/29/29998.00 ±0.0331.E-09 86.E-1014499/27/29998.00 ±0.0324.E-09 66.E-10total intensity55.E-09 15.E-09611/29/29967.35 ±0.0812.E-09 21.E-1014499/27/29967.35 ±0.089A.E-10 16.E-10total intensity22.E-09 37.E-10711/29/29937.15 ±0.1049.E-10 50.E-1114499/27/29937.15 ±0.1037.E-10 38-t-lltotal intensity86.E-10 89.t-il811/29/29906.80 ±0.1019.E-10 12.E-1114499/27/29906.80 ±0.1015.E-10 92.E-12total intensity34.E-10 2UE-11911/29/29876.60 ±0.1576.E-11 29.E-1214499/27/29876.60 ±0.1558.E-11 22.E-12total intensity13.E-10 51.E-129-8ground22839.75 ±0.10ll.E-05 36. £-051425122771.22 ±0.20V3.E-06 86.E-06142510-9ground25377.53 ±0.05li>.E-05 49.E-05142580

T1C1Thallium chlorideIsotopicMolecularSpeciesT1203C135T1203C137T1 205C1 35T1205C137Av/pMe/ mmM-Deb ye4.444 mBeMe/ sec2743.913m2617.498m2739.978m2613.548mwecm-1{287}{287}{287}[287}eqQ(Cl)Me/ sec-15.8-15.79-11.75tteMe/ sec11.95011.17511.92011.145Dkc/sec1.112B oMe/sec2737.9552611.9272734.0352608.027AdditionalMicrowaveReferences0518134112691035^~References0518144999001449,1425144914491449IsotopicMolecularSpeciesT1203 C1 35Rotationj'+-j"2*-lVibrationvgroundF'*i7/2FlF"5/2vMe/sec10952.16 ±0.03In-tensity cm300° 195°38.E-07 12.E-06Ref14495/23/210952.16 ±0.032G.E-07 61.fc-07total intensity58.t-07 I8.fc-0617/25/210904.36 ±0.0394.E-08 14.E-0714495/23/210904.36 ±0.0349.E-OB 73.E-OBtotal intensity14.E-07 21.E-074*-3ground21903.16 ±0.2075.E-06 23.E-0514255*-4ground11/211/227376.62 ±0.1022.E-07 67.E-07142513/211/227379.49 ±0.1047.E-06 14.E-0511/29/227379.49 ±0.1038.E-06 12.6-059/27/227379.49 ±0.1030.E-06 9^.t-067/25/227379.49 ±0.1024.E-06 7!>.t-06total intensityIA.E-05 43.E-05113/211/227260.18 ±0.1012.E-06 17.E-06142511/29/227260.18 ±0.1094.E-07 14.E-069/27/227260.18 ±0.1076.E-07 ll.b-067/25/227260.18 ±0.106l*E-07 89*E-07total intensity35.E-06 Sl.fc-0681

IsotopicMolecularSpeciesT1203C135Rotationt MJ «-j5*-4VibrationV2F'>i13/2nFii?F11/2vMe/ sec27140.35 ±0.10Intensity cm"300° 195°29.E-07 20.h-07Ref -142511/29/227140.35 ±0.1024.E-07 I6.t-079/27/227140.35 ±0.1019.E-07 13.E-077/25/227140.35 ±0.1015.E-07 ll.fc-07total intensity87.E-07 61. £-07T1203C1372"-lground7/25/210447.98 ±0.06ll.E-07 33. £-0714495/23/210447.98 ±0.0656.E-08 17.t-07total intensity16.E-07 50.E-0717/25/210403.28 ±0.0627.E-08 41.t-0814495/23/210403.28 ±0.0614.E-08 22.L-08total intensity42.E-08 63.t-084«-3ground20895.33 ±0.102UE-06 65.t-061425120806.64 ±0.3054.E-07 82.t-071425T1 205C1355«-424-1groundground7/25/226119.36 ±0.1010936.48 ±0.0241.E-06 I3.t-0590.E-07 28.lr-06142514495/23/210936.48 ±0.02A7.E-07 15.t-06total intensity14.E-06 42.t-063/23/210939.30 ±0.022A.E-07 74.t-0717/25/210888.80 ±0.0322.E-07 33.t-0714495/23/210888.80 ±0.0312.E-07 17.t-07total intensity34.E-07 50.E-0727/25/210841.66 ±0.^356.E-08 39.t-0814495/23/210841.66 ±0.0329.fc-08 21.fc-08total intensity85.E-08 60.E-084«-3ground21872.16 ±0.1018.E-05 55.t-0514255

IsotopicMolecularSpeciesT1205C137Rotation1 MJ +-J2*-!VibrationVground'I F'7/2ftFlF"5/2vMe/sec10432.38 ±0.06Intensity cm300° 195°25.E-07 78.C-07Ref14495/23/210432.38 ±0.0613.E-07 *l.t-07total intensity38.E-07 12.fc-063/23/210434.48 ±0.0667.E-08 21.t-0717/25/210387.80 ±0.1265.E-08 98.t-OB14495/23/210387.80 ±0.123

IsotopicMolecularSpeciesT1 2Q5F19Rotat'ion» »J «-J1^-0VibrationV1'1F 1 11FlItFVMe/sec13244.92 ±0.04Intensity cm300° 195°59.t-07 50.E-07Ref14492«-l2ground13155.78 ±0.0626669.76 ±0.1060.E-08 15.E-0647.L-05 13.E-0414491425126489.86 ±0.2047.E-06 40.E-061425Til Thallium iodide 2.813SA0--OIsotopicMolecularSpeciesT1 203 I 127T1 205 r 127ReferencesAv/pMe/mmM-Debye4.60 p4.60 p1732B eMe/ sec817.510 m814.460 m1449wecm" 1{150}{150}9900a eMe/ sec1.981.9891309, 1449eqQ(I)Me/ sec-523-436.81309, 1449Dkc/sec0.0561449AdditionalMicrowaveReferences10351341IsotopicMolecularSpeciesT1 203-[ 127Rotationj'«-j"6*-511*-10Vibrationvgroundground12F lP*15/2F iF"13/2VMe/ sec9801.20 ±0.0517963.217919.217875.8Intensity cm~300° 195°13.t-07 4

IsotopicMolecularSpeciesT1205I127Rotation1 MJ «-J5*-46^510*-9VibrationVground12ground1groundF**;13/215/215/29/211/27/213/217/215/219/217/215/2ttFiMF11/213/213/27/29/25/211/215/213/217/215/213/2VMe/ sec8138.66 ±0.038117.06 ±0.038097.22 ±0.059755.55 ±0.049757.30 ±0.039758.18 ±0,039761.27 ±0.029763.27 ±0.029764.52 ±0.039734.016268.26 ±0.1016268.26 ±0.1016268.26 ±0.10Intensity cm""300° 195°18.E-07 60.fc-07ll.E-07 25.6-0751.E-08 81.t-0fl17.6-07 58.E-0721.t-07 71.t-0714.E-07 48.t-072i».t-07 86.fc-0736.E-07 12.E-0630.E-07 LO.t-0675.E-07 17.fc~06ll.fc-06 37.t-0697.E-07 33.E-0687.E-07 30.t-06Ref14491449144914491309142525/223/221/223/221/219/2total intensity16270.38 ±0.1016270.38 ±0.1016270.38 ±0.1029.E-06 OO.fc-0615.E-06 50.t-0613.E-06 ^5.fc-0fe12.E-06 ^»l.t-06119/217/215/217/215/213/2total intensity16228.26 ±0.1016228.26 ±0.1016228.26 ±0.1040.E-06 14. £-0552.E-07 12.E-0647.E-07 11. £-0642.E-07 98.E-071425total intensity14.E-06 33.t-0625/223/221/223/221/219/216230.50 ±0.1016230.50 ±0,1016230.50 ±0.1071.E-07 17.t-0664.E-07 l^.b-0658*E-07 13.E-0623total intensity16191.416152.019.E-06 45.E-0617.E-06 26.t-0681.E-07 87.t-071309130985

IsotopicMolecularSpeciesT1205 ][ 127Rotation"""134-12154-14164-15174-16VibrationVground12groundgroundgroundground12F'•i25/223/221/231/229/227/229/227/225/235/233/231/235/2MFlftF23/221/219/229/227/225/227/225/223/233/231/229/233/2VMe/sec17896 tO17852.817809.221148.78 ±0.0521148.78 ±0.0521148.78 ±0.05total intensity21149.81 ±0.1021149.81 ±0.1021149.81 ±0.10total intensity24402.36 ±0.1024402.36 ±0.1024402.36 ±0.10total intensity24403.14 ±0.1024403.14 ±0.1024403.14 ±0.10total intensity24403.20 ±0.1026029.54 ±0.3027655.37 ±0.1027588.22 ±0.2027520.39 ±0.20Intensity cm"1300° 195°95.E-06 32. £-0546.E-06 li.E-0522.E-06 35. £-0624.E-06 82.E-0622.E-06 76. £-0621.E-06 70.E-0667.E-06 23.E-0531.E-06 IO.E-0528.E-06 96. £-0626.E-06 89. £-0685.E-06 29.E-0537.E-06 13. £-0535.E-06 12. £-0533.E-06 11. £-05IO.E-05 36.E-0546.E-06 16. £-0543.E-06 15. £-0540.E-06 14. £-0513.E-05 44. £-0546.E-06 16. £-0529.E-05 97. £-0534. £-05 12. £-0417*E-05 38. £-058CUE-06 12. £-05Ref13091309130914251425142514251425142586

Table 2.Casimir's Function andHyperfine IntensitiesCasimir's function is given by the expressionf=[3C(C+l)/4:-where C=F(F + 1) -1(1 + 1) -J(J+1) and I, J, and F are theangular momentum quantum numbers. The hyperfine intensitiesH(I, J', F' ; I, J", F") are defined under Computation of Intensities. Both f and H are given for 1 = 1/2 to 9/2 in steps of 1/2and for J=0 to 10 in steps of 1/2 and 11 to 20 in steps of 1.

I1/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/21/2J01/21/2113/23/2225/25/2337/27/2449/29/25511/211/26613/213/27715/215/26817/217/299F1/2103/21/2215/23/2327/25/2439/27/25411/29/26513/211/27615/213/28717/215/29819/217/2CASIMIFTSFUNCTION•000000.000000•000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000J + l — JF + \+~f.666667.625000.250000.600000.333333.583333.375000.571429.400000.562500.416667.555556.428571.550000.437500.545455.444444.541667.450000.538462.454545.535714.458333.533333.461538.531250.464286.529412.466667.527778.468750.526316.470588.525000.472222.523810.473684F^ F.333333.125000.066667.041667.028571.020833.015873.012500.010101.008333.006993.005952.005128.004464.003922.003472.003096.002778.002506F- \+~ FJ *~ JF*-F+ 1F + 1*- F.250000.111111.062500.040000.027778.020408.015625.012346.010000.008264.006944.005917.005102.004444.003906.003460.003086.002770F«- F.500000.555556.222222.562500.312500.560000.360000.555556.388889.551020.408163.546875.421875.543210.432099.540000.440000.537190.446281.534722.451389.532544.455621.530612.459184.528889.462222.527344.464844.525952.467128.524691.469136.523546.47091489

06£9180**000051*18*1£Z*518*1**£65Z60*65Z611*OOOOZ**££££80*19991**1£01£0*01£01£*01Z18**009115*ZZ598**£91Z15*95158**£81Z15*868*8**69*£15*0£6£8**££Z*15*0£8Z8**880515*01518**Z50915*01108**1*1115*00*81**00*815*U£91**6*8615*£Z6£1**Z*51Z5*005Z1**005ZZ5*4 -+ 4000050*Z58150*000080*111111*96Z96Z*565000*159000*0£1000*918000*816000*1*0100*681100*Zl£100*009100*068100*89ZZOO*005ZOO*J -»l > dr -~ r195000*850100*ZZZZOO*955500*615810*linn*d-l-J1IZ1ZO*1£01£0*1€01£0*££££50*££££50*££££80*££€£80*8*18*1*££££££*195000*5Z9000*£69000*Z11000*998000*816000*Z11100*11ZIOO*18*100*6£1100*010ZOO*£^00-J •*• J19991**OOOOOZ*96Z96Z*199991*00008Z*mm*00005Z*19999**581581*000005*955555*50818**8Z9115*61118**S61Z15*98*98**1Z8Z15**1158***15£15*8*8*8**98Z*15*118£8**Z51515*651Z8**6Z1915*18*18**00008**615815*19Z81**OOOOZ5*06191**00051**1Z1ZZ5*J^» + Jr-~i + r5Z1810*OOOOSZ*00005Z*-6Z*110*00005Z*-OOSZ90*000005*00005Z*-000050*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*000000*NOUDMHJZ/l1z£Z/lZ/£Z/50 IzZ/lZ/£1Z/6£Z/l*Z/l£Z/6£Z/5£Z/l€Z/££Z/5£Z/l£Z/££Z/6ZZ/l£Z/1ZZ/6ZZ/5ZZ/1ZZ/£ZZ/5ZZ/1ZZ/£ZZ/61Z/1Z6 01JZ/5ZZ zZ/€Z/£111z/tZ/l0ozoz61618181111191915151*1*1£1£1ZlZl11110101Z/61Z/61riii ii ii iiii i iZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lZ/lI

11 1 1 11 1111L11I111i1 11i11L1111111111I111111J5/25/23337/27/27/24449/29/29/255511/211/211/266613/213/213/277715/215/215/288817/217/217/2999F5/23/24329/27/25/254311/29/27/265413/211/29/276515/213/211/287617/215/213/298719/217/215/210 98CASiMlR-SFUNCTION-.250000.218750.083333-.250000.200000.087500-.250000.187500.090909-.250000.178571.093750-.250000.171875.096154-.250000.166667.098214-.250000.162500.100000-.250000.159091.101563-.250000.156250.102941-.250000.153846.104167-.250000.151786.105263-.250000.150000.106250-.250000.148438.107143-.250000.147059J+ I

IJ19/219/219/2F21/219/217/2CASIMIR-SFUNCTION.107955-.250000.145833F + l^ F.363636.330310.300000J+ I^JF +• F.003023.003023F - \~ F.000007J +~ JF «-F -f IF + 1*- F.003326.003324F*- F.363341.326683.29667611111 1 111 11110101011 111112121213131311109121110131211141312.108696-.250000.144737.110000-.250000.142857.111111-.250000.141304.112069-.250000.140000.362319.330579.301587.360000.331019.304348.358025.331361.306667.356322.331633.308642.002755.002755.002315.002315.001972.001972.001701.001701.000006.000004.000003.000002.003017.003016.002516.002515.002130.002130.001827.001826.362062.327300.298571.359803.328302.301833.357870.329074.304537.356198.329680.3068161 11141414151413.112903-.250000.138889.354839.331852.310345.001481.001481.000002.001584.001583.354738.330166.3087611 11151515161514.113636-.250000.137931.353535.332031.311828.001302.001302.000001.001386.001386.353453.330561.3104421 11161616171615.114286-.250000.137097.352381.332180.313131.001153.001153.000001.001223.001223.352312.330887.3119081 111 11171717161818191919181716191817201918.114865-.250000,.136364.115385-.250000.135714.115854-.250000.135135.351351.332305.314286.350427.332410.315315.349593.332500.316239.001029.001029.000923.000923.000833.000833.000001.000001.000001.001088.001087.000973.000973.000876.000876.351293.331158.313198.350378.331387.314342.349551.331581.3153631 13/22020202120193/2.116279-.250000.134615.348837.332577.317073.000756.000756.000000.000793.000793.348801.331748.3162800.000000.500000.333333.1666673/23/21/21/2215/23/2,000000.000000.437500.156250.156250.156250.031250.062500.312500.312500.0625003/23/211.050000-.200000.400000.210000.090000.106667.010000.016667.150000.350000.04444492

I3/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/2J13/23/23/23/22222 5/25/25/25/233337/27/27/27/244449/29/29/29/25 55511/211/211/211/2666613/213/213/2F1/232107/25/23/21/24321 9/27/25/23/2543211/29/27/25/265 4313/211/29/27/2765415/213/211/29/2876CASIMIFTSFUNCTION.250000.062500-.187500.062500.312500.071429-.178571.000000.250000.078125-.171875-.031250.218750..083333-.166667-.050000.200000.087500-.162500-.062500.187500.090909-.159091-.071429.178571.093750-.156250-.078125.171875.096154-.153846-.083333.166667.098214-.151786-.087500.162500.100000-.150000-.090909.159091.101563-.148438-.093750J+l-*-JF + I«-F.083333.375000.233333.131250.062500.357143.244896.160000.100000.343750.251116.178571.125000.333333.254630.191327.142857.325000.256667.200521.156250.318182.257851.207407.166667.312500.258523.212727.175000.307692.258876.216942.181818.303571.259027.220353.187500.300000.259048.223161.192308.296875.258984.225510F*- F.083333.058333.072917.056250.040816.052245.040000.030134.039063.029762.023148.030234.022959.018333.024062.018229.014876.019590.014815.012311.016250.012273.010355.013693.010331.008830.011692.008814.007619.010099.007608.006641.008809.006633F- !

i3/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/23/2J13/2777 715/215/215/215/28 8 8817/217/217/217/29 99 919/219/219/219/210101010111111111212121213131313141414 F517/215/213/211/298 7 619'/217/215/213/210 9 8 721/219/217/215/21110 9823/221/219/217/225/223/221/219/227/225/223/221/229/227/225/223/231/229/227/2CASIMIR-SFUNCTION.156250.102941-.147059-.096154.153846.104167-.145833-.098214.151786.105263-.144737-.100000.150000.106250-.143750-.101563.148438.107143-.142857-.102941.147059.107955-.142045-.104167.145833.108696-.141304-.105263.144737.110000-.140000-.107143.142857.111111-.138889-.108696.141304.112069-.137931-.110000.140000.112903-.137097-.111111J+ I

IJ3/2 143/2 153/2 153/2 153/2 1503/2 163/2 163/2 163/2 163/2 173/2 173/2 173/2 173/2 183/2 183/2 183/2 183/2 193/2 193/2 193/2 193/2 203/2 203/2 203/2 202 0222222222222222221/21/2F25/233/231/229/227/235/233/231/229/237/235/233/231/239/237/235/233/241/239/237/235/243/241/239/237/225/23/2CASlMlfrSFUNCTION.138889.113636-.136364-.112069.137931.114286-.135714-.112903.137097.114865-.135135-.113636.136364.115385-.134615-.114286.135714.115854-.134146-.114865.135135.116279-.133721-.115385.134615.000000.000000.000000F + I*- F.224138.272727.256112.240472.225806.271429.255846.241128.227273.270270.255600.241701.228571.269231.255372.242205.229730.268293.255161.242653.230769.267442.254964.243053.231707.466667.400000.140000J+ !

I22J5/25/2F3/21/2CASlMl^SFUNCTION.078125.218750F + l — F.102857.066667J+ I—JF *• F.030476F - 1^ FJ *- JF *-F + IF + »— F.054857.035556F*- F.042921.0311112222222222333337/27/27/27/27/25432111/29/27/25/23/2.083333-.125000-.091667.050000.200000.087500-.118750-.100000.031250.187500.288889.220000.163690.119048.085714.280000.220606.171111.130952.100000.024444.035357.034722.023810.019394.028283.027937.019048.000952.001786.001587.000606.001111.000952.031429.044643.042857.028571.024242.034921.034014.022857.282857.181071.112500.071429.057143.275758.190837.131066.093129.0771432222222222444449/29/29/29/29/26543213/211/29/27/25/2.090909-.113636-.105519.017857.178571.093750-.109375-.109375.007813.171875.272727.220606.176485.140000.111111.266667.220280.180496.147071.120000.015758.023111.022909.015556.013054.019224.019100.012929.000404.000727.000606.000280.000496.000404.019259.028000.027500.018519.015664.022920.022626.015238.269630.197185.144500.109537.092593.264336.201416.154454.122136.1047622222225555576543.096154-.105769-.112179.000000.166667.261538.219780.183566.152727.127273.010989.016234.016154.010909.000200.000350.000280.012987.019091.018909.012727.259740.204286.162000.132000.114545222211/211/2U/211/211/215/213/211/29/27/2.098214-.102679-.114286-.006250.162500.257143.219194.185968.157343.133333.009377.013886.013832.009324.000147.000254.000200.010940.016138.016020.010774.255726.206255.167842.139872.1225592222226666687654.100000-.100000-.115909-.011364.159091.253333.218571.187881.161172.138462.008095.012009.011973.008059.000110.000188.000147.009341.013815.013736.009231.252198.207614.172449.146264.129231222213/213/213/213/213/217/215/213/211/29/2.101563-.097656-.117188-.015625.156250.250000.217941.189429.164396.142857.007059.010487.010462.007033.000084.000143.000110.008067.011956.011902.007992.249076.208548.176142.151535.134865222277779876.102941-.095588-.118213-.019231.247059.217320.190699.167143.006209.009236.009217.006190.000065.000110.000084.007037.010446.010408.246296.209183.179145.15594196

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17/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/2J5/25/25/23 333333 7/27/27/27/27/27/27/27/24 44 4 V 4449/29/29/29/29/29/29/29/255 55 5 55511/211/211/211/211/211/211/2F3 2113/211/29/27/25/23/21/27654 321015/213/211/29/27/25/23/21/28 7 6 5 4 32117/215/213/211/29/27/25/23/29 8765 43CAS»MIR*SFUNCTION-.022321.078125.167411•083333-.071429-.097619-.047619.035714.119048.178571.087500-.062500-.098214-.062500.008929.087500.151786.187500.090909-.055195-.097403-.071892-.009276.065399.132653.178571.093750-.049107-.095982-.078125-.022321.049107.118304.171875.096154-.043956-.094322-.082418-.032051.036630.107143.166667.098214-.039541-.092602-.085459-.039541.026786.098214J+ I^JF + l*- F.073661.040923.016741.222222.168269.123106.085979.056122.032738.014881.212500.166667.127604.094792.067708.045833.028646.015625.204545.164848.130536.101240.076599.056277.040000.027778.197917.162997.132468.106061.083523.064631.049242.037500.192308.161199.133741.109736.089002.071387.056818.045455.187500.159493.134572.112588.093407.076923.063101F

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I7/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/2J99 9 9999919/219/219/219/219/219/219/219/21010101010101010111111111111111112121212121212121313131313131313F25/223/221/219/217/215/213/211/213121110 9 8 7 627/225/223/221/219/217/215/213/229/227/225/223/221/219/217/215/231/229/227/225/223/221/219/217/233/231/229/227/225/223/221/219/2CASIMIFTSFUNCTION.107143-.020408-. 082533-. 093037-.064526-.008403.065126.147059.107955-.018669-.081439-.093344-.066288-.011093.062500.145833.108696-.017081-.080418-.093576-.067833-.013485.060150.144737.110000-.014286-.078571-.093878-.070408-.017551.056122.142857.111111-.011905-.076950-.094030-.072464-.020876.052795. 141304.112069-.009852-.075517-.094089-.074138-.023645.050000.140000J+ 1— JF + I— F.166667.150429.135461.121733.109220.097910.087807.078947.164773.149476.135329.122307.110390.099567.089844.081250.163043. 148587.135178.122794.111418.101043.091673.083333.160000.146983.134843.123565.113138. 103556.094823.086957.157407.145575.134489.124137.114513.105611.097436.090000.155172.144331.134133.124568.115632.107321.099638.092593F *• F.004333.007344.009097.009648.009035.007265.004298.003934.006673.008274.008781.008225.006612.003906.003587.006090.007557.008024.007518.006042.003565.003017.005131.006374.006775.006350.005100.003003.002573.004381.005448.005794.005431.004360.002564.002220.003784.004709.005011.004698.003770.002214F - l~ F.000053.000123.000179.000198.000166.000088.000044.000101.000148.000162.000135.000071.000037.000085.000123.000134.000111.000058.000026.000060.000087.000095.000078.000040.000019.000044.000063.000068.000056.000028.000015.000033.000047.000051.000041.000021J — JF^F + If + !48.100119.090 06.082/37.076 > 74.162738.144171.127137.113; 33. 102084.092352.084760.079444.159764.1433?2.128815.116171.105337.096288.089045.083701.157221. 142493.129396.117878. 107901.099449.092539.087237.155022.141701.129775.119203.109960.102033.095436.090218109

17/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/27/2J14141414141414141515151515151515161616161616161617171717171717171816181818181818191919191919191920F35/233/231/229/227/225/223/221/237/235/233/231/229/227/225/223/239/237/235/233/231/229/227/225/241/239/237/235/233/231/229/227/243/241/239/237/235/233/231/229/245/243/241/239/237/235/233/231/247/2CASIMIR'SFUNCTION.112903-.008065-.074245-.094086-.075525-.025986.047619.138889.113636-.006494-.073108-.094044-.076691-.027989.045567.137931.114286-.005102-.072087-.093976-.077683-.029724.043779.137097.114865-.003861-.071165-.093893-.078536-.031239.042208.136364.115385-.002747-.070330-.093799-.079278-.032575.040816.135714.115854-.001742-.069569-.093700-.079927-.033760.039575.135135.116279J+ I

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14444449/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/2J20202020202001/21/21113/23/23/23/2222225/25/25/25/25/25/233333337/27/27/27/27/27/27/27/24444F2120191817169/25411/29/27/2654313/211/29/27/25/276543215/213/211/29/27/25/23/2876 5 432117/215/213/211/2CAS«MIR*SFUNCTION-.085404-.086411-.061174-.013529.052885.134615.000000.000000.000000.050000-.133333.091667.062500-.104167-.052083.114583.071429-.083333-.083333.005952.130952.078125-.067708-.091146-.039063.049479.143229.083333-.055556-.091667-.061111.005556.083333.152778.087500-.045833-.089583-.072917-.020833.045833.110417.160417.090909-.037879-.086580-.079545J+ I

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I9/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/29/2J18181818181919191919191919191920202020202020202020 F35/233/231/229/227/247/245/243/241/239/237/235/233/231/229/249/247/245/243/241/239/237/235/233/231/2CASIMIR-SFUNCTION-* 072 344-.040293.007051.066667.135714.115854.020325-.042710-.076961-.085970-.073116-.041612.005493.065315.135135.116279.021318-.041741-.076401-.086017-.073792-.042785.004100.064103.134615J+I

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0049 Hershberger, W. D. , J. Appl. Phys. 17. 495(1946)The absorption of microwaves by gases.0051 Kellogg, J. B. M. ; Millman, S., Revs. Mod. Phys. 18,323 (1946); Molecular beam magnetic resonance method.Radiofrequency spectra of atoms and molecules.O (plus severalothers)H2(MB)0053 Pur cell, E. M. ; Pound, R. V. ; Bloembergen, N. , Phys.Rev. 70, 986 (1946); Nuclear magnetic resonance absorption.19470080 Hughes, H. K. , Phys. Rev. 72, 614 (1947); The electricresonance method of radiofrequency spectroscopy. Themoment of inertia and electric dipole moment of CsF.CsF (MB)0105 Van Vleck, J. H. , Phys. Rev. 71, 413(1947); Theabsorption of microwaves by oxygen.0109 Weidner, R. T. , Phys. Rev. TL, 1268 (1947); Microwavespectra of IC1 at 4. 5 cm. wavelength.19480112 Bardeen, J. ; Townes, C. H. , Phys. Rev. 73, 627(1948)ICN, quadrupole splitting.0127 Gordy, W. , Revs. Mod. Phys. 2£, 668(1948); Microwavespectroscopy.0138 Lamont, H. R. L. , Phys. Rev. 74, 353 (1948); Atmospheric absorption of microwaves.0139 Lamont, H. R. L. , Proc. Phys. Soc. 6^, 562(1948)Atmospheric absorption of millimetre waves.0158 Strandberg, M. W. P. ; et al, MIT Research Lab. Electronics (Oct. 1948)0162 Townes, C. H. ; Merritt, F. R. ; Wright, B. D., Phys.Rev. 7_3, 1249 (1948)0163 Townes, C. H. ; Merritt, F. R. ; Wright, B. D. , Phys.Rev. 7_3, 1334 (1948)0165 Weidner, R. T. , Phys. Rev. 73, 254 (1948); IC1, purerotational transition.19490172 Beringer, R. ; Castle, J. G. , Jr., Phys. Rev. 75, 1963(1949); Microwave magnetic resonance absorption in oxygen.0173 Beringer, R. ; Castle, J. G. , Jr., Phys. Rev. 76, 868(1949); Zeeman effect in NO.IC1IC1, ICN,BrCN hyper finereview of severalmoleculesC»°V H2°OCS,OCSe, CsIC1, rotationIC1, rotationIC1°zNO125

0190 Gilbert, D. A. ; Roberts, A. ; Griswold, P. A., Phys. FC1Rev. 76, 1723 (1949); Nuclear and molecular informationfrom the microwave spectrum of FC1.0195 Gordy; Gilliam; Livingston, Phys. Rev. 76, 443(1949) I, CH IMicrowave spectrum of I ,1OZOO Hicks, B. L. ; Ossofsky, E. ; Jones, R. N., Ballistics OHRes. Lab., Tech. Note 130, Nov. (1949); Free radicalsand microwave spectroscopic techniques.0202 Hughes, V. ; Grabner, L. ; Rabi, I. I., Phys. Rev. 76, RbF (MB)8 S 87471 (1949); Radio frequency spectrum of Rb F, Rb F.0207 Kusch, P., Phys. Rev. 75, 887 ( 1949); Molecular LiBr, LiCl, LiF,6 Lil(MB)hyperfine structure Li .0208 Kusch, P., Phys. Rev. 76, 138 (1949); Sign of quadrupole Li , LiBr, Na ,moment in Li. {MB)0209 Kusch, P., Mann, A. K. , Phys. Rev. 76_, 707 (1949) LiBr, Lil, (MB)Precision measurement of the ratio of the nuclear g7 6values of Li and Li .0217 Loubser; Townes, Phys. Rev. 76, 178 (1949); Spectroscopy HI, H Nbetween 1. 5 and 2 mm. wave-length using magnetron harmonics.0246 Strandberg, M. W. P; Meng, C. Y. ; Ingersoll, J. G. Q ZPhys. Rev. 75, 1524 (1949); Microwave absorption spectrum of O .0252 Trischka, J. W. , Phys. Rev. 7^, 1 365 (1949); The moment CsF (MB)of inertia and electric dipole moment of CsF from radiofrequencyspectra.19500263 Beringer, R. ; Castle, J. G. , Jr., Phys. Rev. 78, 340 NO(1950); Microwave magnetic resonance spectra of NO.0264 Beringer, R. ; Castle, J. G. , Jr., Phys. Rev. 78, 581 NO(1950); Magnetic resonance absorption in NO..0268 Bleaney, B. , Research _3» 490 (1950); Spectroscopy at Reviewcentimeter wave lengths.0271 Burkhalter, J. H, ; Anderson, R. S. ; Smith, W. V. ; OGordy, W. , Phys. Rev. 77, 152 (1950); Fine structureof microwave spectrum of O .0272 Burkhalter, J. H. ; Anderson, R. S. ; Smith, W. V. ;Gordy, W. ; Phys. Rev. 79, 224 (1950); Fine structure of O126

0273 Burkhalter, J. H. ; Anderson, R. S. ; Smith, W. V.;Gordy, W. ; Phys. Rev. 79, 651 (1950); The fine structureof the microwave absorption spectrum of oxygen.0284 Gilbert, D. A. ; Roberts, A., Phys. Rev. 77, 742(1950)Nuclear and molecular information from the microwavespectrum of FC1.0285 Gilliam, O. R. ; Johnson, C. M. ; Gordy, W. , Phys. Rev.78, 140 (1950); Microwave spectrum in the region from2- 3 mm.0291 Grabner, L. ; Hughes, V., Phys. Rev. 79^, 819(1950)39The radio frequency spectrum of K F by the electricresonance method.0292 Henry, A. F. , Phys. Rev. 79^, 213(1950)0293 Henry, A. F. , Phys. Rev. .80, 396 (1950); The Zeemaneffect in oxygen.0294 Henry, A. F. , Phys. Rev. 8£, 549 (1950); Hyperfinestructure of Zeeman levels in nitric oxide.0296 Hughes, V. ; Grabner, L. , Phys. Rev. 79_, 314(1950)Or Q "7The radio frequency spectrum of Rb F and Rb F byelectric resonance method.FC1CO, CH 3F, ICNKF (MB)°zNORbF (MB)0305 Klages, G. , Experientia £, 321 (1950); Absorption of Reviewmicrowaves in gases and liquids (a general review).0306 Kolsky, H. G. ; Phipps, T. E. , Jr. ; Ramsey, N. F. , Jr. ; H (MB)Silsbee, H. B. ; Phys. Rev. 79_, 883(1950).0307 Kolsky, H. G. ; Phipps, T. E. , Jr. ; Ramsey, N. F. , Jr. ; H (MB)Silsbee, H. B. ; Phys. Rev. 8£, 483(1950)0323 Maier, W. , Z. Elektrochem. 54, 521 (1950); Microwave Reviewspectra and molecular structure.0332 Mizushima, M. , Busseiron kenkyu 29_, 25 (1950); The width Reviewof microwave absorption bands of gases.0333 Mizushima, M. , Phys. Rev. 77_, 150(1950) H Z (IR)0362 Smith, D. F. ; Tidwell, M. ; Williams, D. V. P. BrFPhys. Rev. 77, 420 (1950); Microwave spectrum ofBrF.0363 Smith, D. F. ; Tidwell, M. ; Williams, D. V. P. BrClPhys. Rev. 79, 1007 (1950); Microwave spectrum of BrCl.0374 Wilson, E. B. , Jr., Faraday Soc. Discussion _9, 108 Review(1950); Determination of molecular structure with microwavespectroscopy.127

0375 Woodward, Nature 165, 198 (1950); Induced molecularvibrational and rotational absorption.0376 Zeiger, H. ; Bolef, D. ; Rabi, I. I. , Phys. Rev. 78, 34035 37(1950); Molecular beam spectrum of T1C1 and T1C1at zero fields.HC1T1C1 (MB)19510379 Anderson, R. S. , Thesis, Duke U. (1951)0380 Anderson, R. S. ; Johnson, C. M. ; Gordy, W., Phys.Rev. 83, 1061 (1951); Resonant absorption of oxygen at2. 5 millimeter wavelength.0381 Anderson, R. S. ; Smith, W. V. ; Gordy, W. , Phys. Rev.82, 264 (1951); Line breadths of the fine structure of themicrowave spectrum of oxygen.C>0385 Beringer, R. ; Castle, J. G. , Jr. , Phys. Rev. 81, 82(1951); Microwave magnetic resonance spectrum of oxygen.0386 Brown, S. C. , Phys. Rev. 82, 568 (1951); Breakdown inhydrogen at 100-Me. frequency.0397 Ewen, H. I. ; Purcell, E. M. , Phys. Rev. _83, 881 (1951)Radiation from hyperfine levels of interstellar hydrogen.0402 Frosh, R. A. ; Foley, H. M. , Phys. Rev. 82,, 337(1951)The hyperfine spectra of diatomic molecules.0408 Gokhale, B. V. ; Strandberg, M. W. P. , Phys. Rev. 82,327 (1951); Microwave absorption spectrum of oxygen.NO, O , hyperfineLiC>0409 Gokhale, B. V. ; Strandberg, M. W. P. , Phys. Rev. 8,4,844 (1951); Linebreadths in the 5 mm. microwave absorptionof O^.0411 Grabner, L. ; Hughes, J. V., Phys. Rev. £2, 561(1951) RbF (MB)Further evidence for a two quantum transition in molecularspectroscopy.1738 Greenhow, C. ; Smith, W. V., J. Chem. Phys. _19_, 1298 O^(1951); Molecular quadrupole moments of N and O .Lt £>0413 Hill, R. M.; Smith, W. V., Phys. Rev. £2, 451 (1951) CO, NOMicrowave collision diameters and associated quadrupolemoments.0422 Johnson, C. M. ; Trambarulo, R. ; Gordy, W. , Phys. Rev.84, 1178 (1951); Microwave spectroscopy in the region fromtwo to three millimeters. II' C°128

0425 Karnaugh, M. ; Margenau, H. , Phys. Rev. B2,, 342(1951) NOTheory of magnetic resonance in NO0427 Kolsky, H. G. ; Phipps, T. E. , Jr. ; Ramsey, N. F. , Jr. ; H (MB)Silsbee, H. B. ; Phys. Rev. 81, 1061 (1951); Deuteronquadrupole moment and the radiofrequency spectra of Hand D- in low magnetic fields.0437 Luce, R. G. ; Trischka, J. W. , Phys. Rev. 82, 323(1951) CsCl(MB)Radiofrequency spectra of CsCl.0445 Miller, S. L. ; Javan, A.; Townes, C. H. , Phys. Rev. 82, O10 —— ^454 (1951); O spin.0446 Miller, S. L. ; Javan, A. ; Townes, C. H. , Phys. Rev. 83, O18209 (1951); O spin.0462 Ramsey, N. F. , Jr., Physica 17, 388 (1951); Radiofrequency H (MB)spectra of H and D by a new molecular beam resonancemethod.0487 Trischka, J. W. ; Swartz, J. C. ; Luce, R. G. , Phys. Rev. CsF (MB) Stark83, 881 (1951); A new electric-field design for the molecu- effectlar beam electri-resonance method.0489 Weber, J. ; Phys. Rev. 83, 881 (1951); Microwave collision Hdiameters.0497 Wilson, E. B. , Jr., Ann. Rev. Phys. Chem. 2 t 151 (1951) ReviewMicrowave spectroscopy of gases.19520500 Anderson, R. S. ; Smith, W. V. ; Gordy, W. , Phys. Rev. C87, 561 (1952)0502 Artman, J. O. ; Gordon, J. 16 P., Phys. Rev. — 87, 227(1952) OPressure broadening of O lines in the millimeter wavelength region.0507 Beringer, R. ; Ann. N. Y. Acad. Sci. 56, 814(1952) O , NOMicrowave resonance absorption in paramagnetic gases.0508 Beringer, R. ; Rawson, E. B. , Phys. Rev. 86, 607 NO(1952); Lambda-doubling in a microwave spectrum.0514 Boyd, D. R. J. ; Thompson, H. W. , Spectrochim. Acta HI (IR)_5, 308 (1952); The fundamental vibration band of hydrogeniodide.0516 Bray, P. J. ; Barnes, R. G. ; Harrick, N. J. , Phys. Rev. H (MB)87 3 229 (1952); Magnetic moment ratios in hydrogen-likemolecules.129

0518 Carls on, R. O. ; Lee, C. A. ; Fabricand, B. P., Phys.Rev. 85, 784 (1952); The molecular beam electric resonancemethod study of thallium monochloride.0527 Duchesne, J. ; J. Chem. Phys. 20, 1804 (1952); Nuclearquadrupole coupling constants and molecular vibrations.0536 Fabricand, B. P. ; Carlson, R. O. ; Lee, C. A. Jr. ;Rabi, I. I., Phys. Rev. 86, 607 (1952); The rotationalspectrum of potassium chloride.0539 Frosch, R. A. ; Foley, H. M. , Phys. Rev. J38, 1337(1952); Magnetic hyperfine structure in diatomic molecules.T1C1 (MB)KC1KC1 (MB)NO,0545 Gordy, W. ; Ann. N. Y. Acad. Sci. 55_, 774(1952)Microwave spectroscopy above 60 kMc.0549 Harrick, N. J. ; Barnes, R. G. ; Bray, P. J. , Phys.Rev. 85, 716 (1952); Quadrupole moment of the electrondistribution in the hydrogen molecule.0565 Jones, L. C. ; Bushkovitch, A. V. ; Potter, C. A. ;Rouse, A. G. , Jr. ; Phys. Rev. 87, 227 (1952); Variationof collision diameters with mix ratio in binary mistures inmicrowave pressure broadening.0583 Miller, S. L. ; Kotani, M. ; Townes, C. H., Phys. Rev.86, 607 (1952); Magnetic hyperfine structure in the oxygenmolecule.°2* HeC>0597 Ramsey, N. F. , Jr. ; Phys. Rev. 85, 60 (1952); Theoryof molecular hydrogen and deuterium in magnetic fields.0598 Ramsey, N. F. , Jr. ; Phys. Rev. 87, 1075(1952)Vibrational and centrifugal effects on nuclear interactionsand rotational moments in molecules.centrif. dist, vib.*rot. hyperfine0601 Roberts, F. F. ; Proc. Phys. Soc. 65B, 460 (1952)Microwave Faraday rotation in liquid oxygen.0607 Salpeter, E. E. ; Newcomb, W. A., Phys. Rev. 87,150 (1952); Mass corrections to hyperfine structure.0619 Smith, W. V. ; Ann. N. Y. Acad. Sci. 55, 891 (1952)Pressure broadening.1728 Stitch, M. L. ; Honig, A. ; Townes, C. H. , Phys. Rev.86, 607 (1952); High temperature microwave spectroscopy -spectrum of KC1, T1C1.0621 Stitch, M. L. ; Honig, A. ; Townes, C. H. , Phys. Rev.86, 813 (1952); Microwave spectroscopy at high temperaturespectra of CsCl and NaCl.KC1, T1C1CsCl, NaCl130

0622 Swartz, J. C. ; Trischka, J. W. , Phys. Rev. 88, 10856 19(1952); Radiofrequency spectra of Li F by the molecularbeamelectric-resonance method.0628 Trischka, J. W. ; J. Chem. Phys. 2Q_, 1811 (1952); On theinternuclear distance and dipole moment of the LiF molecule.LiF (MB)LiF0637 Wieland, K. ; Waser, J. , Phys. Rev. 8J3, 385 (1952); Themolecular spectrum of iodine excited in the presence of aninert gas.19530649 Arnowitt, R. ; Phys. Rev. 92, 1002 (1953); The hyperfinestructure of hydrogen.1732 Altshuller, A. P. ; J. Chem. Phys. 2J_, 2074(1953)Dipole moments of gaseous thallous halides.0650 Artman, J. O. ; Gordon, J. P. , Phys. Rev. 20, 338(1953); Pressure broadening of oxygen lines in the millimeter wave-length region.0654 Bates, D. R. ; Poots, F. , Proc. Phys. Soc. 66A, 784(1953); Properties of the hydrogen molecular ion. I.Quadrupole transitions in the ground electronic state anddipole transitions of the isotopic ions.0671 Burrus, C. A. ; Gordy, W. , Phys. Rev. 92_, 1437(1953)One-to-two millimeter wave spectroscopy III. NO and DI.H, H ZTIBr, Til4NO, HI0679 Dieke, G. H. ; Cunningham, S. P. ; Byrne, F. T. , Phys.Rev. 92, 81 (1953); The Zeeman effect in the molecularspectra of hydrogen.H ,Zeeman0684 Fabricand, B. P. ; Carlson, R. O. ; Lee, C. A, ; Rabi, I. I.Phys. Rev. 9_1, 1403 (1953); The rotational levels of KBrand their hyperfine structure.0693 Harrick, N. J. ; Barnes, R. B.; Bray, P. J. ;Ramsey, N. F. , Jr. ; Phys. Rev. 90, 260 (1953); Nuclearradiofrequency spectra of D and H in intermediate andstrong magnetic fields.0699 Honig, A. ; Stitch, M. L. ; Mandel, M. , Phys. Rev. 92,901, (1953); Microwave spectra of CsF, CsCl, CsBr.0716 Klein, J. A. ; Nether cot, A. H. , Jr., Phys. Rev. 90.*1018 (1953); Microwave spectrum of DI and 1. 5 mm.wavelength.0721 Kusch, P. ; Phys. Rev. 92, 268 (1953); Sign of quadrupoleinteraction.KBr (MB)H 0 (MB)CsF, CsCl, CsBrHILiCl (MB)131

0722 Lee, C. A. ; Fabric and, B. P.; Carlson, R. O.jRabi, I. I. , KC1 (MB)Phys. Rev. 91, 1395 (1953); Molecular-beam investigationof rotational transitions. I, The rotational levels of KC1and their hyperfine structures.0736 Miller, S. L. ; Univ. Microfilms, Pub. No. 4585, Disserta- Otion Abstracts 13, 110 (1953); The microwave absorptionspectrum of oxygen,0737 Miller, S. L. ; Townes, C. H. , Phys. Rev. 9£, 537(1953) Q ZThe microwave absorption spectrum of O and O Oz0738 Miller, S. ; Townes, C. H. ; Kotani, M. , Phys. Rev. 90, O542 (1953)0741 Mizushima, M. ; Phys. Rev. £1, 222 (1953); On the frequen- QZcies of the microwave absorption lines of oxygen.0752 Poots, G. ; Proc. Phys. Soc. 66A, 1181 (1953); The effect QZof variation of the dipole moment with internuclear separationon the relative intensities of the second negative band systemof oxygen.0757 Ramsey, N. F. , Jr., Phys. Rev. 89^, 527 (1953); Psuedo- H^quadrupole effect for nuclei in molecules.0758 Ramsey, N. F. , Jr. ; Science 1 \1_, 470 (1953); Electron HZ (MB)distribution in molecular hydrogen.0764 Sanders, T. M. ; Schawlow, A. L. ; Dousmanis, G. C. ; OHTownes, C. H. ; Phys. Rev. 89, 1158 (1953); A microwave spectrum of the free OH radical.0775 Tate, P. ; Strandberg, M. W. P. , Phys. Rev. 9_1_, 464 KC1, NaCl(1953); Stark effect in high temperature microwave spectroscopy.0792 Wimett, T. F. ; Phys. Rev. 9J., 476 (1953); Nuclear H Zresonance line structure in HD and molecular shieldingin HD, H , and D .0793 Wolfsberg, M. ; J. Chem. Phys. 2j_, 2166 (1953); Note on N Za nitrogen molecule calculation.19540797 Artman, J. O. ; Gordon, J. P. , Phys. Rev. 96, 1237 O(1954); Absorption of microwaves by oxygen in the millimeter wave-length.0803 Barnes, R. G. ; Bray, P. J. ; Ramsey, N. F. , Jr., Phys. HRev - 94, 893 (1954); Variations of hydrogen rotationalmagnetic moments with rotational quantum number andwith isotopic mass.132

0804 Basov, N. G. ; Prokhorov, A. M. , Zhur. Eksptl. Teoret.Fiz. 27, 431 (1954); Application of molecular clusters toradiospectroscopic study of rotational spectra of molecules.0807 Bemski, G. ; Nierenberg, W. A. ; Silsbee, H. B. , Phys.Rev. 94, 767 (1954); Spin-orbit interaction in RbF and CsF.0812 Birnbaum, G. ; Maryott, A. A., Phys. Rev. 95, 622(1954)Microwave absorption in compressed gases.0832 Dousmanis, G. C. ; Phys. Rev. 94, 789 (1954); Microwavespectrum of the free OD radical.0839 Gallagher, J. J. ; Bedard, F. D. ; Johnson, C. M. , Phys.14 16Rev. 93, 729 (1954); Microwave spectrum of N O .0843 Gordy, W. ; J. Chem. Phys. _22, 1470 (1954); Relation ofnuclear quadrupole couplings to the chemical bond.0844 Gordy, W. ; J. Phys. Radium 15, 521 (1954); Spectroscopyfrom 1 to 5 mm. wavelength.0845 Gordy, W. ; Burrus, C. A., Phys. Rev. 9j, 419(1954)Spectrum of DBr in the one-millimeter wave region.1741 Henry, A. F. ; Beringer, R. ; Rawson, E. B. , Phys. Rev.94, 343 (1954); Microwave resonance in nitric oxide: Adoubling and hyperfine structure.CsF (MB)CsF, RbFHBr, HC1OHNOReviewReviewHBrNO0855 Hill, R. M. ; Gordy, W. , Phys. Rev. 9J5> 1019(1954)Zeeman effect and line breadth studies of the microwavelines of oxygen.0857 Honig, A. ; Mandel, M. ; Stitch, M. L. ; Townes, C. H.Phys. Rev. 93, 953 (1954); Alkali halides.0858 Honig, A. ; Mandel, M. ; Stitch, M. L. ; Townes, C. H.Phys. Rev. 96, 629 (1954); Microwave spectra of thealkali halides.0860 Ishiguro, E. ; Koide, S. , Phys. Rev. 94, 350(1954);Magnetic properties of the hydrogen molecules.0885 Liuima, F. A. ; Bushkovitch, A. V. ; Rouse, A. G.Phys. Rev. 96, 434 (1954); Pressure broadening ofOCS in foreign gas mixtures.0890 Marple, D. T. F. ; Thesis, Syracuse U. (1954); Radio-6frequency spectra of Li Gl by the molecular-beamelectric-resonance method.0895 Meyers, R. J. ; Gwinn, W. D. , Ann. Rev. Phys. Chem.385 (1954); The microwave spectra of gases.Lil, LiBralkali halidesH 2He, 02LiCl (MB)Review133

0898 Mizushima, M. ; Phys. Rev. 94, 569 (1954); Theory of NOthe hyperfine structure of NO molecules.0899 Mizushima, M. ; Phys. Rev. 94, 789 (1954); Theory of NOthe hyperfine structure of NO molecules.0900 Mizushima, M. ; Hill, R. M. , Phys. Rev. 9_3, 745(1954) QZMicrowave spectrum of O .L*0917 Sanders, T. M. , Jr. ; Schawlow, A. L. ; Dousmanis, G. C. ; HOTownes, C. H. ; J. Chem. Phys. 22, 245 (1954); Examinationsof methods for detecting OH.0920 Schneider, E, E. ; Phys. Rev. 9J3» 919 (19 54); Hyperfine LiFstructure in the paramagnetic resonance of X-rayed LiF.0933 Stoicheff, B. P.; Can. J. Phys. _32, 630 (1954); High- NZresolution Raman spectroscopy of gases. III. Ramanspectrum of nitrogen.0938 Tate, P. A. ; Strandberg, M. W. P., J. Chem. Phys. 2,2, NaCl, KC11380 (1954); Stark effect in the microwave spectra of potassiumchloride and sodium chloride.0941 Tinkham, M. ; Strandberg, M. W. P., Phys. Rev. 9J3, O^622 (1954); Selection rules in the microwave magneticresonance spectrum of O .o0944 Trischka, J. W. ; Braunstein, R. , Phys. Rev. 96.' 968 RbCl (MB)(1954); Rotational spectra of RbCl by the molecular beamelectric resonance method.0955 Aamodt, L. C. ; Fletcher, P. C. , Phys. Rev. 98, 1224 COSe, Se(1955); Spin, quadrupole moment, and mass of SE?519550965 Barrett, A. H. ; Mandel, M. , Phys. Rev.

0972 Carrara, N. ; Universita di Firenze (Italy). Tech. Rept. ONo. 7_ - Fundamental research on electromagnetic theoryand microwave spectroscopy. May 14, 1955; Study ondependence from pressure of the absorption lines of Oin the 2 cm region - absorption spectrum of the molecule16of oxygen O in the microwave region - Part I.0973 Carrara, N. ; Universita di Firenze (Italy). Tech. Rept. ONo. 11 - July 6, 1955; Study on dependence from pressureof the absorption lines of O in the 2 cm~ 1 region - absorp-16tion spectrum of the molecule of oxygen O in the microwaveregion - Part II.0980 Dousmanis, G. C. ; Phys. Rev. 97.* 967 (1955); Magnetic NOhyperfine effects and electronic structure of NO.0981 Dousmanis, G. C. ; Phys. Rev. 98, 1160 (1955); Magnetic NOhyperfine effects and electronic structure of NO.0982 Dousmanis, G. C. ; Sanders, T. M. , Jr. ; Townes, C. H. HOPhys. Rev. 100, 1735 (1955); Microwave spectra of freeradicals OH and OD.0992 Gallagher, J. J. ; King, W. C. ; Johnson, C. M. , Phys. NORev. 98, 1551 (1955); The microwave spectrum of N O .1017 Ketelaar, J. A. A. ; Colpa, J. P. ; Hooge, F. N., J. Chem. HPhys. 23, 413 (1955); Pure rotational absorption spectrumof hydrogen.1029 Lin, C. C. ; Mizushima, M. , Phys. Rev. 100, 1726(1955) NOTheory of hyperfine structure of NO molecule. II. Errataand some additional discussion.1035 Mandel, M. ; Barrett, A. H. , Phy. Rev. j?8, 1159(1955) TIBr, T1C1, T1F,Pure rotational spectra of the thallium halides. Til1036 Maryott, A. A. ; Birnbaum, G. , Phys. Rev. 99, 1886 O(1955); Microwave absorption in compressed oxygen.1041 Mizushima, M. ; Cox, J. T. ; Gordy, W. , Phy. Rev. NO98, 1034 (1955); Zeeman effect in the rotational spectrumof NO.1042 Mockler, R. C. ; Bird, G. R. , Phys. Rev. 98.* 1837 CS(1955); Microwave spectrum of carbon monosulfide.1045 Nethercot, A. H. , Jr. ; Rosenblum, B. , Columbia CORadiation Lab. Rept., May 31, 1955, Millimeter wavespectroscopy of CO.1046 Ninomiya, M. ; J. Phys. Soc. Japan 10, 829 (1955); Ro- CrOtational analysis of CrO bands.135

1061 Rosenblum, B. ; Nethercot, A. H. , Jr.; Phys. Rev. 97,84 (1955); Microwave spectra of tritium iodide and tritiumbromide.HBr, HI1062 Schwartz, C. ; Phys. Rev. 9JL' 380 {1955); Theory of hyper- Ga, Infine structure.1064 Sheridan, J. ; Research 8^ 88 (1955), Microwave spectroscopyof gases.Review1077 Tinkham, M. ; Strandberg, M. W. P.; Phys. Rev. 97,937 (1955)1078 Tinkham, M. ; Strandberg, M. W. P. ; Phys. Rev. 97,951 (1955)1079 Tinkham, M. ; Strandberg, M. W. P. ; Phys. Rev. 99_,537 (1955); Line breadths in the microwave magneticresonance spectrum of O .C>1080 Tomita, K. ; Phys. Rev. 98, 1197 (1955); On the rotationaltransition in solid H .1731 White, R. L. ; Revs. Mod. Phys. £7, 276 (1955); Magnetichyperfine structure due to rotation in £ molecules.FC11094 Willshaw, W. E. ; Lament, H. R. L. ; Hickin, E. M. ; Proc.Inst. Elec. Engrs. , London, 102, Part B No. 1(1955)Experimental equipment and techniques for a study ofmillimetre-wave propagation.1098 Zhabotinskii, M. E. ; Uspekhi Khim. 24, 730(1955)Radiospectroscopy and structure of molecules.Review19561106 Barrett, A. H. ; Univ. Microfilms, Pub. No. 16270,Dissertation Abstracts 16, 1153 (1956); Microwave spectraof InCl, InBr, Ini, GaCl.1107 Battaglia, A. ; Gozzini, A. ; Bruin, F. ; Arch. sci. _9, 68(1956); Measurements on some absorbing gases as a functionof pressure at a wave length of 32 mm.InCl, InBr, Ini,GaClReview1120 Carrara, N. ; Nuovo Cimento Suppl. 4^, Series 10, 1593(1956); Molecular spectroscopy of oxygen by means ofmicrowaves. The shape of the absorption lines.1124 Cowan, M. ; Gordy, W. ; Duke U. Microwave Lab. (1956)Further extension of microwave spectroscopy in the submillimeterwave region.1125 Cowan, M. ; Gordy, W. ; Phys. Rev. 104, 551(1956)Further extension of microwave spectroscopy in the submillimeterwave region.HI, COCOS, HI, CO136

1127 Cox, J. T. ; Gordy, W. ; Phys. Rev. 101, 1298(1956) COZeernan effect of some linear and symmetric-top molecule.1132 Dousmanis, G. C. ; Univ. Microfilms, Pub. No. 16804, HO(1956); Microwave spectra of OD, and of OH in II , state.1141 Gallagher, J. J. ; Johnson, C. M. ; Phys. Rev. 103, 1727 NO(1956); Uncoupling effects in the microwave spectrum ofnitric oxide.1143 Genzel, L. ; Klier, M. ; Z. Physik 144, 25 (1956); LiFSpektraluntersuchungen im gebiet um 1 mm wellenlange.III. Dispersionsmessungen am LiF.1144 Ghosh, S. N. ; Edwards, H. D. ; AF Surveys in Geophysics O , CO82 (1956); Rotational frequencies and absorption coefficientsof atmospheric gases.1162 Hulthen, E. ; Neuhaus, H. ; Phys. Rev. 102, 1415 (1956) BiHMagnetic hyperfine structure in bismuth hydride and deuteride.1192 Mandel, M. ; Barrett, A. H. ; Bull. Am. Phys. Soc. J^ GaBr, GaCl, Gal284 (1956); Microwave spectra of GaCl, GaBr, Gal.1193 Marple, D. T. F. ; Trischka, J. W. ; Phys. Rev. 103, LiCl (MB)597 (1956); Radio-frequency spectra of Li^Cl by themolecular beam electric resonance method.1198 Miescher, E. ; Helv. Phys. Acta 29_, 135 (1956); Rota- NO (UV)tional analysis of NO"*" bands*1199 Miescher, E. ; Helv. Phys. Acta 29_, 401 (1956); Rota- NO (UV)tional analysis of the B' band (B |2 A - XZII) of the NOmolecule.1203 Mizushima, M. ; NBS Report 5016 (1956); Theory of the NOStark effect of NO molecule.1205 Nethercot, A. H. , Jr. ; Rosenblum, B. ; Columbia HIRadiation Lab. Rept. , June 15, 1956; Millimeter wavespectroscopy.1210 Ninomiya, . M. ; J. Phys. Soc. Japan 11, 970 (1956); Rota- HOtional intensity distribution of the OH band.1217 Perkins, K. L. ; Bushkovitch, A. V. ; Kieffer, L. J. He, QZBull. Am. Phys. Soc. J_, 13 (1956); Foreign gas pressurebroadening of OCS.1227 Rosenblum, B. ; Nethercot, A. H. , Jr. ; Bull. Am. Phys. COSoc. _1_, 13 (1956); Microwave determination of carbon andoxygen mass ratios.137

1235 Solomon, I. ; Bloembergen, N, ; J. Chem. Phys. 25,261 (1956); Nuclear magnetic interactions in the HF molecule.1239 Stevenson, M. J. ; Columbia Radiation Lab. Kept. , June 15,1956; Microwave spectroscopy of free radicals.1244 Trischka, J. ; J. Chem. Phys. 2_5, 784 (1956); Electricdipole moments of the lower vibrational states of molecularCsF and CsCl.HFHN, HSCsF, CsCl (MB)19571269 Barrow, R. F. ; Proc. Phys. Soc. ^70, 632 (1957); Therotational analysis of the bands of the A II + -X'ZJ+ systemof T1C1. °T1C11284 Cowan, M. J. ; Gordy, W. ; Bull. Am. Phys. Soc. 2^212 HC1(1957); Submillimeter wave spectroscopy: DC1.1291 Ehrenstein, G. ; Stevenson, M. J. ; Columbia Radiation Lab. HO5th Quarterly Prog. Report (1957); Microwave spectroscopyof free radicals.1306 Gordy, W. ; Cowan, M. J. ; Bull. Am. Phys. Soc. 2, 212 CO(1957); Precision measurement of millimeter and sub-millimeterwave lines of CO.1309 Happ, H. ; Z. Physik 147, 567 (1957); Microwave spectrum Til, Bid,of thallium (I) iodide and bismuth chloride in the 3-cm. - and1. 5-cm. -band.1320 Jones, L. H. ; Goldblatt, M. ; J. Mol. Spectroscopy J^ 43(1957); Infrared spectrum and molecular constants of gaseoustritium fluoride.1341 Mandel, M. ; Univ. Microfilms, Pub. No. 21639, Dissertation Abstracts 17, 1676 (1957) Microwave spectra ofthe thallium halides, GaBr, and Gal.1349 Mizushima, M. ; Phys. Rev. 105, 1262 (1957); Theory ofthe hyper fine structure of NO (nitric oxide) molecularelectronic structure.HF (IR)GaBr, Gal, T1C1,TIBrNO1357 Peter, M. ; Strandberg, M. W. P. ; Research Lab. Elec- NaCltronics, MIT, Tech. Rept. 336 (1957); Theoretical andexperimental study of molecular-beam microwave spectroscopy.1361 Quinn, W. E. ; Baker, J. M. ; L Tourrette, J. T. ; HRamsey, N. F. , Jr. ; Bull. Am. Phys. Soc. 2,, 200(1957); Radio-frequency spectrum of hydrogen deuteride.1362 Ramsey, N. F. , Jr.; Lewis, H. R. , Phys. Rev. 108, H (MB)1246 (1957); Theory of hydrogen deuteride in magnetic fields.138

1363 Richardson, J. M. ; Bull. Am. Phys. Soc. 2, 318(1957)Experimental evaluation of the oxygen microwave absorptionas a possible atomic frequency standard.1365 Rosenblum, B. ; Nethercot, A. H. , Jr. ; Bull. Am. Phys.Soc. 2, 44 (1957); Nuclear mass ratios and magnetic effectsin CO71367 Rosenblum, B. ; Nethercot, A. H. , Jr. ; J. Chem. Phys.27, 828 (1957); Quadrupole coupling constant and molecular17structure of CO1368 Russell, A. M. ; Univ. Microfilms, Pub. No. 21928,Dissertation Abstracts 17, 1790 (1957); Rotational magnetic6 ~moments of Li F and Li F.1368 Russell, A. M. ; Phys. Rev. 106, 1100 (1957); Rotational/ 7magnetic moments of Li F and Li F.1370 Schlier, C. ; Z. Physik 147, 600 (1957); Measurement ofthe hyperfine structure of potassium fluoride with the molecular beam resonance method.1383 Stevenson, M. J. ; Bull. Am. Phys. Soc. _2, 31(1957)The quadrupole moment of O1386 Stoicheff, B. P.; Can. J. Phys. 35, 730 (1957); Highresolution Raman spectroscopy of gases. IX. Spectraof H , HD, and D .L* L*1392 Thomas, L. F. ; Heeks, J. S. ; Sheridan, J. ; Arch. Sci.10, 180 (1957); Studies of conjugation and hyper-conjugationin several molecules by microwave spectroscopy.1411 Wilcox, "W. S. ; Southern Research Inst. , Birmingham,Alabama. Final tech. rept. Feb. 27, 1957. Oxygenanalysis by microwave absorption measurements.1414 Zahn, C. T. ; NBS Tech. Rept. - Final Rept., Dec. 31,1957. Microwave absorption of gases.19581425 Barrett, A. H. ; Mandel, M. ; Phys. Rev. 109, 1572(1958); Microwave spectra of the Tl, In, and Ga monohalides.1432 Blaser, J. P. ; Bonanomi, J. ; Nature 182, 859 (1958)Comparison of NH maser with Cs atomic frequencystandard.COCOLiF (MB)LiFKF (AB)co,H 2 (R)Review°2ReviewT1F, T1C1, TIBr,Til, InCl, InBr,Inl, GaCl, GaBr,GalH N, Cs (maser)(AB)139

1434 Boudouris, G. ; Ilias, D. ; Comptes rendues 246, 730 (1958)Microwave absorption of some gaseous solutions.NH + A,NH + CH Cl1435 Boudouris, G 0 ; Ilias, D. ; Comptes rendues 246, 1407 (1958)Measurements of the absorption of microwaves by binarygaseous mixtures.1436 Burrus, C. A. ; J. Chem. Phys. 2S_, 427 (1958); Starkeffect from 1. 1 to 2. 6 mm. wavelength: PH PD , DICO. *1739 Burrus, C. A. ; Graybeal, J. D. ; Phys. Rev. 109, 1553(1958); Stark effect at 2.0 and 1.2 millimeters wavelength:nitric oxide.NH + NH C HO £ £NH C H + AL* L* !DHP, HI, CONO1438 Colpa, J. D. ; Ketelaar, J. A. A. ; Molecular Phys. j_,343 (1958); Pressure-induced rotational absorption spectrumof hydrogen. II,1440 Cowan, M. ; Gordy, W. ; Microwave Lab. , Duke U.Precision measurements of millimeter and submillimeterwave spectra: DC1, DBr, and DI. Aug. 1, 1958.1441 Cowan, M. ; Gordy, W. ; Phys. Rev. Ill, 209 (1958); Precision measurements of millimeter and submillimeter wavespectra: DC1, DBr, DI.1449 Fitzky, H. G. ; Z. Physik 151, 351 (1958); The microwaverotation spectrum of thallium (I) halides.1452 Garrison, A. G. ; Univ. Microfilms, Pub. No. 2732,Dissertation Abstracts 19, 546 (1958); Millimeter wavespectroscopy of molecular beams at high temperature.1454 Graff, G. ; Paul, W. ; Schlier, Ch.; Z. Physik 153, 38(1958); Measurement of the hyperfine structure of T1F bymeans of the molecular-beam-resonance method.HC1, HBr, HIHC1, HBr, HIT1C1, Til, TIBr,T1FReviewT1F (MB)1463 Hurle, I. R. ; Sugden, T. M. ; J. Sci. Instr. 3JJ, 319 CS(1958); Microwave spectrometer for study of free radicals(results presented for CS. )1486 Mizushima, M. ; Phys. Rev. 109, 1557 (1958); Theory of NOthe Stark effect of the NO molecule.1492 Pannetier, G. ; Guenebaut, H. ; Bull. Soc. Chim. France1958, 1463; The rotational structure of the 0, 1 and 1, 0HNbands of the NH radical in the II- S transition.1497 Quinn, W. E. ; Baker, J. M. ; LaTourrette, J. T. ;Rarnsey, N. F. , Jr. ; Phys. Rev. 112, 1929 (1958); Radiofrequencyspectra of hydrogen deuteride in strong magneticfields.H (MB)d*140

1498 Ramadier, I. J. ; Amat, G. ; J. Phys. Radium 1^, 915 (1958)Rotational energy of linear molecules. Fourth-order corrections.Review1499 Richardson, J. M. ; J. Appl. Phys. _29, 1 37 (1958); Experimental evaluation of the oxygen microwave absorption asa possible atomic frequency standard,1500 Ring, P. J. ; O'Keefe, J. G. ; Bray, P. J, ; Phys. Rev.7 19Letters _!_, 453 (1958); Li and F nuclear magneticresonances in neutron-irradiated LiF.1501 Rosenblum, B. ; Nethercot, A. H. ; Townes, C. H,Phys. Rev. 109, 400 (1958); Isotopic mass ratios, magnetic moments and the sign of the electric dipole momentin carbon monoxide.1502 Rosenblum, B. ; Townes, C. H. ; Geschwind, S. ; Revs.Mod. Phys. 30, 409 (1958); Recent determinations ofatomic mass ratios by microwave spectroscopy.1503 Russell, A. M. ; Phys. Rev. Ill, 1558 (1958); Magneticmoments due to rotation in Li F and Li F.LiFCOH, C, O, S. Rb,CO, CS, RbClLiF1505 Sessler, A. M. ; Foley, H. M. ; Phys. Rev. 110, 995(1958); Hyperfine structure of deuterium and nucleonnucleonspin-orbit potentials.1506 Sheridan, J. ; Boll. Sci. Fac. Chim. Ind. Bologna 16, 71(1958); Recent progress in the microwave spectroscopy ofgases.Review1511 Tolbert, C. W. ; Douglas, J. H. ; Britt, C. O. ; Tech. Rept.Texas U. Electrical Engineering Research Lab. May 15, 1958Measured absorption of millimeter wavelengths by oxygen atpartial atmospheric pressure.19591529 Burrus, C. A. ; J. Cherru Phys. 30, 976 (1959); Zeemaneffect in the 1- to 3-millimeter wave region: molecular gfactors of several light molecules.HBr, CO, HI,CL1530 Burrus, C. A. ; J. Chem. Phys. 31, 1270 (1959); Starkeffect at 0.93, 1. 18, and 1. 5 millimeters wavelength; DC1,DBr, and DLHC1, HBr, HI1534 Colpa-Boonstra, J. P. ; France Centre Natl. RecherchesSci. 77, 41 (1959); Rotational spectra of pure molecularhydrogen induced by pressure.141

1547 Favero, P. G. ; Mirri, A. M. ; Gora . , W. ; Duke U. NOMicrowave Lab. (1959); Millimeter- wave rotational spectrumof NO in the 7T/ state.1558 Iddings, C. K. ; Platzman, P. M. ; Phys. Rev. 113, 192 H Z(1959); Nuclear structure correction to the hyperfine structurein hydrogen.1559 Iddings, C. K. ; Platzman, P. M. ; Phys. Rev. 115, 919 H(1959); Meson corrections to the hyperfine structure inhydrogen.1587 Maryott, A. A. ; Kryder, S. J. ; J. Chem, Phys. 31, NO617 (1959); Nonresonant microwave absorption and electric dipole moment of NO in the gaseous state.1591 Mizushima, M. ; Tech. Rept. - Colorado University, OJan. — Mar. 1959. Research studies in connection withmicrowave spectrum of the O molecule.1599 Pannetier, G. ; Guenebaut, H. ; Hajal, I. ; Bull. Soc. Chim. HNFrance 1959, 1159; Rotational analysis of the (O, O) bandof the II - S transition of the ND radical.1605 Ransil, B. J. ; J. Chem. Phys. ^30, 1 1 13 (1959); Quadrupole COcoupling constant, dipole moment, and electron populationof CO.I9601641 Cowan, M. J. ; Univ. Microfilms, Pub. No. 26Z, Disser- HI, HC1, HBr, COtation Abstracts 20, 4139 (I960); Microwave spectroscopyin the 0. 5 to 1.5 millimeter wave region: HI, DC1, DBr,DI, and CO.1654 James, T. C. ; Norris, W. G. ; Klemperer, W. ; J. Chem. LiH (IR)Phys. 32, 728 (I960); Infrared spectrum and dipole momentfunction of lithium hydride.1667 Lefebvre-Brion, H. ; Moser, C. M. ; Phys. Rev. 118, 675 NO(I960); Calculation of the magnetic hyperfine structure couplingconstants of NO.1673 Lin, C. C. ; Phys. Rev. 119, 1027 (I960); Hyperfine structure NOof the microwave spectra of the NO molecule and the nuclearquadrupole moment of nitrogen.1674 Lin, C. C. ; Hijikata, K. ; Sakamoto, M. ; Oklahoma U. NOResearch Institute (I960); Electronic structure and hyperfine structure constants of NO molecule.1682 Maryott, A. A. ; Birnbaum, G. ; J. Chem. Phys. 32, 686 O(I960); Microwave absorption in compressed oxygen.142

1684 Mizushima M. ; J. Chem. Phys. 32, 691 (1960); Theoryof microwave absorption by compressed oxygen gas.1693 Radford, H. E. ; NBS Report 7011, (1960); The microwaveZeeman effect of free hydroxyl radicals.1709 Wharton, L. ; Gold, L. P.; Klemperer, W. ; J. Chem.Phys. 33, 1255 (I960); Dipole moment of lithium hydride.°2HOLiH1713 Zimmerer, R. W. ; Rev. Sci. Instr. 31, 106 (1960); Precision Zeeman modulation microwave spectrometer.Additions to Bibliography1728 Stitch, M. L. ; Honig, A.; Townes, C. H. ; Phys. Rev.86, 607 (1952); High temperature microwave spectroscopy-"spectrum of KC1, T1C1.1731 White, R. L. ; Revs. Mod. Phys. -27, 276 (1955); Magnetichyperfine structure due to rotation in S molecules.1732 Altshuller, A. P.; J. Chem. Phys. 2_1, 2074 (1953); Dipolemoments of gaseous thallous halides.1738 Greenhow, C. ; Smith, W. V. ; J. Chem. Phys. 19, 1298(1951); Molecular quadrupole moments of N and O .1739 Burrus, C. A.; Graybeal, J. D. ; Phys. Rev. 109, 1553(1958); Stark effect at 2. 0 and 1. 2 millimeters wavelength:nitric oxide.KC1, T1C1FC1TIBr Til°2NO1741 Henry, A. F. ; Beringer, R. ; Rawson, E. B. ; Phys. Rev. NO94, 343 (1954); Microwave resonance in nitric oxide: Adoubling and hyperfine structure.1744 Van Vleck, J. H. ; Report 664 from Radiation Laboratory HO. O.MIT (March 1, 1945); Further theoretical investigations onthe atmospheric absorption of microwaves.1863 Madden, R. P.; Benedict, W. S.; J, Chem. Phys. 2,3, 408 OH (IR)(1955); Pure rotational lines of OH.1958 Zimmerer, R. W. ; Mizushima, M. ; Phys. Rev. 121, 152 O(1961); Precise measurement of the microwave absorptionfrequencies of the oxygen molecule and the velocity of light.1959 Hendrie, J. M. ; Kusch, P.; Phys. Rev. 107, 716 (1957) O1960 Bowers, K. D. ; Kamper, R. A. ; Lustig, C. D. ; Proc. ORoy. Soc. A251, 565 (1959)1961 Ehrenstein, G. ; Townes, C. H.; Stevenson, M. J. ; Phys. OHRev. Letters 3, 40 (1959)143

9900 American Institute of Physics Handbook, McGraw-Hill BookCo., Inc. (1957)9901 Herzberg, G. , Molecular spectra and molecular structure. I"Spectra of Diatomic Molecules: D. Van Nostrand Co. , Inc. ,(1947)9902 Herzberg, G. , Molecular spectra and molecular structure. II."Infrared and Raman Spectra of Polyatomic Molecules" D. VanNostrand Co. , Inc. , (1947)144

Microwave Spectral TablesThis five-volume NBS Monograph will present a comprehensive compilation of microwave spectra including measured frequencies, assigned molecularspecies, assigned quantum numbers, and molecular constants determined fromthese data. The first two volumes are now available and the other three willfollow at approximately six-month intervals.Titles of the volumesI. Diatomic MoleculesII. Line Strengths of Asymmetric RotorsIII. Hindered RotorsIV. Symmetric and Asymmetric RotorsV. Frequency Listing

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